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By Nina Panteleeva, Elena Afonina, Stanislav Titkov, Jury Buksha

"Flotation processing of water-soluble minerals (potassium ores, sedimentary salts of salt lakes) is currently the main method for production of potassium fertilizers and concentrated carnallite which is the initial product for production of metallic magnesium. Flotation of sylvite (KCl) and halite (NaCl) is carried out in the electrolyte solutions: KCl-NaCl-H2O and KCl-NaCl-MgCl2-H2O. The report presents the results of studies of the effect of concentration and the electrolyte type on the size of air bubbles in a flotation cell in comparison with the floatability of mineral constituents of potash ores. The floatability in electrolytes of various compositions has been studied: - of sylvite (KCl) by alkylamines, - of halite (NaCl) by alkylmorpholines, - of silicate-carbonate slimes contained in the ore by ethoxylated surfactants. The reagent modes (regimes) activating the flotation desliming of potash ores have been developed."

Jan 1, 2014

By D. Whittles, S. Kingman, S. Bradshaw, N. Miles

The influence of microwave energy at high electric field strength on ore strength has been investigated. Two ores of varying mineralogy were treated in both multimode and single mode microwave cavities. After treatment, any change in strength relative to untreated ore was established. It was shown that in the multimode cavity reduction in strength was related to the applied power level. Results of tests carried out in the single mode cavities showed that, for both ores, reductions in ore strength > 50% could be achieved in very short periods (<1 second). Thermal stress analysis showed that the mechanism of microwave induced failure was the development of tangential stresses at the grain boundaries. It was concluded that operation at 915 MHz with high power and short residence times gives feasible scale-up possibilities.

Jan 1, 2003

By Ronel du Plessis, John C. Davidtz, Jan D. Miller

Recent results from electrochemical measurements demonstrate that trithiocarbonate (TTC) collectors are more readily oxidized to their corresponding dithiolates than the dithiocarbonate/xanthate (DTC) collectors. Based on the traditional analysis of collector adsorption, trithiocarbonates might then be expected to be effective for bulk sulfide mineral flotation. Previous bench-scale flotation research had shown that TTC collectors are very effective for the flotation of copper sulfide minerals and PGM (platinum group metal) sulfide minerals. More recently, the TTC collectors were evaluated for auriferous pyrite recovery in benchscale plant scale flotation testing in the United States and in plant tests at Anglogold in South Africa. TTC collectors were also applied in bench-scale testing of a PGM ore. In each case an improved separation efficiency was realized. Fundamental studies at the University of Utah examining the effect of collector structure (functional group, -O-CS2 versus .S-CS2), specifically with respect to auriferous pyrite flotation, are in progress. The effect of collector structure was evaluated with air as well as nitrogen as the flotation gas medium. Experimental techniques utilized included electrochemically controlled contact angle measurements to evaluate mineral hydrophobicity and infrared spectroscopy to explain collector adsorption phenomena at the mineral surface.

Jan 1, 2003

By Z. H. Zhang

Shizhuyuan is a world-class WO3, Mo, Bi and CaF2 poly-metallic deposit; it has rich reservation, but great difficulty in ore?s processing; thereby, for many years, it has been the target problem of beneficiation technologies. This paper, while briefly reviews its main scientific and technological advancement, pays special attention to the complete set of new technology and technical index achieved in recent years, which is characterized by using full-floatation flow-sheet as the backbone flow-sheet, explores some key factors influencing tungsten floatation, and presents a brief introduction to such new equipment as flotation column and comprehensive utilization of fluorite.

Jan 1, 2014

By Axel Pankewitz, Andrew Smith, Mathias Stender, Christian Behrens

"Particle size measurement is one of the most important factors in obtaining peak performance of the mineral processing plant in order to ensure efficient milling and flotation circuit operation. Off-line particle distribution analysis technologies only allow an infrequent check of the ore slurry size and hence do not allow for timely process monitoring or intervention. Most existing on-line particle size analysers suffer from a variety of disabilities such as poor statistics, non-representative sampling or mechanically complex setup. This paper will describe an Ultrasonic Extinction based method which overcomes many limitations of existing online analysers and has proven its performance for mineral applications over many years. Installation examples will be given. Since new technologies usually raise e questions about comparability and agreement to common particle size analytical methods e.g. sieving or laser diffraction analysis, extensive studies were performed comparing these different technologies to quantify the quality of results as well as its mathematical robustness."

