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By Maurice C. Fuerstenau

The kinetics of leaching galena with ferric chloride and ferric nitrate have been examined as a function of ferric concentration, salt concentration, temperature and particle size. Diffusivity of ferric complex ions was also established as a function of ferric chloride concentration and temperature. In the presence of 3 M NaCl, leaching rate is controlled by product layer diffusion when ferric chloride is added as oxidant. With NaCl concentrations less than 3 mole/liter rate decreases with decreased NaCl concentration, and, thus, rate is apparently not controlled by product layer diffusion. It is suggested that rate is controlled by lead chloride solubility at the reaction interface under these conditions. When ferric nitrate is added as oxidant, leaching rate is limited by chemical reaction control. An electrochemical model is presented. Activation energies are 8.1 and 11.3 kcal/mol in the ferric chloride and ferric nitrate systems, respectively.

Jan 1, 1984

By Raymond B. Ladoo

"The talc and soapstone deposits of Vermont have been worked more or less continuously for nearly 100 years, but all of the early efforts seem to have been directed toward the production of slabs for foot warmer, and other similar uses. Altho soapstone of good quality occurs at several places, much of the material first utilized was really talc and was not massive enough to be cut successfully. The grinding of talc in Vermont seems to have commenced in about 1902 and has shown continuous growth since that time. Statistics compiled by the Geological Survey in Mineral Resources of the ,United States show that the production of talc in Vermont has increased, from 8,978 short tons valued at $65,525 in 1905 to 93,960 short tons valued at $625,150 in 1917. Until 1917, New York was the leading producer in both tonnage and value with Vermont second, but in 1917, Vermont took the lead in tonnage produced, although not in value, with a production of over 47% of the total tonnage produced in the United States and over 35% of the world's pro-duction. This increase in production will probably be continued, though possibly at decreased rate, for the reserves of talc In Vermont are large.Active talc mines and mills in Vermont are found in four districts: Chester, Windsor County; Rochester, Windsor County; Waterbury, Washington County; and Johnson, Lamoille County, These mines and mills are distributed as shown in the following table:While there are a great many other known deposits of talc and soapstone in Vermont, some of which have been worked, those listed above are the only ones which have survived and are producing on a commercial basis. The closing down of many mines and quarries, for example, those at Perkinsville, Stockbridge, Reading, Cavendish, and Athens, has been attributed to several causes. Of these causes the most important seem to be exhaustion of the deposit, poor grade, long haul to the railroad, poor management due to lack of knowledge of mining methods and failure to consider talc mining strictly as a business proposition. The companies which are now operating with greatest apparent success are those which have realized the present and future possibilities of their industry, and have invested sufficient capital in both equipment and personnel to establish their companies on a firm business basis."

Sep 1, 1919

By Sheridan J. Rodgers

Toxic fumes generated during shot firing were measured in a phosphate rock mine and a copper mine. Fumes generated during firing of explosives in the Bureau of Mines 1350 ft3 test chamber were measured also. The release of fumes from water gels, ammonium-nitrate oil mixtures and nitroglycerin based explosives was studied. Direct reading instruments were used to monitor the fume concentrations. The amount of CO produced per unit weight of nitroglycerin explosives (0.41 ft3/200 grams) was higher than that produced by ammoniumnitrate-oil mixtures (0.24 ft3/200 grams) and water gels (0.16 ft3/200 grams). The amount of NOx produced by nitroglycerin based explosives was also higher than the amount produced by water gels or ammonium nitrate-oil mixtures.

Jan 1, 1976

By Thomas J. Peters

The Goat Rocks RARE II further planning areas contain no known mineral resources and have very low mineral potentials. County mining records show only one mining claim area; however, no mineralized material was found at the described location. Andesite suitable for building stone may be present, but similar material can be quarried more economically elsewhere. Several anthracite coal prospects are near the area, but the likelihood of finding an economic deposit of coal or other fuel is very low.

