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This paper discusses the implementation and potential limitations of the method for estimating sampling and analytical errors of multiple source mine output blended into a shipping product, described by Everett and Ziegelaar (2010). The practice of quality measurement varies between iron ore miners. The common objective is to monitor effective resource utilisation and control of product quality to customers. A flow diagram is given presenting the various options used by iron ore mine operators and the merits of the different options are discussed.

Mar 1, 2010

By T Leidich, M Van Zyl, H Lacy

Mining ‘as usual’, until the most recent decades has resulted in limited landform planning and a general lack of mine waste landform design. Material characterisation, mine planning and dedicated professionals undertaking these tasks were rarely available or in place at the majority of mines. This has led to landform instability, erosion, sediment and poor quality water emanating from mine landforms. In many cases rehabilitation and reclamation failed and these sites have ‘landform features’ that are difficult to relinquish or leave and have little or no apparent land use. In many cases mined landscapes around the world have resulted in a less functional and degraded environment, with deleterious impacts on surrounding ecosystems.This situation is now slowly being addressed, as global companies, academics and practitioners and their organisations have started to exploit the ideas from an integration of earth sciences and mining through the application of planning software dedicated to the design of landforms.This development has had its genesis primarily in the United States. We suggest that process has been driven, in recent decades, by the application of resources in response to the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), (USA Congress 11 December 1980) and other mine reclamation legislation enacted by federal and states regulators in the USA. The combining impact has seen a huge transfer of capital back from the public purse and ‘potentially responsible parties’, into abandoned mines to affect control, remediation, and reclamation/rehabilitation of those mines.Given this investment in rehabilitation and reclamation, people engaging in the business of landform planning have had the opportunity to address landform reclamation of historic and active sites. The skills of engineers and scientists with improved technology, waste rock characterisation and modelling tools have been combined resulting in the evolution of landform design and in mine planning of active mines. This has delivered cost-effective, sustainable mine closure designs for over 30 years. Integration of mine design with an understanding of geomorphic principals and the natural landscape, coupled with waste and soil characterisation, yield a positive result. Recently work has been applied across large and small-scale projects by companies. As these processes develop, ideas and concepts are evolving that active mines, or mines in the early planning stages, could use to help reduce double handling, and in the long run reduce overall project and closure costs, more effectively attain the desired final land use, and enhance the industry’s reputation and licence to operate.CITATION:Leidich, T,?Lacy, H?and Van?Zyl,?M,?2014. Application of design concepts and engineering controls necessary to deliver well-designed and rehabilitated landforms, in Proceedings Life-of-Mine 2014 , pp 55–66 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

Exploring long-term future possibilities for your business and methods for achieving them are critical functions of leadership. More than ever, strategic initiatives today have to be planned and delivered in an environment of disruptive change û driven by shifting business or regulatory imperatives, new technologies and global economic change, and diverse stakeholder interests. The notion of The Future as a single inevitable outcome is obsolete. There are many possible futures. This paper explains an innovative process û known as scenario planning û to help executives in the construction and testing of longer-term strategies to deal with uncertainty.

Jan 1, 2006

By M Spagnolo, M Ashley, D, L Reemeyer

PasmincoÆs Century Concentrator in North West Queensland commenced operations in November 1999. The nameplate production capacity of 500 000 tpa of zinc metal production in concentrate was achieved in August 2002. Completion of the production ramp up was successful due to the culmination of a number of initiatives throughout 2001 and 2002. Mine to mill interaction to understand and eliminate head grade related bottlenecks affecting Concentrator production and reduce feed variation. Grinding circuit process development û operating and process control strategies to improve stability and reduce grind size to support zinc recovery. Pumping upgrades to control spillage in ultrafine zinc flotation Low density zinc flotation strategy û to improve silica-sphalerite separation to improve zinc recovery while maintaining acceptable silica in final concentrate. Flotation circuit process development û froth crowders, froth cameras and reagent control strategies to improve primary zinc flotation performance. Review and implementation of longer campaigns between planned shutdowns to improve availability. Team reorganisation û to improve setting and implementation of metallurgical strategies. This paper describes these initiatives and their contribution in achieving the production target. It also notes the ball mill motor failures that delayed the successful achievement of the ramp up, and CenturyÆs response to minimise the production impact. The paper also outlines the capital improvement program that was implemented to improve zinc recovery to design 82.5 per cent recovery once the production rate had been achieved.

