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By Marc-André Villiard, C. St-Onge, V. Silla, J-C Milot

Rio Tinto Fer et Titane (RTFT) operates a metallurgical complex in Sorel-Tracey, Canada. In the Ore Preparation Plant (OPP), ilmenite ore is roasted through four parallel rotary kilns generating 95% of the plant wide sulphur dioxide (SO2) emissions. RTFT proactively set an annual emission cap for SO2 to be achieved by 2015. To achieve this targeted SO2 reductions, a technology evaluation and selection exercise was carried out, followed by detailed engineering and implementation. After a detailed evaluation of SO2 scrubbing technologies, the Circulating Dry Scrubber (CDS) system was selected as the most appropriate desulphurization system for this application. The system was implemented and commissioned from 2013 to 2015. General performance testing conducted in May 2015 demonstrated that the system achieved and surpassed the anticipated design values in terms of SO2 removal efficiency and hydrated lime utilisation. This paper summarizes the SO2 technology selection process, design features of the selected technology, project implementation and final performance testing of the SO2 abatement system.

Jan 1, 2015

By M. Sukhram

In the year 1992, T.A. Utigard published a paper titled "The measurement of the heat-transfer coefficient between high temperature liquids and solid surfaces." In that work, he instrumented an agglomerate of materials with thermocouples to infer the heat transfer coefficient of a high temperature liquid on a solid. The purpose of that research was to help in the design and operation of metallurgical reactors. Since that time there have been many researchers that have worked to characterize heat, mass, and momentum transfer phenomena in high temperature metallurgical processing operations. This paper presents results from the author’s experience with instrumenting thermocouples in copper elements coated with carbon to infer velocity of high temperature liquid metals. It also presents a methodology to determine velocity of a high temperature liquid by inferring the local heat transfer coefficient at a solid-liquid interface

Jan 1, 2015

By G. Minhas, M. Pule, Y. Laffitte, M. c. McGurn, T. Tzanetakis, Peacey. J., R. Susilo

Titanium (Ti) metal production from titanium tetrachloride (TiCl4) using magnesium (Mg) as a reducing agent is the well-known Kroll process. A chloride route is used to avoid oxidation of the titanium sponge. The sponge is consolidated into ingots and can then be made into powder by melting and atomizing or by hydriding/dehydriding. Attempts at direct powder production have met with difficulties, including low Ti yield and the formation of very fine particles (particles between 25-100 µm are desired). This paper discusses two methods to produce Ti powder in a molten salt medium using magnesium powder as a starting material instead of a pool of molten magnesium. The first method is a direct reduction of gaseous TiCl4 injected in the melt with the magnesium powder in suspension in the molten salt. The second method is a two stage TiCl4 reduction reaction where recycled Ti was used to form titanium dichloride (TiCl2) in the first stage followed by addition of magnesium powder into molten salt in the second stage. A correlation between Ti yield and processing variables such as TiCl4 to Mg ratio, Mg particle size, TiCl2 concentration in the melt, and reaction temperature was studied. The Ti powder formed was also analyzed for particle size distribution. Despite challenges and difficulties encountered, this paper shows some promising results which could provide guidance to others working on direct Ti powder production.

Jan 1, 2015

By Krishna Parameswaran

In this paper, we attempt to answer an often asked question, how can metal mining be compatible with the principles of sustainable development. Starting with the classic Brundtland Commission definition of sustainable development as "development that meets the needs of the present without compromising the ability of future generations to meet their own needs," we make the case that mining is or should be sustainable, using examples of sustainable practices at ASARCO LLC, an integrated U.S primary copper producer. These examples cover the entire mining cycle starting with exploration, mining, beneficiation, smelting, refining, closure and post-closure and post-mining land use. It is hoped that the presentation will challenge the mining industry to even greater innovation as future mineral development projects are planned.

