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By Jochen Petersen, Thandazile Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques. The anodic dissolution process has been established to be a seven-electron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions. The number of electrons transferred in the carbonate and sulphate salts suggests that the sulphur is oxidised to a thiosulphate intermediate and the copper and iron released as Cu+ and Fe2+. The Cu+ and Fe2+ is subsequently oxidised in solution in non-Faradaic reactions. The deportment of Fe2+ and S2O32- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, however observations made on the mineral surface after leaching do not support the formation of elemental sulphur. Scanning electron microscopy and energy-dispersive spectroscopy analysis of the mineral surface suggest presence of an iron–sulphur surface layer completely free of copper under the ammonia–ammonium sulphate conditions, an iron-rich surface layer under ammonia–ammonium perchlorate solutions and absence of surface layer build up under ammonia–ammonium carbonate solutions. INTRODUCTION Hydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different approaches to hydrometallurgical treatment of chalcopyrite can be carried out. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base-metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilisation of copper(I) and copper (II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation 1 (Beckstead & Miller, 1977a):"

Jan 1, 2015

By Charles G. Patmon

This paper describing the methods of dredging and treatment of gold-bearing gravels at the Lancha Plana Gold Dredging Co.'s dredge is one of a series of similar papers being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The dredge is located near the Mokelumne River, 12 miles west of San Adreas, Calif.; it is accessible by an improved dirt road from Jackson, which is about 20 miles distant.

Jan 1, 1932

By E. B. Kester

In the commercial evaluation of coal tars, a distillation analysis properly carried out is of considerable importance. Close attention must be given to this operation in order to obtain consistent results and to secure the minimum decomposition of the tar compounds, Which in Many cases are sensitive to undue heat effects. Low-temperature tars in particular contain compounds of this nature, while in the case of tars produced at high temperatures the large proportion of pitch present has an adverse influence during a distillation. If excessive cracking takes place, the composition of the distillate will naturally vary from the normal, with the result that all the analytical criteria subsequently obtained are affected. Where tars, produced over wide ranges of carbonization temperatures are investigated as in the survey of gas, coke, and by-product making properties of American coals now being conducted at the United States Bureau of Mines Pittsburgh Experiment Station, the method of distillation must necessarily be the same for all of the tars studied. Also, it mast function equally well for both low and high temperature tar permit accurate fractionation, and reduce adventitious decomposition to a minimum. The authors are aware that certain types of distillation analysis which do not meet the above requirements may give results comparable with those of the large stills of a by-product coke-plant where one type of tar is produced. These may be simpler and shorter and entirely suitable for control work, but at the same time have little value in a fundamental investigation.

Jan 1, 1932

By S. Babendererde

The twenty-ninth Sir Julius Wernher memorial lecture of the IMM, presented at Tunnelling '97, London, 2-4 September 1997. The tunnelling industry is well prepared to face the challenge from the population explosion in urban areas in the near future. Many well-established yet redundant concepts are still impeding progress, however, including the prediction of excessive surface ground settlements. The correct selection of TBM can minimise these, and ground deformations can be avoided completely if the appropriate techniques are applied. Advanced techniques have been used in the Tokyo Bay Crossing, where the tunnel lining was installed by robots. Other advanced techniques include the use of a sliding slip form to give temporary support to an extruded tunnel lining, the chemical processing of ground by polymers during earth-pressure balanced tunnelling and the use of electronic monitoring and steering devices in TBMs. There will be challenges to tunnelling in urban environments, as open cut techniques will no longer be tolerated. Two examples of mined stations are briefly discussed

Jun 19, 1905

By Isaac Girón Bermeo

El presente texto desarrolla dos nuevas aplicaciones de la centrifugación en la metalurgia extractiva. El primer caso refiere al uso de centrífugas en el desaguado de los lodos anódicos lavados que provienen de la refinación electrolítica del plomo, donde las centrífugas del tipo de "bola" o de rotor giratorio sólido de fabricación nacional, son las que trabajan con mayor eficiencia y rapidéz. El segundo caso, señala al tratamiento del residuo de lixiviación de zinc y así obtener un cake de suficiente humedad para su pelitización posterior y a una capacidad que de otro modo exigiría, una mayor inversión que otra clase de equipo.

