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By A. Holland, T. Krumins, E. Olin, J. F. M. Castilleja, J. Geldart, C. Fleming, I. Jackman

A flowsheet has been developed to treat the flotation tailings from a copper mine in Mexico to recover gold and silver by cyanidation and carbon-in-pulp (CIP). The plant will treat ~15,000 t/day of a 60:40 blend of current flotation tailings and the mine’s historic tailings. The tailings also contain a significant amount of cyanide-soluble copper, and the economic viability of the project is strengthened by recovering most of the copper and cyanide associated with this process. The solution and solid phases in the CIP tailings will be separated in a counter current decantation (CCD) circuit and the CCD solution overflow will be treated by a SART Process. Copper precipitates as a salable copper sulphide product in the SART Process and the cyanide that is associated with the copper complex is regenerated as free cyanide. After SART, a portion of the SART product solution will be recycled to leach to reuse the free cyanide, while the remaining solution will be used as wash water in the CCD circuit. Incorporation of the SART Process in the flowsheet allows the CIP circuit to be operated aggressively as a gold plant, which means most of the silver in solution passes through CIP to SART. Silver co-precipitates with copper in SART and is recovered very efficiently with the copper sulphide by-product. Incorporation of SART also allows the leach and CIP circuits to be operated with relatively high levels of free cyanide, which enhances silver leach kinetics and helps keep copper from loading onto the carbon in CIP. The flowsheet was developed in the laboratory and successfully demonstrated in a fully-integrated pilot plant in 2018.

Jan 1, 2019

By P. Kordi, L. Egorova, R. J. Bowell, D. Gurevich, V. Sedov, A. Mikhailov, D. A. Holwell

ABSTRACT Reconnaissance exploration in the Kuene region Namibia has included geological mapping, soil and stream sediment geochemistry, and ground geophysical methods. Copper mineralization occurs within a well-defined belt with north-northwest to south-southeast trend, parallel to the regional strike of the sedimentary rocks. The occurrences vary in size but are generally stratabound. The mineralization is centred on the transition from calcareous shale and interbedded limestone, through carbonate rocks, to quartzite. Geochemical anomalies have been identified correlating to induced polarization (IP) and magnetic anomalies. The anomalies identify one potential metallogenic zone more than 17 km in strike length.

Jan 1, 2012

By J. E. Nesset, F. Rosenblum, J. A. Finch, R. Payant

ABSTRACT Under certain conditions of moisture and oxygen, sulphides can spontaneously self-heat. We tested a hypothesis that galvanic interaction between some sulphides can promote self-heating. Galvanic interaction is controlled by the rest potential difference between sulphides and particle size. A series of binary sulphide mixtures was tested. Individual sulphides and mixtures with low rest potential difference did not self-heat, but mixtures of high rest potential difference did. When testing pyrite-sphalerite mixtures, self-heating increased inversely with particle size, with the fineness of the pyrite governing self-heating, indicating the rate-limiting step is the reduction reaction. The results support the hypothesis that galvanic interaction contributes to sulphide self-heating. A possible mechanism based on hydrogen sulphide as an intermediate product is proposed. The understanding gained will be of interest to those involved in storage, shipping, and disposal of sulphides.