Jan 1, 1981

By Elton L. Litchfield, Milton L. Weiss

Studies were made on the projectile impact sensitivity of explosives by subjecting explosive samples to the impact of metal projectiles fired from a 0.50- caliber gun . The projectiles , in the form of right cylinders , made plane surface to plane surface contact with the explosives . Pressures in the explosive were investigated with an expendable pressure transducer in some instances . The physical model of the projectile - explosive interaction describes , in principle , the duration of the peak shock pressure in terms of the projectile and explosive geometry and the steady- state penetration of the explosive . Of the explosives studied , liquid hydrogen- solid oxygen and liquid oxygen - solid or liquid hydrocarbon fuel were the most shock sensitive ( requiring an initiating shock of about 1.0 kb or 987 atmospheres pressure ) ; cast TNT was the least sensitive ( requiring an initiating shock of more than 110 kb pressure ) . Measurements of pressure in the explosive showed some moderate space resolution by the transducer and gave pressure distributions in agreement with expectations from the model of the shock processes . The appearance of the recovered projectiles and the calculated initiation shock pressures suggest that the solid explosives were initiated directly to high- order detonation , whereas the liquid explosives were probably initiated to low- order detonation-- with a subsequent , later transition to high- order detonation .

Jan 1, 1965

By J. P. Morris

"INTRODUCTION In the investigation being conducted by the Bureau of Mines concerning the production and utilization of sponge iron, it soon became evident that more information was needed regarding methods for determining the degree of reduction attained in the manufacturing process. Sponge irons made by different processes vary in physical characteristics and chemical composition, and a method of analysis that is suitable for one type is not necessarily applicable to all others. For example, the hydrogen-evolution method, which measures the volume of hydrogen evolved upon treating the sample with acid, accurately determines the oxygen content of some types of sponge iron. However, when the sponge iron contains combined carbon, hydrocarbon gases are also-evolved and large errors may result. Probably no single method will give accurate results in all instances, and for this reason it is desirable to have several reliable procedures available and to know the limitations of each.For measuring the degree of reduction, determination of either metallic iron or oxygen should suffice, although for practical application of sponge iron to the production of steel the oxygen content is more significant. After consideration of proposed methods of analysis in regard to their suitability for routine use and the probable influence of other substances, four procedures were chosen for investigation:(1) Mercuric chloride method.(2) Copper sulfate method.(3) Hydrogen-reduction method.(4) Hydrogen-evolution methods."

Sep 1, 1945

Continuously monitor and record respirable dust levels underground by a reliable, sensitive, and fast-response device. Approach A light-scattering photometer, having a LED (Light Emitting Diode) light source and other significant improvements, has been designed and incorporated into a portable continuous monitor. How It Works The monitor continuously draws air into the sampling inlet through a cyclone that removes dust particles larger than respirable size. The dusty air enters the photometer vertically downward through a cylinder which is intersected by the optical system. (This cylinder appears as a circle in the drawing of the photometer.) The center of he column of dusty air intersects a beam of pulsing light from the LED, causing some of the light to be reflected, scattered, and refracted. Only the light that is scattered at an angle of about 700 from the light beam passes through a lens to the photodetector which generates an output voltage Signal proportional to the dust content in the air. This signal is detected, amplified, and converted to a digital readout directly in milligrams of dust per

Jan 1, 1979

By Paul S. Goodman

This report examines the feasibility of Employee Assistance Plans for the coal industry. Three issues are examined in detail. First, the prevalence of off-the-job factors such as alcoholism, drug abuse, and marital problems are examined in a sample of miners from the eastern, midwestern, and western underground coal fields. Then data were presented that examined the link between these off-the-job factors and behaviors critical to the mines such as absenteeism and turnover. Lastly, we examined the effectiveness of the major Employee Assistance Program in underground coal mining--the HELP Program. The report contains recommendations on whether coal mining companies should implement these programs and how these programs should be designed.

Jan 1, 1986

By Gilbert L. Forst

The objective of this program is to identify and evaluate superior, lightweight substitutes for selected coal mine roof support concepts such as crossbars, posts, and crib blocks. Engineering analysis and concept design identified, through tradeoff studies, that some materials are promising, from a technical standpoint, as support substitutes: E-glass reinforced polyester resin, high strength low alloy steel, aluminum, and very high early strength (VHE) cement. An economic analysis indicates that none of the lightweight substitutes are economically competitive with wood on an initial cost basis; however, in terms of life cycle costs based on current dollars, the high strength low alloy steel appears competitive for crossbars, and the VHE cement and E-glass/resin appear competitive for posts.

Jan 1, 1978

By Foster Fraas

Almost all minerals show irreversible changes in electrical conductivity after heating in the temperature range 100° to 800° C. This effect can be detected with only a limited number of minerals with the standard ionizing-electrode-type separator, which differentiates between nonconductors and conductors in the single-particle resistivity range of 1011 to 1013 ohms. Tests outside this range with other type separators, such as the static field type, increase the number of minerals with which the effect can be detected to almost all that were tested. Irreversibility may be the result of an alteration of adsorption layers, volatilization of surface cations or anions, or an oxidation or reduction. One example is limonite, which decomposes to hematite and passes through two minima and two maxima in conductivity in the temperature range 100° to 900° C.

