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By Whitehead A. B

INTRODUCTIONDuring the past few years there has been considerable interest in developing the so-called direct reduction processes for treating iron oxides. The various methods proposed were recently reviewed by Scortecci and Palazzi (1960).In particular the application of fluidized bed techniques received considerable attention and, on first examination, this seems to be the ideal method 'of dealing with fine iron oxides. Several difficulties (e.g. product agglomeration) require the method to be investigated further before its potentialities can be fully assessed.PROPOSED FLUIDIZED BED REDUCTION PROCESSESBrassert and De Jahn (1951) were among the earliest to suggest the use of fluidized beds for the reduction of iron ore to metallic iron. Their patent was followed by many others proposing similar concepts, mainly from Lewis (1955), Ogorzaly (19.56), Shipley (1956), Agarwal (1960'), Osborn (1958), Texaco Development Corporation (1956) and Stelling (1957).The H-iron process (Squires and J ohnson, 1957; Lubker and Bruland, 1960) is the only scheme that has been an economic success. This process, mentioned later, manufactures a 'premium quality product in the form of sized iron powder.AIM OF THE PRESENT WORKThe work reported here was performed to assist in the formulation of a comprehensive pl'ogramme of research into fluidized bed reduction processes to be undertaken at the...

Jan 1, 1962

By Roxborough F. F

The ability of the Australian minerals industry to successfully manage the changes and challenges that face it in the 21st century depends ultimately on the quality of its human resources. Mining engineers have a vital role in this regard. The education and training that universities are currently giving to mining engineers is under challenge and needs to be reassessed in the light of industry directions for the 21st century. At one extreme is a push for a `finished product' graduate, up and running in `the flavour of the month' issues. At the other extreme are moves to reduce face-to-face university teaching hours and return to the time honoured university concept of `reading' for a degree. The lessons of Mourn make it apparent that neither approach is appropriate to the industry's future needs (Windridge, 1996). Basic knowledge gets rusty with time and new skills need to be learned. In order to conduct mining operations safely, productively and competitively, mining engineers must now accept the need to be prepared for continuing professional development as a career imperative. The concept of being professionally or statutorily qualified for life is no longer valid. This calls into question the purpose, content, structure and mode of delivery of university courses, all of which need to engender the principle and facilitate the cause of continuing professional development. This paper presents a model which aims to deliver a quality assured university education for mining engineers for the 21st century at undergraduate, postgraduate and professional level. The model extends beyond traditional university boundaries to match industry requirements to international best practice. It is based on collaborative alliances and innovative presentation modes which will provide industry access to undergraduate and postgraduate course elements presented by a broad range of national and international academic and industry authorities. It offers the prospect for preserving the best of university ideals in higher education, for developing and maintaining programs of direct relevance to industry needs and for a structured involvement in the continuing professional development of mining engineers.

Jan 1, 1997

By Sen G

An amount of explosives, whether it be cylindrical, spherical, etc in configuration, with a hollow cavity in one face or end is known as a hollow or shaped charge. When this charge is initiated, a focussing of explosive energy will occur within this cavity. This focussing, or concentration of detonation products creates an intense localised force greater than just the simple detonation of a conventional explosive, (without a hollow cavity). If this hollow cavity explosive is directed against a target material this concentrated force is capable of creating a deeper penetration than the same amount of explosive without the hollow cavity. If a metallic liner material is used in the hollow cavity, upon detonation of the explosive this liner will form into a high velocity penetrating jet. Depending on the explosive type and the liner material's configuration the jet tip can travel up to 10 km/s. Linear shaped charges were developed using the abovementioned shaped charge concept but instead of being formed about an axis, they are elongated and constructed along the principal axis. Therefore instead of creating a narrow circular penetration jet, it forms a thicker planar cutting jet ideal for linear cutting purposes. Using Linear Shaped Charges (LSC) for pre-splitting is expected to result in more accurate directional fracture propagation, while minimising lateral micro fractures in the surrounding rock mass which is required to remain undamaged.