Jan 1, 2012

By T. V. Vijaya Kumar

Most of the iron ore washing plants set up in India consist of sizing of the ore by dry / wet screening, washing and classification by screw classifiers followed by multi-stage hydrocycloning of screw classifiers? overflow. The underflow of the hydrocyclones forms the concentrate which is used for pellets making. As the cut-point of hydrocyclones is generally at 20 microns, relatively lower diameter cyclones in a cluster with parallel feeding are used. This is found to, often, result in choking of the spigots, at times, by extraneous material as well reporting along with the slurry. It is observed to lead to sub-optimum performance of the cyclones with loss of iron values into cyclone overflow and thereafter into tailings. Analysis of data of an operating beneficiation plant (Beneficiation Plant - 1, BP - 1) of M/s Jindal South West (JSW) Steel Limited, Karnataka, India over a period of one year indicated that weight recovery of the concentrate from two-stage hydrocycloning was 45% (with respect to feed to the cyclones) and assaying 63.43% Fe, 4.43% SiO2 and 2.32% Al2O3. CSIR - National Metallurgical Laboratory - Madras Centre (NML - MC), India developed flotation process for processing screw classifier overflow with a view to improve the recovery of ultrafine iron values from it. Detailed investigations at laboratory scale flotation column and on-site pilot plant trials proved that the production of the concentrate and productivity of the plant could be enhanced by adopting reverse cationic column flotation technology. It was established that a typical screw classifier overflow analyzing 60.54% Fe, 5.95% SiO2 and 3.67% Al2O3 could be upgraded to 64.21% Fe, 2.64% SiO2 and 2.20% Al2O3 with 82.7% weight and 84.7% Fe recovery. This translates into an increase of 80% in weight recovery of the concentrate compared to what is being obtained, at present, by two-stage cycloning. It had an added advantage of reduced SiO2 in the concentrate. Thus, SiO2 in the final concentrate could be reduced to 2.64% from 4.43% by adopting column flotation. The concentrate so generated meets the stringent specifications, especially in terms of alumina in it(should be less than 2.50%) for pellets making. Later, JSW Steel Limited set up the flotation plant in BP - 1 based on the process developed by NML - MC and was commissioned in 2010. Keywords: iron ore, washing, ultra fines, alumina reduction, column flotation

Sep 1, 2012

By B. K. Gorain

"The Air-Metabisulfite (AMBS) process has been developed to treat complex copper, molybdenum and precious metals (gold, silver) bearing ores using brackish and sea water. This process was able to produce significantly better copper concentrate grades and higher recovery than possible using conventional lime and/or cyanide based processes for certain complex ores with high sulphide gangue minerals. The AMBS technology in now used commercially following a rigorous evaluation process emanating from laboratory curiosity to plant applications. In addition, many projects have embraced this technology at a feasibility level involving various complex ore bodies.This paper presents a summary of the findings from testing the AMBS technology on various ores types. Experiences gained from this successful development from bench to piloting and then to plant applications are also presented in this paper.INTRODUCTIONProcessing of sulphide copper, molybdenum and precious metal ores typically involves flotation of copper bearing minerals while depressing non-sulphide and other non-copper sulphide minerals such as pyrite, pyrrhotite and sometimes arsenopyrite. Though in many precious metal ores, the values are in these sulphide minerals as well. The conventional method employed in the industry to produce a saleable copper concentrate requires depression of these non-copper sulphide minerals using an alkaline pH above 9.5, though 10.5 to 11.5 is more common. Alkalinity is controlled by the addition of a pH modifier. Lime is normally employed as a pH modifier due to its relatively low cost; however, the costs associated with adding lime can be significant and the effectiveness of lime as a depressant could be drastically reduced when the process water supplied to the flotation circuit contains high level of dissolved salts. In some cases, a small amount of cyanide is used along with lime to depress non-copper sulphide minerals especially when its proportion to copper sulphide minerals in the ore is higher than three."

Jan 1, 2016

By R. K. Collings

The annual production of mineral and mineral-based wastes in Canada is conservatively estimated to be 400 million tons. Over 90 per cent of this amount is waste rock or mill tailings from the mining and mineral processing industry. The remainder are slags and ashes from the metallurgical industry, and sludges from the chemical industry. Because of impurity content, remote location, or both, most wastes have limited usefulness and, indeed, are a liability in that they must be transported to waste disposal sites and contained therein. Certain mineral wastes do, however, have potential value. Some contain small percentages of metals that may be economically recoverable with price increases; others consist of mineral material that may be used for such purposes as road base, construction aggregate, railroad ballast, and in the manufacture of bricks or blocks. Increased interest has been shown in mineral wastes in recent years. This paper reviews the types of mineral wastes available in Canada, briefly describes a number that have potential value, and notes possible uses and related research by CANMET and other organizations.

