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By Jürgen Kretschmann

The Islamic Republic of Iran is a very important producer of raw materials in the world. The country holds 68 types of minerals, including salt, sand and gravel, chrome, lead, zinc, copper, coal, gold, and iron-ore. With more than 37 billion tons of measured and indicated reserves and 55 billion tons of total mineral resources, Iran is ranked among the 15 major mineral-rich countries. Sangan iron-ore mines (SIOM) is one of the biggest iron ore mining complexes in Iran, located in a remote, but strategically important area near the Afghanistan border. The Iranian government has planned several mining projects in this region for a stepwise development over the next 5 years to satisfy the growing demand of the Iranian steel industry. In cooperation with private companies, these projects shall be realized as sustainable as possible. This paper introduces SIOM and describes socially responsible activities undertaken during the initial development of this mining complex. The effects of these activities will be demonstrated. Unique attributes of the Sangan area have a significant impact on the acceptance of SIOM by regional stakeholders. The government has made several social investments that benefit workers´ families and the community. They are attempts to build social capital for the mining operations and demonstrate a commitment for socially responsible mining to the communities and the local population. They aim to create a balance between the local and regional expectations and requirements and the necessity to secure the corporate profitability at a reasonable and sustainable level. Investment in socially responsible activities is not a choice but a necessity to improve the relations between mining companies and stakeholders in the communities. It is recommended that social investments should be carefully planned and implemented from the early stages of mining activities, and should proceed throughout the life cycle of the mines.

Aug 1, 2013

By Yann Sivry, S. Subramanian, Divyasree C. Prabhakaran, Jean Riotte

The potential of a bacterial strain isolated from water samples collected from a chromite mine in Odisha, India has been assessed for the bioremediation of hexavalent chromium, a toxic environmental pollutant. The isolate was identified as Sphingopyxis sp., a Gram negative bacterium, adopting molecular biological protocols and biochemical characterization techniques. Detailed investigations on the bioremoval of Cr(VI) were carried out using Sphingopyxis sp. cells and the various parameters affecting the biosorption process were evaluated. About 55 % biosorption of Cr(VI) was obtained using Sphingopyxis sp. bacterial cells and the residual chromium in solution was found to be bio-reduced to the trivalent form, namely Cr(III). Thus, complete bioremediation of Cr(VI) could be achieved using the mine isolate, with contributions from both biosorption and bioreduction mechanisms. The Cr(VI) biosorption isotherm obtained for the isolate was found to follow a typical Langmuirian behavior and the free energy value of biosorption was determined to be ~-25 kJ/mol, indicative of involvement of chemical binding forces in the bioremediation process. The chromium biosorption kinetics by the isolate followed a pseudo second order reaction. The FTIR spectral studies revealed that carboxyl, hydroxyl, amino and phosphate groups were involved in the biosorption process. X-ray photoelectron spectroscopic studies on the bacterial cells interacted with Cr(VI) confirmed the presence of both Cr(VI) and Cr(III) on the cell surface. The electrokinetic studies revealed that the surface potential of the bacterial cells were less electronegative subsequent to interaction with Cr(VI), compared to the cells alone, which further testified to the binding of positively charged Cr(III) ions, formed by bioreduction of Cr(VI), to the bacterial cell surface. A marginal shift in the iso-electric point obtained for the bacterial cells interacted with Cr(VI), corroborated the involvement of chemical binding forces in the bioremediation process.

Jan 1, 2016

By Yoshimasa Funakawa, Kazuhiro Seto, Akio Kobayashi

A new hot rolled high strength steel consisting of ferrite matrix and nanometer¬sized precipitates was developed. The ultra fine precipitates were identified as TiMoC2, and the strengthening by the precipitates was evaluated more than 300MPa in case of TS/800MPa grade steel. Due to the strengthening effect of the ultra fine precipitates, alloy elements for solid solution hardening can be reduced. It is notable that the steel shows very high yield strength (730MPa in case of TS/800MPa) and very high local elongation leading to excellent stretch flange formability at the same time. The mechanical properties of the steel are attractive for chassis parts and structural parts of auto body. The steel has been produced commercially, and applied to the parts successfully.