Jan 1, 1995

A small-charge rock excavation method based upon the Penetrating Cone Fracture (PCF) technique has been demonstrated to be capable of excavating the hardest of rocks. The PCF technique involves drilling shallow holes in the rock which are then pressurised at the bottom by a propellant charge device. A controlled fracture is initiated at the hole bottom comer and propagates in such a manner as to excavate the rock at an energy efficiency three to five times better than explosives. Due to the low flyrock velocities and airblast pressures realised with PCF breakage, the method may be used in close proximity to equipment and personnel and is thus ideally suited for integration into continuous hard rock excavation systems. Over the past 18 months full-scale testing of the PCF method has been carried out in mines in the US and Australia. This testing has utilised a 76 mm diameter gas injector for hole pressurisation and employed propellant charges ranging from 80 to 320 gm. In addition to extensive data on rock excavation performance, data on ground motion, dust, carbon monoxide and air blast have been obtained. These data indicate that none of the parameters associated with PCF breakage are detrimental to the development of PCF-based, continuous-excavation machines. Machines employing the PCF method may range from simple single-boom machines for secondary breakage and small precision-blasting jobs to integrated systems with several booms, continuous mucking capabilities and ground-support equipment for drifting and tunnelling.

Jan 1, 1993

Mining is an intensive resource development industry, where operations are often of relatively short duration and can result in dramatic impacts on the natural environment during the operational period and for many years post mining. An integral component of all mining operations is water û through exploration, resource definition, mine development and operation, rehabilitation and the long-term post-mining land use. Water is a basic requirement in the provision of worker amenities, in drilling, as a means of dust suppression, as a medium for washing or processing the mine product, and as an aid in establishing vegetation on post-mining landforms. Water also plays an important role in mobilising environmental contaminants and is the primary medium for the transport of contaminants off the mine or processing site into the wider environment. It is for this second reason that the mining industry considers water management as a key component of mine management. Cost-effective water management relies on planning that incorporates a total mine system approach commencing prior to exploration and continuing through to rehabilitation and decommissioning. One of the primary considerations that will provide confidence to both government and community at the time of mine closure and lease relinquishment, will be the evidence that any water originating from, or passing through, the mine site is of a quality that will not have any negative impact on the surrounding environs into the future. The role of vegetation in stabilising disturbances to a landscape is well known, as is the recognition of vegetation being a fundamental component of the water cycle through the physiological processes resulting in the transfer of water back to the atmosphere through transpiration. In terms of water management at a mine site, the two crucial issues are the æquantityÆ and æqualityÆ of water that enters a receiving æoff-leaseÆ catchment. In terms of tolerances of the receiving environment, the total load of potential contaminants becomes critical, a reduction in which can be achieved through reduced volumes of water discharged, reduced chemical and physical concentrations of contaminants in that water, and ideally, both. This paper examines the potential role of vegetation in reducing the quantity of water released from a site, and secondly considers vegetation in the role of influencing the quality of that water.

Jan 1, 2003

Development of the Davcra flotation cell has continued over the past seven years. Preliminary testwork on single cells has now been extended to a com- plete Davcra flotation circuit, to cells ranging from 5 to 400 tons per hour capacity and to cells operating on a variety of materials. Operation of both test and production units has shown the Davcra cell to be competitive with conventional flotation machines. It offers a lower capital cost installation than conventional cells and in addition has a number of. operating advantages, particularly in its adaptability to automatic control.'

Jan 1, 1971

By B Veera Reddy

For thick seam extraction, the Blasting Gallery (BG) method is ideal for obtaining the maximum percentage of extraction at fast rates. The continued use of this mining method is threatened by strata control and spontaneous heating problems. The strata control problems are managed, to some extent, by supporting the roof with cable bolting and roof bolts of 2.5 m length and with regular induced blasting. However, a number of BG panels were sealed off prematurely due to spontaneous heating problems, losing 1.12 million tonne of coal. The use of compressed CO2 for controlling mine fires is not uncommon in the coal mining industry, but its use is something new for controlling active spontaneous heating in a BG working panel goaf. This method was attempted at the BG I/8 panel of the Godavarikhani (GDK) 8 Incline, Singareni Collieries Company Limited (SCCL). The spontaneous heating was effectively controlled and the remaining coal in the panel was completely extracted by continuous flushing of carbon dioxide (CO2) into the goaf for 40 days. One thousand and twenty four CO2 cylinders, each of 45 kg at 80 bar pressure were flushed into the goaf at the rate of 25 to 30 cylinders (350 m3 of CO2) per day. A quantity of 35 510 tonne of coal was extracted during the period from 30 July 2002 to 7 September 2002. The main objective of this paper is to present the complete process of controlling the spontaneous heating by CO2 flushing and to report on the study of the behaviour of gases and their analysis. The unique experience of controlling the active spontaneous heating in the working Blasting Gallery I/8 panel goaf at GDK 8 Incline with CO2 flushing (till the completion of the panel) will go a long way in establishing a working procedure for handling fire/spontaneous heating problems in BG panels.