Jan 1, 1978

By Arthur V. Petty

The Bureau of Mines has investigated the effect of refractory oxide additions, introduced in soluble form, on the refractory properties of 42-, 58-, and 70-pct-A1203 brick. Brick having porosities ranging from 12 to 16 pct were impregnated with solutions containing chrome, chrome-iron, zirconium, calcium, magnesium, cobalt, nickel, tin, and manganese ions. Additions of some of these ions provided dramatic improvements to such properties as hot modulus of rupture, hot load, and particularly slag resistance. These improvements can be related to reduction of porosity, amorphous grain boundary phases, formation of more refractory bond phases, and reduction of the wettability of Al203-containing refractories by metallurgical slags. Fifty-eight-percent-AI203 brick, impregnated with chrome, showed hot modulus of rupture, hot load, and slag resistance two to five times better than those of untreated 70-pct-AI203 brick. This could result in reducing the Nation's dependence on imported refractory-grade bauxite generally required for high-A1203 brick, as domestic alumina resouces could be used to produce the improved refractories.

Jan 1, 1984

By Vladimir Adamek

This paper describes the Bureau of Mines development of a novel subsidence prediction methodology suitable to the mining and geologic conditions in the Northern Appalachian Coal Region. It describes the computation of vertical and horizontal movements, inclination, curvature, and horizontal strains. The substance of this method is the separation of the effects of lithology by introducing a correlation between hypothetically homogeneous overburden and existing lithologic conditions, while providing for different mining conditions, i.e., underground geometry and overburden thickness. The effects of lithology have been expressed in the form of a variable subsidence coefficient within the subsidence trough. The subsidence co-efficient is considered a constant for other predictive methods. Field data from 16 test sites at 11 Bureau longwall panel studies were used in the analysis. For each panel, the characteristics of the variability of the subsidence coefficient were defined. Regression analysis of the subsidence coefficients from all test sites on their locations relative to the edges of their respective panels yielded a third-degree polynomial equation. The results from additional longwall panel studies, not included in the regression analysis, were used to prove the validity of this method. To facilitate the use of this precalculatlon methodology, a computer program was written in BASIC for use on a personal computer.

Jan 1, 1987

By N. Dashbold, E. Rudnik

"Waste electric and electronic equipment currently comprises the fastest-growing waste stream in the world, but at the same time it is seen as an important source of metals for the recycling industry. E-waste is usually treated pyrometallurgically, with hydrometallurgical methods used to a lesser extent. This paper reports the results of research on the selective recovery of copper from smelted low-value electronic waste. Pyrometallurgical pretreatment of the scrap allowed the removal of plastics and the increase of metal content in the material. The obtained alloy of copper, zinc, tin and silver was a multiphase solid consisting of two brass phases and inclusions rich in iron, lead and silver. Copper alloy was further anodically dissolved in ammoniacal chloride solution. It resulted in high degradation of the material and accumulation of the metals mainly in the slime. The slime was then leached in acid or ammoniacal chloride and sulfate solutions followed by selective copper electrowinning. Hydrochloric acid was the most efficient solvent for the slime, but ammoniacal solutions were more selective for copper. Copper could be leached with 96 to 100 percent and 87 percent efficiency from the slime by the chloride and sulfate solutions, respectively. Copper with 90 to 99 percent purity at current efficiency of 42 to 76 percent was obtained from the acid solutions, while copper with 98 to 99 percent purity at current efficiency of 60 to 86 percent was deposited from the ammoniacal baths. IntroductionObsolete electrical and electronic equipment makes up the fastest-growing waste stream in the world (Baldé et al., 2015), due not only to the introduction of wider ranges of new types and models of a variety of electronic products but also to the shortening of their life-spans, sometimes referred to as planned obsolescence by producers (Keeble, 2013). About 42 million tons of electronic waste, or e-waste, are estimated to have been generated globally in 2014 (Baldé et al., 2015), and it is expected that in the European Union alone the waste electrical and electronic equipment (WEEE) stream will reach more than 12 million tons by 2020 (European Commission, 2015). Accurate evaluation of e-waste generation (Wang et al., 2013) and its global transport (Breivik et al., 2014) is difficult, mainly due to a lack of high-quality data related to its market and socio-economic dynamics.Many countries introduced legislation to control e-waste flow, collection and recycling. For example, Directive 2012/19/EU on waste electrical and electronic equipment (European Parliament and the Council of the European Union, 2012) obliges all E.U. members from 2016 to maintain a minimum collection rate of 45 percent of the total weight of WEEE collected. From 2019, the minimum collection rate to be achieved annually shall be 65 percent of the average weight of electronics placed on the domestic market in the three preceding years, or alternatively 85 percent of WEEE generated in the territory of the particular member."