Jan 1, 2015

By J. M. Bowen, P. Wemyss

"Gold losses to natural carbonaceous matter during cyanide leaching have been investigated for over a century. The variation in the severity of the problem from one ore to another has led to a range of different processes being implemented at different mine sites. Most commercial options utilise one or more of the following processes: roasting, carbon pre-flotation, organic blinding, CIL, chlorine passivation, pressure oxidation, biological passivation, elevated temperature CIL, RIL and thiosulfate. This paper provides a background to identify the most appropriate process or combination of processes for a particular ore. It also presents information on how these processes may be implemented, drawing on information in the literature and from current or recent applications at operations such as the following: Stawell, Kumtor, Penjom, Twin Creeks, Macraes Flat, Kittilä, Fosterville, Inata, Carlin, Goldstrike, and Jerritt Canyon. Various process options have been dismissed, or deemed unsuccessful due to limited knowledge available on the strengths and weaknesses of the different options and their implementation. The authors have collectively been involved in flowsheet development and project implementation in four commercial plants that have treated preg-robbing ores.INTRODUCTION Cyanide processing has been the mainstay of gold recovery for well over a century. It is generally a very effective process with over 90% recovery on free milling ores, but complex and refractory ores may only give 0–50% recovery with conventional processing (La Brooy et al., 1994). People have written about gold losses to natural carbonaceous matter during cyanidation for over a century e.g. Feldtmann, (1915). The earliest reports related to African operations, but the issue has since been reported in Canada, North and South America, Australia, Russia and China. The phenomenon is usually referred to as ‘preg-robbing’ dating from the times before the use of granular activated carbon for gold recovery, when gold was lost from the pregnant solution before it could be separated from the leach solids and recovered by cementation. Many excellent reviews have been published e.g. Dunn et al. (2013), summarising the options considered and where they have been applied commercially."

Jan 1, 2017

By M. Kim, M. Ha

"The effect of red mud on the melting behavior of ferronickel slag was investigated by a laboratory-scale horizontal tube furnace. Melting and softening of slag samples fluxed with different amount of red mud was examined by in-situ visualization technique at temperature range from 1400 to 1550°C. FactSageTM 7.0 was used for the thermodynamic calculation of multi component system of ferronickel slag and red mud. Liquid phase area was extended to lower temperature by adding red mud indicating its suitability as a flux material. X-ray diffraction analysis confirmed the dependency of the phase changes on the red mud content. Microscopic observation by scanning electron microscope (SEM / EDX) clarified the phase transformations from olivine to spinel along with red mud additions.INTRODUCTION Ferronickel smelting by submerged arc furnace (SAF) is an energy intensive process performed at high temperature range 1500–1600°C. During the smelting process of saprolitic nickel laterite ore with a nickel content of 2.2–2.3 pct, a large quantity of ferronickel slag is being produced that account for 97 pct of ore charged. To achieve ferronickel grade of 15–20 pct Ni, electrical energy of 80 to 85 MW is used for the melting and reduction of nickel oxide (NiO) and iron oxide (FeO) in the ore (Rodd et al., 2010). Unreduced components, mostly MgO, SiO2 and partly FeO are removed from the furnace in a liquid slag form by a tapping operation. Due to the high melting temperature, forsterite (Mg2SiO4) based slag containing approximately 10 pct FeO requires typical process temperature of 1600°C. Flux in metallurgical process is a medium that decreases melting and operating temperatures while it increases fluidity of the liquid slags. Calcite and fluorite are examples of flux materials used for the ironmaking, steel refining and continuous casting process. Oxide systems based on CaO - CaF2 - SiO2 - Al2O3 - MgO cover most of the slag composition in ferrous metallurgy accordingly. Crucial operating factors for ironmaking and steelmaking slags are basicity (typically CaO/SiO2 ratio), viscosity and impurity levels. These are extensively controlled by the fluxes. General metallurgical fluxes such as limestone, dolomite and calcium fluoride are abundant in nature and supplied to steel mills at low prices. Meanwhile, in copper flash smelting process, silica is supplied with copper concentrate to remove iron oxide (FeO) generated from sulfide oxidation. FeO - SiO2 binary system formulates eutectic area at 25–38 pct of silica that has low melting temperature below 1205°C. Fayalitic system (Fe2SiO4) that has low viscosity (0.1 Pa·s) (Park et al., 2011) facilitates easy separation of slags from molten sulfide mattes. Recently, copper plants actively utilize recycled raw materials as a flux. Various recycled glasses are ground and fed to copper smelting process as a partial replacement of silica ore. Applying industrial wastes to smelting processes is advantageous since the operators can reduce the production cost remarkably. Not to mention the consumption of recycled materials can ultimately minimize the environmental risks and the waste management costs. The authors, therefore, investigated the reasonable waste materials that can be effectively used for ferronickel smelting process. Prerequisites for potential fluxing materials are non-recyclable property, low transportation cost and excellent performance as a flux."

