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By W. S. Hargratt

THE present era of exploitation of the Little Long Lac and Sturgeon River areas commenced in 1925, when Beardmore Gold Mines started development of what is now the property of Northern Empire Mines. A shaft was sunk in 1927-28 and a very limited amount of underground work was carried out, following which the property was shut down. It remained idle until 1932, when Empire Star Mines, a Delaware Company, optioned the property. This Company formed the Northern Empire Mines Company, Limited, to operate the mine, and immediately instigated an aggressive programme of surface and underground development. By the summer of 1933, sufficient ore was indicated to justify the installation of a small mill. The decision was also reached to bring in electric power. A power-line was built from Hydro, the Ontario Power Commission's development on the Nipigon river, to the mine, a distance of approximately 50 miles. This work was entirely financed by Northern Empire Mines. Mill construction was commenced in October, 1933, and completed by March, 1934, thus making this mine the first producer in this district.

Jan 1, 1940

By P. J. Le Roux

"Mining worldwide and definitely in South Africa, is constantly under pressure to reduce its cost structure so as to sustain profitability. In underground gold mines where an open stope mining method is employed, dilution often has a significant effect on the viability of sustaining profits. Target Mine practices Open Stope mining Method and it was found that in some open stopes dilution was in excess of 10%, which has a significant impact on the sustainability of the mine.Dilution in excess of 10% can result in the reduction of the recovered grade from 5,5 to 4,5 grams per ton (g/t). The reduction of 1 g/t in recovered grade results in a potential loss of about ZAR21 Million per month bases on a gold price of ZAR240 000 per kilogram. Based on Life of Mine projections the potential loss of income could be as much as ZAR3,3 Billion. A reduction in dilution would have the opposite effect. There are a number of factors which affect dilution of which falls of ground in open stopes is a major contributor. The falls of ground can be attributed to a number of factors such as beam failure as a result of a larger than normal expected roof area (hydraulic radius too large), poor ground conditions, and poor blasting. The cost of damage to or loss of trackless equipment as a direct result of the falls of ground in open stopes, is very significant. The review of financial figures has indicated that this could be as high as ZAR491 million. This combined with the added cost of transport, hoisting, secondary blasting, milling and plant treatment costs of ZAR293 results in an estimated opportunity loss of ZAR784 million.Currently there is a significant amount of data available in the mining industry which could be effectively used to develop suitable back analysis techniques but to date this has not been used effectively. If dilution can have such an impact on current and future mining ventures then the optimization of back analyses for the prediction of dilution in open stoping could assist significantly in the reduction of dilution in massive open stopes. Rockmass classifications, geotechnical information, blast techniques, blast design, the stress strain environment and hydraulic radius all have an effect on, or play a role in the evaluation of dilution. Each of these factors will be taken into consideration to ultimately determine a measurable or calculated percentage of dilution in massive open stopes.The amount of overbreak in an open stope can be determined by subtracting the planned stope volume in m3 from the actual measured final stope volume in m3, which is obtained from the CMS (cavity monitoring system). This is in turn divided by the planned stope volume in m3 to determine the percentage overbreak. The CMS wireframe is imported into the geological model and its grade re-evaluated. From this the actual percentage dilution for this open stope can be determined. The dilution obtained can result in a major reduction of recovered grade for the open stope, but can also increase the recovered grade. The latter is normally the exception rather than the rule.When analysing data from Target mine the following was achieved:• Using 11 years of data a method of measuring and predicting the percentage dilution in open stoping was developed. This took into account rock mass quality, stress-strain state, and the hangingwall hydraulic radius (size of stope hangingwall exposed).• Implementation of this prediction method resulted in a reduction in falls of ground in open stopes. The benefit of this was a reduction in the damage to mechanised equipment resulting from less falls of ground which had a positive effect on the profit margins of the mine. As a direct result the recovered grade from the open stopes increased due to the reduction in the amount of dilution.• A design criterion, Dilution Stress-Strain Index (DSSI), was developed which allows the user to calculate, with certainty, the stability of the open stope and determine if m"