Jan 1, 2004

By F. Chiesa

Experimental results on thin and thick castings poured in aluminum A356 and magnesium AZ91E by the low pressure permanent mold process have been compared to the result of filling simulations for thin and thick castings. If the results of modeling is reliable when the liquid remains above the liquidus temperature, this is no longer the case when partial solidification occurs. The visco-elastic behavior of a partially solidified liquid is difficult to put into equation as it depends on the amount of shear it has been been subjected to. Attempts to predict misruns with a commercial software has been proven to be very difficult if not impossible; divergence of the numerical solution has been observed unless prohibitively long computing times are used. In order to overcome these difficulties from a practical standpoint, a simple method is proposed which consists in tracking the temperature of the advancing liquid metal front so as to make sure it will always be above so-called `Misrun Critical Temperature' (MCT) determined experimentally for thin and thick aluminum A356 and magnesium AZ91E castings. If the liquid metal front falls below this temperature, a cold-shut or misrun is likely to happen at this location. The values of MCT for thin and thick in aluminum A356 and magnesium AZ91E were determined experimentally on misrun castings of extreme geometries (a thin 2.5 mm wall cover and a 6mm to 25 mm thick bell housing). MCT was found to be lower for magnesium AZ91E and for the thicker castings.

Jan 1, 2011

By J. J. Hussey

"Abstract-The ""Brunswick Horizon"" an informally named ore-bearing unit near the top of the Nepisiguit Falls Formation in the Ordovician Tetagouche Group, hosts the Brunswick No. 6 and No. 12 base-metal mines, as well as the former Austin Brook iron mine, in northern New Brunswick. Detailed structural analysis of the No. 6 and No.12 mines led to the prediction that a massive­ sulfide deposit may have been repeated by F1 folding along the Brunswick Horizon. A subsequent drilling program discovered the new massive-sulfide North End Zone at a vertical depth of 1100 m, 1 km north of the No. 12 underground workings. By the end of 1990, Zn-Pb-rich massive sulfides had been delineated over a strike length of 200 m and a down-dip extent of 170 m. Rock units intersected in the North End Zone are generally thinner and vary somewhat from those at the Brunswick No. 12 mine. Thinning of the hanging wall rocks may be primary, may result from attenuation along F2 folds, or may represent truncation by a thrust fault. The newly discovered sulfide zone indicates that significant potential exists for the discovery of other deposits at previously unexplored depths.SOMMAIRE-Dans le nord-est du Nouveau-Brunswick ""l'horizon Brunswick"" est le nom usuel de la zone qui contient les mines de métaux de base Brunswick No. 6 et No. 12, ainsi que l'ancienne mine de fer Austin Brook, toutes situées sur le dessus de la Formation ""Nepisiguit Falls"" dans le Groupe Tetagouche d'âge Ordovicien. Une analyse détaillée de la structure des mines No. 6 et No. 12 à permis a van Staal de prédire qu'un gîte de sulfures massifs pourrait se répéter dû à une déformation F1, au nord de Brunswick No. 12. Suite à un programme de forage, la nouvelle zone de sulfures massifs appelée le ""North End Zone"", profonde de 1100 rn, et à une distance d'un km au nord des chantiers souterrains, fut découverte vers la fin de l'année 1990, les sulfures massifs riches en Zn-Pb ont été délimités sur une longueur de 200 rn et une hauteur de 170 rn le long du pendage. Les unités de roches intersectées dans le ""North End Zone"" sont généralement plus minces et sont quelque peu différentes de celles de la mine Brunswick No. 12. L'amin­ cissement des roches pourrait être primaire ou être le résultat de l'atténuation le long des plis F2, ou soit tronqué par une faille. La nouvelle découverte d'une zone de sulfures indique un potentiel énorme pour la découverte d'autres g ""tes à ces profondeurs inexplorées."

Jan 1, 1992

By Jonathan Peck, Jim Gray

"With the implementation of more advanced monitoring, control and locating systems in surface mines, there is an ever increasing need for their mine-wide integration toward achieving over-all optimization. AQUILA Mining Systems Ltd. is developing the basis for a comprehensive real-time monitoring, control and information system called the Total Mining System or TMS. This system is being designed to address both current and future needs of open pit mines toward improving productivity and minimizing costs, through better two-way information flow between each component in the operation. At a basic level, feedback from equipment and process monitoring will enable decision making to be based on quantitative, on-demand information, thus permitting proactive rather than reactive planning. Dynamic planning would be a valuable tool as market conditions fluctuate, equipment fleets age and variations in the grade, quality, geometry and hardness of the mined material all contribute to either changing production targets or levels of achievable performance. Such a capability could be implemented within the next two years.At a higher level, and within five years, autonomous operation and/or real-time supervisory control of mobile and stationary equipment in open pit mines will be achieved. A discussion is provided in regard to the development and implementation of an autonomous haultruck and blasthole drill, to demonstrate the need for such a system.This paper outlines a preliminary program for the design, development and implementation of this system, primarily in relation to high-level communications and its role in the future automation of open pit mobile equipment."