Jan 1, 2003

By R A. Pakhomov, L V. Krupnov, P V. Malakhov, I M. Dymov

The article presents results of thermodynamic calculations and laboratory studies, focusing on the cobalt behaviour during oxidative smelting of copper-nickel mattes. The compositions of the studied solutions are related to the products formed during the second stage of the converting process of copper-nickel matte at the Nadezhdinsky Metallurgical Plant (NMP) of MMC Norilsk Nickel company. These sulfide products typically contain from 1.5 to 12 wt per cent of iron. The obtained experimental results and thermodynamic calculations indicate that adjusting the CaO ratio to increase the proportion of CaO or complete replacement of SiO2 with fluxes containing CaO leads to a significant increase in cobalt recovery rates in the matte phase (with an iron concentration of 2.5 wt per cent) raising them from 30 per cent to 45 per cent. Meanwhile, the recovery rates of copper and nickel remain constant.

Aug 21, 2024

By B Rusk, L Corriveau, P Emsbo, R P. Xavier

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Porphyry-Cu (Mo-Au) deposits and iron oxide-copper-gold (IOCG) deposits are both characterised by the presence of abundant halite-saturated fluid inclusions that reflect the circulation of hyper-saline hydrothermal brines. While it is widely accepted that brines involved in the formation of porphyry copper deposits derive from unmixing of moderate-salinity, intermediate-density fluids that exsolve from crystallising magmas, the source of brines that form IOCG deposits remains enigmatic and intensely debated. In this extended abstract, we summarise the fluid inclusion characteristics of both deposit types and present trace element compositional data for halite-saturated fluid inclusions from both porphyry copper deposits and IOCG deposits from around the world.While both deposit types typically contain halite-saturated fluid inclusions, vapour-rich fluid inclusions in IOCG deposits are less common than in porphyry deposits and evidence for fluid immiscibility is rare. IOCG deposits also typically lack intermediate-density fluid inclusions that characterise the deeper quartz-rich veins in many porphyry deposits. Many IOCG deposits contain CO2-only fluid inclusions, a type of fluid not observed in porphyry Cu deposits.Our fluid inclusion compositional data show that most porphyry Cu (Mo-Au)-related brines are dominated by Na, K and Fe and contain elevated concentrations of Ca, Cu, Pb, Zn and Mn up to around the one per cent level. On the other hand, IOCG brines are Na-Ca-Fe-dominated and typically contain far less Cu, Mn and Zn than porphyry brines. In addition to Ca, these fluids are also strongly enriched in Ba and Sr relative to porphyry-related brines. Such compositions are consistent with extensive fluid-rock interaction and/or an evolved sea water contribution to IOCG brines.A sea water or basinal brine source for IOCG brines is further supported by bromine concentrations that are much higher than is characteristic for porphyry-related brines. Porphyry brines have Cl/Br molar ratios of between 800 and 3000, which is characteristic of primary magmatic brines, whereas the Cl/Br composition of IOCG brines is more variable. For example, Na/Cl/Br ratios of most IOCG deposits in the world-class Carajás district fall on or near the sea water evaporation curve (most Cl/Br molar ratios are between 200 and 1000) and are diagnostic of sedimentary bittern brines. A few of the deposits in this district also show evidence of the input of subordinate amounts of magmatic brine. At Ernest Henry, in the Cloncurry district of Australia, most Cl/Br ratios plot close to the sea water evaporation curve, but Cl/Br ratios of up to ~5000 in several samples suggest the input of lesser amounts of magmatic fluids, and possibly evaporite-dissolution-derived fluids. Taken together with geologic constraints, these data strongly suggest that porphyry-type deposits form from the circulation of dominantly magmatic fluids, while IOCG deposits form from large-scale circulation of high-salinity fluids sourced dominantly from sedimentary basins with variable input of magmatic volatiles.CITATION:Rusk, B, Emsbo, P, Xavier, R P, Corriveau, L, Oliver, N and Zhang, D, 2015. A comparison of fluid origins and compositions in iron oxide-copper-gold and porphyry-Cu (Mo-Au) deposits , in Proceedings PACRIM 2015 Congress, pp 271–280 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By J G. Shellnutt, Y Iizuka, T W-Y Hsia, T-C Liu