Jan 1, 2015

By D. V. Dorling, J. T. Bowker, J. A. Gianetto

Over the last few years, interest in the development and construction of large diameter, high pressure pipelines from the Mackenzie Delta in northern Canada and Alaska's North Slope has steadily increased as a result of the projected decline in recoverable natural gas from existing reserves in western Canada. The success of such enormous pipeline projects, which will require utilization of a strain-based design approach, is largely based on successful application of high strength line pipe steels, such as X80 and X100. To fully realize the economic benefits of high strength steels, welding processes and procedures must be developed to ensure that the requirements for high strength and good low temperature toughness are confidently obtainable in field girth welds used in the construction of such pipelines. This study aims to provide a better understanding of the factors that control weld metal strength and toughness for a series of mechanized X100 girth welds produced using a range of narrow-gap gas-metal arc welding procedures. The attainment of high yield strength (> 810 MPa) is considered to be an important target to ensure overmatching strength relative to the longitudinal property distribution of X100 line pipe steel. Some factors that have been considered in this evaluation include influences of gas-metal arc welding process variants (single and multi-wire) and changes in welding procedure specifications, including joint preparation. Key components of this work relate to the reliable measurement of weld metal strength variation through-thickness and as a function of position around the circumference of a given girth weld.

Jan 1, 2005

By Floyd Smith

Based on underground observations made in .the coal mines of the Dominion Coal Company Ltd., this paper deals with the stress phenomena in the approach roads and headways and in the gob areas associated with the longwall method of total extraction. The deformation of roadways during development and the deformation of roadways during the total extraction period is delineated and presented in graphical form .. Conclusions are made as to the feasibility of the introduction of the retreat method of longwall extraction in one of the colhenes. The importance of future studies are enumerated, especially. those pertaining to the determination .of the opti.m.um sizes of protective pillars and to increasing the efficiency of the current methods of artificial roadway support.

Jan 1, 1967

By C. D. Anderson, C. G. Anderson, P. R. Taylor

"Rare Earths have become critical for our energy and materials driven society. While primary production must ramp up to fill growing demands, the recycle of these strategic elements must also be initiated. This paper will outline the potentials of and metallurgical technologies employed for Rare Earths recycle from various secondary sources.INTRODUCTIONWhen investigating the recovery of rare earths from secondary sources it is necessary to understand the nature of the sources to be processed. As of 2009, the USGS reports the distribution of rare earths by end use, in decreasing order, was: chemical catalysts 22%, metallurgical applications and alloys 21%, petroleum refining catalysts 14%, automotive catalytic converters 13%, glass polishing and ceramics 9%, rare earth phosphors for computer monitors, lighting, televisions 8%, permanent magnets 7%, electronics 3%, and others 3% (USGS, 2011). Additionally, it is reported that the amount of recycling was quite small and consisted primarily of rare earth magnet scrap, although with the sharp increase in the price of rare earths, and the potential shortage in supply, focus in this area is continually growing. Thus, the opportunities, whether realistic or not, are extremely vast in the recycling of rare earth containing materials. The following subsections will present methods proposed for the recycling of rare earths based on the feed material type.RECYCLING OF RARE EARTH MAGNETSCurrently, investigations are ongoing in the area of recycling production scrap and end-of-life materials in the rare earth magnet industry. The following techniques illustrate potential methods for the recovery of rare earths from secondary RE magnet sources.Recycling of Rare Earth Magnet Sludge by Selective ChlorinationDuring the production of neodymium magnets, a by-product of production is the so called “magnetic sludge”. This by-product contains high amounts of neodymium, thus a process for the recovery of Nd has been proposed. In this process the Nd present is selectively chlorinated/distilled by the addition FeCl2 via the following reactions."