Jan 1, 1995

By L. Cáceres, G. Leinenweber, P. Bustamante

"Given the severe scarcity of fresh water sources in Northern Chile the use of seawater has become the only alternative to allow mining expansion. This option however poses several technological challenges as a result of the high concentration of natural salts that promote various forms of metal corrosion. Therefore the steel piping protection has been a constant challenge for design engineers responsible for solving the problems of corrosion. Known protection alternatives are varied and expensive, a few of them are rubber coatings, protection based centrifuged concrete, extra wall thickness of pipes in combination with corrosion inhibitors, extra wall thickness of pipes without using corrosion inhibitors, and the use of highly corrosion resistant steel materials.In this framework the aim was to study the corrosion kinetics of carbon steel pipe API 5L X70 under electrochemical and weight loss testing. The test conditions include a range of seawater velocities between 0.2 to 3.0 m/s.For electrochemical experiments the API 5L X70 steel specimen was a 4 mm diameter disk embedded in an 8 mm diameter Teflon rod and exposed to seawater. Duplicated coupons were placed in a standard test apparatus that was built according to the standard ASTM D 2688 – 94.The main results were: a) corrosion mechanism explained in terms of the counterparts partial processes which are the hydrogen evolution and oxygen reduction reaction; b) for the test specimen a corrosion band like feature that suggest a lateral dispersion of aggressive solutions from corrosion pits; c) a range of corrosion rates between 1 and 1.96 mm/year for flow rates between 0.2 and 3.0 m/s; and d) a convenient inhibitor dose between 20–25 mg/L for optimum inhibition efficiency to obtain a maximum value of 80% for corrosion efficiency."

Jan 1, 2016

By F. Parada, R. Parra

"The neutralization process of SO2 from coal burning plants is a well-defined technology using limestone to form CaSO4 according to the following reaction: CaCO3 + SO2(g) + 1/2O2(g) = CaSO4 This paper presents the results of a study carried out to validate the option of capturing SO2 using gases from a non-ferrous smelter; SO2 content was up to 12% using a three-stage fluidized bed reactor. The difference in SO2 content affects equilibrium conditions and kinetics, rendering a direct extrapolation of the high efficiency achieved for low SO2 content impossible. The R&D program consisted of a laboratory study using a semi-pilot operation of a one-stage fluidized bed reactor and the construction and operation of a three-step reactor prototype. Results show that the reaction proceeds according to the unreacted core model that imposes a compromise between CaCO3 conversion and SO2 capture. For high SO2 capture, the calcine from the reactor contained CaSO4 and CaO. A complete capture of SO2 from gases with 8 vol.% can be achieved with a mean reaction time of two hours at 800°C."

Jan 1, 2007

By E. S. Moore

DEEP oxidation and-secondary enrichment of ore deposits, although so important in many parts of the world, are comparatively rare in the Canadian shield. Intensive glaciation during the Pleistocene epoch accounts for their rarity. Glaciation has cost Canada much in the destruction of not only enriched ore deposits, but placers that must have been developed near our numerous gold deposits during the long period of weathering that pre-ceded the Pleistocene. There seems to be a very common misconception regarding the average depth of rock that has been removed from the shield by glaciers. These bodies of ice are usually given credit for the removal of the greater portion of the thousands of feet of rock that we know has been eroded from this large area since Precambrian time. As a matter of fact, the average thickness of solid rock removed can be measured in tens rather than even hundreds of feet, although very deep erosion has resulted in some sections where the glacial ice has been constricted in depressions, such as deep valleys and lake basins. On the other hand, there are few areas within the shield where the glaciers have not disturbed practically all of the mantle rock and some feet of the underlying bed-rock. The chances of finding deeply oxidized cappings and enriched ore deposits are therefore comparatively few and these have been found chiefly where favourable structural and topographic conditions for their formation and preservation have existed. Faulting has been responsible for several of these deposits, and easily decomposed rocks, such as. sulphides and carbonates, have been very important factors. Topographic features, such as high and resistant hills, favourably situated with respect to the ore deposits have, in a few cases, played a part in providing protection from glacial erosion and in furnishing head for the descent of surface waters. At least four cases of oxidation to depths quite abnormal in the Canadian shield have so far been found in Ontario. These are the Helen and Josephine iron mines in the Michipicoten district, the Keeley silver mine in South Lor-rain, and the Ross gold mine in Hislop township, Cochrane district. A deeply oxidized zinc deposit of unusual interest occurs in the Precambrian rocks in New York State, not far from the Canadian border, and there arc the well-known iron deposits in the Lake Superior region of the United States.