Jan 1, 2005

Standard petrographic profiles for many Permian seams from New South Wales and Queensland have been drawn up. The standard profiles of seams of the same age and from one or more coalfields were used to compile an idealized or type seam sequence for those coals in which more than half the seam profiles were similar to one another. A marked similarity existed between at least 7 of the 10 type seam sequences formed. The configurations of the vitrite-plus-clarite contents of the plies of 95 per cent of the seams could be formed from different arrangements of 3 basic sequences: (i) a two-ply sequence with a lower vitrite-rich and an upper vitrite-poor ply; (ii) a two-ply sequence with a lower vitrite-poor and an upper vitrite-rich ply; and (iii) a four-ply sequence of 3 plies with vitrite-plus- clarite decreasing upwards, terminating in a vitrite- rich ply. The third basic sequence was very similar to a succession described for some British Carboniferous coals. Eighty per cent of the Australian Permian coal seams studied began with the first (i) basic type of sequence and are interpreted as originating in peat- forming areas which became progressively drier. More than half the seams were formed in an area with a stable depositional surface level which was subject to oscillations of small amplitude.. Many (30%) were formed in an area with a steadily rising depositional surface level.

Jan 1, 1969

By Whiten WJ

A method that allows data to be mass balanced and screen models to be fitted in a single step is described. The inclusion of several variables to describe the feed data in the fitting procedure allows a mass balance to be conducted at the same time as the fitting of the screen model. Analysis of Groote Eylandt Mining Company screening data has demonstrated that this method is ideally suited to applications where complete stream data are not available. Also, certain random fluctuations in screen model parameters arising from the fitting of consecutive mass balances and screening models are significantly reduced. A cubic spline function with fixed knot positions corresponding to particle sizes and variable (fitted) cumulative percent passing values is used to describe the feed size distribution. When the spline function is interpolated at the experimental feed particle sizes a fitted feed size distribution is obtained. This feed size distribution is then used as input to the screen model calculations from which product size distributions are generated. Since both feed and product size distribution data are used to minimise the residual errors between the observed and fitted stream size distributions, a mass balance is Conducted simultaneously with the screen model parameter fitting.

Jan 1, 1984

Although laterite ores already provide a significant proportion of the world's nickel and cobalt production it is anticipated that they will surpass sulphide ores as a source of nickel in the next century. The most recent period of greenfield nickel project construction was during the 1970s when it was notable that all of the eight new plants were based on treating laterite ores. This was because of the relatively large selection of available high grade laterite ore deposits amenable to cheap open cast mining and a paucity of high grade sulphide ore prospect alternatives. Of the three processing options for treating laterite ores: 1. smelting for the lower horizon saprolite ore, 2. ammonia; and 3. acid leach for the upper horizon limonite ore, smelting currently accounts for about 80 per cent of nickel production. In the future, as saprolite ore grades decline because of relatively high exploitation rates, the incentive to process the large untapped reserves of limonite ore will increase. The high cobalt content of limonite ore also makes it ideally suited to processing by a hydrometallurgical rather than smelting route. With only two exceptions, all saprolite smelting operations have a Class 2 nickel end product (largely ferronickel) and do not produce a cobalt by-product. As a result of technological advances, the modified ammonia leach process for limonite and transition ore as undertaken at Yabulu, now allows the production of pure nickel metal as a Class 1 product, along with significant tonnages of cobalt by-product. The mixed Ni-Co sulphide intermediate product of the pressure acid leach processing of limonite ore at Mon is converted to Class 1 nickel and cobalt metal at Fort Saskatchewan, Canada.