Jan 1, 2017

By Olaf Kessler, Jan Kalich, Michael Reich, Julia Osten, Uwe Füssel

Modern automobile bodies consist of different materials, e.g. aluminium alloys and high strength steels. Mechanical joining, e.g. clinching, is very suitable for joining aluminium and steel sheet. But clinching needs a sufficient ductility, which is no longer supplied by high strength steels. Laser-assisted clinching has been shown, to be able to join aluminium and high strength steel sheet successfully. Thereby the steel sheets were heated locally for short times to increase their ductility. Due to the thermal contact between steel and aluminium sheet the aluminium alloys also achieve a local short-time heat treatment. This fact may cause a significant impact, as aluminium sheet in automobile bodies is often used in T4 (or similar) condition and later artificially aged during the paint bake cycle. Aluminium alloys 6016 and 6181 have been short-time heat treated with heating rates up to some 100 K/s. Precipitation and dissolution processes have been monitored in-situ by calorimetry. Mechanical properties have been investigated on as well as after short-time heat treatment by deformation dilatometry. The results show, that suitable short-time annealing parameters during laser-assisted clinching can increase ductility and at the same time act as retrogression for aluminium sheets, resulting in increased strength after aging.

Jan 1, 2015

By D. F. Zhang, X. Q. Jiang, N. Tahreen, D. L. Chen, F. S. Pan, D. Y. Li

Alloying with rare-earth elements has been proven to be an important tool for magnesium to achieve superior properties via texture randomization. The role of yttrium in texture weakening and the link between texture and formability are fairly well known. Since annealing is a vital part of metal processing which could significantly contribute to ductility, it is important to ascertain the impact of annealing in terms of texture change. Also, an understanding about texture development during pre- and post-deformation annealing is essential to improve the industrial deformation processing as texture is closely related to formability. While there is independent information in the literature regarding the effect of rare-earth addition and heat treatment on the texture formation, no systematic studies have been reported on the collective impact of yttrium addition, annealing and deformation on texture evolution. The present study was, therefore, aimed to identify the inter-relationship among texture evolution, yttrium content, heat treatment and deformation behavior in an extruded Mg-Zn-Mn-Y alloy. Annealing at 450°C for 1 hour and uniaxial compression tests at a certain amount of deformation were performed. The deformed and annealed samples were then subjected to annealing and compression test, respectively, followed by texture measurements. It was observed that yttrium addition effectively weakened the crystallographic texture in all conditions, which was evident from the changes in the microstructures and textures.

Jan 1, 2015

By R. B. Nourse, S. F. Gwynn-Jones, S. Nikolic, M. L. Bakker, I. McDougall, H. Joubert