Jan 1, 2017

By C Hedemann, N Silveste, H Davis, C J. Moran

For nearly two decades water scientists have been debating the need to use appropriate models for the questions being asked and the data available. This paper puts forward a rationale for a hierarchical framework for water balance modelling as it applies to mine sites. The hierarchy is based on the complexity of models and their data requirements. Scientific models are the most complex and require the most data; next is engineering models, then systems models and the simplest representations are given by conceptual models. A position is put forward that systems models have a range of uses that the others do not provide. A systems model, called SiteMiser, is described and its calibration illustrated. The model is applied to seven coal mines from the Northern Bowen Basin in Central Queensland. Currently, there is little relationship between total water use and coal production. This relationship is not any stronger when fresh (raw) water is compared to reused water. Leading practice water use levels are simulated for all sites. The simulation results demonstrate that there is considerable opportunity to reduce water consumption and, in particular, to import less fresh (raw) water to the sites.

Jan 1, 2006

By S. J. Swainson

PHOSPHATE ROCK is a low- priced commodity. This fact has influenced the choice of mining and beneficiating methods to a greater degree, perhaps, than in most other low-grade mining operations. The fact that many yards of everburden and matrix must be stripped and mined per ton of salable "rock" produced and sold has necessitated he development of relatively simple btneficiating plants having high capacity and low capital and operating costs. The law of diminishing returns must always be reckoned with in phosphate mining and washing, and often recovery must be sacrificed in favor of costs in order to achieve the highest over-all economic efficiency. The phosphate-bearing formation, known as "matrix," is composed of (1) phosphate pebbles, which are somewhat rounded in shape and which vary in size from 1-in, to micron sizes, (2) rounded quartz grains usually smaller than 10 mesh, and (3) clay, of varying "stiffness," which is the binder of the matrix. The phosphate pebbles vary in hardness. Their color, which varies from white to black, is not a reliable indicator of the Bone Phosphate of Lime (B.P.L.) content of the