Jan 1, 1996

By L Whitbourn, K Yang, P C, E Ramanaidou

The potential of hyperspectral mineral mapping within a mine environment is demonstrated. Central to this capability has been the development of portable or vehicle-mounted, hyperspectral mine face-mapping systems. Data from these systems were used to detect subtle mineralogical variations and map their distribution across rock faces in a fashion that previously was not possible. In one study, the data usability was enhanced by ædrapingÆ the mineralogical determinations over a three-dimensional æmodelÆ of the rock-face. The eventual melding of the spectral mine face-mapping and three-dimensional spatial technologies will result in a new generation of mineralogical and structural information becoming available to mine geologists, engineers and metallurgists. Specific uses for spectrally-derived, mineral mapping data sets could include:ore grade mapping systems based on either direct detection of ore minerals themselves (eg iron and nickel oxides), or mineralogies that may be used as surrogates for ore-grade information (via various alteration minerals) after a suitable orientation survey; detecting mineralogies that have a deleterious effect on milling, metallurgical processing or have occupational health implications (talc, swelling clays, carbonates, asbestos, etc); selective mining and blending by collecting, processing and displaying such mineralogical images in near real-time to monitor ore grade and quality, and allow the separation of ore from waste during loading operations at the mine face; a mineral detection and mapping capability to assist in structural and geotechnical mine planning applications; and an enhanced geological detection and mapping capability for ore mineral species or alteration mineralogies that may be used to vector further mineralisation, update the existing mine ore model, or provide input to assist in the control of autonomous mining equipment. Within the Woodlawn open pit, Fe- and Mg-chlorites and phengitic- micas associated with sulfide mineralisation were detected and mapped. Subsequent studies using a second generation face-mapping system demonstrated the direct detection of ore-grade materials for iron-ore and nickel laterite mining activities. Satisfactory and meaningful results were extracted from data that were collected under a variety of challenging conditions. However, these non-ideal climatic and operational conditions would be expected under most operational situations in a mine environment. Development of a system using artificial illumination, permitting night-time (and eventually underground) operation and elimination of atmospheric absorption effects is underway.

Jan 1, 2006

The implementation of a process information management system (PIMS) is to provide a single online, real-time information system. This system provides a unique and completely open view for everyone, based on the key business drivers. It is structured around the three key concepts: process, maintenance and stocks. It combines numerous applications and provides accessibility to common tools and reports, through a web-based user interface, for every one from the floor operator to the General Manager. This æunique and commonÆ view displays raw, online process information that provides a quick health check of the operation at a glance, highlighting areas that require further investigation. The system is based on a hierarchical system of views, from the overview of the whole plant flow sheet to the more detailed operational shop view. It provides a synthetic view between continuous and batch operations, enabling the tracking of each batch produced. The batch view displays the critical batch components, and a comparison with each component of an ideal batch. This enables detailed analysis of each batch to identify areas of improvement. The information system will consist of an online reconciliation of stocks and flow data. This enables focus on the recovery of each process unit on a regular basis. This paper discusses the design strategy for the Process Information Management System, to ensure a unique and open view on the key business drivers is achieved and implemented successfully.

Jan 1, 2005

By P A. Dowd

This paper describes an integrated approach to the evaluation of ore loss and ore dilution via geostatistical simulation of in situ geology and grade characteristics, simulation of blasting mechanisms and simulation of loading from a blast muck pile. The approach is demonstrated on a case study. The sequential Gaussian method is used to simulate in situ bench grades on the scale of the smallest selectable volume within a blast muck pile. The simulated grades of these component volumes are interpreted as the reality that would be available with exhaustive sampling. The simulated bench is subjected to a blast simulator, based on the SCRAMBLE model, which effectively moves each of the component model volumes to its final resting place in the blast muck pile. Ore/waste delineation and selective loading processes are applied to the simulated muck pile to determine the degree of selectivity that can be achieved by various sizes of loader and types of loading and to quantify ore dilution and ore loss. An in situ model representing the reality of knowing only the data and information that are available from specific grade control drilling and sampling grids is obtained by sampling the geostatistically simulated model on a specified grid. The volumes comprising the in situ model are then populated by estimates based only on the data and from the specified grade control drilling and sampling grids. Different drilling and sampling grids are used to generate different models, each reflecting the levels of data and information available. Selectivity is assessed as a function of the drilling and sampling grids as well as the size and type of loader. Performance is assessed against the ideal selectivity that could be achieved on the perfect knowledge model comprising the simulated values of each component volume. Costs, prices and financial criteria enable an optimal selection of the grade control drilling grid, size of loader, type of loading and blast design.