Jan 1, 2012

By L. Vinnett, I. Panire, J. Yianatos, F. Ruiz

"The effect of operating variables on the flotation performance at steady-state has been extensively used for modelling and simulation of separation processes. However, the dynamic characterization of key variables such as gas dispersion (Sauter mean diameter of bubbles, D32, and bubble surface area flux, SB) and froth discharge rate is rather scarce. In this paper, an experimental design allowed identifying the dynamic response of the flotation process in a laboratory scale flotation cell, using a two-phase system, airwater. The installation included automatic control for the superficial gas rate, JG, and the pulp level. Gas dispersion was evaluated in terms of the Sauter mean diameter of a bubble population and the bubble surface area flux, SB = 6·JG/D32. The D32 was measured using the McGill Bubble Size Analyzer (MBSA) along with a semiautomated algorithm. In addition, the froth discharge velocity was measured in real-time using a Visiofroth system. The control variables were the superficial gas rate and the frother concentration (Teefroth). The dynamic characterization of the flotation process is useful to design algorithms that allow the direct or indirect control of metallurgical variables such as flotation rate, concentrate grade and mineral recovery.INTRODUCTIONGas dispersion indicates the way the gas entering a flotation machine is dispersed throughout the volume of the equipment (Schwarz & Alexander, 2006). The gas dispersion is typically characterized in terms of the bubble size (dB), gas holdup (eG), superficial gas rate (JG), and bubble surface area flux (SB =6·JG/dB) (Finch et al., 2000). All these variables have significant impact on the metallurgical performance of flotation machines. For example, Perez-Garibay et al. (2014) investigated the effect of the particle size, bubble size distribution, superficial gas rate and collector dosage on the flotation performance, for the separation of a sphalerite mineral. The authors observed that recovery increased with the superficial gas rate ranging from JG = 0.04 to JG = 0.08 cm/s and also a maximum recovery was obtained for bubble size close to 300 µm. Gorain et al. (1998) reported a strong correlation between the flotation rate constant and the bubble surface area flux in a zinc cleaner circuit. Both variables were directly proportional at three froth depths in the range of hF =7 - 45 cm. Dobby & Finch (1986) incorporated the effect of the superficial gas rate and the bubble size on the flotation efficiency by means of a kinetic model for the rate constants. Yianatos & Contreras (2010) developed a model to estimate the carrying capacity in large flotation cells by including the bubble surface area flux."

Jan 1, 2016

By Larry A. Morris

The environmental impacts of industrial activities have become very serious concerns of the public over the past few decades. Not surprisingly, governments have responded with legislation and regulations to force industry to operate in a more environmentally responsible manner and, more recently, have prompted industry to initiate voluntary measures in response to specific environmental issues. The concept of Product Stewardship has evolved as a system or vehicle for the industrial sector to demonstrate an active concern about the environmental impact of their products, services and processes.

Jan 1, 1996

By R. O. Loutfy, J. C. Withers

"Titanium powder is produced from a small fraction of sieved sponge, HDH of sponge or gas blown from a melt produced billet. Ore from foreign sources is chlorinated in a very high temperature fluid bed to make TiCl4, then vacuum distilled purified and then reduced to sponge by Kroll processing. Domestic ores of ilmenite or perovskite can be carbothermically reduced to Ti2OC which can be chlorinated at low temperatures of 250–400°C to produce TiCl4 which can be electrolyzed in a fused salt to Ti powder, or the Ti2OC used as an anode in electrolysis to produce Ti powder. The electrolysis process can be operated continuously to produce Ti powder at a lower cost than Kroll processed sponge including produce control size powder. Electrolysis processing was scaled up and operated at the commercial demonstration stage on a continued basis that verifies the potential of a low cost process to produce Ti powder.INTRODUCTIONTitanium and alloys of titanium powder have been elevated to strategic status resulting from a focus of producing meltless titanium components as well as a feed for additive manufacturing processing. However, the high cost of titanium powder has limited wide scale implementation of using titanium powder as a feed to any process to produce titanium components. Titanium powder free of alloying is available as sponge fines from the Kroll process as illustrated in Figure 1. Titanium alloy powder is much more expensive, also illustrated in Figure 1 produced from an alloy ingot or mil product as the feed and then transformed into powder by one of several melt form processes which accounts for the high cost of titanium alloy powder at approximately $60–150/lb. Ton lots of titanium alloy powder (i.e. Ti-6Al-4V) from one source is quoted at $120/lb. in the U.S. It appears that alloy powder production cost by current processing is not sensitive to volume."