Jan 1, 1944

By C T. Portelli

Belt conveyor transfers are the most likely location for high wear rates and failures. Belt transfers are necessary to change the direction of conveyed material and will remain a part of belt conveyor systems into the future. Burden being accelerated due to fall and changes in direction from one system to the next, prevents steady state flow which introduces component fatigue. The conveyor belt is considered the greatest cost item over the life of a belt conveyor system and consumes considerable downtime to replace, therefore a financial incentive exists to preserve this high-cost item. Other issues created at the transfer include health risks of uncontained dust and product losses due to spillage. Additional consideration to support the belt is one way to improve the life of components and contain dust within the transfer chute. The humble impact cradle/bed has changed little over the years whilst conveyor systems have achieved ever greater flow rates. Further development of the impact cradle is an opportunity to reduce maintenance costs and increase uptime. The peak technology on the market for conventional impact belt support is the dynamic impact cradle, which ensures the belt support area under the chute allows for some dynamic travel, whilst also maintaining a consistent skirt board area. The impact energy at a transfer when installed with Kinder Australia’s dynamic impact belt support system was measured to further understand the forces involved and how they compare with static belt support systems. Adding further dynamic capacity to the load zone has been shown to increase belt life by at least 30 per cent. Other components also benefit from reducing impact energy in the transfer and the incorporation of polyurethane bushes at roller supports has been employed further increase roller and frame life. Kinder Australia has developed a unique and innovative range of belt support technologies that further promote dynamic travel whilst maintaining a consistent skirt board area without a significant increase in belt-friction tension. This technology combines slider rails with rollers that can absorb impact independently within the support system and/or utilising exotic slider materials to overcome high belt speeds and/or system capacities. Kinder Australia has a vast library of documented case studies and application data to ensure the future systems being offered will survive, provide better chute sealing and protect the conveyor belt.

Sep 18, 2023

By Xiaolong Bi, Shaohua Luo, Longjiao Chang, Shiyuan Cao, Jianan Liu

iliary agent was proposed. The mineralogical transformation and silicon extraction kinetics of laterite nickel ore in alkaline hydrothermal treatment were studied. The effects of reaction temperature (175 ~ 250℃), molar ratios of sodium hydroxide to ore (1.05 ~ 1.2:1), and laterite nickel ore particle size (44 ~ 178 μm) on the extraction ratio of silica were investigated by using the shrinking core model. The results show that the extraction ratio of silica increases with the increase of reaction temperature, sodium hydroxide to ore molar ratio, reaction time, and the decrease of raw ore particle size. The kinetic analysis shows that the separation of silica in laterite ore can be described by internal diffusion model. The apparent activation energy (Ea) of the reaction was 8.87 kJ mol− 1, and the kinetic modeling was established.

Dec 2, 2021

By Xun Zhang, Hang Qiu, Andrea R. Gerson4, Shaomin Lei, Yubiao Li, Yu Meng, Zhenyu Pei, Min Lin

Efficient separation of trace muscovite from the surface/interface of quartz grains was accomplished during oxidizing calcination and catalytic pressure leaching of the hydrothermal quartz. Experimental results suggest that 98.97% or more of the muscovite was separated when quartz sand was calcined at 900 °C for 5 h and then leached by hydrochloric acid and ammonium chloride solutions as substitutes for leaching agents containing fluorides. The chemical processing techniques show high selectivity in purifying quartz sand by transforming mineral muscovite into active structures during oxidizing calcination, and then dissolving the active substances during catalytic pressure leaching

By Alan Alves Vieira

Uma das maneiras mais eficientes de aumentar a campanha dos refratários de conversores é o uso de técnicas de slag splashing e slag coating. Nestes processos, antes de sua execução, a escória de fim de sopro é modificada pela adição de materiais contendo, principalmente, MgO. Escórias de conversor contendo alto teor de FeO tem, como fase de equilíbrio mais provável a magnesiowustita (MW). Este estudo visa determinar se, nos curtos tempos de processo em conversor, e sempre a temperaturas bastante inferiores ao ponto de fusão do MgO, ocorre a dissolução do MgO e a saturação da escória em MW ou se a escória se mantém fora de equilíbrio. Os resultados indicam que a MW é formada e, em muitos casos, sua composição pode ser prevista com razoável precisão através de cálculos de equilíbrio por termodinâmica computacional.