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The formation of magmatic oxide ore deposits hosted in chemically-evolved layered gabbroic intrusions is attributed to a variety of petrological processes, but there is little to no consensus on the general applicability of each model. Complicating the matter further is that many layered gabbroic intrusions are spatially and temporally associated with alkaline A-type granites, suggesting that there is a petrogenetic relationship between the two types of chemically different rocks. Our experimental results show that petrological modelling using a starting composition of high-Ti basalt from the Emeishan large igneous province can produce evolved silicic liquids that resemble the compositions of microgranular enclaves from the syenitic unit of the bimodal, oxide ore-bearing Baima igneous complex. The experimental results confirm that bimodal gabbro-granitoid complexes can form from a common parental magma and that early crystallisation of Ti-rich magnetite can explain the formation of the oxide ore deposits in the lower parts of the layered gabbroic intrusions. We conclude that crystallisation of a typical high-Ti basaltic parental magma can produce world-class giant magmatic oxide ore deposits and that the occurrence of some alkaline granites may be an indicator of their presence.CITATION:Shellnutt, J G, Hsia, T W-Y, Liu, T-C and Iizuka, Y, 2015. Cogenetic formation of the peralkaline syenite and oxide ore-bearing layered gabbroic intrusion of the Baima igneous complex, Emeishan large igneous province, south-west China , in Proceedings PACRIM 2015 Congress, pp 317–324 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By P Cooper

Continuous improvement using six sigma methodologies commonly follows the DMAIC methodology of define, measure, analyse, improve and control. A key requirement in the use of this approach is to ensure that data is trusted, validated and contextual. In today’s production environments it is common to find disparate technology comprising the system architecture and highly customised interfaces between the various technology layers. This complexity often leads to inaccurate data presented at the operations management layer or worse, data that is not trusted. Identifying defects and making corrective actions cannot be efficiently carried out unless trusteddata can be easily obtained with a production context. It is also common to find that disparate systems of this nature present information in multiple ways and through multiple presentation systems. This paper discusses how the use of web-based technologies in an integrated technology stack can aid the accessibility, accuracy and trust of data used in decision-making and also how a unified visualisation environment can lead to greater operator efficiency.

Jul 11, 2011

By S A. Campbell

There has been a reduction of coal production in the United States due to environmental pressure and the increased use of natural gas. This reduction will require coal producers and consumers to make decisions on whether to sample more to verify contract quality or sample less in an effort to cut costs.CITATION:Campbell, S A, 2014. The shrinking coal market in the US – sample more or sample less?, in Proceedings Sampling 2014 , pp 3–6 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By B Murphy

Seeking to reduce the likelihood of uncontrolled personnel entry into the operating footprint of a dragline, Coronado Global Resources initiated a review of proximity detection systems currently available and equipment interactions in and around dragline operational areas. At the time of the assessment, there were no established personnel proximity detection systems in compliance with functional safety standards for large machinery in Australia. Our primary objective was to guarantee a functionally safe outcome, particularly by implementing a performance-level-rated system in accordance with AS4024 (Safety of Machinery series of Australian Standards). Applying appropriate detection technologies, the goal was to reduce the residual operating risk for machine-to-machine and machine-to-personnel interactions. A comprehensive analysis of available or in-development technologies was conducted, and a layered approach (demonstrated in Figure 1) was adopted to achieve the desired risk reduction by segregating the sensing zones into distinct areas using diverse and disparate technologies consisting of radar (short); light detection and ranging (LiDAR) (medium); and optical (long). To address the potential limitations of each technology, overlapping layered sensing zones were designed. With LIDAR and optical using two distinct artificial intelligence (AI) systems to classify detections, these were specifically trained to handle the unique environments of a mining operation.