Jan 1, 2016

By A. Warczokand

The cleaning of copper smelting slag requires magnetite and cuprous oxide reduction. The slag reduction with coke, injected coal powder or bunker oil is strongly endothermic and requires heat generation by fuel combustion or the use of electric energy. The reduction of fayalitic slag with calcium carbide is slightly exothermic and the formed calcium silicate modifies the slag. Thus, the additional energy is required only for covering furnace heat losses. Results of crucible scale tests showed the rate of slag reduction approximately five times higher in comparison of the slag reduction with coke under the same conditions. It seems that the effect of exothermic reaction and slag modification with CaO at the reaction interface results in very high rate of slag reduction. Industrial scale tests carried out in the Anglo-American Chagres Smelter demonstrated the possibilities of effective reduction and cleaning of the slags from a flash smelter and Peirce-Smith converters in a Teniente Slag Cleaning Furnace. The slag reduction was carried out without any reductant or stirring gas injection, simply by calcium carbide charging through a furnace mouth, and was very fast.

Jan 1, 2007

By Bahaa Hussein

Considerable number of methods and procedures has been introduced for trending and progress reporting of engineering, procurement and construction projects. This paper introduces a novel method, designed to augment the set of indices for measuring schedule performance. The concept behind the developed method is to provide early warning by dynamically evaluating the schedule cumulative impact of construction projects. The proposed method is designed to highlight the gradual deterioration in schedule status resulting in a cumulative impact due to the aggregation of small delays encountered during the execution of non-critical activities, and can be used as an add-on utility to existing software systems that perform CPM scheduling. The proposed method is based on a developed formulation for quantification of the Schedule Compression Index, which takes into consideration the remaining project activities durations. The index is developed based on periodic comparisons of ?Current Schedules? and the project ?Baseline Schedule? using the summation of the remaining activities durations. A numerical example is presented to demonstrate the application and capabilities of the developed method. It is expected that the developed index together with other schedule performance indices would be of value to decision makers and members of project teams.

Aug 1, 2013

By P. Rosario

"Current industry practice for HPGR assessment and sizing relies on conducting a series of tests using pilot-scale machines with roll diameters of 700 mm to 1000 mm. Substantial amounts of sample are required for such pilot test programs, typically 1 to 10 tonnes of the sample is needed depending on the level of study and complexity of the resource. Collection of large quantities of representative samples during the early stage development is challenging and expensive, thus significantly hinders the HPGR technology from being incorporated into early-stage designs. A robust and reliable laboratory test is therefore needed to allow a fair consideration of HPGR for early stage projects. With support from the Canadian Mineral Industry Research Organization (CAMIRO), the NBK Institute of Mining Engineering at the University of British Columbia (UBC) developed a suite of Piston Press bench-scale tests that correlated to pilot and full scale HPGR operating information (Davaanyam, 2015; Davaanyam et al, 2015; McClintock, 2018). The Piston Press Tests (PPTs) are capable of assessing the HPGR technology at the scoping, pre-economic analysis (PEA), and pre-feasibility (PFS) stages of project development. This paper will briefly describe the theory on which the PPTs are based, and then presents a case study conducted for a copper deposit to show how the PPTs are being used for scoping and pre-feasibility level studies. Specifically, the PPTs are being used to provide information for preliminary sizing and selection of an HPGR and to assess the effect of ore variability on HPGR performance. The results are also applied to developing HPGR circuit designs and can be incorporated in simulation so that optimum design parameters can be selected.INTRODUCTION It is widely accepted that high pressure grinding rolls (HPGRs) offer a viable energy-efficient solution for the modern comminution flowsheet design. Table 1 summarizes selected examples of HPGR applications in the hard rock mining industry. The main benefits of HPGRs are energy savings which leads to lower operating costs, and its stable operating characteristics that can better cope with variations in ore hardness when compared to the conventional SAG mill-based comminution circuits."