Jan 1, 2014

By Sumantra Bhattacharya

The per capita energy consumption in India is 510kgoe/year, the global average being nearly 1818kgoe/year. Correspondingly low is the per capita CO2 emission at 1.25t against the world average of 4.39t.65-70%, at times more, of India?s power generation from about 190,000 MW installed capacity, is however coal fired.India therefore has to secure diversified sources of energy and solar power is increasingly being looked as the real alternative to the existing over dependence on coal. To ensure sustainable solar power it is essential to secure its raw material base that is ?silica?, hitherto considered as ?minor minerals?. That calls for immediately addressing the issues of land availability, solar power cost, developing a dynamic inventory of silica containing minerals, appropriate processing technology and strong regulatory framework for sustainable mining and processing of all silica rich minerals. Keywords: silica, silicon, Thar, power generation, India, quartz, solar power

Sep 1, 2012

By S. Saha

Minerals in coals cause operational problems in various coal utilization technology as well as act as diluents towards its heat value. Indian coals contain higher percentage of mineral matter compared to foreign coals due to its formation through drift origin. Efficient utilization of high ash coal in environment friendly manner is the driving force for the development of clean coal technology. Coal gasification offers practical means meeting stringent environment controlled parameters for producing power, chemicals, liquid fuels and clean energy on a single platform. It is well accepted that gasification technology has sufficient potential for sustainable development of clean coal technology. Gasification reactivity depends on the coal properties and operational parameters as well as minerals present in coal. Minerals not only create operational problems but on the other side also catalyze the gasification and combustion reaction. Therefore to understand the effect of minerals on the gasification reactivity, present paper proposes to study the variation of gasification reactivity with various gravity cuts such as, 1.4-1.5; 1.6-1.7; and 1.8-1.9 of a selected coal. Gasification reactivity has been studied by thermo gravimetric analyzer (TGA) using CO2 as gasifying agent. Surface properties such as, true density, apparent density, porosity, surface area of different gravity cut samples have also been measured to find out the effect of gravity separation on gasification reactivity. Keywords: gasification, reactivity, mineral matter, gravity separation

Sep 1, 2012

By J. A. Sweet

The issues facing graduate training in the mineral processing industry are not too different today from those that prompted the initiation of the Anglo American Platinum Graduate Development Programme (AGDP) in 2002. Graduate metallurgists in South Africa enter the industry from different undergraduate programmes at various tertiary institutions, and so the knowledge and skills of the young graduates varies. Further, the geographical expansion of the industry combined with the downsizing of business units means that there are fewer opportunities for young graduates to be mentored through their first few years on site. Anglo American Platinum chose to address these issues by implementing an intensive, structured graduate training programme for all their new metallurgical graduates, known as the AGDP. The first two years of experience of the AGDP, from the viewpoints of both graduates and lecturers, were presented to the mineral processing community at the IMPC in Turkey in 2006 (Sweet et al, 2006). From the beginning, the programme was structured in a modular fashion to include a basic technical ?toolbox? including statistics, the scientific method and sampling protocols, while the mineral processing content comprised advanced learning in comminution, classification and flotation (later extended to include hydrometallurgy). Technical communication ? both written and verbal ? was included from the start. The programme was focussed very strongly on site work (?learning by doing?), with a major integrated site campaign conducted and analysed by each cohort. In 2012 the AGDP will accept its ninth cohort into the programme. This paper describes how Anglo American Platinum and the University of Cape Town have developed and adapted the programme over the last few years, in response to the challenges of the global recession, skills retention, and the changing operational needs of the company. The programme, which was drawn up to accommodate around 15 concentrator-only graduates, now accommodates 35-40 concentrator, smelter and refinery graduates annually. The programme has also been modified to facilitate new graduates spending most of their first year on the operations. The benefits of the programme for Anglo American Platinum have been tangible, and will be discussed in the paper. Keywords: graduate training, technology transfer