Jan 1, 1938

By Walter I. Nelson

THE geology of the Copper Mountain mine has been ably described by Dr. Victor Dolmage in Memoir 171 of the Geological Survey. Reference is invited to that paper for a more extended description of the geology of the ore deposits than will be given here. The important orebodies of the mine occur in fragmencal volcanic rocks, parallel with and adjacent to the gabbro of the Copper Mountain stock. In the mine area, the contact strikes N.45°W. and dips either vertical or steeply co the southwest. For a distance of 500 feet or more from the contact, the fragmental rocks have been intensely metamorphosed both dynamically and hydrothermally. The dynamic effects are reflected in the foliation and fracturing parallel with the contact, which occurs throughout the mine, and the volcanic rocks within this foliated zone are, in places, highly schistose. Superimposed upon thi.s structure is a system of fine, straight, parallel frac-tures that strike nearly normal to the foliation (and contact) and dip between 65° and 75° to the north; it is with this last-described fracture system that the ore minerals are structurally associated. The fractures are mineralized with bornite and, to a considerably less extent, with chalcopyrite and some pyrite. A notable characteristic is the extreme fineness of the fractures; even in high-grade ore they are rarely larger than pencil lines. The tenor of the ore, therefore, varies directly with the fracture spacing. Replacemcnr of the host-rock between two or more fractures, varying in degree from finely disseminated sulphides to masses of nearly solid bornite up to 18 inches wide and 2 to 3 feet long, is not uncommon in the higher-grade portions of the orebodies. Two structural types of orebody are recognized in local nomenclature: the 'contact' orebodies, so-called because they occur along the contact; and 'outlying' orebodics, which are enclosed in the volcanics. The former arc tabular or lenticular bodies elongated along the strike and dip of the contact. The 'outlying' orebodies are coniform, chimney-like masses roughly elliptical in plan; with depth, their roots plunge at steep angles toward the contact. All of the orebodies are cut by a number of light-coloured granophyre and felsite porphyry dykes. These dykes-the so-called 'mine' dykes -enter the mine area from the north, curve gently southeasterly across the orebodies, and then cross the contact into the gabbro at the south end of the mine. All the dykes dip vertical to steeply east.

Jan 1, 1941

By Georges Croisé, Les-Lee Thompson, Adrien Debergé

Membrane filtration systems have regained focus in recent years as an effective means of liquid-liquid separation to increase the concentration of valuable elements, recover reagents or remove impurities. ORANO Mining (formerly AREVA) investigated this cost optimization process opportunity as early as 2011 for implementation at the Trekkopje project (Namibia). The key focus was to separate and recycle bicarbonate from the uranium bearing eluate solution. The performance targets were successfully achieved at lab- and pilot scale with an ultrafiltration and nano-filtration configuration system. Early 2015, ORANO Mining further launched an investigation into the use of membranes for acid recycling at the KATCO In Situ recovery mine in Kazakhstan based on the favorable results from the original bicarbonate application. KATCO is the world leader in ISR uranium mining with an eluate processing capacity of 80 000 m3/yr. This site consists of two processing plants namely, Muyumkum and Tortkuduk, located 40 kilometers apart, both operating under acidic conditions whereas precipitation and packaging are based in Tortkuduk only. This paper serves to present the results from the integration of a nano-filtration system at the Muyumkum satellite processing plant. The project consisted of screening laboratory bench studies conducted at ORANO-CIME followed by process validation at KATCO through further bench and pilot test work. The feasibility study assessments were successfully concluded which led to the implementation at an industrial scale in Muyumkum of a nano-filtration process to reduce eluate volumes being sent to the uranium precipitation section whilst achieving effective separation of uranium from sulfuric acid. Nano-filtration technology has drawn significant attention due to the efficiency and reproducibility of the process and its moderate capital cost relative to operational savings. The reliability of the previous results is a great opportunity to reduce operative expenditures within ORANO’s next ISR mining project in Mongolia.

