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By J. L. Holman

The Bureau of Mines is investigating recovery of Ni, Co, Cr, and other metals from mixed contaminated supera110y scrap. The scrap is melt-refined and cast into anodes for electrodeposition of recyclable Ni-Co alloy. Melt oxidation using roasted superalloy grinding sludge as oxygen source can divert the Cr to the slag but with excessive Ni-Co loss. Melt oxidation-carburization or direct melt carburization retains -95 pct of the Ni-Co in the anode alloy. With direct carburization, -90 pct or more of the Cr and other refractory metals report to the anode alloy, largely as carbide phases insoluble in electrolysis. Electrorefining data relate parameters such as controlled cathode potential, Fe and Cr impurities, pH, and compartmented cell use, to current efficiency and Ni-Co deposit quality. Recovery of -90 pct of the Ni-Co in the scrap can be achieved. Preliminary experiments to recover Cr, W, and other metals from the anode sludge and other byproducts are discussed. 347

Jan 1, 1987

By A. B. Clayton

The Bumpus Cove area is in Unicoi County, Tenn., about 9 miles south of Jonesboro and 5 miles northwest of Erwin. Iron and lead ores were mined in the Bumpus Cove area before the American Revolution. The production of those metals continued intermittently until 1916. In 1850 this area was the most important producer of iron in the South. In 1911 several carloads of zinc ore was recovered from old dumps and shipped to Missouri smelters. In 1913 systematic mining of zinc ores was begun and continued until 1916. After that year, mining again became sporadic and continued so until discontinued in 1943.

Jan 1, 1949

By O. Durand

The Cerro Verde Hydrometallurgical Plant, located at Arequipa in the southern part of Peru, started its operation in 1977 with a design capacity of 33,000 MT/year of copper cathodes. The plant has treated 61,055,000 MT of ore mainly oxides with a content of 1.01% total copper and 0.67% of soluble copper. The leaching plant has three pads that produce 4.0 gpl copper solution. The solvent extraction plant has four trains with three extraction stages, two stripping stages with a single mixer in all stages. The mixer-settlers are 316 stainless steel and the pumps are vertical turbines. The flowrates of 1,300 gal/mil of aqueous and 1,300 gal/min of organic at a 1/1 ratio. The electrowinning plant contains 208 commercial cells and 18 starting sheet cells. Each cell has 47 anodes and 46 cathodes. In addition to describing the hydrometallurgical plant, this paper also mentions efforts directed at reducing costs and improving operations. The initial results from leaching secondary sulfides, which started October 1985, are also discussed.

Jan 1, 1987

By ALICE V. Petar

Like many gem materials, amber has a colorful history which may be traced through the writings of the ancients and the ornamental relics discovered from time to time. Like few gem materials, however, it is distinctly useful in products whose value has no connection with the gem industry. Long prized for its beauty, amber was fashioned into articles of jewelry and ornaments to please the fancy of ancient rulers and to find a place among treasured pos- sessions in their tombs; it has been used by adherents of various creeds for rosaries and other religious symbols; and although still sold for these pur- poses it also lends itself to such commercial purposes as raw material for varnish. Amber is only on the border-line of the mineral kingdom; actually it is of vegetable origin, having been formed as resin from trees of the conifer family that existed during the Tertiary period. It is the hardest of the fos- sil gums. The United States produces no amber, although a few occurrences are known. Most of the world's supply comes from East Prussia, where it is ob- tained from both land and sea. For many years pieces of amber were gathered from the Baltic by fishermen and deep-sea divers; and although about 10 per- cent of the Prussian amber is still recovered from the sea, most of the out- put is mined from open pits on the Samland Peninsula.