Sep 1, 2012

By M. C. Harris

"In the flotation process the contact angle is an important indicator of the hydrophobicity of a mineral particle. There is considerable literature showing that the contact angle increases when the chain length of the alkyl group associated with the collector molecule used to render the valuable mineral particle hydrophobic increases. The extent to which an alkyl group interacts with surrounding water molecules is quantified thermodynamically by the excess Gibbs energy. In the present paper it is shown that there exists generally a strong linear relationship between the excess Gibbs energy of the alkyl group associated with the collector and the contact angle. The structure-activity of such alkyl groups is in turn related to the total surface area, molecular volume, the molar volume, molecular weight of the functional groups in the molecule and interaction energies. It is proposed that the demonstrated relationship is indicative of the role which the alkyl group component of the collector, which is attached to the mineral particle, plays in increasing the extent to which water molecules at the surface of the mineral are rejected from the surface thus increasing the contact angle. The relationship between excess Gibbs energy and surface tension is further explored with a view to relating the observations quantitatively to the parameters in the Young equation.INTRODUCTIONThe issue of wettability of materials is of great importance to many industrial applications. Wettability studies usually involve the measurement of contact angles which indicate the degree of wetting when a solid and liquid interact. As is well known the contact angle (O) is the angle between planes tangent to the surfaces of the solid and the liquid at the wetting perimeter which is the zone where the air, water and solid phase merge. When the air bubble attaches to the solid surface there is an increase in the air/solid interface area and a decrease in the solid/water interface area. For attachment to occur the cosine of the contact angle should be less than 1 and this will be promoted if the interfacial surface tension between the air and the solid (? SV) is low. Classically the relationship between these parameters has been expressed through the Young equation (1) for a perfectly flat surface:"

Jan 1, 2018

By J. Lindström, J. Hamuyuni, M. Lundström, J. Aromaa

"The rising demand for metals today, coupled with the scarcity of primary sources for raw materials threatens both technological advancements and industrial manufacturing. In order to meet the demand, metals and other resources trapped in waste streams, have to be harnessed. This philosophy supports circular economy, where metals and other resources are kept in a closed loop. The pickling acid recovery system of most stainless steel production is one such example where the dissolved metals such as iron, nickel and chromium are currently not completely recovered due to the limitations of the current technologies. The aim of this study was to assess the available metals recovery methods from extremely concentrated acids. The main aim is to simultaneously recover metals and keep sulphuric acid reusable in acid circulation process. From the available literature, the most promising methods were chosen for laboratory experiments. Based on experimental work, the results and observations of electrodeposition, solvent extraction, and freeze crystallization are provided. KEYWORDS Pickling acid, metal recovery, solvent extraction, cathodic polarization, Freeze crystallization. INTRODUCTION Pickling in stainless steel production is an essential surface treatment process (Regel-Rosocka, M. (2010); Agrawal and Sahu, 2009). It is applied for removing surface films such as oxides and chromium-depleted layers to improve the corrosion resistance and surface finish of steel (Regel-Rosocka, 2010). Whilst the process greatly improves the surface finish of the stainless steel, it generates large amount of used acid, containing dissolved metals including chromium, iron, and nickel (Agrawal and Sahu, 2009). Recovery of acid is common practice for most steel producing industries (Nyman and Koivunen, 1986). In this work, acid regeneration process is investigated so as to simultaneously reusing sulfuric acid and recovering the dissolved metals. Recovery of valuable metals even in very small amounts would also bring additional revenue to the steel production industry. At a time when metal production has also been challenged by lack of natural resources for raw materials, secondary sources for metals such as the acid pickling process therefore, have greater potential as supplements. From earlier studies, electrodeposition (Giovanardi and Orlando, 2011; Kuznetsov et al., 200; Rögener et al., 2012; Surviliene et al., 2006), solvent extraction (Alguacil and López 1996; Haghshenas et al., 2009; Kesieme et al., 2013) and freeze crystallization (Beyer et al.,2003; Hasan et al.,2017; Van der Ham et al., 1999) are some of the most established potential methods. Earlier studies have also shown that simultaneous recovery of acid and metals would require combination of different methods. This is primarily due to the nature of very stable metal containing complex compounds formed during pickling. These complexes must be broken down to free the metals for further recovery processes."

