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By Kazuyoshi Shimakage, Shinji Hirai, Kenji Wada

"An amorphous zirconium oxide coating was prepared by the sol-gel process using zirconium tetra-n-butoxide on the surface of aluminum to improve the corrosion resistance to salt, acid and alkaline attacks. The coating films formed on the smooth aluminum substrates under UV-irradiation indicated an excellent corrosion resistance for salt, acid and alkaline attack tests. For example, the corroded area of coating film in salt attack test for 3600ks in the order of sol-gel coating· film< chromate film <boehmite film, and the sol-gel coating film had the best corrosion resistance. The coating film prepared on the coarse aluminum substrate by a boiling treatment after heat treatment at 573K also had greater corrosion resistance, and a water-avid surface appeared a contact angle of approximately 3°.IntroductionAs given in a previous paper1; a composite film consisting of a porous layer of anodically grown aluminum oxide filled with amorphous zirconium oxide and an amorphous zirconium oxide coating layer deposited thereon via the sol-gel process utilizing the dip-coating technique, was prepared to improve the alkaline corrosion resistance of aluminum. The alkaline corrosion resistance of these composite films was increased in the range of 24 to 50 times those of conventional anodic oxide films anodized in sulfuric acid. As a result, it was proved that heat treatment at 573K after dip-coating was an important process to .remove organic component from gel film and to accelerate the densification of coating layer. Furthermore, the effect of ultraviolet (UV) irradiation at ambient temperature on the densification of coating layer was also examined to lower the heat-treatment temperature2.Then, a sol-gel film prepared by UV irradiation at ambient temperature indicated that alkaline corrosion resistance of aluminum was superior in the range of 2.4 times to 2. 6 times that of the conventional composite film heated at 573K."

Jan 1, 2000

By D. R. Murray

"In 2017, Nutrien Allan Potash remediated a portion of the concrete liner in the production shaft. A set of underslung work platforms and collection boxes were used in conjunction with hydraulic splitters, jackleg drills and hand chippers to excavate and remove the broken concrete. New concrete was placed with the original pressure relief design, using a shaft slip form. Shortly after excavating, it was found that the estimated breaking rate and amount of original concrete in-situ was under estimated. Fifteen feet of excavated concrete (2719cu.ft) and ten feet (of replaced concrete was completed on April 28, 2017, and operation of the production shaft was returned to mine operations. During February 2019, Nutrien Allan Potash began remediation of a portion of the concrete liner in the service shaft. The project is different than the 2017 project, as the remediation has occurred during normal running operations and occurred only on night shift. Rather than hydraulic splitters and hand chippers, the new method includes a concrete saw and mechanical excavator from a working platform. The selected method is based on the lessons learned from the 2017 project in the production shaft. The service shaft project was scheduled to be completed in July, 2019. INTRODUCTION Nutrien Allan Potash is located approximated 75 km east of the city of Saskatoon, Saskatchewan, Canada. There are currently two shafts at Nutrien Allan Potash: the Production Shaft and the Service Shaft, transporting people and material from surface to a depth of 3,335 ft. The Production Shaft was completed in 1967, with one section of grey cast iron tubbing installed in the Blairmore formation between the 1605 and 2037 ft Levels. A second set of cast iron tubbing was installed in the Duperow formation between 2203 and 2463 ft Levels in 1999. The remainder of the concrete as of todays standards is designed as a pressure relief liner. The Service Shaft was completed in 1968, with one section of grey cast iron tubbing installed in the Blairmore formation between the 1600 and 2048 ft Levels. A second set of cast iron tubbing was installed in 1981, with 169 ft installed through the Duperow formation. The remainder of the concrete as of todays standards is designed as a pressure relief liner. PRODUCTION SHAFT REMEDIATION During the second quarter of 2015, the Mine Engineering team were notified of an area of concern in the production shaft. The shaft specialists of Golder Associates Ltd (Golder, formerly Alan Auld Canada) were contacted to complete an inspection of the production shaft liner with emphasis on the area of concern. Based on the inspection and documentation review, it was determined that the concrete at the 2804 foot elevation had been broken out for some time and was retained with #8 rebar bolts with resin encapsulation. The broken concrete was encroaching on the clearance to the conveyance."