Nov 20, 1967

By Rajni Patel, John McDonald, Steve Dubnewych, Michael McKenna

The Upper Reach segment of the Northeast Interceptor Sewer (NEIS) is a3.2-km-long tunnel excavated in interbedded marine sedimentary deposits with approximately 40 m of cover. The tunnel was initially classified by Cal/OSHA as “potentially gassy.” During excavation, high levels of hydrogen sulfide and methane were encountered, prompting Cal/OSHA to reclassify the tunnel as “gassy.” In addition, the tunnel excavation encountered an abandoned, 100-year-old water tunnel known as the “Narrows Gallery.” This existing tunnel was completely full of water and under 30 m of hydrostatic head. This paper will discuss the unanticipated difficulties and design solutions implemented to construct a gassy tunnel exposed to high volumes of water.

Jan 1, 2005

By J. Dean Warner

From 1984 through 1987, the Bureau of Mines investigated numerous prospects and new discoveries of columbium, rare-earth elements (REE), uranium, zirconium, and other metals associated with the multi-phased peralkaline granite at Bokan Mountain, southeastern Alaska. This report summarizes the mineral evaluations and estimates indicated and inferred resources for those prospects containing significant tonnage and grade. A total of approximately 96.2 MM lb Cb205 (43 pct of the tonnage at a grade exceeding 0.125 pct Cb205), and 11.8 MM lb U308, 27.9 MM lb Th02, 133.0 MM lb Y203, 637.6 MM lb ZrO2, and 241 MM lb REO are estimated to be contained within nine deposits totalling 37.8 million tons (at least 80 pct of resource tonnage also exceeds 0.5 pct Y203 + REO). Generally, half of the REO content is composed of the heavy yttrium subgroup. Several deposits also contain beryllium and tantalum; 2.1 MM lb of Ta205 and 8.9 MM lbs of BeO were estimated. These estimates would likely be substantially increased with additional exploration. Four deposit types were investigated; shear zones and fracture-related deposits, pegmatites, mineralized dikes, and placers. Mineralized dikes contain most of the beryllium, columbium, tantalum, yttrium, zirconium, and REE resources, whereas shear zones and fracture-related deposits (Ross-Adams mine) contain the principal of the uranium resource. Pegmatites are similarly mineralized as are dike deposits, and contain low levels of gold. Placer potential is suggested, but no deposits were found.

Jan 1, 2011

By T. V. Swaminathan

Monazite sand is normally processed by, the caustic soda route to produce mixed rare earths chloride, thorium hydroxide and trisodium phosphate. Bulk of the mixed rare earths chloride is used for the preparation of FC catalysts. Recently some of the catalyst producers have shown preference to cerium depleted (lanthanum enriched) rare earths chloride rather than the natural rare earths chloride obtained from monazite. Therefore, a process for producing cerium depleted rare earths chloride, cerium p thorium and uranium from Rare earths + thorium hydroxide obtained by treating monazite based on stepwise hydrochloric acid extraction, was developed in our laboratory. The process involves drying of the mixed rare earths-thorium hydroxide cake obtained by monazite-caustic soda process followed by stepwise extraction of the dried cake with hydrochloric acid under specified conditions.

Jan 1, 1989

By S. Doombos

To convert the railway-bridge across the Oude Maas between Dordrecht and Zwijndrecht into a vertical lifting bridge, a drastic adaptation of the existing piers is necessary. Extra piles have to be placed quite close to the present piers to bear the extra weight of lift-towers and bridge-sections. This article describes the special technology applied to drive steel tubular piles l800 mm. in diameter and 36 m. in length vibration-free into position. At the same time a method of pile-point-reinforcement has been applied to minimize the settlements.