Jan 1, 2018

By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018

By M. Bergerman

Sossego was the first Vale SAG mill operation to process copper-gold ore. It is located in Para state, south east of Amazon region in Brazil. The comminution circuit was designed to treat 41 000 metric tons per day comprising primary crushing, one 11.6 m SAG mill operating in closed configuration with cone crushers, followed by two 6.7 ball mills. In the first three years of continuous operation Vale investigated alternatives for obtained improved performance of the circuit by investigating operating conditions, mainly focusing on SAG mill. A number of actions were then implemented, which resulted in significant increase in overall production. Vale then decided to further assess the performance of the comminution circuit as a function of ore characteristics. A comprehensive ore characterization program was then conducted, together with the calibration of mathematical models on the basis of surveys carried out at the industrial circuit. The simulator was then used to predict the production level associated to each ore type, as well as to establish the optimized circuit configuration and tailored operating conditions. The ongoing validation program is planned to consolidate the selected strategy, as well as showing the benefits in adopting such indices in mine planning, as opposed to rather simplistic approaches. This paper describes in detail the main aspects of optimizing the industrial circuit performance, as well as the successful method for predicting the production as a function of ore characteristics.

Jan 1, 2014

By L. S. Zhou

HermesTM metal magnetic liner (MML) has been invented and manufactured by China Metallurgy and Mining General Co. (CMMC). This paper describes its mechanism, structure, magnetic field distribution, application, economic benefit and safety performance. The 10 years? service life in Benxi Steel?s Waitoushan Mine, along with 6 years? technological analysis on its application in 5500mm×8800mm (diameter × length) ball mill in Anshan Steel?s Diaojuntai mineral processing plant, has proved its advantages such as super reliability, long service life, light weight, thin thickness, low noise and short payback period. It has also demonstrated its positive effects on the grinding process such as high productivity, energy-effective performance and low consumption of grinding media. It reduces labour intensity and improves working conditions, due to its easy installation, free maintenance and the fact that it doesn?t require fastening bolts or cause slurry leakage. It is de-signed scientifically in accordance with the varieties of processing lines, mill specification, ore type and grinding media, and has been applied in different grinding processes for magnetite, hematite, gold ores, nonferrous ores and other materials. HermesTM MML has three types of products: General, Composite and Heavy-duty. They are designed to meet the requirements from customers in China and abroad. So far, more than 400 sets of MML have been applied in ball mills with diameter rang-ing from 1500mm to 5500mm. It has become highly popular in American market recently due to its safe and effective performance.

Jan 1, 2014

By U. A. Peuker

"Steam Pressure Filtration (SPF) is a modified cake filtration process and is characterized by both washing and excellent de-watering of the filter cake. Compared to conventional gas differential pressure filtration, the filter cake is treated with saturated or superheated steam replacing pressurized air. Invented in the early last century, Steam Pressure Filtration has reached technical maturity in the 1990ies for inorganic particle systems, fine chemicals and coal. Especially the de-watering performance for fine particles systems below 50 µm make Steam Pressure Filtration an excellent option for the processing of fine tailings streams, to produce a stable material, which can be described by the methods of solids mechanics instead of paste rheology. The washing, which is due to the condensing steam, is able to reduce the ion load of the solid. This additional effect is able to generate a dry tailings material, which shows a reduced leaching potential of mobile ions, which originally derive from the process water. INTRODUCTION Steam Pressure Filtration is a process concept especially of hyperbaric filtration, which started its market entry in the 1990ies (Bott 1996, Bott 2002). Even though there have been many attempts to apply steam on filters before, the success story began with the combination of hyperbaric filtration and steam application and the technical solution to limit the steam treatment to a defined zone on the filter. This resulted from the scientific findings that steam mainly enhances the de-watering during the mechanical filtration (Gerl 1999). There are no or minor positive effects of steam application to a filtration process during cake filtration and after the steam breakthrough has occurred. Furthermore that time a sufficient control technology to regulate the steam consumption as well as suitable filter cloths became available. There is a growing need for de-watering technology in the mining industry, not only for the concentrate but also for the tailings streams. Several reasons argue against the established solution of damping the tails as suspension or paste into tailings ponds. There are ecological, political, societal and economic reasons, which question the tailings ponds more and more. Due to the increasing costs in the building and monitoring of tailings dams, which contain the tailing ponds, the concept of dry stocking using filtration technology comes into the game (Jansson 2016). Dry stocking converts the tailings stream form the suspension or paste state, into a material, which can be stockpiled. The latter typically is a moist flowable disperse particle system. The conversion involves a de-watering step, in which different types of filter equipment can be used, e.g. filter presses, membrane filter presses, automatic press filters or hyperbaric filters. For coarse products also vacuum filter can be applied. Due to its excellent de-watering performance and the easy scale-up properties Steam Pressure Filtration is further option for dry tailings stacking."