Jan 1, 2019

By L. H. Gevantman

A program for the compilation of evaluated physical and chemical numerical properties data is being pursued at the National Bureau of Standards within the Office of Standard Reference Data. This program is being sponsored by the Department of Energy and managed by the Battelle Office of Nuclear Waste Isolation in Columbus, Ohio. The intent is to assemble a reliable body of numerical properties data concerning candidate mineralogical materials in which high-level radioactive wastes are to be buried. The ready accessibility of the data to site designers and the credibility achieved through the evaluative process are designed to help assess and compare the feasibility of each candidate material for use as a disposal site. Both generic and site-specific data are to be assembled. To date, generic rock salt properties have been assembled and published by the NBS as NBS Monograph 167. Details of the effort to produce this book are discussed.

Jan 1, 1982

By Andre Cezar Zingano

"The empirical approach for pillar design assumes that geological conditions should be perfect, such as horizontal seams, and that pillar strength and behavior will only depend on the coal seam strength and the vertical pressure caused by the overburden thickness on the coal seam; this vertical pressure is based on the tributary area. Empirical methods do not consider the effect of the interface between the roof and pillar or the floor and pillar.The effect of the interface shear strength on final coal pillar strength has been studied since the 1960s. However, few case studies have been generated from that, especially in shallow underground coal mining (less than 100 meters). This case study involves a mining section at the 101 coal mine in the Santa Catarina state of Brazil, which is experiencing pillar rib spalling and yielding because of a 1-to 2-cm-thick clay layer at the area of contact between the coal seam and immediate roof. The depth of the coal seam is 60 m on average and 2.3 m in height. This particular section also has 12-14% (7-8°) of seam inclination. The pillar size varies from l lxll to 13xl2m; thus, the safety factor (SF) based on the ARMPS approach is more than 1.5. The objective of this paper is to determine the cause of the pillar yielding and study the effect of the clay layer at the interface between the roof and pillar, including the inclination of the coal seam. This study conducted empirical and numerical models (2D and 3D) to understand the effect of the thin clay layer. The conclusion is that the clay layer affected the strength of the interface between roof and pillar, causing rib spalling and reducing the pillar strength.INTRODUCTIONPillar stability and deformation depends on the coal seam strength and vertical pressure caused by the overburden thickness on the coal seam, and this vertical pressure is based on the tributary area. The effect of the interface shear strength on the final coal pillar strength has been studied since the 1960s. However, few case studies have been generated from that, especially in shallow underground coal mining (less than 100 m). This interface could be represented by a thin clay layer or an abrupt contact between the coal seam and a rigid sandstone layer of the immediate roof. These two interface conditions are found in the coal mines of Brazil, and the effect of the interface shear strength could increase when the seam's inclination is higher."

Jan 1, 2016

By Daniel W. Su

This paper presents the implementation and evaluation of the hydraulic fracturing technique and Longwall Visual Analysis (LVA) software to mitigate the impact of a 1,000-ft (305-meter) widemassive sandstone channel on a 1,500-ft-wide (457-m-wide) longwall face. Based on a underground roof geology reconnaissance program, four frac holes were drilled and fraced along the center axis of the sandstone channel. To further provide detailed monitoring of the longwall face, the Longwall Visual Analysis (LVA) software was installed to track the face pressure and cavity formation index. In mid-December 2011, the longwall face approached and entered into the western edge of the sandstone channel. The longwall face mined through the center axis of the sandstone channel in mid-January 2012 and advanced outby the eastern edge of the sandstone channel in early February 2012. Results from daily underground observations and production delay analysis confirmed the effectiveness of the hydraulic fracturing program and the validity of the LVA Software.