Jan 1, 1989

By C. Bachmann, M. J. Laurila, A. J. Widenman, A. Klein

Elemental analysis of slurry streams using X-ray fluorescence (XRF) has long been employed. However, detector technology has limited the application of XRF devices. Using detector technology employed on NASA's Mars Pathfinder to analyze soil samples, Process Control, Inc. has developed an on-line analyzer to mount on a sampling system. The prototype XRF elemental analyzer was installed at Detroit Edison's Monroe Power Plant in January, 1998 and has been employed to monitor feedstock quality. A slurry system has been developed for flotation control. This paper describes the testing of the analyzer using the new, draft ISO standard for evaluating the performance of online analyzers (ISO/DIS15239).

Jan 1, 1999

By Will H. Coghill, Fred D. DeVaney, R. S. Dean

Part I CONTENTS

May 1, 1934

By C. E. Rork

This paper discusses various mechanical improvements that have been gradually incorporated in the copper-willing plants of the Southwest daring the past 14 years, power plants for concentrators, use of large-size units of equipment, and the effect of plant capacities on costs. The improvements in mechanical equipment and plant design have contributed in the reduction of operating costs; in some instances a saving in the capital cost per ton of daily capacity milled has resulted.

Jan 1, 1935

By Virgil Miller, Glenn L. Allen

The purpose of this report is to present a comprehensive review of the technology of alumina and aluminum production in the former Japanese Empire , which consisted of the Japanese Home Islands and her dependencies , Formosa , Manchuria , and Korea . Pertinent background material and statistics are given when deemed necessary to make the report self - contained and to make clear the factors underlying Japan's tremendous accomplishments in the production of aluminum .

Apr 1, 1949

By V. N. Rampton, C. F. Gleeson

"Exploration results over three overburden drilling anomalies defined by the Ontario Geological Survey in 1981 in the Kirkland Lake area, Ontario are presented. The anomalies come from lowland areas where overburden is thickest. By mapping the bedrock and surficial geology, by prospecting, humus sampling and shallow till sampling over the surrounding upland surfaces, one can initially evaluate such overburden drill anomalies without costly reverse circulation drilling. The drilling should follow, if necessary, only after surficial base data has been obtained. Preliminary work on these three properties has defined the presence of at least two styles of gold mineralization. One occurs in silicified zones in intermediate volcanics closely associated with northwesterly trending faults and shear zones. The second occurs in quartz-carbonate alternation zones in volcanics intruded by quartz-feldspar porphyry dykes. IntroductionThe three examples presented in this paper present first-hand information on an approach to the follow up of several geochemical anomalies that were found by the Ontario Geological Survey when they carried out reverse circulation overburden drilling as part of the Kirkland Lake Initiative Program (KLIP) in 1980 (Routledge et al., 1981). The initial approach is relatively simple, systematic, and cost and technically effective. It readies the properties for further exploration, or conversely, it could downgrade the properties as viable gold targets."

Jan 1, 1987

Choosing the correct delay time for many blasting applications is an important and critical blast design parameter for controlling fragmentation, muckpile shape, swell, digability, throw, ground vibration and airblast. BAl and its affiliates have monitored thousands of full scale blasts in a variety of field conditions, spanning over 15 countries, with sophisticated blast monitoring instrumentation. In some blast environments, a small change in the choice of delay times used had a dramatic and pronounced effect on the overall blast results. In other blast environments, large changes in the choice of delays used had absolutely no effect on the final results in terms of specific outputs. In environments which were sensitive to the delay selection, the type of explosive, dynamic response time of the rock mass (TMIN), integrity of the material, burden and rock mass geometry, all played a very important ,role.

Jan 1, 1998

By Bernard Woolley

The history of the use of calcium aluminates in mining is discussed including a review of very rapid hardening concretes, anchoring using cement capsules and pumped ground control systems. Specific reference is made to the long term performance of highly abrasion resistant orepass lining in South Africa and the use of rapid hardening materials for a range of applications in Australian coal mine where water infiltration creates difficulties or where rapid repair or return to service is required. The topics covered in detail are, high strength abrasion resistant concretes with a 20 year, 30 million ton ore pass life. Rapid reinstatement of wet and worn roadways using mineral dewatering and rapid roadway rebuild solutions, all in I maintenance shift. The different applications are illustrated using examples from operating mines.