Jan 1, 2004

By Mingmin Dou

The behaviour and deportment of indium during the precipitation of sodium jarosite from Fe2(S04)3 - Na2SO4 solutions were investigated. Indium is readily precipitated with sodium jarosite, and the extent of In precipitation increases as the In concentration of the solution increases. It was shown that In 3+ substitutes for Fe 3+ in the jarosite structure to form a nearly ideal solid solution series. On a molar basis, the precipitation of Fe is slightly favoured over that of In, and the difference is reduced as the pH increases. Sodium jarosite precipitation becomes kinetically rapid at temperatures >70¦C, but increasing temperatures in the range 70 to 150¦C affect neither the relative precipitation of In and Fe nor the composition of the jarosite product. Low Na2SO4 concentrations result in reduced product yields and jarosite precipitates in which H3O' > Na+. The hydronium-rich precipitates have reduced In contents. Increasing the ZnSO4 concentration of the solution slightly increases the quantity of jarosite formed and results in the incorporation of -0.3 per cent Zn in the jarosite structure. Otherwise, the presence of ZnSO4 has no significant effect on the composition of the jarosite. Seeding accelerates the rate of jarosite precipitation but has a negligible influence on the deportment of In. The jarosite precipitation reaction at 98¦C is relatively rapid and near-steady state conditions are achieved in - 6 h even in the absence of seed. The initially precipitated jarosite is slightly enriched in In with respect to Fe. The ferric ion concentration of the solution has a significant influence on both the amount of jarosite formed and its composition. In particular, the jarosites precipitated from dilute Fe3+ media have significantly enhanced In contents. Hence, it may be possible to recover - 25 per cent of the dissolved In, at the 1000 mg/L level, in a jarosite precipitate assaying - ten per cent In by the controlled oxidation-precipitation of sodium jarosite from a ferrous sulphate processing solution.

Jan 1, 1993

By P Collins, C Sheriff

The Sand Queen gold mine is a typical Archaean narrow, high-grade gold quartz lode deposit within a shear hosted system. Initial mining during 1904 - 1948 produced 181 659 ounces of gold from 248 564 tonnes of ore milled at an average production grade of 22.7 g/t Au, which equates to a minimum of 750 ounces per vertical metre. The current mining operation is using the old Sand Queen main shaft to access the Sand George deposit, which is a narrow quartz lode system discovered in the same shear structure along strike to the south of the Sand Queen mine workings. Current underground resources contain 360 200 tonnes at a grade of 11.8 g/t Au for 136 500 ounces. Mining is scheduled to produce 20 000 ounces of gold annually. Re-opening of the Sand Queen mine and underground development of the Sand George lodes has revived several grade control issues relevant to a narrow, ænuggettyÆ gold lode mining environment. These include the dependence of assay grade of individual samples upon a number of factors, including how and where a sample is collected, how and where it is analysed, and how grade data is used to estimate an æaverageÆ grade. Ideally, the only way to achieve an acceptable estimate of ætrue gradeÆ is to mine and mill a large parcel of ore (eg >100 tonnes) from each lode or ore type. In a mining operation producing relatively small tonnages from a number of separate ænuggettyÆ gold lodes, availability of resources and operational constraints may preclude intensive sampling for predictive grade control. At the Sand Queen mine, one of the key issues has been to establish a reliable system for estimation of gold grade with which to reconcile milling data. Extensive use has been made of detailed geological data to understand the grade distribution within individual lodes and between lodes, so as not to rely solely on assay results.

Jan 1, 2008

By M.J. Mitchell

Platinum-group minerals (PGM) are recorded from a number of localities along the Waiau River, western Southland, and the south coast of the South Island, New Zealand. At each locality, small amounts of PGMs were recovered as by-products of historical gold mining operations. During the period 1890-1950 an estimated 1000-2000 oz. of "platinum" were recovered from the region, the only area within New Zealand where PGM have been commercially exploited. The PGM suite of southern New Zealand consists of Pt-Fe alloys, IPGE (iridium subgroup, platinum-group elements) alloys, sperrylite (PtAs2), cooperite (PtS)and braggite ((Pt,Pd)S). The composition of Pt-Fe alloy exhibits considerable variation and two compositional populations are recognised. Some Pt-Fe alloy grains are chemically zoned. Iridium is the most abundant IPGE alloy phase and often contains considerable Pt, in contrast to osmium and ruthenium alloys. Cooperite and braggite grains are characterised by extremely low concentrations of Ni. R^~

Jan 1, 1995

This paper summarises the current status of the mining sector in Poland in terms of vertical transport system safety. Selected results of research programs conducted at the AGH-UST relating to mine hoist system safety are reviewed. The conclusions support the notion that the costs of vertical transport systems can be reduced, while at the same time maintaining the required safety and reliability levels. Novel solutions: movable fender beams HWR, linings modar« and the integrated shock absorbers PHH for conveyance guiding systems fully confirm this hypothesis.