Jan 1, 1959

By Mark P. Zaitsoff

The project involved design, construction, and testing of hydraulic models of culverts, decant and open channel spillways which are typical drainage structures used for protecting mine waste embankments. MSHA (The Mine Safety and Health Administration, U. S. Department of Labor) made a motion picture of the tests. Tests results and products in the forms of graphs, tables and films, demonstrate the principles and factors which govern the function and performance of the three types of drainage structures.

Jan 1, 1981

By Henry Kreisinger

Some of the investigations conducted by the Bureau of Mines have for their object the collecting and disseminating of information regarding methods by which the fuels of the country may be most efficiently used. As the analysis of flue gases tends to develop better methods of firing, which in turn reduces waste of fuel, the Bureau of Mines in this bulletin presents for the benefit of those in charge of boiler plants and all other persons interested detailed information on methods of sampling and analyzing flue gases, and on the utilization of the analyses in promoting boiler-room economy. This bulletin is intended to be a companion to Technical Paper 80,a and is written in plain and nontechnical language, as far as possible, so that it may be readily understood by persons who have not had the advantage of a technical education. Whenever possible, illustrations of apparatus and methods of handling have been used rather than elaborate descriptions.

Jan 1, 1915

By Donald R. Alvic

For electric utilities serving the aluminum smelter industry in the United States, sulfur oxide (SOx) abatement legislation could bring about increases in the costs of generating electricity. This paper documents the method and assumptions used in estimating these increases, and the contains the results of the estimation. 1.2 SMELTER INFORMATION The smelters used in this study were identified by the Bureau of Mines (BOM) and are listed in Table 1.1. Also included in Table 1.1 are the electric utilities that serve these smelters. Compliance costs were estimated for these utilities. Some of the utilities are unique in the way that the information is handled or in the way the utility is operated; these are discussed below. 1.2.1 Big Rivers and Associated Co-ops, Data for Big Rivers and Associated Co-ops were gathered by George Mason University (GMU) students for BON and are included in this study.

Jan 1, 1988

By F. K. McIntosh, L. A. Dahmers

"INTRODUCTION North Carolina has been the leading producer of mica in the United States, accounting for roughly 50 percent of the Nation's output. The producing area is a belt some 100 miles in width lying in the Mountain and Piedmont sections in the western part of the State. Ashe, Watauga, Avery, Mitchell, Yancey, Buncombe, Haywood, Jackson, Macon, Transylvania, Rutherford, Cleveland, and Lincoln Counties supply the bulk of production, while small amounts have been produced in Gaston, Catawba, Burke, Wilkes, Yadkin, Stokes, and Person Counties.To assist the operators and expedite the production of mica during the recent emergency, the Bureau of Mines drilled four of the more promising mica properties in this State. The results of this exploratory program are recorded in this report.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Division, L. B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyzes samples and makes beneficiation tests."

Apr 1, 1948

The mine surveillance and communication system hereafter described provides continuous local and remote monitoring of several parameters critical to normal mine operation at each of ten underground sites in the Bruceton Research Mine. The techniques employed are well proven and have been care-fully chosen to provide the best solution to the technical problems involved while giving special attention to economic considerations.

Jan 1, 1973

By F. B. TOUCH

This bulletin deals with a topic that is exceedingly wide, and will doubtl~ be under consideration and discussion so long as there are enough known deposits of oil and gas remaining in the earth to make their revelopment profitable. The Bureau of Mines has repeatedly called attention to the importance of protecting oil or gas sands from the encroachment of water, and the purpose of this paper is to summarize existing knowledge of methods and devices. Water may gain access to an oil-bearing formation from several sources-from water sands above or below those. containing the oil, or by encroaching through the oil sands as the oil is withdrawn. In short, it may enter a well from the "top, bottom, or side." Such ingress of water is a most serious detriment to the recovery of oil from the ground. As the art of drilling and developing oil properties has progressed, increasing thought, labor, and money have been expended on various methods, devices, and equipment for arresting the migration of water from its normal subsurface position into the porous strata containing valuable oil or gas accumulations. At an early stage in the oil-field development of California, it became evident that considerable modification of accepted drilling practices was necessary in order to meet the conditions imposed by the poorly consolidated shale, clay, sand, and bowlder beds penetrated, as well as the hard layers of sandstone and calcareous shale, which vary greatly in thickness, hardness, and frequency. These hard streaks are commonly called " shell," and are so reported in the well logs. As deeper and deeper territory was prospected, drillers from the older fields of the Ea,st, as well as from Texas and Louisiana fields, took part in the operations. Xhe practice evolved was thus based on the wide experience of a most cosmopolitan group of men who, considered as a group, were not hampered by being limited to the knowledge of the practice at any one locality.