Jan 1, 2012

By Andrea Donadon

This article introduces the Danieli Total Asset Management System, which involves 360 degrees service methods and equipment. Danieli Condition Monitoring System and Danieli Torque Monitoring System are fundamental to evaluate the conditions of the working components in heavy duty transmissions. The first one monitors the vibrations and the lubrication fluid conditions with the purpose to identify the presence of malfunctions, by detecting any variation of the signals from the standard values. The second one monitors the transmitted torque for each spindle and gearbox, with the aim of detecting any anomaly in torque distribution and magnitude, and evaluating the residual life of the mechanical parts, on the base of a dedicated fatigue damage algorithm. All these features are useful in avoiding serious damages to machines, facilities and people, but allow also planning the maintenance and overhaul activities with efficiency, in order to achieve the best plant availability and reliability. The data analysis is made by the IntelliCMS software, which interfaces with plant and Danieli operators and includes the possibility to cooperate by remote connections, simplifying service activities and support. All these features allow providing new full service programs, where the client is totally supported in maintenance, overhauls and substitutions. This is the best way to ensure the most efficient, high quality and reliable after sales assistance.

Aug 16, 2017

By R. Letsaole, H. Mabowa, J. Sehat, J. Tshilongo, T. Rampfumedzi, N. Ntsasa, A. Mkhohlakal1

This study explores the use of co-collectors to enhance the recovery and determination of rhodium during fire assay with lead collection, followed by acid dissolution using conventional hot plate methods. Rhodium, a critical platinum group metal, poses analytical challenges due to its low natural abundance and complex chemistry. Among the co-collectors tested, palladium and tellurium demonstrated significantly improved rhodium recoveries, ranging between 100% and 120%, whereas silver resulted in poor recovery and higher error margins. These findings highlight that co-collectors can enhance the efficiency and sensitivity of platinum group metal analysis, although their effectiveness is dependent on the chemical interaction with the target element. Acid dissolution was essential to ensure complete digestion of prills prior to analysis, enabling accurate quantification of rhodium. Overall, the findings suggest that palladium and tellurium are effective co-collectors for rhodium determination in fire assay, while silver and lead flux alone are unsuitable. This work provides important insight into optimising fire assay procedures for reliable rhodium analysis, with potential benefits for platinum group metals recovery and economic evaluation.

Mar 6, 2026

By R. M. Imhof, M. J. G. Battersby, G. Ciernioch

Pneumatic flotation is rapidly becoming accepted in the main stream of flotation techniques. Imhoflot is a pneumatic flotation process that in recent years has undergone progressive development. It combines short flotation times with excellent selectivity by employing intense pre-aeration and dispersion. K+S GmbH (K+S), Germany, has installed a complete Imhoflot flotation plant at its Sigmundshall plant. The plant treats hard salt consisting of sylvine, halite, anhydrite and kieserite. The reason for selection was that Imhoflot achieves the required grades of plus 60 weight percent K2O whilst offering lower operating costs than conventional flotation installations.

Jan 1, 2002

By P. K. Frempong, S. D. Butt

"A case study for the application of a novel geostatistical technique for resource estimation of a narrow steeply dipping, gold-silver mineralized quartz vein deposit is presented. The technique is novel in two respects. First, mineral grades are kriged directly rather via the accumulation method more often applied to vein deposits and, second, a modified 2D ordinary kriging algorithm is used that allows the calculation of a single grade and variance for irregular shaped blocks of varying sizes. The objective of this investigation was to evaluate the suitability of this novel geostatistical technique for resource estimation of the Poura mine deposit and, if appropriate, to lay a firm foundation for future geostatistical work at the mine.The reserve estimation concentrated on the remnant ore blocks and pillars in both underground and surface workings. The data, which was collected in 2D coordinates with grade and vein thickness values, was first analyzed statistically and used to compute experimental semi-variograms. Appropriate semivariogram models were fitted and various aspects of the estimation technique were evaluated using cross-validation error analysis, with acceptable results. A block kriging computer program called Krige2D was developed to implement the modified 2D kriging algorithm and calculations. Production data were not available to evaluate the computed block resources, but they were compared with a previous resource data determined using an arithmetic approach. The geostatistical technique estimated slightly higher grades but lower overall tonnages as compared to the earlier arithmetic estimates."