Jan 1, 2005

By M Rimes

This paper describes a technique to predict achievable head grades and likely variances from target grade for the Shovelanna Iron Ore Project, in the Pilbara region of Western Australia. The block model from which the production schedule is produced was created from a wide spaced drilling program and was classified as an Inferred Resource under the JORC Code. Ideally, production schedules and target grades would be determined using a combination of Proved and Probable reserves. However sometimes it is necessary to consider the requirements of potential off-take parties who have specific grade tolerances. A technique is needed to simulate mining sequences and grade variations early in the planning process, using an æexplorationÆ block model rather than the normal æminingÆ block model. Marketing contracts require examination whether the target grade {Fe, P, SiO2, Al2O3 can be kept constant, or must be revised during the life of the mine. A model (written in ExcelÖ using Visual Basic macros) develops a feasible, close to optimal, mine plan from block model data. Cut-off grades for minable ore are chosen. The model evaluates ore tonnage, grade and stripping ratio against depth. Outputs at this stage include plots of slices through the orebody, at nominated x, y and z coordinates, showing ore grade, waste, drill hole locations and topography. The model then searches for a feasible satisfactory mine plan. The initial grade target is the average for the identified ore blocks. The available block list (ABL) at any time is the set of ore blocks, any one of which can be mined without removing any other ore block. The entire initial ABL has an unacceptably large ætotal grade stressÆ, defined as [(Grade-Target)/Tolerance]2, summed over the four relevant minerals {Fe, P, SiO2, Al2O3}. The model trims the ABL, removing the block most harming the total stress. Trimming is repeated until the total grade stress reduces to an acceptable level. The trimmed ABL defines the first mine campaign. Removing the trimmed block set, a second ABL is exposed, which is again trimmed and mined. The process is automatic: a few seconds computation provides a complete mine plan. Re-running the model with adjusted grade limits quickly shows whether a uniform target can be achieved or whether the target must be modified during the mine life.

Jan 1, 2007

By G Neely

COPING WITH COMPLEXITY In every industry, and mining is no exception, plant and processes increase in complexity over time and managers and operators need correspondingly more knowledge. The mine manager has to delegate details to operators, engineers, metallurgists, accountants, safety specialists, personnel officers and the rest. Is it reasonable then, to expect the Mines Inspector to be competent to judge the conduct of all these operations against the criterion of the regulations? Obviously not, but what are the alternatives? One is a superficial inspection where the inspector goes on a hazard hunt for broken steps and missing handrails. Another is one in which an army of specialist inspectors marches on a mine, sometimes outnumbering the staff. Each is competent to assess some part of the operation and if he or she can find an opposite number among the mine staff, they can discuss details. But what good does it achieve? The system acts to remedy present defects and to make recommendations which, if only they were followed, would prevent the same things happening again. Given that this process has been going on since the first Factory Act of about 1840, how is it that there are any more defects left to put right? The answer of course is that defects keep appearing, and new defects arise as fast as the old ones are found and corrected. Further progress can only be made by preventing defects at their source.

Jan 1, 1994

Computer programs for the storage, retrieval and use of basic thermodynamic and physical property data for chemical substances are described. Methods are presented for the collection, critical assessment and pre- processing of source data for files containing enthalpy, entropy and heat capacity data for 3000 compounds, enthalpy and excess entropy for 200 dilute solutions and critical propert- ies and vapour pressure for 600 compounds. Retrieval programs are discussed which allow the tabulation or plotting of many basic and derived thermodynamic properties for chemical substances or balanced reactions. Examples are given of the use of such data to infer the stability or corrosion resistance of materials and the feasibility, yield and heat release of reactions. A general purpose calculation program is discussed which allows the equilibrium compos- ition to be found for complex systems with many species and phases, using the method of Gibbs energy minimization. Methods of correction for non-ideal behaviour in these systems are discussed, as well as methods for fixing, maximizing or minimizing any desired property of the system. Examples are given of the simulation of various laboratory Experiments and industrial processes by this method.

Jan 1, 1977