Jan 1, 2020

By Tassos Grammatikopoulos

The St. Lawrence deposit is a large wollastonite skarn (ca. 9 Mt @ 41.3% wollastonite) adjoining the gabbroic-to-syenitic Leo Lake pluton in the granulite facies of the Frontenac Terrane of the Grenvillian Central Metasedimentary Belt. It occurs within a horseshoe-shaped horizon of quartzite, open to the east. The skarn extends over 1.2 km2, and comprises wollastonite-dominant, wollastonite-clinopyroxene, and diverse quartz-feldspar-sulphide (-titanite) layers, interbanded with, and strongly folded within, the quartzite. As in the world-class wollastonite deposits of the Willsboro district, New York State, no carbonate protolith is preserved and calcite is a negligible constituent of the mineralized zones. Wollastonite development is nonetheless ascribed to metasomatism of a metacarbonate unit by magmatogene, silica-rich, CO2-poor (XCO2 < 0.05) fluids, at P = 350 MPa and ca. 560 oC, or, alternatively, 550 MPa and ca. 630 oC. Several high grade zones, averaging >40%, but locally exceeding 80%, of translucent, white, tabular wollastonite grains, with lengths of 0.2 - 2 cm, have been delimited by drilling. Preliminary beneficiation studies yield high aspect-ratio and high-purity (low Fe and Mn) concentrates. St. Lawrence compares favourably to other known prospects and operating wollastonite deposits; having good chemical and physical properties, low iron content, and high aspect ratios (>20:1). In addition, the deposit has a favourable size and location, and will benefit from a low Canadian dollar. Canada currently has no wollastonite production.

May 1, 2002

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By S. V. Ulianov, A. Y. Senchenko, A. A. Shvets, A. V. Aksenov

Development of an efficient technology to process complex ores containing gold and antimony as well as silver is described in the paper. The results from the testwork aimed at the valuables recovery by means of flotation are presented. A process sample of antimonite gold-bearing ore was studied in TOMS institute aiming at development of a technology to process such an ore with generation of antimony concentrate and sulphide gold-containing concentrate. Material composition study indicated that the ore included 5.3% of sulphides: arsenopyrite – 2.4%, pyrite -2.4%, and antimonite – 0.5%. Gold is present as an isomorphic dissemination in arsenopyrite. At sighter testing stage a direct selective flotation flowsheet was chosen to process the ore. Antimonite flotation was activated due to addition of lead nitrate. A single cleaning of a rougher flotation concentrate resulted in antinomy concentrate with 30% Sb content and 71% recovery. Au recovery into antimony concentrate did not exceed 1%. Sb flotation tailings were used to float the remaining sulphides and gold. The resulted sulphide concentrate was characterized by Au content of 20 g/t at about 80% recovery, arsenic content - 10% at ~80% recovery, and sulphur content - 18% at ~81% recovery. The sulphide concentrate can be forwarded to further processing aiming at gold recovery. Given that the concentrate is highly refractory it should be pretreated (bacterial or pressure oxidation, Albion process) prior to cyanidation in order to liberate gold from sulphides. The proposed technology allows one to solve the problem of precious metals recovery from antimonite ores.

Jan 1, 2016

By J. Muralha, L. Lamas

"Given the results of triaixial tests, regressions are commonly used to evaluate the parameters of failure criteria that model intact rock strength and to perform statistical inferences used to evaluate characteristic values defined in EC7. Statistical robustness of these inferences is affected if the basic hypothesis underlying regression are not met, namely homoscedasticity (constant variance of the errors). This paper presents analyses of 23 sets of triaxial tests, starting by the evaluation of the regression parameters of the Mohr-Coulomb linear criterion and of the Hoek-Brown non-linear criterion, followed by carrying several statistical tests to check the homoscedasticity null hypothesis of independence between the variance of intact rock strength and the confining stress.INTRODUCTIONThough rock engineering design is clearly included in the scope of Eurocode 7(EN1997-1), its implementation raised a wide discussion regarding the applicability of structural safety concepts to geotechnical design of construction works in or on rock masses. The basis of the limit state design philosophy adopted in EC7 is that, for each particular design situation, all the possible limit states for a structure, or part of it, shall be considered and that it shall be demonstrated that the likelihood of any limit state being exceeded is sufficiently small. Though EC7 allows the limit states to be verified by one or a combination of methods, use of calculations is by far the most used, and it is often confused with the EC7 itself. It involves using characteristic values of actions, ground properties and geometrical data, as well as obtaining their design values by the partial factor method.Characteristic value of a given material property is defined in Eurocode (EN 1990) as: “value of a material or product property having a prescribed probability of not being attained in a hypothetical unlimited test series. This value generally corresponds to a specified fractile of the assumed statistical distribution of the particular property of the material or product”. As regards the design value of a material or product property, according to the Eurocode it is a “value obtained by dividing the characteristic value by a partial factor”."