Jan 1, 2018

By X. P. Guo

In this paper the test results of flotation of the kyanite ore from a Chinese mine are described. The objective of this work is to determine effective recovery process to obtain kyanite concentrate with high quality and high recovery for a new concentrator design. The valuable minerals of the ore are kyanite, garnet and magnetite, contents of them are 14.0%, 5.9% and 1.2%, respectively. The gangue minerals are mainly biotite, feldspar and quartz, contents of them are 33.8%, 17.8% and 25.6%, respectively. The kyanite in the ore contains a little iron. In laboratory flotation tests the factors affecting the flotation such as slime, alkalinity of pulp, and flowsheet configuration are studied. The interference of biotite on kyanite flotation as well as selective flotation of garnet is examined. On the basis of above-mentioned results the flowsheet of ore treatment comprising de-sliming, mica flotation, low intensity magnetic separation of magnetite, high intensity magnetic separation of garnet and coarse biotite as well as flotation of kyanite is pre-sented for comprehensive recovery of kyanite, garnet and magnetite. The kyanite concentrate con-taining more than 59% Al2O3 is obtained with a kyanite recovery of 70.0%. The contents of Fe2O3and biotite in kyanite concentrate decreased from 2.02% and 5% to 1.30% and 1%, respectively. The disadvantage of low kyanite grade in raw ore is compensated by accessory recovery of garnet and magnetite in the ore.

Jan 1, 2014

By Katarina Theander, Robert J. Pugh

The generation of froth with a critical degree of stability and height is an important aspect of the froth flotation. In this paper we have studied the synergism and anti-synergism in frothing behaviour in a mixed flotation collector/frother mixture (a model fatty acid; sodium oleate and a model frother; nonionic (polyethyleneoxide alkyl C14E6). Values of the collector / frother molecular interaction parameters (the ß-parameters) were determined from the surface tension data using regular solution theory. The frothing characteristics of the system were evaluated using a glass column equipped with a series of conductivity electrodes, which enabled the water content of the froth to be determined. From these measurements, the dynamic frothability and static froth stability were determined. It was concluded that the synergism/anti-synergism in frothability was depended on the molecular composition of the surfactant system, the diffusion of monomer to the thin film interface and on the breakdown of the mixed nonionic/anionic micelles.

Jan 1, 2003

By N. S. Voiloshnikova

Large-scale continuous ?Resin-In-Pulp? process tests were conducted at Irgiredmet. The object for testing was the sample of oxidized gold ore from one of Siberian deposit. Weak-base ion ex-change resin PuroGold was used as adsorbent. The duration of ?Resin-In-Pulp? tests was sufficient for a completing of three cycles ?Adsorption/Elution?. Gold in feed was 0.95 mg/L. Gold in solid phase of adsorption tails? 0.065 g/t. Gold in liquid phase of adsorption tails? 0.026 mg/L. Total gold in adsorption tails ?0.11 g/t. Gold recovery ?94.3 %. The use of regenerated resin had practically no effect on gold losses with adsorption tails. Alkaline cyanide solution (NaCN-20g/L, NaOH- 5g/L) was used as eluent for gold elution from loaded resin. Elution temperature ?60 °C. Number of eluent bed volumes passed ?10. Loaded resin analysis was following (g/ton): Au? 1700~1250; Ag? 400~460; Cu? 250~450; Zn? 5100~9600; Fe? 860~1200. Elution efficiency: Au? 95.3%~97.8%; Ag? 84.0%~88.0%; Cu? 84.0%~88.0%; Zn? 97.0%~99.0%. Although high zinc resin loading was shown zinc was eluted efficiently. The adsorption properties of fresh PuroGold resin, PuroGold resin after 3 cycle ?Adsorp-tion-Elution?cycles in comparison with AM-2B resin were tested. It was shown from adsorption isotherms that selectivity of PuroGold resin slightly less in comparison with AM-2B resin mainly due to its higher zinc adsorption properties. It was founded on base of test results that adsorption properties of PuroGold resin was practically constant during three ?Adsorption/Elution? cycles. Gold may be efficiently recovered by resin tested. There were no difficulties during gold elution from loaded resin and its regeneration. PuroGold resin was recommended for industrial use in RIP process. Process design criteria were developed and plant design is on progress at the moment.