Jan 1, 2019

By C. Overton, R. W. Nice

"With todays economic trials and tribulations we have all become deeply engaged in costs and cost cutting in our field of mineral processing. Grinding is one of the most expensive unit operations. The cost of grinding media is the most expensive item in grinding costs. Therefore, it is only reasonable to attack the cost-cutting area by trying to reduce the consumption of media. This introduces the field of autogenous or rock-on-rock grinding.Rock-on-rock grinding is not new to us. It has been known for many decades;The South Africans used pebble grinding in the '20's for gold.Mr. B. Crocker was prompted for the same reasons to introduce pebble grinding at Lakeshore Mines in Kirkland Lake during the last war.The Buffalo Anchorite used beach pebbles in grinding prior to the war.Autogenous and semi-autogenous grinding is used quite successfully in the iron ore field. Base metals have their examples in Australia at Caba, in Africa at Komato and in Sweden at Aitik.Recently three mills in British Columbia and one in Arizona started with autogenous mills in their circuits. One was originally conceived to utilize a modified autogenous grind with a crusher in the circuit. All except the same mill had contingency plans for converting to semi-autogenous. All four mills have since converted to the semi-autogenous mode. These are Island Copper, Lornex, and Similkameen in B.C. and Pima Mining in Arizona."

Jan 1, 1975

By D. J. Lloyd

"Bending is involved in the forming of many sheet parts and it is important to understand the phenomena involved. In this paper the basic equations describing bending on a global scale are compared with strain measurements of bent sheet. The development of strain on a local, microstructural scale is also investigated, as is the general aspects of plasticity and the failure process. It is shown that the global equations can be used to estimate the strains involved and the local strains can be attributed to various aspects of the plasticity. The bendability can be related to the fracture strain of the sheet and the ability of a sheet alloy to accommodate the necessary bending to form the part can be assessed.INTRODUCTION The ability of a sheet alloy to undergo bending without failure is an important capability in the forming of many parts and it is useful to be able to assess the bendability of an alloy during its development. The basic mechanics of bending were developed in the 1950s (Lubhan & Sachs, 1950; Hoffman & Sachs, 1953). When a sheet is bent the upper bend surface is in tension, the lower surface in compression and at some point within the sheet there is a plane of zero strain which is referred to as the neutral axis. For sheet exhibiting limited plasticity the neutral axis is static and occurs at the mid-point of the sheet thickness but for sheet exhibiting extensive plasticity the neutral axis progresses deeper in to the sheet as bending progresses. This results in two expressions for the maximum strain at the upper bend surface depending on the motion of the neutral axis. For Al alloys such as AA6111, AA6016 and the like extensive plasticity occurs and the neutral axis is expected to move during bending. However, very few studies have examined how the neutral axis motion and the strains develop, compared with the mechanics analysis. Geist and Parker (1984) used hardness measurements to investigate neutral axis motion but these experiments did not have the resolution necessary to compare the results with experiment but did indicate neutral axis motion. To understand the nature of plasticity and failure during bending it is important to know the extent of neutral axis motion, the scale of strain gradients developed through the sheet and the maximum strains occurring at the bend surface, finally comparing experimental results with the theoretical predictions. The influence of microstructure on the evolution of strain and failure can then be considered in the context of these parameters. Recently, bending in some automotive Al alloys has been reported mainly from the microstructural perspective (Lloyd, 2000, Lloyd et al., 2002, Mattei et al., 2013) and FEM studies have also investigated the development of plasticity under bending, demonstrating the tendency for strain localization (Becker, 1992, Shi et al., 2014)."