Jan 1, 2004

A case study for the application of a novel geostatistical technique for resource estimation of a narrow steeply dipping, gold-silver mineralized quartz vein deposit is presented. The technique is novel in two respects. First, mineral grades are kriged directly rather via the accumulation method more often applied to vein deposits and, second, a modified 2D ordinary kriging algorithm is used that allows the calculation of a single grade and variance for irregular shaped blocks of varying sizes. The objective of this investigation was to evaluate the suitability of this novel geostatistical technique for resource estimation of the Poura mine deposit and, if appropriate, to lay a firm foundation for future geostatistical work at the mine. The reserve estimation concentrated on the remnant ore blocks and pillars in both underground and surface workings. The data, which was collected in 2D coordinates with grade and vein thickness values, was first analyzed statistically and used to compute experimental semi-variograms. Appropriate semi- variogram models were fitted and various aspects of the estimation technique were evaluated using cross-validation error analysis, with acceptable results. A block kriging computer program called Krige2D was developed to implement the modified 2D kriging algorithm and calculations. Production data were not available to evaluate the computed block resources, but they were compared with a previous resource data determined using an arithmetic approach. The geostatistical technique estimated slightly higher grades but lower overall tonnages as compared to the earlier arithmetic estimates.

Feb 1, 2004

Coal has been mined in the central Appalachian coalfields of southern West Virginia, western Virginia, and eastern Kentucky for more than a century. The dwindling reserve base consists in large part of coal that would have been considered unmineable by earlier generations. Nearly every current operation is working on a property where coal has been extracted in the past, from seams either above, below, or both. NIOSH is conducting research aimed at helping mine planners prevent hazardous conditions due to multiple seam interactions. To-date, more than 300 case histories have been collected from underground mines, mainly from central Appalachia. This paper focuses on several of the more challenging situations that have been encountered, including: • Room-and-pillar development 20 ft (6 m) beneath full extraction workings at a depth of 1,000 ft (300m) of cover (Virginia) • Pillar recovery 45 ft above full extraction workings at 900 ft (270 m) of cover (Virginia) • Near-simultaneous room-and-pillar mining with pillar recovery with 40 ft (12 m) of interburden and 1,500-2,000 ft (450-600 m) of cover (Kentucky) • Longwall mining directly beneath main entries in overlying seams (West Virginia) • Some of these operations have been highly successful in overcoming the challenges, others less so. The lessons learned from their experience will help ensure that these and similar difficult reserves can be mined safely.

Jan 1, 2006

By Timothy Barton

The uniaxial compressive strength (UCS) is the most fundamental measurement used in geotechnical rock characterization for mine design. While there are standardized procedures for how to conduct UCS tests, there are no firm guidelines as to when to conduct them. However, it is well known that the strengths of at least some rocks can change during the time between when the core first comes up out of the hole and when it is prepared and tested in the lab. The goal of this NIOSH (National Institute for Occupational Safety and Health) study was to evaluate UCS changes occurring in a broad range of weak coal measure rocks over a one-year time span. The study found the highest moisture contents were measured when the core was fresh, immediately after it was taken from the hole. The specimens then dried rapidly over the next few weeks. Subsequently, sample moisture contents decreased slightly in the winter and increased in the summer in response to the ambient changes in humidity. The measured UCS of the core also changed during the year, apparently in response to changes in the moisture content. The UCS values from the dry, winter months were, on average, 60% higher than the values obtained when the core was fresh, and the summer UCS was approximately 11% lower than the winter UCS. These findings have implications for the use of UCS as an input parameter for both empirical and numerical mine design methods. UCS values of unprotected core tested weeks to months after drilling can be significantly stronger and indicate stronger roof sequences than warranted. In order to obtain the most representative and reliable UCS value, it is necessary to test the core, or wrap and seal it, at the drill site shortly after recovery.