Jan 1, 2015

By Kazutoshi Haga, Ariunbolor Narankhuu, Ariuntuya Battsengel, Yasushi Watanabe, Altansukh Batnasan, Akita University

"Rare earth minerals are usually concentrated by flotation, magnetic or gravity separation methods to produce concentrates that are subsequently leached with hydrochloric (HCl), sulfuric acid (H2SO4) or nitric acid (HNO3). About 75 % REEs are lost in gypsum by-product when apatite is dissolved in H2SO4, whereas more than 80% of REE can be extracted from the apatite using HCl and HNO3 leaching processes, respectively. Therefore, the main aim of this study was to find an efficient process of dissolution of rare earth elements (REEs) from apatite ore by sulfuric acid solution due to its lower cost. In order to optimize the dissolution process, effects of different parameters, namely, concentration of H2SO4 (0.05 – 6 M), solid/liquid phase ratio (1:50 – 1:100), temperature (20 – 80 ºC), agitation speed (300 – 900 rpm), and leaching time (0.5 - 6 h) on the dissolution of REEs from apatite ore were examined in various intervals. The contents of main REEs in the apatite ore used in this study were (as % wt): 3 % La, 6 % Ce, 0.6 % Pr, 2.1 % Nd, 0.2 % Sm and 0.3 % Y. X-ray diffraction (XRD) analysis identified fluorapatite and phlogopite as main minerals in the ore. The results obtained from leaching experiments showed that more than 85% of REEs were dissolved from the apatite ore under the optimized conditions, which were: 1 M H2SO4, particle size of -150 + 100 µm, S:L phase ratio of 1:50, agitation speed of 500 rpm at 20 ºC for 1h. The XRD analysis revealed that main mineral compositions of the residues from 1M and 6 M H2SO4 leaching are gypsum (CaSO42H2O) and hemigypsum (CaSO40.5H2O), respectively.INTRODUCTIONThe term rare earth elements (REEs) denote the group of 17 chemically similar metallic elements consisting of the 15 lanthanides, plus yttrium (Y) and scandium (Sc) in the periodic table. These metallic elements are generally divided into two sub-groups; (1) the cerium sub-group, which is called “light rare earth elements” (LREEs), includes the elements from lanthanum (La) to europium (Eu), and (2) the yttrium (Y) sub-group elements, which are known as “heavy rare earth elements” (HREEs), are the remaining lanthanides from gadolinium (Gd) to lutetium (Lu) plus yttrium (Gupta and Krishnamurthy, 2005). The REEs occur together in the minerals due to their chemical and physical similarities, which cause problems of separating them from one another (Abreu and Morais, 2014). Although REEs are relatively abundant in the earth’s crust, they are typically dispersed and rarely occur in concentrated forms, making them economically challenging to obtain. There are a wide variety of rare earth minerals, however economic deposits of REEs in mining are bastnasite (La, Ce) FCO3, monazite (Ce, La, Y, Th) PO4, and xenotime YPO4 (Binnemans, 2013; Xie, et al, 2014). Due to the unique physical, chemical, catalytic, electrical, magnetic and optical properties of REEs, demand of these elements has increased dramatically with the advent of new technologies in electronics, communication, construction, energy and medicine (Jordens, et al, 2013). Since 1990, China has provided about 90 % of REEs worldwide. Japan and United States are the largest consumers of China’s REEs. In 2010, China announced to reduce REEs exports to Japan, as it tended to increase prices of REEs and to reduce a stable supply of REEs in the world market (Humphries, 2013). Therefore, there has been an increase in recent exploration activities intended to reveal new commercial sources of REEs and to bring them into production (Antico, et al, 1996). Apatite is an important host mineral for REEs in igneous and metamorphic rocks and can be used as an ore for those metals (Kanazawa and Kamitani, 2006). Apatite is also the main source of phosphate fertilizers and phosphoric acid (Habashi, 2013; Emsbo, 2015)."