Sep 1, 2024

By Y Chung, B Choi, H Lee

Numerous studies have explored refractory corrosion in the presence of slag and/or metal, utilising the Finger Rotating Test (FRT). Recent experimental results revealed that corrosion initially increased with rising rotation velocity but was then suppressed above a critical rotating speed, under conditions involving a two-liquid solution of slag and molten steel. This phenomenon indicated that the liquid/liquid interface movement occurred during spindle rotor. However, understanding of the phenomenon, known as the rod climbing effect, remains inadequate in the case involving slag, molten steel and refractories. To gain deeper insights, a simulation experiment was conducted on the phenomenon using silicon oil/water and the phenomenon was analysed using computerised simulation software (Ansys Fluent). Experimental modelling demonstrated that interfacial movement occurs even at low rotation velocity, as low as 200 rev/min, when the viscosity of silicone oil is at 100 cP. Computational analysis utilising the Volume of Fluid (VOF) method and a realisable k-ε turbulence model elucidated that interface elevation during rotor rotation arises due to viscosity disparities between the two fluids. Furthermore, this movement is more pronounced when the viscosity difference is lower. Additionally, the study findings suggest that higher density differences between two liquids suppress the phenomenon of interface movement.

Jun 19, 2024

By M Alston

Many organisations struggle to yield meaningful outcomes from incident investigations. This paper will demonstrate that we can discover systemic issues by rethinking the ‘Why’ and ‘How’ of investigations, fostering genuine risk reduction. Key points: 1. Shift from ‘prevent recurrence’ to ‘learn and reduce risk’: conventional investigations focus narrowly on recurrence prevention, resulting in narrowly focused investigations with limited ability to identify and reduce organisational risk. Redirecting our objective to learning and improvement opens avenues for broader risk mitigation. 2. Understanding daily work for risk insights: recognise that work is not always completed in full compliance with procedures. Workers will adapt how they complete tasks influenced by the conditions and management systems that exist every day. Understanding the conditions and systems affecting everyday work is vital for uncovering systemic risks. 3. Unearth systemic issues through in-depth exploration: many investigations address surface concerns such as lack of training, incorrect procedures, equipment not being maintained, and missing overarching organisational risks. Systemic, organisation-wide risks are not identified. To discover these systemic issues and create shared learnings, investigators must question management systems, including resourcing, planning and risk management. 4. Design actions for safe failure: common actions like discipline and training fall short and do not reduce risk. Resilience emerges from well-designed controls. Incorporate planning, better resources, interlocks, and guarding to bridge the gap between task execution and risk. 5. Investigation Reports as a Business Case: Investigation reports should not simply state historical information regarding an incident. They are to facilitate decision-making and be presented as a business case to drive change. Organisations can move beyond localised risk and ineffective administrative actions by changing investigation objectives and methods. They can facilitate learning, understand daily work intricacies, identify systemic issues, and enhance the capacity for safety, driving lasting risk reduction.

Apr 16, 2024

By B Yang, L Wang, C Y. Ng

Flotation process intensification is often achieved through changing chemical reagent scheme or flotation machine or both, which likely brings a hefty burden to the flotation plants in terms of capital or operating expenditure. A novel approach to flotation process intensification is the use of acoustic sound, which has been demonstrated to be effective in improving the flotation of various mineral systems with different type of flotation cells. This approach was based on the dynamic stabilisation effect of acoustic sound on the flotation froth. The present work aims to understand the influence of various experimental conditions on the effectiveness of the approach. First, the effects of sound frequency and amplitude were studied with column flotation of silica particles. Results showed that the flotation performance was improved only within a certain range of frequencies and above certain amplitude. The study was then extended to the mechanical flotation of quartz particles with various size ranges and at two solids concentrations. With sound, the recoveries of different size fractions within the range of 20–212 μm were all increased. In particular, the recovery of 150–212 µm particles was increased from 0 per cent to approximately 25 per cent, demonstrating the potential for extending the upper limit of particle size in flotation by using acoustic sound. Furthermore, mechanical flotation of chalcopyrite particles at various collector dosages (50–150 g/t) was carried out with and without sound. Results showed that the increment of the final flotation recovery was increased with sound at different collector dosages. Overall, acoustic sound has the potential to be used as an effective and versatile method for flotation process intensification.