Jan 1, 1918

By Martin Hertzberg

The early and reliable detection of the self-heating of combustible substances in mines is of considerable importance to the mining community. This Bureau of Mines report describes the results of a variety of studies of incipient combustion and its detection. Heated samples of coal, wood, and various polymers were used to evaluate the relative sensitivities of several types of detectors. The laboratory results indicate that submicrometer particulate detection is the most universal and sensitive method. Carbon monoxide detection was as sensitive as submicrometer particulate detection for pyrolyzing coal but was relatively insensitive to pyrolyzing wood or plastics. The conventional type of ionization smoke detector was the least sensitive for coal and of intermediate sensitivity for wood and plastics. Self-heating experiments with Pittsburgh seam coal piles of varying particle sizes gave ignition temperatures of 170° C for 4-to 7-µm dust, which increased monotonically with particle size. The measured heating rates were compared with data from an adiabatic calorimeter to obtain preexponential rate constants. The preexponential rate constants varied linearly with the surface area per unit mass of sample as would be expected for heterogeneous surface oxidation. The propagation behavior of ignition waves and the overall self-heating appears to depend critically on the magnitude of the convective flows induced, which counteract the depletion of oxygen in the void spaces of the pile. Classical theories of thermal ignition require substantial modification to be applied reliably to such cases.

Jan 1, 1977

By S. Raghavan

An investigation of the possibility of improving the grinding characteristics of a gabbro ore containing copper and nickel sulfides via a thermal shock treatment technique has been carried out. The results obtained indicate that the breakage characteristics of the gabbro are particles can be significantly improved by preheating the are particles to a temperature around 400°C followed by rapid water quenching. For a given power input and feed size, the thermally treated material produces a product of much finer distribution than the untreated material. An assessment of the improvement in grindability has been made by calculating feed size selection functions for untreated and heat-treated materials.

Jan 1, 1981

By J. B. Cheung

The results of a program to demonstrate the technical feasibility of hydraulic borehole coal mining are presented in this report. The hydraulic borehole method of coal mining involves inserting a hydraulic mining device into a borehole that has been drilled from the surface into the underground coal bed. The borehole mining device issues a jet of water under high pressure, which breaks the coal. These pieces of coal, along with the water, form a slurry, which flows to the base of the borehole where it is pumped to the -surface. Phase I of the program encompassed the design, fabrication and factory-testing of a hydraulic borehole mining device. The program was successfully completed with the field tests being conducted at the Wilkeson-Carbonado Coal Field near Wilkeson, Washington. The technical feasibility of hydraulic borehole coal mining was demonstrated by mining 32 tons of coal at a depth of about 75 ft over a period of 4 hours.

Jan 1, 1976

By Terrence J. Stobbe

The authors investigated the nature, cause and treatment of 234 back injuries which occurred in 156 different situations in underground coal mines. A detailed interview was conducted with each injured miner as 137 variables were explored to provide a complete picture of the injury scenario. The miners worked at 23 mines in six states. An important finding of the study was that sudden movement, which occurred in 527 of the injuries, is a more frequent factor than heavy lifting in causing hack injuries. Along with sudden movement, other major injury causing factors were equipment seat design, lifting, cable handling, and slips/trips. No significant differences were found between the injury scenarios associated with lost time and non-lost time injuries; thus, both sets of scenarios should he used in doe loping back injury control strategies. Medical treatment and rehabilitation varied in content and quality. Dialogue between the medical, rehabilitation and mining communities is needed to develop an effective treatment strategy. Back injury control related training was found to be inadequate in most mines. Mine specific training for physical stress recognition and potential sudden torte release should he added to the training currently given. Based on the information collected in this study, recommendations were made regarding equipment design, mechanical assists and procedures for material handling, training, etc., which, if implemented, will assist in reducing the frequency of back injuries in underground coal mining.

Jan 1, 1989