Jun 1, 1934

By Theresa M. Bodus

The strength of roof shales is, in part, a function of the preferred orientation of clay minerals within them. Therefore, analysis of clay fabric under both air-dried and hydrated conditions should be helpful in understanding roof shale failure. Core samples were collected from the Energy, Anna, and Lawson shales, which are locally present as roof shales of the Herrin No. 6 coal of southern Illinois. The Clay Fabric Index (CFI) was measured for thirty core samples, using X-ray diffractomtry, to investigate the relationship between clay fabric and roof collapse in coal mines. Greater CFI values indicate a weaker preferred orientation among clay minerals, which generally results in a weaker inter-grain bond. Average CFI values for air-dried samples were: 0.15 for Anna shale; 0.20 for Energy shale; and 0.37 for Lawson shale, .After the introduction of water, average CFI values increased to: 0.28 for Anna shale; 0.22 for Energy shale; and 0.43 for Lawson shale. The laboratory results indicate the following: [l] under air-dried conditions, Anna shale is the most stable, followed by Energy and Lawson shales; and 121 under hydrous (mine) conditions, Energy shale is the most stable, followed by Anna and Lawson shales. In mine environments where roof failures involving Energy shale have occurred, planar trends delineated by a relatively high density of small (0.2-4 cm diameter) iron concretions have been reported along the failure surface. Radial cracks have been observed around unsealed anchor bolt holes in the Anna shale. Instability of the Lawson shale is ubiquitous in coal mines. In the laboratory, similar physical changes were noted in the shale samples after the introduction of water, including [l] increased hydration around the perimeter of iron concretions in Energy shale, [2] radial extension cracks in Anna shale, and 131 extreme slaking of Lawson shale. Measured increases in the CFI reflect the observed physical changes of the samples upon the introduction of water, which probably reflect changes in strength that may result in roof failures in hydrated mine environments.

Jan 1, 1989

By Olliver J. G

Over 400,000 tonnes of kaolin, sillimanite, mica, kyanite, feldspar and rutile have been mined from the unique Williamstown orebodies since their discovery in the early 1900's. Numerous companies; both large and small were associated with the early development of these deposits but since the formation of Australian Industrial Minerals in 1947, this company has been the only significant producer. A combination of mining and management problems almost forced closure of the mine in the late 1970's but this was averted by a changed attitude towards mine planning. Mine development is now based on detailed geological and technical investigations, exploration for additional ore reserves is being conducted and laboratory and pilot scale studies are being undertaken to utilise both low grade ores and waste materials. The professional approach to mine and market development will ensure that Williamstown mineral products will continue to be available for many years.

Jan 1, 1989

By Jack L. Taylor

As expected from similar crystal structures and favorable atomic size factors, titanium, vanadium, and molybdenum are completely soluble in one another above the transformation temperature of titanium. The fl phase parameters of the continuous solid solution are shown graphically. Limiting compositions for retained fl phase have been determined. VANADIUM and molybdenum both have body-centered-cubic structures at all temperatures and, from the atomic diameter comparison factor, 3.9 pct, would be expected to form a complete series of solid solutions. The existence of complete solubility has been confirmed by work' at the Jet Propulsion Laboratory. Furthermore, vanadium and molybdenum have favorable atomic size factors to form complete binary solid solutions with the B phase, high temperature form of titanium, which also has body-centered-cubic structure. Pietro-kowsky and Duwez' and Hansen et al." have established the existence of the complete series of solutions in these binary systems. It would be logical, therefore, to expect that p-titanium, vanadium, and molybdenum would be completely soluble in one

Jan 1, 1957

Results of laboratory studies on the flotation of marmatite (zinc sulphide) with new reagents, which were developed to avoid the use of copper sulphate, are presented.Episulphides were chosen as the basis for the reagents because of their reported special chemical affinity for zinc and cadmium. Attempts were made to solubilize and introduce functional groups to episulphides with organic and inorganic acids, ammonia, phenol, aniline, diethylamine, and pyridine. As a class of reagents, the episulphide-amine combination was generally found effective in zinc sulphide flotation to a greater or lesser degree. Best results were obtained with ethylene sulphide-aniline combination. Although anilino-ethyl mercaptan is the reported reaction product of aniline and ethylene sulphide, it was concluded that the effective zinc sulphide flotation with ethylene sulphide-aniline combination is not entirely due to the formation of the mercaptan.The economics of the possible usage of ethylene sulphide-aniline reagent are discussed.