Jan 1, 1997

By Mohammed Z. Islam

As cities are growing all over the world, the need for urban transportation facilities are on the rise. Designers (of these facilities) today are faced with a number of constraints for their design, of the most is the space limitation and impact of new construction activities to the community. A typical subway station, as the focus of this paper, is approximately 600 to 1000 feet long, 50 feet wide and 2 to 3 story high. With such a large volume of construction activities, it is easily realized why underground stations are becoming obvious choice for larger cities eventhough the cost could be 2 1/2 to 3 times as much as an aerial station and 4 to 5 times that of an at-grade station [O'Neil et. al.(1977)]. Since cost is an important factor which is always increasing, therefore, the designer should have a good planning, consider alternatives for design and come up with a realistic design with minimum impact to the community. This paper is about the geotechnical considerations that the designer should be aware of. PLANNING A 1977 report [O'Neil et. al.(1977)] on the construction costs for a number of underground subway stations indicate that about 4 0% of the cost is site-controlled, 35% is structural items, and 25% is finish and equipment. It is seen that of opportunity exists for cost savings in the site selection and proper use of the site. Once the site is selected, the cost of construction become controlled by urban conditions at the site, geotechnical conditions, station size and depth. Therefore, the design-solution is very much site-specific. The geotecnical designer should collect the following information at the early phase of the design:

Jan 1, 1993

By Faruk Oksuz, Clay Haynes, Miguel Sanchez, Patrick Finn, Roger J. Maurer

The Milwaukee Metropolitan Sewerage District’s (MMSD)’s challenges of basement flooding and wet weather sewer overflows are being creatively addressed with the Northwest Side Relief Sewer tunnel. The $132 million, 20-foot diameter, and37,740 feet long conveyance and storage tunnel excavation in dolomite at depths reaching 165 feet below ground surface has been successfully completed within13 months in April 2004. This paper includes Owner’s perspective on the overall project, and the design and construction details by the Designer and the Contractor. The project contract documents included a comprehensive Geotechnical Data Report and the Geotechnical Baseline Report.

Jan 1, 2005

By Thomas Leonard Watson

Jan 1, 1906

By V. Prostakova, M. Shevchenko

The copper smelting gas / slag / matte / metal / solids system with the Cu-Fe-Ca-Si-O-S major elements has been a long-term focus of the present overall research program using integrated experimental and modelling approach for the phase equilibria characterisation and development of a thermodynamic database. A systematic investigation of phase equilibria of slag systems in equilibrium with Cu metal is providing information for systems where copper coexists in slag with lead, zinc, and aluminium oxides as major components. Experimental studies involve high-temperature equilibration of synthetic samples; rapid quenching; and measurement of the compositions of equilibrium phases using electron probe X-ray microanalysis (EPMA). Particularly important feature of the present study a wide range of temperatures (660-1670°C) being characterised that reveals major inconsistencies in the existing thermodynamic description of the multicomponent system, and allows to establish the thermodynamic properties from phase equilibria in a reliable way. FactSage-based thermodynamic modelling is integrated with experimental research. Initial thermodynamic assessments are used to identify priorities for experiments, planned to provide specific data for thermodynamic optimisation. Significant improvement in the accuracy of the phase equilibria description is achieved, in particular in the PbO-Cu2O-SiO2, ZnO-Cu2O-SiO2, and Cu2O-CaO- Al2O3 systems in equilibrium with metallic Cu. INTRODUCTION Slags high in lead and copper are generated in primary metal production in the smelting of lead sulfide concentrates and in pyrometallurgical metal recycling systems. The compositions of these slags are varied due to increased fraction of recycled materials in the feed as well as introduction of previously unused chemical elements to modern technology. Therefore, their processing becomes chemically more complex; in that way they contain a large number of different metals. These slags form complex non-ideal solutions (with possible formation of several immiscible slags) that can coexist with stoichiometric solids, solid solutions, mattes and molten metal depending on the bulk composition and process conditions. Predicting the outcomes of smelting and refining processes is becoming increasingly difficult. To assist in the optimisation of these metallurgical processing operations, a comprehensive research program is underway to develop accurate thermodynamic databases for these non-ferrous process systems.

Jan 1, 2019