Aug 24, 2022

By A M. Ebbels

"Underground mine scheduling decision-making has been based on production requirements, equipment productivities and the mine planner’s instincts on the best scheduling strategy for the mine to optimise the net present value (NPV) of a project.In the last few years, innovative software has been developed to optimise underground schedules based on NPV. The schedule optimisation tool (SOT) allows the user to set up scenarios based on grade, metal content, capital and operating costs.This paper discusses the results of two case studies undertaken using the SOT software to optimise the NPV of the projects.In each case study, the SOT software has been applied in two ways:using the original mine planner’s scenario and determining whether the NPV could be improved by changing resource capacitieschanging the scheduling goals to determine whether a different mining strategy would have a better NPV outcome.The outcomes of the case studies demonstrate that the mine layout and design were contributing factors to the overall improvement of the NPV and that SOT has a more noticeable impact on the NPV of projects where less sequence constraints are required, such as geotechnical sequencing and access development.CITATION:Ebbels, A M, 2016. Optimising underground mining strategies, in Proceedings Project Evaluation 2016, pp 60–65 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 8, 2016

By T Baumgartl, A Costine, B Boshrouyeh, M Edraki

In mineral processing, the management of tailings may become increasingly more challenging with a change of ore type and the quality of water used in the plant. This, in turn, may affect the overall costs of the operation and water usage and, in the long-term, pose challenges for mine closure and rehabilitation. Depending on the applied treatment technique, the short and long-term properties of tailings are largely determined by the fine particles. Most clay materials and ultrafine particles exist in tailings from oil sands, coalmines and base metals, bringing about challenges in dewatering performance. Moreover, given the growing concern for water scarcity, the minerals industry is increasingly turning towards the use of saline water, which poses yet another challenge for tailings management. The high salt content alters the behaviour of clay particles, making dewatering a more complex process than in freshwater systems (Boshrouyeh Ghandashtani et al, 2022; Costine et al, 2018). High-density techniques for tailings management have been used for several years in the mineral industry. In this regard, one of the novel and promising dewatering methods is in-pipe or inline flocculation, where the polymer is added at high dosages to thickener underflows, giving additional (likely denser) aggregation, releasing more water on deposition compared to low solids thickening. Previous research in the field of flocculation has primarily focused on the process of flocculation itself, specifically the settling rate and size of aggregates, rather than the long-term impacts of the produced tailings materials (Liu et al, 2020; Jeldres et al, 2017). This is particularly true for the novel method of this technology, where polymer is added to the thickener underflow. Furthermore, these studies have used small-scale set-ups using buckets/beakers, plungers and mechanical stirrers for the flocculation process. Unfortunately, these methods lack the necessary control over the properties of the treated tailings, which can lead to irreproducible mixing and dispersion of viscous polymer solutions (Fawell, Costine and Grabsch, 2015). Consequently, a system that can work with a wide range of operational conditions for high-solid tailings material is essential for reliable and reproducible results. The objectives of this study were to determine the effect of different type of polymers in the presence of monovalent and divalent salts on the inline flocculation of artificial tailings. The next step was to evaluate the impact of high-dosage polymer addition on geotechnical properties such as settling rate, consolidated density, rate of consolidation and the hydraulic conductivity of tailings. In addition, this research aimed to fill a knowledge gap and investigate the feasibility of using polymer-treated tailing in removing the copper ions and then quantify the performance of produced aggregates under time-dependent processes.

Aug 2, 2023

By M Jahani, M Taji

For suitable production planning in an open pit mine, and also to carry out the optimisation process during the mining production cycle, prediction of fragment size distribution is required prior to carrying out the blasting operation. For this purpose, many prediction models, such as empirical models, were presented. The proficiency of these models differs in various conditions and mines. Therefore, in this paper the most important models, including SveDeFo, Kuz-Ram, CZM, Modified Kuz-Ram in 2005, Kuznestsov-Cunningham-Ouchterlony (KCO) and also Gheibie et al, were examined by the information of 20 blasts in Gol-Gohar iron ore mine. Fourteen images were taken on average for each blast. For image processing analysis Split-Desktop software was used. After examination, it was understood that none of the available empirical fragmentation models had presented acceptable performance, except the Kuz-Ram model for magnetite ore, which had somewhat acceptable results. However, this model for blasting patterns in hematite presented unsuitable results. Examination and comparison of two important distribution functions, Rosin-Rammler and Swebrec, were carried out and it was observed that the performance of Swebrec for fines was far better than Rosin-Rammler. This result for the upper part of fragment size distribution curve, coarse, is the reverse.CITATION:Jahani, M and Taji, M, 2015. Comparison of empirical fragmentation models at the Gol-Gohar iron ore mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 707–714 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