"Tenova Pyromet’s core furnace knowhow and expertise has been built within the ferroalloy and nickel/platinum group metal (PGM) industries with the supply of electric furnaces for a number of nickel/PGM operators, including Eastplats, Lonmin, and Anglo-Platinum in South Africa, Mineraçào Serra Da Fortaleza in Brazil, and Norilsk Nickel in Russia. Tenova Pyromet has also supplied the electrode columns and associated electrode equipment – the heart of the electric furnace technology – for cobalt recovery in furnaces in Zambia and the Democratic Republic of the Congo. The quantity and size of projects undertaken by Tenova Pyromet has provided the opportunity to continuously improve furnace designs and the scope of supply, culminating in the most recent nickel/PGM project currently under construction at Northam Platinum. Through this innovative culture, the Tenova Pyromet Base Metals Initiative was formed in 2015 to develop the Novasmelt™ Furnace; a next generation optimised Top Submerged Lance (TSL) furnace design. The combination of Tenova Pyromet’s advanced Novasmelt™ product with our industry leading electric furnace technology are discussed with reference to applications for nickel and cobalt production. Flowsheet arrangements are compared summarising potential capital savings, operating requirements and achievement of downstream product quality.INTRODUCTION Tenova Pyromet is a leading player in the field of smelting technology development and equipment supply. Tenova Pyromet is the result of the union of three furnace suppliers under the Tenova banner: Techint Technologies (Tagliaferri), Core Furnace Systems Corp (Lectromelt) and Pyromet Technologies. The furnace experience of the combined groups dates back over a century with the earliest Lectromelt going into production in the early 1900s. Throughout the modern era, Tenova Pyromet has developed a reputation for providing dependable innovative smelting technology, high quality equipment and sound project execution to a worldwide client base with customer plants operating in Europe, Southern Africa, North America, South America, Russia, Kazakhstan, the Middle East, South Korea, and India. Tenova Pyromet’s core knowledge and expertise was developed in the South African ferroalloy, base metals, and platinum group metals (PGM) smelting industries. Tenova Pyromet has spent considerable effort on development and has contributed significantly to improve the state of the smelting industry. Tenova Pyromet’s electrode columns have become widely renowned and are now providing significant benefits, especially in increased furnace availability, to many smelting furnace operators. The electrode column is the heart of the furnace as it delivers a controlled amount of electrical energy, at an optimum depth in the burden/bath, to the smelting process. Every furnace is custom designed to the specific operating range and optimal operating point of that furnace and process"

Jan 1, 2017

By J. Girard, V. Aubé, M. Barakate, S. Bellec, M. R. Eddahabi, Y. Chaik, M. Deshaies

"The activated carbon used in the carbon-in-leach (CIL) process to absorb gold is subject to breakage. This carbon breakage can be minimized, but it will always be necessary to deal with fine carbon particles, known as carbon fines. These fines contain a significant amount of gold and mining operations generally struggle with the treatment of this product. Since IAMGOLD’s Essakane mine is located in Burkina Faso, shipping carbon fines out of the country was not considered a viable solution due to the logistical burden and legal procedures in place. A benchmarking study demonstrated the complexity of treating carbon fines on site. IAMGOLD partnered with the host government to find an innovative approach to economically recover the gold locked in these fines. This paper describes the new circuits commissioned in July 2016 built to improve carbon fines collection, incinerate the carbon fines and leach the gold in the ashes produced by incineration. These new circuits successfully demonstrate that it is possible to extract more than 94% of the gold content in the carbon fines. This is profitable for the company as it improves the overall mill recovery rate by 1.0% to 1.5% and significantly decreases gold inventory build-up on site.INTRODUCTION The activated carbon used in the carbon-in-leach (CIL) to absorb gold is subject to breakage. This breakage can occur in the CIL tanks, the stripping circuit, the regeneration process or anywhere throughout the pumping and handling processes of carbon through the circuit. Fine carbon particles are invariably created and, because of their small size, present a large specific surface which favors gold absorption (Hilsher et al., 2014). At the very beginning of operations at Essakane, the carbon fines were recovered by means of a thickener and a filter press, but the circuit was undersized and inefficient. Subsequently, a decantation basin was used to settle the fines before the thickener. The settled fines were shovelled from the basin into bags. All these bags were stored in the backyard of the plant. The average tonnage of carbon fines recovered monthly was 23.5 tons with a gold grade at 1938 g/t."