Jan 1, 1974

By G. R. Hopkins

For several years prior to about the middle of 1928 both the number and capacity of natural-gasoline plants showed a steady increase; this resulted from a material gain in the supply of casinghead has due to the discovery of a number of flush fields with relatively high gas-oil ratios. From 1928 to date some form of proration has been continually in force, with a consequent curtailment in the supply of wet gas. This decline in available gas and a severe decrease in prices, due largely to the increasing competition of light refinery products, has eliminated virtually all of the weaker units during the last 5 years, with the result that the number of plants declined from 1,155 on January 1, 1928 to 19035 on January 1, 1930, to 909 on January 1, 1932, and then to 859 on January 1, 1934, The struggle of the small high-cost producers to exist is illustrated further by the trend in the number of shut-down plants, which has increased from 36 on January 1, 1930 to 100 on January 1, 1932 and to 128 on January 1, 1934. The increase in the number of plants prior to 1929 resulted in a material gain in the total capacity, but the decline in number between 1929 and 1932 was not followed by a corresponding decrease in capacity, as gains resulting from the construction of a few very large plants overbalanced the loss due to the dismantling of a large number of small ones. However, the low prices of 1932 and 1933 supplied little incentive for new construction, and the total capacity declined in approximately the same ratio as the number. Thus the total capacity declined from 11,387,000 gallons daily on January 1, 1932 to 13,060,000 gallons daily on January 1, 1934, Of the latter 9,181,000 gallons (91 percent) represented the capacity of the operating plants and 679,000 gallons (9 percent) the capacity of the idle plants.

Jan 1, 1934

By Syd S. Peng

According to accident statistics (l, 2), roof fall accidents occur quite frequently at the intersections of underground? openings and account for up to 30% of the roof fall fatalities. But this figure will certainly go up considerably if roof falls not associated with any fatal accident are included in the analysis. Unfortunately, nonfatal roof falls are seldom documented. In the underground coal mines, there are two types of entry intersections. One is the three-way (V type) and the other is the four-way (T type) intersections. A three-way intersection occurs whenever the mainline track haulageway turns at an angle into a section haulageway. The four-way intersections by far the most common type in the U.S. under-ground coal mines are formed by the intersections of two entries which are oriented perpendicular to each other or by the intersections of entries and crosscuts. However, crosscuts are frequently driven at an angle to the entry to facilitate machine movements. The four-way intersections formed by this method of crosscut development are angled. At the intersection of two underground openings, the diagonal roof span is wider than the width of each individual opening. This is one of the major reasons why roof falls occur more likely at the intersections than in the entry between pillars. Consequently, special intersection support plans are usually employed (Figs. 1 and 2) for intersections. The most popular practices are to decrease roof bolt spacing 1 ft. less than or to increase roof bolt length 1 to 2 ft. longer than those employed in the entry between pillars (3). The increase in bolt length or decrease in bolt spacing can be applied to all of the bolts in the intersection or employed only for the strategically located bolts depending on the individual mine practices. These rather generalized practices seems to be adequate for some areas but in many cases inadequate for others. Occasionally, the neighboring two lines of chain pillars are staggered such that the crosscuts in one row of chain pillars face the centers of the chain pillars in the neigh-boring rows. This layout forms T-type three-way intersections which are also inadequate for most weak roofs (3, 4). A study was therefore initiated to develop special techniques for intersection supports. The first phase of the study was the analysis of the stress fields for the underground entry intersections. A three-dimensional stress analysis was necessary for this purpose. Unfortunately, the three-dimensional problems of complicated boundary conditions are beyond the existing analytical methods. The three-dimensional finite element method (FEM) was therefore employed in this study. In the analysis, square pillars of 40 feet wide and an entry height of 8 feet were assumed while entry widths varied at 14, 20 and 26 feet. This model was selected to simulate the mine where roof falls data were collected. The second phase of the study was the collection of field data. The sizes of the roof falls including heights, lengths and widths were collected and analyzed. In the third phase study, the results of the first and second phases were compared and discussed. The analysis of field data revealed an arching zone within which roof falls occurred. The arching zone above an entry obtained empirically was compared with the calculated stress contours. Assuming that the bolts must be anchored in the rock strata outside the arching zone, the preferable systems of bolting were proposed. Also the amount of pretension required to inhibit sliding between layers was discussed.