The cloud transform simulation is a technique used to generate realisations of correlated attributes. The principle of this technique is to partition the scatter diagram between the input attributes into several interval classes and derive for each class a cumulative distribution function (CDF) using only the data pairs of the scatter diagram in that class. The simulation then proceeds like a traditional Monte Carlo simulation but using the derived CDF in each class.The cloud transform simulation has the advantage of being a simple and fast technique that is able to reproduce the uncertainty in the relationship between the two input attributes regardless of whether the relationship is linear or not. However, the technique has three major drawbacks. First, the number of classes has an impact on final simulated results and there is not a robust approach to define such number. Second, simulated results exhibit some saw tooth variations that are unrealistic and third the reproduction of the spatial continuity of the simulated attribute is not guaranteed.This paper presents the use of the quantile regression approach in order to overcome the first two disadvantages of the cloud transform simulation. Details of the technique and how it can be coupled with the cloud transform simulation are presented along with a real case study.

Sep 26, 2011

By A Satyanaga, H Rahardjo, K G. Mercer

The soil-water characteristic curve (SWCC) is one of the most essential soil properties in unsaturated soil mechanics. The water flow and storage characteristics of an unsaturated soil are closely related to the amount of water contained in the pores and the negative pore-water pressure in the soil. These are both in turn, related to the particle-size distribution and the plasticity of the soil. The SWCC is obtained by laboratory testing which is difficult to perform, costly and time consuming. There is a significant advantage in establishing typical SWCC envelopes for different soil types from a geotechnical design and analysis viewpoint. This paper presents some of the research work undertaken by UWA and NTU to develop SWCC envelopes for soil types classified in terms of the ASTM D2487 Unified Soil Classification System (USCS). This was done by establishing a large database of soils from across the world, classifying them according to ASTM D2487 and undertaking SWCC testing for each soil. This paper presents the SWCC test results from a selection of three of the most common soil classifications encountered in geotechnical engineering practise.CITATION:Mercer, K G, Rahardjo, H and Satyanaga, A, 2018. The development of soil water characteristic curves for soil types classified according to the USCS, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 263–273 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By H Kim, J Park, J Lee

Silico-ferrite of calcium and aluminium (SFCA) is a bonding phase in the iron ore sinter. The phase transition upon melting of SFCA was investigated with Differential Scanning Calorimetry and Confocal Laser Scanning Microscope. The initial melting of SFCA occurred at 1183.2°C and a massive melting was found at around 1351.1–1358.2°C. A phase transition-melting was investigated at 1476.5–1478.7°C. The liquid phase was composed of immiscible phases. The present results would be utilised to design a new iron ore sinter for better processing performance in a hydrogenenriched ironmaking process.

Jun 19, 2024

By Y-B Kang, W-Y Cha, Y-M Cho

Molten slag used in the secondary refining process (RH process) for the production of Ultra-Low C (ULC) steel is typically composed of CaO-Al2O3-MgOsat.-FetO with minor constituents. FetO in the RH slag is the main source of reoxidation of the molten ULC steel in the ladle by 2Al + 3(FetO) = (Al2O3) + 3Fe, thereby serving as the source of the alumina inclusions. On the other hand, FetO also enhances the fluidity of the slag, thereby increasing inclusion absorption capacity. Optimum slag chemistry design is therefore required to produce clear ULC steel. The reoxidation kinetics was investigated in the present study by employing high-temperature experiments and developing the reaction rate model. Initial compositions of slag ((% CaO)0/(% Al2O3)0 and (% FetO)0)) and reaction temperature were varied and change of [% Al] in the molten steel was measured. The rate-controlling step was analysed. It was found that the rate-controlling step in some cases changed during the reoxidation: from a mass transport of Al in the molten steel to a mixed transport including Al2O3 in the molten slag. The experimental data validated the reaction rate model based on the elucidated reaction mechanism and FactSage thermodynamic database. The model suggested that high (% CaO)0/(% Al2O3)0 suppresses the reoxidation only when (% FetO)0 is low (5 or lower in the present study).

Jun 19, 2024