Jan 1, 2008

By William R. Yernberg

The combined 80th Annual Minnesota Section of SME Meeting and 68th Annual University of Minnesota Mining Symposium was held April 17 and 18, 2007, in Duluth, MN. About 350 mining industry professionals attended the conference, including engineers, executives, mining managers and suppliers from the United States, Canada, Australia, Finland and Brazil. This year’s theme was “Consolidation – Growth – Technology.” The 80th Annual Minnesota Section of SME meeting included concurrent technical papers sessions, a keynote session that featured two distinguished speakers and a general managers session in which taconite mine operators provided updates on their operations. The Minnesota Section meeting also offered an SME short course titled “Control the Feed, Control the Mill.” More than 50 individuals at-tended the short course.

Jan 1, 2007

By B Mohanty, M P. Roy, P K. Singh

"The measured response of residential structures is a critical indicator of troublesomeor potentially damaging ground vibrations. A study was conducted to evaluate theresponse of structures situated in the periphery of four open-pit coal mines in India. Although, most of the structures were at far-off distances from the present blasting sites, an attempt was made to document the response of structures to blast vibration for future applications to optimize the blast designs for the safety of the structures. The study involved a total 215 blasts, employing one-, two- and three-hole calibration study, and production blasts. The bench height varied from 7.5 m to 42 m, and boreholes loaded with emulsion and slurry explosives were 250, 260, 270 and 310 mm in diameter. The explosive detonated in a blast were between 300-198400 kg whereas in a delay it was 33-24800 kg. Up to 12 tri-axial vibration sensors were located in overburden along a linear array from 25 m to 6.5 km distance from the blasts. Altogether, 1512 blast vibration signatures were recorded. Production and specially fi red single-charge blasts allowed the determination of natural ground frequency. The fundamental frequency of the structures ranged between 3.13 to 10.6 Hz, the same as those of the ground vibrations. The amplifi cation of vibration in the structures was in the range of 1.6 to 5.6. The study details the interaction between ground vibrations and selected structures, and the means to reduce amplifi cation of vibrations in the structures and persistence of vibrations through improved blast design."

Jan 1, 2008

By N. R. Shoko, J. Chirasha

Zimbabwe Alloys has been producing Low Carbon Ferrochrome since 1953. A number of operational and technical advances have been made since then. Some of these advances improved production significantly. Process control, however, remained a challenge not only in the production process itself but also in the handling of finished product. In addition the handling of the slag created an environmental problem. Process control issues were addressed by Zimbabwe Alloys Limited and Japan Metal & Chemicals (JMC) entering into a Technical Transfer Agreement. The aim of the technical transfer was to improve production, alloy quality and, thereby, the financial performance of Zimbabwe Alloys. In addition, the Low Carbon Ferrochrome production process was made environmentally friendlier by modifying the final slag handling methodology. The aspects that are covered and discussed in this paper are, ladle refractory lining changes, improved control of the process, changes in the alloy casting methodology and granulation of the final slag. The improved control of the process was enhanced by the conversion from ladle duplexing to argon purging, introduction of on-line sampling and introduction of second stage process. The combined effect of the above was a significant improvement on on-grade material production, production efficiencies, unit cost of production and a cleaner working environment.

Jan 1, 2004

By B. R. Zernich

Advances in tunneling technology, such as Earth Pressure Balance and Slurry Shield methods, have allowed the tunneling industry to construct tunnels in increasingly difficult ground conditions. In recent years, a number of civil projects including large diameter train tunnels, subway tunnels, water tunnels, sewer tunnels, and combined sewer tunnels have been successfully completed deep beneath the water table in soft ground conditions utilizing modern day Tunnel Boring Machines (TBM). With the increase in difficult ground conditions and higher water pressure comes the inherent need to utilize compressed air to gain access to the TBM?s cutterhead and cutting tools. This paper focuses on one such instance in Los Angeles, CA in which Traylor Brothers Inc. performed a cutterhead intervention by compressing the heading of an 11-foot diameter tunnel to approximately 3 bar gauge pressure. This paper focuses on the environmental controls used to manage ventilation, oxygen levels, temperature, and pressure, as well as discusses the problems associated with toxic gases and the increased risk of fire. The paper will also cover the physical science of the environment and the increased risks of performing basic job functions while in a compressed air heading.