Jan 1, 1978

By K. Honkivaara, S. Junnikkala, J. Aho, K. Föhr, P. Lampinen

"Bubble area flux has been claimed to be a major tool to dimension flotation equipment. The paper describes laboratory scale (batch and 301 continuous cell using plant feed) and small-scale (1 ,8m3) industrial experiments with coarse-grained massive sulphide ore.Samples were taken with different froth thickness and air addition rates while the bubble size was measured with an UTC capillary device. Problems of averaging the bubble size measurements and the bubble area flux measurements are also discussed.Material balances were calculated using the commercial program BILCO. The flotation rate constants were calculated for pulp and for froth assuming that we can extrapolate the flotation rate constant of the pulp phase from tests using very thin froth thicknesses.The results indicate that the bubble area flux is not alone an adequate dimensioning tool. With fine sizes there was a nearly linear relationship between the bubble area flux and rate constant for constant impeller revolutions. For coarse sizes the form of the relationship is non-linear and seems to go through a maximum value. Thus the final flotation outcome is not a simple function of bubble area flux but depends on the particle size distribution and other more traditional flotation cell dimensioning variables. The effect of the froth residence time in the total recovery of coarse particles is large, but will not be treated in this paper."

Jan 1, 2000

By Helen Francis

Over the last decade, lower ore grades and deeper mine environments have demanded that mining companies develop new technologies (tools and processes) to ensure a mine?s economic sustainability. At Inco Ltd., this demand has lead to the focus of technological development within the area of automation. Delineation (Drilling and Interpretation) is a key step in the determination of ore grade and location and therefore was chosen as a priority area for enhancement through automation. Focusing on the tools (the diamond drill) automation, significant benefits have been consistently achieved in terms of productivity, process efficiency, operational safety, cost reduction, component life cycles and machine reliability. It is suggested that optimum benefits have yet to be achieved, and will not be achieved until the human aspects of automation have been properly addressed. Since project inception, the human aspects of automation were recognized as critical to the success of the diamond drill automation project. However, it was only upon the installation of the Automated Diamond Drill in the field and its continued use on a daily basis that this issue received due attention. The human aspects of automation can be broadly addressed as economic, physical and psychological. This paper, with examples from the field, will discuss the human aspects of automation in each of these areas. The paper will draw from observations and experiences acquired throughout this project and recommend implementation strategies that should be utilized in future automation projects to enhance both the acceptance of automation and the success of the automated process itself.

May 1, 2002

By Burns K. L

Keyboard patterns of hundreds of minor faults with vertical displacements of 3 mm to 2 m occur within the Greta coal seam and cause serious mining problems in collieries. Many of the faults are concentrated in linear zones termed swarms. One swarm is 600 m wide and more than 800 m long and others are of comparable size.The minor faults between the swarms are normal and are relatively widely spaced and show dip-slip movements, but the faults within a swarm are clustered and show strike-slip and oblique-slip movements. Fault swarms ofthis size and frequency have not previously been described from the Sydney Basin or on a comparable scale elsewhere but appear to be a widespread phenomenon in Australian coalfields. The faults are assigned to classes onthe basis of orientation which are then assigned to sequential phases I to IV on the basis of offsetting relations between representatives of each class. Phase I faults are minor thrusts. Phase IT, Ill, and IV faults are concentratedin the swarms and show sinistral strike-slip and normal dip-slip movements. The interference of slickenlines indicates that multiple movements have occurred within a single phase; their order is (i) strike slip (ii) dip slip and (iii) oblique slip. All faults truncate and post-date both cleat and sedimentary "stone" dykes.Phase I minor thrusts trend at a high angle to the Hunter Thrust and are considered to predate the Late Permian movements on the Hunter Thrust. Phase II and III minor faults are younger and may be any age between the latePermian and Tertiary.