Jan 1, 2017

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Previous testwork by the authors has indicated that both granular coconut shell based activated carbon and a new microporous carbonaceous bead, Lewatit® AF 5, are highly effective in improving the oxidation kinetics and decreasing the elemental sulphur yield when assisting the atmospheric oxidation of pyrite. While the two carbon catalysts show similar results and improvements to the pyrite oxidation, there are differences between them. For example, the activated carbon assisted oxidation showed faster kinetics than the AF 5 assisted oxidation, while elemental sulphur seemed to remain adhered to the surface of the AF 5 after oxidation when much of the elemental sulphur formed during the activated carbon assisted tests was found in the oxidation residue. The objective of this paper is to investigate the differences between the two catalysts through the use of scanning electron microscopy, photography, Raman spectroscopy, surface chemistry analysis, and Brunauer-Emmett-Teller (BET) surface area analysis. With this investigation the authors should be able to achieve a better understanding of the surface chemistry of the two carbon catalysts (i.e. functional groups, charges, acidity etc.) and help explain the strengths and/or the weaknesses of the catalysts when applied to the atmospheric oxidation of pyrite.INTRODUCTION Previous research conducted by the authors, indicated that both a granular coconut shell based activated carbon (activated carbon) and a microporous carbonaceous bead, Lewatit® AF 5 (AF 5), acting as a catalyst enhanced atmospheric pyrite oxidation in ferric sulphate media by approximately 40% when compared to unassisted oxidation and that elemental sulphur yields were increased from 23% to approximately 69 and 63% when assisted by AF 5 and activated carbon respectively (Cowan, Jahromi, & Ghahreman, 2017). The study indicated that although total pyrite oxidation assisted by the two catalysts was similar, differences were noticed in the impact that the two catalysts had on the outcome of the oxidation. Kinetic curves in the Cowan et al. study indicated that atmospheric oxidation of pyrite seemed to reach completion after 48 hours of oxidation when assisted by activated carbon. A similar trend was noticed in the kinetic curves for oxidation when assisted by AF 5, however the oxidation curve did not reach completion until approximately 96 hours (Cowan et al., 2017). This observation indicated that the kinetics of pyrite oxidation are enhanced by both catalysts, oxidation kinetics are much faster when assisted by activated carbon rather than AF 5."

Jan 1, 2017

By Fazel G. Jahromi, Ahmad Ghahreman

"Atmospheric leaching of arsenical sulfide concentrates, and especially enargite leaching, is one of the major challenges within the current hydrometallurgy research area. One of the recent processes developed for sulfide ore treatment is atmospheric leaching in the presence of AF 5, a novel carbon based catalyst, in chloride media. The quantification of different ion concentrations during enargite and chalcopyrite leaching in the presence of AF 5 were measured and the copper recovery rates of 97% and 96% were achieved. The objective of this study is to shed light on the leaching mechanism of the sulfide minerals. Based on the speciation of iron and copper by different titration methods, the AF 5 catalyst first reduced ferric and cupric ions and then oxidized ferrous, cuprous and arsenite ions. The oxidation behavior of the catalyst enhanced the leaching results. The AF 5 catalyst also caused in situ precipitation of scorodite in leaching experiment. The speciation of ions in the chloride media were simulated by Phreeqc software and the dominant species in the leaching solution were determined.INTRODUCTION The hydrometallurgy of copper has been used for several decades and is still under development for more complex copper sulfide minerals due to their refractory nature. Most of the world copper reserves are in the form of chalcopyrite; and enargite is known as a major contaminant. Pyrometallurgical processing of enargite is problematic due to arsenic release and tight environmental regulations (Peacey, Gupta, and Ford n.d.). On the other hand, lower recoveries in the hydrometallurgical processes make most of these processes impractical. Several leaching processes have been developed for the leaching of copper sulfide minerals. Some of the common treatment methods for copper sulfide minerals are pressure oxidation leaching (POX), CESL, Activox, Albion process, atmospheric ferric sulfate leaching, Dynatec, Galvanox, and Hydro copper process (Barr, Defreyne, and Mayhew 2005; Conner and Anderson 2013; D.G. Dixon, Mayne, and Baxter 2008; Hyvärinen and Hämäläinen 2005; Palmer and Johnson 2005; Rohner, Bartsch, and Ngoviky 2012). Generally it is not viable to dissolve copper sulfide minerals at ambient pressure in mild acidic media and dissolution of these refractory minerals requires harsh conditions in the presence of oxidant materials (Biswas and Davenport 2002). Ferric ions have been used as an oxidant in different media in copper sulfide leaching processes. U. S. Bureau of Mines’ Reno Metallurgy Research Center in 1969 (Haver and Wong 1971) investigated ferric chloride leaching of chalcopyrite. Dutrizac and Macdonald (1972) studied ferric sulfate leaching of enargite. Based on this study, 50% of the copper was recovered at 80-85 ºC after 7 days of leaching. Cupric ions can also be used as an oxidant. Parker, Paul, and Power (1981) stated that cupric/cuprous couples are more effective than ferric/ferrous couples in chloride media because they are rapid and reversible. The Hydro Copper process leaches copper sulfide minerals in chloride solution catalyzed by cupric ions. In this process, copper dissolves as cuprous ions in presence of cupric ions (about 10 g/L) (Hyvärinen and Hämäläinen 2005)."