Jan 1, 2018

By John Blackshaw

NEW sources of supply of tungsten concentrates became necessary when the flow from the Far East was blocked in 1942. In Canada, one source has been noted in the workings of the Hollinger mine at Timmins, Ontario. For many years, a small amount of scheelite had been removed with the gold ore, and an appreciable tonnage of scheelite still remained in the mine. At the request of the Dominion Government, a plant was built to recover this scheelite in the form of a concentrate that could be used by the alloy-steel industry without further preparation. The plant began operating early in March, 1942, and a small tonnage of ore, carrying scheelite and gold values, has been treated daily since then. The possibility of recovering the scheelite had been considered on several previous occasions. Each time the proposal had been given up because the total profits from the enterprise were estimated to be insufficient to repay the capital cost of building the recovery plant. At the time the plant was built, additional information had been gathered about the tonnage and grade of the scheelite ore in the mine, and several thousand tons of ore grading higher than 0. 25 per cent WO3 (tungstic trioxide) were known to be available.

Jan 1, 1943

By V. Thangadurai

The critical problems in commercialization of the present solid oxide fuel cells (SOFCs) and useful electrical and physical properties of IT-SOFCs electrolytes are discussed briefly. The conductivity behavior of the perovskite-type and perovskite-related structure metal oxides are summarized. Perovskite-type La0.9Sr0.10ao.8Mgo.203_8 (LSGM) exhibits high ionic conductivity of 0.1 S/cm at 800 °C. In order to improve the electrical conductivity of LSGM and the In analogue of LSGM, substitutions have been made at the A-and B-sites. Substitution of trivalent La3+ by isovalent Pr3+ in LSGM and La09Sro ilno.sMgo.202.85 (LSIM), yield new mixed conductors. Among the investigated compounds in the present study, La0APro.4Sro.21no sMgo.2028 exhibits the highest total electrical conductivity of 3.2 x 10-5 S/cm at 200 °C in air with the lowest activation energy of 0.44 eV (200-700 °C). LSIM and Pr-substituted LSGM and LSIM perovskites show p-type electronic conductivity in the oxygen partial pressure range 10-5 ? 0.21 atm at 750 °C. The perovskite-type solid solution SrSn1-xFex03 exhibits compositionally driven phase transitions. For example, compound of the composition x = 0 to 0.3 crystallizes in an orthorhombic GdFeO3-like perovskite structure, where as that of x = 0.4-0.9 crystallizes in simple cubic SrTiO3-like, and that of x = 1 in orthorhombic structure. The electrical conductivity of SrSn1_xFex03 increases with the increasing Fe content and reaches a value of about 10-1 S/cm at 25 °C in air for x = 1. Compounds with low Fe content exhibit both ionic and electronic conductivity, while the higher Fe content 0.5) perovskites are electronic conductors over a wide range of oxygen partial pressure of 10-22? 0.21 atm at 750 °C.

Jan 1, 2005

By M. A. Cawley, J. W. Jordan

"IntroductionTHE ORE PILLARS in the lower ""A"" ore body of Waite Amulet Mines, Limited, can be divided into two groups, those mined in the open by sub-level blast-hole methods, and those to be mined .against coarse rock fill. Of the three pillars in the last group one has been mined and is dealt with in this paper. The method of mining pillars against coarse rock fill was suggested by the late Dr. Oliver Hall, who was Consulting Engineer for the Company when recovery of No. 2 East pillar was being planned.HistoryThe Waite Amulet mine is in northwestern Quebec, nine miles north of the town of Noranda. The property is approximately three miles long by one mile wide. The present Company, which was formed by the amalgamation of Amulet Mines, Limited, and Waite Ackerman-Montgomery Mines, Limited, commenced operations in the summer of 1937. In the fall of 1939 a new .flotation mill was erected with a capacity of 1,200 tons per day, which was increased to 1,800 tons per day in 1943. The mill is presently operated at 1,400 tons per day.To date, seven orebodies have been found, the major ones being Lower A, East Waite, and Waite. Three separate concentrates are produced, copper, zinc, and pyrite. Total tonnage mined to the end of 1954 from all orebodies has been 7,340,000 tons, which averaged 4.6 per cent copper, 5.3 per cent zinc, and 0.037 oz. gold and 1.27 oz. silver per ton."