Jan 1, 1978

Importance of Strain to Fragment Strength in Blasting Induced Pre-Conditioning When a rock is blasted, cracks propagate through the rock causing the rock to fracture. This paper focuses on applying the results from a series of small scale blasting tests were designed to show the effect that varying blast variables such as explosive type and explosive energy have on the resulting strength of the post blast fragments. It was shown that the velocity of detonation of the explosive product affects the reduction of fragment strength. This has important implications for the downstream comminution process. The observations from these tests are then explained with reference to the principles of fracture mechanics. A simple but effective prediction of blast induced preconditioning is shown.

Sep 13, 2010

By Wayne Trudel, Lloyd McEvers, Lori Clarke, Eric Saderholm, Charles Lynn Bolin, Leroy Schutz

Newmont mine geologists in Nevada are most proficient when applying technical expertise with multi-departmental teams in three main settings. The first is value creation through near-mine discovery, development and reserve conversion. Since 1986, geologists have created substantial net asset value in developing more than 1.35 kt (43 million oz) into quality Nevada surface and underground gold reserves. The second setting is value realization by supporting mine operations with ore control, selective mining, reconciliation investigations and strategic planning. The investment of technical research on reconciliation investigations led to new concepts and practices that highlighted opportunities for large revenue and reserve gains. In 2002, more than $65 million in projected revenue was added to the Gold Quarry south layback. Kriged mine polygon construction and controlled blast heave at the Lone Tree Mine provided millions of dollars in mining efficiencies. High-quality geologic advice in selective mining at the Twin Creeks Mine helped obtain $4.3 million revenue gains throughout 2002-2003.

Jan 1, 2004

By David Miller, James Santoro

Blasting is often required in urbanized areas to allow for economical execution of construction, demolition, and mining. Several examples of operations that require blasting in built up areas include: rock blasting for foundation and utility excavations; surface and underground mining for mineral extraction; and explosives demolition. Although explosives demolition is an engineering discipline, not at all like rock blasting, it still uses explosives for the felling of structures that have outlived their usefulness. Through the use of modem technology and implementation of extra safety precautions, explosives are used safely in congested areas to make the performance of critical work economical and feasible. This paper discusses several precautions required when undertaking various types of rock blasting and explosives demolition in congested areas. It also presents the adverse effects that must be considered when blasting in congested areas. The effects identified include flyrock, vibration and airblast, fumes, and non-elastic (permanent) ground deformations/overbreak. Measures for mitigating and controlling these adverse effects to provide on-site and public safety are presented.

Jan 1, 2000

By Jack I. Paige

In this Bureau of Mines study, two fluidized-bed reactors were designed, built, and operated, one as a sorber for S02 and the other as a contactor for the regeneration of the sulfur-laden alkalized alumina. The target of 90 percent removal of S02 from a flue gas stream containing 0.3 percent S02 was attained by using a sorbent feed of 10-15 grams per minute into a 5-inch bed depth of alkalized alumina. The sorption unit was operated at about 330° C. Complete regeneration of the laden alkalized alumina containing 5 to 10 percent sulfur was accomplished in approximately 1/2 hour. An excess of reformed propane at about 730° C was the regenerating gas. Attrition losses, a major problem with this sorbent, ranged from 0.9 to 7.9 percent of the inventory. Data from these tests demonstrate, within experimental error, the validity of equations developed from short-term, thin-bed tests related to sorption and regeneration rates.