Oct 30, 2017

By Rafael Sartim

A indústria siderúrgica possui aspectos ambientais associados ao seu processo produtivo ligados em grande parte à emissão de material particulado, efluentes líquidos e geração de resíduos. A emissão de material particulado ocorre durante diversas etapas do processo produtivo, cabendo a estes a aplicação de sistemas para o controle ambiental. Em especial, a planta de sinterização possui como característica emissões primárias ligadas à exaustão da máquina, e secundárias referentes aos sistemas de captações em linhas de peneiramento, retorno de finos e pontos de transferência de correias transportadoras. Para o tratamento das emissões secundárias, a ArcelorMittal Tubarão possui um sistema de despoeiramento. Em virtude de melhorias de processo e alterações na produção, o sistema necessita de uma maior vazão para atendimento à demanda atual. Neste contexto, este trabalho se propôs a avaliar e testar a técnica de supressão de pó em pontos de transferência entre correias transportadoras para verificar sua aplicabilidade. Como conclusão, constatou-se que esta técnica é aplicável em regiões específicas com bons resultados na redução de emissão visível. Além disso, o uso do supressor reduz a quantidade de captações necessárias ao sistema complementando o controle do atual sistema de despoeiramento.

Aug 16, 2017

By Jael Moutinho dos Santos

Em função do elevado consumo de corpos moedores de alto Cromo e do alto custo de sua fabricação com matéria prima nobre, busca-se o desenvolvimento de novas ligas de corpos moedores na busca de um melhor custo benefício. Devido ao efeito sinérgico do perfil de desgaste envolvendo fenômenos corrosivos e abrasivos em bolas de moinho, o desenvolvimento de novas ligas de ferro fundido branco alto cromo tem sido uma alternativa para suportar o desgaste precoce provocado por tais fenômenos. As amostras de corpos moedores, analisados mediante ensaio de análise química, dureza, análise micrográfica e seguidos de ensaios de moagem (úmido e seco), servirão a um desempenho comparativo para se designar a melhor liga a ser aplicada nos processos de moagem secundária de minério de ferro a úmido.

Oct 30, 2017

Semisoluble salt minerals are characterized by their ionic bonding and are distinguished from soluble salt minerals by their limited solubility in water. One group of semisoluble salt minerals being considered is the alkaline earth salt minerals, including fluorite (CaF2), calcite (CaCO3) and apatite (Ca5F (PO4)3), as well as celestite (SrSO4) and barite (BaSO4). Another group of semisoluble salt minerals being considered is the rare-earth salts, which include bastnaesite ((Ce, La) CO3F), monazite (CePO4) and xenotime (YPO4). Surface chemistry features of these selected semisoluble salt minerals are discussed with respect to flotation separations. First, the surface chemistry features of alkaline earth semisoluble salt minerals are reviewed, and then the surface chemistry features of rare-earth semisoluble salt minerals are examined. The discussion includes electrokinetic behavior, wetting characteristics and collector adsorption.

By H. W. Brandt

A field test was designed to inject a specially formulated two compound epoxy resin into the roof rock ahead of a working face to cement fractures and formation interfaces at the Westmoreland Coal Co., Winding Gulf Div., Eccles No. 5 Mine, Eccles, West Virginia. Five 30 foot long X 2 inch diameter, hold were drilled at an angle of 15° above the plane of roof line front the face of a working entry. The epoxy resin compounds were pumped through a proportioning unit and mixed in-line before being discharged into the drill hole under treatment it injection pressures up to a maximum of 450 psig. When the coal face was advanced an anomalous failure of the roof rock occurred in the treated section. Further testing was suspended until the cause of the failure could he determined. The polymers were tested, under confined conditions, in 2 inch pipe columns. Extreme temperature and pressure (up to 2400 psig) rises were recorded as they cured, It was concluded that this pressure source fractured the rock and caused the roof failure. The entire program was terminated after it was determined that the heat rise and resultant high pressures could not he controlled chemically or mechanically.

Jan 1, 1978

By Max J. Spendlove

This Bureau of Mines publication reviews current recycling trends in the United States. Although near-term prospects are poor for recycling most present wastes, urban refuse is an important exception. Such wastes comprise a mine above ground, and much less processing energy is normally required to recycle the constituents of urban ore than to obtain them in equal amounts from natural raw materials.

Jan 1, 1976