Jan 1, 2014

By Rob Morrison, Andrew Scott

"Long before a modern mine commences operations it has already become a wealth of information. After start up, it can generate enormous quantities of data - especially with semi-automated data acquisition by instrumented mine equipment.However, much of this data is of limited use for evaluation of (potential) performance unless it links in some way to the site business model.An underlying reason for this waste of data is that the different cultures, financial, technical, community, environmental, etc, not only have many areas of interest but also have very different conceptual models by which they evaluate performance.It is too ambitious to attempt to bring all of these cultures together - in a single step.However, the success of the Mine to Mill - project has demonstrated that substantial operational value can be added by using a more integrated approach to comminution. The next logical step is to integrate measurement and then to track performance from ore body model to saleable product and waste disposal. From resource to product also represents a path from very sparse, highly variable data to much more detailed measurement and more representative sampling.However, in both cases the data collected is strongly focused on the technical requirements - not on the business model.This paper considers how to define at least some of the key decision points in terms of some case studies.Performance data from many areas might be used to derive simple models which can then be used for forecasting and optimisation of planning."

Jan 1, 2003

By Y. P. Huang

Experiment results and operation practice on reutilizing old tailings dumped at SCIM (Shang-chang Iron Mine) of KISCO (Kunming Iron and Steel Corp.) are presented. In a production period over 30 years SCIM dumped about 8 million tons of iron ore tailings. For improving resources utilization instead of wasting, experiments on processing for reutilization of the old tailings are con-ducted. These tailings are fine size fractions of weathered iluvial ores rejected out by classification- des-liming in ore washing and dressing processes, containing TFe 21%~22% in hematite mainly and limonite occasionally. Their particle size distribution, in average, is of 72.26% minus 0.037mm and 30.88% minus 0.005mm. Existence of plenty of micro-fine particles makes the tailings refractory to process, resulting in poor metallurgy. The whole sample of the old tailings without size-classification is fed into experimental process. Slon-100 type high grads WHIMS (wet high intensity magnetic separator) with cyc-pulsing is adopted, which magnetism-focusing rod?s diameter is changed from 3mm into 2mm. Operational conditions of optimizing rougher separation tests are strengthened. An iron concentrate assaying 52.21% Fe at quantity rate of 18.39% and iron recovery of 44.40% is obtained. Operational practice shows that metallurgy and economy of the old tailings treatment are close to what achieved at experiments. It is estimated, therefore, that some 1.4 million tons of this iron concentrate may be recovered from the old tailings. This means that KISCO has moved its key one-step in re-mining and reutilizing the secondary resources, which would be a good demonstration in this industry. This is also of social and economic significance in response to China government?s request on reducing consumption of resources and establishing society with economy for achieving sustainable development.

Jan 1, 2014

By S. J. Dai

The cadmium and cyanide are main poisonous components in cyanide electroplating cadmium waste water of an electroplating plant in Shenyang. The content of cadmium is about 26 mg/L and the content of cyanide is about 11.782 mg/L in this waste water. The main form of cadmium and cyanide are ions which are Cd2+and CN?. Because the cadmium and cyanide exceeded the standard seriously, the waste water must be disposed before it discharges. The microbiological method of treating heavy metals in wastewater has many advantages. For example, it has a fast adsorption velocity, high processing efficiency, wide range of pH and temperature, few invest, low running cost, no the second pollution and so on. At the same time, the CN? could be degradated by some microbiology. The physical nature, the chemical nature of Bacillus mucilaginosus, the adsorbing condition and adsorbing regular of Bacillus mucilaginosus to cadmium in the wastewater are studied by using Bacillus mucilaginosus as adsorbent removing cadmium from electroplating wastewater. The experimental results show that the adsorbing rate of cadmium is over 92%, under the room temperature(about 25?), stiring revolution in adsorption being 800 r/min for 30 min, pH being 5 , the bacteria being cultured after 5d with the biomass of Bacillus mucilaginosus 40g/L (wet weight). The mechanism in biosorption process of Bacillus mucilaginosus to cadmium is analyzed and discussed by TEM , Zeta potential,and infrared spectroscopy analysis. The results showed, the chemical involving is main adsorbing form, while electrostatic attraction, ions exchange, hydrogen bonding and Van Der Waals force are concerned cooperatively. ?NH2 ?, ?C=O?, ?C=O?NH?CH2, ?CH3, ?OH are main adsorbing groups. At the same time, the floatablity of removing cyanide by Bacillus mucilaginosus is explored.

Jan 1, 2014