Jan 1, 2017

By S. Hume, J. Shepherd

Meso-2,3-dimercaptosuccinic acid(DMSA) was studied as an additive for thiosulfate leaching of gold. DMSA was added to solutionscomposed of either sodium thiosulfate or calcium thiosulfate and the solutions were tested for their ability to leach pure gold samples as well as a calcined gold ore from Barrick Gold Corp. Results showed prolonged leaching of pure gold samples when DMSA was added at a concentration of 5µM; however, higher concentrations were shown to inhibit leaching. Differential capacitance measurements of the interface indicated that DMSA adsorbed as a defective monolayer on the surface of gold at low concentrations and formed a more compact monolayer with increased concentration. It is proposed that a concentration of 5µM DMSA produces a defectivemonolayer on the surface that still allowsthe transport of oxidants to the underling metal while inhibiting the formation of polysulfide passive layers that arise fromdecomposed thiosulfate.The 5µM DMSA/CaS2O3 system was also studied using calcined ore. Results showed that the initial leaching rates in the presence of DMSA are lower than those obtained in thiosulfate alone. However, after 10h, prolonged leaching is again observed when DMSA is included.

Jan 1, 2015

By R. Esteban, D. Runnels, J. Torrealba-Vargas, G. Couture

"Data handling is an important step in the development of a simulator of a mineral processing circuit. The model requires representative data of the scenario to be modeled. The model development involves protocols that must be followed very closely to complete a successful project.Data handling of large and diverse datasets (metallurgical test results, geological data, mining models, historical data, etc.) is a key element of the model. The information needs to be processed, reconciled, interpreted, modeled and presented to support the design or the optimization of a mineral processing plant.Best practice recommends that teams from different disciplines (such as mining, metallurgy, geology and environmental) interact to define the most important variables that could influence the simulator. For example by adopting a geometallurgical approach in the earlier stages of the project, it is possible to consolidate the number of main ore rock types in a testwork program (saving money and time) by involving geologists and metallurgists in the sample selection and data interpretation.Planning the development of a model involves an understanding of the software capabilities but also the limitations and the magnitude of the data required to calibrate the model in case of changes in the project.A successful model requires a deep understanding of the circuit to be modeled and thus plant personnel should be considered as members of the team.This paper describes the use of the "state of the art" tools for data analysis, simulation and optimization; and shows three practical examples of the use those tools in the design of mineral processing plants."