Jan 1, 2016

By F. Khomamizadeh

In this study, deep cryogenic treatment was applied to A319 cast aluminum samples. Although the cryogenic treatment didn&apos;t have any significant effect on mechanical properties of the well degassed and fluxed samples, but the tensile strength of the samples containing a considerable amount of gas and shrinkage defects was improved surprisingly, This improvement was attributed to the strengthening of the a-aluminum matrix which slows down the propagation of the existing defects. There was no significant increase in the hardness after cryogenic treatment, The abrasion resistance of the alloy was improved after cryogenic treatment, by developing a homogeneous protector shield, composed of abrasive grains penetrated into the soft aluminum matrix and kept tight.

Jan 1, 2005

By J. Trojacek

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20th century. Many uranium deposits were discovered in the territory of the Czech Republic. Over a period of 50 years approximately, 110 000 tons of uranium in concentrate were produced. Different mining methods were developed and used. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere ? Straz pod Ralskem where both mining methods ? the underground mining and the acidic in-situ leaching ? were used. The extensive production of uranium led to widespread environmental impacts and contamination of groundwaters. Over the period of ?chemical? leaching of uranium (ca. 32 years), a total of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approximately 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers an area larger than 27 km2. The influenced volume of groundwater is more than 380 million m3. The total amount of dissolved SO4 2- is about 3.6 million tons. Approximately 0.5 % of the contamination is located in the Turonian aquifer. After 1990, a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. The objectives of the remedial activities are the followings : to restore the aquifer to a condition guaranteeing continuing usability of Turonian water of Northern Bohemia Cretaceous, to decommission boreholes and surface installations and to incorporate the surface of leaching fields into the ecosystems taking into account regional systems of ecological stability and urban plans. Nowadays four main remedial technological installations for reaching of these aims are used - the ?Station for Acid Solutions Liquidation No. One?, the ?Mother liquor reprocessing? station, the ?Neutralization and Decontamination Station NDS 6? and the ?Neutralization and Decontamination Station NDS 10?. Total capacity of this complex is sufficient to reach the target values of remedial parameters in 2037. The remediation action consists of: pumping of residual solution to the surface, separating uranium from the solution and reprocessing contaminants into commercially usable or ecologically storable products. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 1.5 billion EUR.

Aug 1, 2013

By C. H. Lau, I. T. Ng

Uniaxial Compressive Strength (UCS) of rocks is an important mechanical parameter for many civil engineering and rock engineering applications such as tunnel excavation, slope stability and foundation design. Macau is one of the world's fastest growing and most densely populated cities, many large and important infrastructures have been being continuously built using pile foundations which are designed to be supported by granitic bedrock. In Macau, the UCS of the granitic bedrock is required almost for every project involving pile foundations and is always measured directly from UCS test in the laboratory. However, direct measurement of UCS requires high quality rock core sample which is not only time-consuming and expensive but also requires high level of operating skill. In view of this fact, estimation of UCS using some empirical correlations will be more practical and efficient because they are relatively fast and economical compared to the direct measurement from UCS test. In the past, some empirical correlations had been established and widely used for estimating UCS of rocks in common engineering practice. However, it has been well recognized that the rock properties are generally varied with sites or geological regions in other words an empirical correlation developed from one region or one country may not be applicable for other regions or countries. Due to the reason that the empirical correlations for predicting UCS for granite are scarce in practice, in this study an extensive experimental program has been performed and a large database containing data such as UCS, Point Load Index (Is50), Schmidt Rebound Hardness (RL), porosity (?), water absorption (S), specific gravity (Gs) and dry density (?d) has been developed. An attempt has been made for developing a new empirical correlation for estimating the UCS of Macau granite. Accordingly, a comprehensive statistical analysis for correlating UCS with Is50, RL, ?, S, Gs and ?d has been performed and a local empirical relationship based on the developed database is proposed for obtaining reliable estimation of UCS for the granite of Macau. Finally, the performance of the proposed correlation is accessed by using another independent testing database developed in this study. It indicates that Is50, RL, ? and S have strong correlation with UCS whereas Gs, ?d have poor correlation with UCS. This study not only proposed a proper predictive empirical correlation for UCS determination for Macau granite but also provides detailed statistical information which is beneficial to engineers for obtaining better characterization of Macau granite.

Jan 1, 2015