Jan 1, 1970

By T. Takayama Filho

Votorantim Metais Zinco is a smelting facility which produces SHG zinc, zinc alloys, sulfuric acid, liquid SO2, copper sulfate, cadmium metal and silver concentrate. It is located at Juiz de Fora, Minas Gerais State, Brazil. This facility has been operating since 1980 and its current capacity is 95,000 tonnes of zinc per year, using mostly imported sulfide concentrates.The plant uses the conventional roast-leach electrowinning (RLE) process, in which iron is removed from the circuit as jarosite. The residues generated by the RLE process, which amount to about 200 t/day (dry weight), were until 10 years ago, deposited in tailing ponds having no impervious lining. More recently, jarosite and other wastes have been deposited in a properly built reservoir, but this is reaching its maximum capacity. In order to decommission these disposal operations and to reclaim the sites in an environmentally acceptable manner, Votorantim Metais concluded in 2004 a rehabilitation project for the old tailings pond and prepared detailed plans for managing the current and future disposal of jarosite-bearing residues. This paper describes the procedure for removing iron from the hydrometallurgical circuit and discusses the past and current status of the residue disposal sites, as well as the future challenges related to the environmentally acceptable handling of iron residues.

Jan 1, 2006

Three stages are involved in the complete design and evaluation of an open cut mine. These are:1. design of the optimu,m ultimate pit, and selectionof the optimum mill capacity,2. development of production schedules, with intermediate pit designs, and3. evaluation of the project, based on factors from stages 1 and 2, by means of discounted cash flow analysis.Stage 1 requires relatively complete information on metal distribution, metallurgical performance, and cost factors, which is used to design a series of pits, corresponding to a range of milling rates.For each milling rate considered there is a unique pit design which maximizes operating profitability. The computer outlines this design (in terms of size, shape, and location; tons and grade of ore; and tons of waste), by considering the effect on profitability of mining each block in the mineralized inventory in relation to every other block which would be affected by its removal.The computer selects only those blocks for mining which result in an overall increase in profitability, maintaining pre-determined wall slope conditions throughout.Both operating profitabilities and capital costs increase with throughput, and the two curves will combine to produce a flat peak in net profitabilities at a certain rate, with its associated pit design.Stage 2 can maximize head grades early in the life of the operation. This increases the projected present value, but there are good arguments for maintaining steady head grades throughout the life of the mine.A modification of the programme used in Stage 1 is used here.Stage 3 is a conventional discounted cash flow analysis, using factors obtained in stages 1 and 2. It can be computerised, but a manual treatment is probably just as fast overall.

Jan 1, 1970

By Garnsey R. G T, Wenk G. J, Toop A, Sowerby B. D

A bulk mineral analyser (BMA) suitable for the determination of Cu or Ni in bulk ore samples has been developed at the Lucas Heights Research Laboratories. This analyser, which uses the nuclear resonance scattering technique, is highly specific to the wanted element. The technique has previously been extensively field tested for copper at Mount Isa, Queensland.The present paper discusses the field trial in 1982 of a commercial prototype BMA for nickel. The trial was undertaken at the lateritic nickel mine at Greenvale, Queensland. The BMA and its shielding, together with a laboratory spectrum analyser, were sited in the sample shed adjacent to the workings. Two hundred and thirty-eight ore samples taken directly from the mine blastholes were assayed by the BMA. The average mass of sample was 12 kg, metal contents varied from 0.2 to 3.5 wt/per cent Ni and 4 to 43 wt/per cent Fe and free moisture varied from 11 to 55 wt/per cent. A measurement took 10 min to complete, although this time could have been reduced at the higher nickel grades. The r.m.s. deviation between BMA and chemical assays was 0.09 wt/per cent nickel. Iron and bulk density were also determined by the BMA, r.m.s. deviations being 1.7 wt/per cent and 0.03 g/cmJ respectively. Similar results could be expected from a BMA in routine industrial use at other nickel mines.

Jan 1, 1983