Jan 1, 2009

By K. D. Mills, R. G. Robins, C. G. Anderson, L. G. Twidwell

Arsenic is a metalloid which has attracted great environmental scrutiny in recent decades. Moreover, its control and deportment is becoming increasingly important in the metallurgical processing of modern complex ores and concentrates. As such the authors of this publication have a combined professional experience of well over 100 years in the study and hydrometallurgical treatment of arsenic. Hence, this paper will cover arsenic fundamentals along with a review of technology for removal, fixation and stabilization. Finally, an application of industrial Alkaline Sulfide Leaching (ASL) of a copper enargite concentrate will be elucidated.

Jan 1, 2014

By B. Sivarama Sarma, Biswabikash Rout

"Seepage control has to be achieved with plastic concrete cut-off diaphragm walls in dam structures. Materials selected for construction of cut-off walls must be durable, impermeable and have stiffness comparable to the surrounding soil.Plastic concrete provides a feasible and economical solution for construction of durable and impermeable cut off walls for dam structures. Plastic concrete wall should not be understood as a concrete wall with similar mechanical properties of concrete used in buildings, piles and spillways sections. Though it consists of the same materials as those of conventional concrete it has the major differences in end product due to predominant addition of bentonite slurry in the mix with very high water cement ratio. This makes the hardened concrete with very low compressive strength less than 5MPa and high failure deformations after the peak load.This technical paper examines a case study, the typical specifications on demand for construction and the issues corresponding to misunderstanding of the material as a structural grade concrete material. Conclusions were drawn based on a few project site quality data and trial mix experimental data. The anomalies in specifications on demand for construction of curtain wall in a dam structure were removed with modifications.INTRODUCTIONDiaphragm walls which are constructed in trenches made of plastic concrete basically serve the function of seepage control under confined measures. They should have the ability to sustain and undergo large plastic strains as compared to conventional concrete. The three basic mechanical properties of plastic concrete cut-off walls are to have least permeability, minimum strength to retain its shape and ability to undergo large deformations under confined loading conditions. The constituents of plastic concrete are cement, bentonite, coarse and fine aggregates, chemical additives to improve flow of concrete and sometimes to retard the setting time and water."

Jan 1, 2017

Separation of Minerals Using Electrical Fields The mineral processing industry requires alternative separation techniques to help deal with rising energy costs and decreasing ore grades. Dielectrophoresis is one possible technology. It uses non-uniform electrical fields to separate particles on the basis of their permittivity. In order to determine its viability, the dielectrophoretic force was measured for individual chalcopyrite particles in ethanol. The measurements were made by attaching the individual particles to glass fibres and measuring how far they were deflected by a non-uniform electrical field. Six sizes of chalcopyrite particles were tested and the force was found to increase as a function of particle radius cubed. The particles were also positioned at different points in the field in order to determine the effect of the electrical field gradient. The force was found to increase with the inverse cube of the distance from the centre of the particle to the pin electrode. With the effect of these parameters fully characterised, the single particle test cell can be used to determine the permittivity of single particles of various composition.

Sep 13, 2010

By Robert J. Timko, Charles D. Taylor, Edward D. Thimons, Tom Mal

A test system was developed for measuring airflow in the National Institute for Occupational Safety and Health (NIOSH) ventilation gallery using a three-axis ultrasonic anemometer. The gallery was used to simulate face airflow conditions in underground mines having a blowing curtain. Airflow data collected at multiple sampling locations between the face and the end of the curtain were used to draw airflow profiles for different curtain setback distances, intake flow quantities and entry widths. In addition, methane was released at the face, measured at the sampling locations, and displayed as methane distribution in the area between the curtain and the face. Entry geometry had a significant effect on airflow patterns, and the flow patterns affected the distribution of methane in the entry. Flow measured at and parallel to the face was a good predictor of methane dilution and removal within two feet of the face.