Jan 1, 2015

By J. Sliwinski, H. Kikutani, J. Atwood, D. Larimer, J. Pyecha

"The Pogo mine start-up milling targets of 2005 are vastly different than the targets of today. Improvements have been driven by unintentional design oversight, continual circuit optimization or optimization due to changing mineralogy. The more significant process improvements to date have occurred in the gravity, flotation and leach/CIP unit operations. Details of the significant improvements are presented along with the impacts to the process.INTRODUCTION Deposit Overview Pogo mine is located along the Goodpaster River, southeast of Fairbanks, Alaska. This deposit sits in the center of the Tintina Gold Province (Figure 1), a region of similar Intrusion Related Gold deposits in Interior Alaska, the Yukon and British Columbia Canada (McCoy et al., 1997). The Pogo deposit is hosted in a rock sequence of amphibolite-grade gneisses intruded by mid-Cretaceous granitic plutons and dikes, which in turn, were cut by and host the auriferous quartz veins of the Pogo deposit.The Pogo deposit is comprised of three distinct zones of auriferous quartz veins spatially adjacent to each other. These are the Liese Zone, North Zone, and the East Deep Zone. The Liese Zone consists of three stacked, massive quartz veins, designated the L1, L2, and L3. Vein thickness averages 3.0 m, with variations from 0.3–18 m thick. The North Zone mineralization is comprised of four veins with more consistent thickness, between 1 and 1.5 m. The East Deep deposit lies northeast of the Liese Zone ore body. It is separated by a post mineralization, quartz diorite pluton. The East Deep Zone is comprised of two stacked massive quartz veins with similar orientation as the Liese Zone."

Jan 1, 2017

By Edouard Asselin, Tasawar Javed

The precipitation of hematite from ferric sulphate - cupric sulphate - lithium chloride acidic solutions was studied in a batch reactor. The effect of several variables on the extent of hematite precipitation as well as on its crystallinity and purity was investigated. The variables studied include: initial ferric concentration (1.5 - 30 g/L), retention time (0 - 12 h), initial sulphuric acid concentration (0 - 30 g/L), temperature (150 - 220 °C) and chloride concentration (0 - 25 g/L). The results show that hematite is preferentially precipitated at lower initial iron concentrations. Longer retention times increased the fraction of hematite in the precipitates but did not affect its crystallinity to a significant extent. On the other hand, higher temperatures increased the purity and crystallinity of the hematite. At lower acid concentrations hematite and goethite were precipitated. However, only hematite was precipitated when the initial acid concentration was > 12.5 g/L. Better crystalline hematite was formed at lower acidities. Increasing chloride concentration increased the amount of hematite and decreased the amount of iron sulphate hydroxide phases, but did not affect the crystallinity of the hematite.

Jan 1, 2015

By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By V. G. Papangelakis, G. A. Moldoveanu

The use of anhydrite (AH) seed, control of acidity levels and ageing were assessed as means to promote the conversion of freshly produced metastable gypsum generated in-situ to the less soluble anhydrite phase and force deposition of calcium sulphate on seed as opposed to on equipment as scale, while achieving lower terminal aqueous calcium concentration as well. It was found that moderate sulphuric acid levels (0.25M) and ageing in the presence of AH seed accelerated the gypsum-AH conversion, achieving 100% transformation of the metastable gypsum generated in situ to the more stable, less soluble AH in 6-7 days, while lower/nil acidity did not promote more than 30% AH conversion for 10 days, even in the presence of AH seed. These findings indicate that anhydrite seeding, ageing and incomplete neutralization are beneficial for scale control as well as achieving lower calcium levels, thus rendering the resulting solution more amenable for recycling.

Jan 1, 2015

"ALTHOUGH Canadian metallurgists have long been active in research, the scope of the work was somewhat limited until the be-ginning -of World War II. The rapid industrial development of Canada during the past ten years has been accompanied by .a similar upsurge in research. However, the wide geographical distribution of the research centres has made it difficult for the individual research workers to meet together and to exchange ideas or even to learn what projects .are being investigated or the nature and extent of the facilities available for work of this kind.The purpose of the present symposium is to assemble data relating to projects under investigation and the facilities employed at the various metallurgical research laboratories in Canada, thus providing some measure of correlation so that workers in different locations may learn what kind of work •is being .done at other points throughout the country.In reporting the symposium it has not been possible to reproduce the papers in full, but excerpts have been selected that give the essentia1 data."

Jan 1, 1952