Jan 1, 1955

By D. Verhulst

The Altair process digests ilmenite concentrate in high-chloride HC1 solution, with complete dissolution of titanium and iron. The Fe(III) ions are reduced to the ferrous form, and the solution is cooled to produce crystalline ferrous chloride. Titanium is transferred by solvent extraction into a purified, concentrated Ti stream, which is spray-hydrolyzed to produce TiO2 hydrate. The hydrate is further calcined with additives to generate a high-quality pigment. All the chloride streams are recycled. In the original flowsheet, the iron chloride is pyrohydrolyzed by spray roasting to regenerate 18% HCl, which is subsequently converted to HC1 gas and water by pressure-swing distillation. A modified flowsheet includes an alternative to iron chloride spray roasting, producing more concentrated HCl and decreasing the amount of solution to be distilled. Improvements in digestion, solvent extraction and final pigment production are also introduced. A 100 t/y pilot plant is being built and will test the new concepts and confirm the overall water, acid and impurity balances of the process.

Jan 1, 2006

By E. Fritz

This paper reviews the history, developments and 10 milestones of the oxygen steelmaking processes, with a special focus on conventional autothermic converters, high-speed converters with a blowing rate up to 5 m3n/t min and allothermic converters with coal addition, post combustion and the possibility to increase the scrap rate up to 50%. Related operating results are introduced. A new process route, which is based on hot metal and chromium ore, is outlined. The cost advantage for the production of 304 stainless steel grade is higher than 100 USS/t. The synthesis of EAF and oxygen converter steelmaking, a comparison of decarburization rates, refining combustion burners for optimized oxygen-management in EAF and an example for a large advanced EAF are outlined. Possibilities of flexible steelmaking and the growth and outlook of worldwide oxygen steelmaking are described.

Jan 1, 2004

By Yi Yang, Mark Zoback

"We report laboratory studies of the time-dependent deformation of core samples from four different formations in the Williston Basin - the Lodgepole formation, the Middle and Lower Bakken formations and Three Forks formation. The laboratory tests reveal varying amounts of viscoplastic deformation in response to applied differential stress. The time-dependent deformation is generally greater in rocks with higher clay and organic content, and can be described by a power-law function. Because the magnitude of the creep strain is linearly proportional to the applied differential stress, we can utilize viscoelastic theory and geophysical logs to estimate the degree to which tectonic stress is affected by viscoplastic stress relaxation. We suggest that viscoplastic stress relaxation results in the Upper and Lower Bakken Formations act as frac barriers during hydraulic fracture stimulation in the Middle Bakken, but the Lodgepole and the Three Forks Formations are not frac barriers.INTRODUCTIONHorizontal drilling and multi-stage hydraulic fracturing in shale reservoirs are critical for successful exploitation of ultra-low permeability shale gas, tight gas and shale oil reservoirs. Characterization of the mechanical properties of the reservoir rocks is essential to understanding the behavior of rocks during drilling and completion. Previous laboratory studies have shown that the timedependent deformation in clay-rich shales can be characterized as linear/viscoelastic deformation (Chang et al., 1997; Hagin and Zoback, 2004a, b; Sone and Zoback, 2013b, 2013c). Sone and Zoback (2013c) showed that laboratory measurements of time-dependent deformation in various gas shale reservoir rocks, and demonstrated that the viscoplastic deformation of these rocks can be characterized by a power-law function. They interpreted the results in the framework of linear viscoelastic theory to quantitatively assess the geomechanical effect of viscous time-dependent deformation over engineering and geological time scales. (Sone and Zoback, 2014) further extended the theory and proposed a viscous relaxation model that can be applied to predict the continuous differential stress magnitude using the geophysical logs. They tested the validity of their model by comparing the stress prediction with the occurrence of drilling induced tensile fractures (DITFs) and the vertical hydraulic fracture penetration observed from microseismicity."

Jan 1, 2015

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016