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By Peter Olubambi, Babatunde Obadele, Oluwagbenga Johnson

"The microstructure and corrosion behaviour of titanium carbide (TiC) reinforced duplex stainless steel matrix surface composites synthesized by laser melt injection technique was investigated. The surface melting operation was conducted using a 4.4 kW CW Nd:YAG laser with laser power of 1.5 kW, scanning speed of 0.4 to 1.0 m/min, beam size of 3 mm and argon shield gas flow rate of 4 L/min. The morphologies and microstructures of the coatings examined using field emission gun scanning electron microscope (FEGSEM) revealed homogeneous distribution of fine precipitates of TiC in the matrix, while X-ray diffraction (XRD) analysis confirm no phase change. TiC addition to the steels significantly increased hardness value to about 547 Hv0.1 but slightly decreased the corrosion resistance of the steels in 3.5% NaCl possibly due to the intergranular carbide coating that prevented chromium from forming continuous passive oxide layers.IntroductionComposite materials evolve from the idea of combining two basically dissimilar materials with different physical and mechanical properties to arrive at a product whose final properties are superior to those of the individual components [1]. Metal matrix composites (MMCs) are receiving much attention and are the focus of intense research and development worldwide for aerospace, automotive and other applications because of their excellent combination of ductility and toughness of the metallic matrix with high hardness and strength of carbides reinforced in the matrix [2]. Surface modification techniques such as laser, thermal spray, plasma spray, chemical vapour deposition have been use to fabricate MMCs. Laser melt injection (LMI) is a surface modification technique known since the 1980s [3] has been used to improve surface properties of metallic alloys such as aluminium, titanium and steels [4-6]. It involves the lateral injection of carbides, ceramics and cermets blown by a gas stream into a liquid metallic pool, created by laser irradiation of the top surface of the base material."

Jan 1, 2012

By Dong Liang, Honggang Zhong, Zhenxing Yin, Qijie Zhai

"2507 super duplex stainless steel (SDSS) has been widely applied in a marine environment, attributing to its excellent pitting corrosion resistance and mechanical properties which are particularly determined by the nitrogen precipitation behaviors and volume fraction of ferrite. In this paper, various cooling rates were obtained by applying four different moulds with the common gating system. By which the influence of cooling rates on nitrogen precipitation behaviors and the ferrite fraction in cast 2507 SDSS was comparatively investigated. The results showed that nitrogen porosity could easily precipitate in cast 2507 SDSS under standard atmospheric pressure. The number of nitrogen holes increased with decreasing the cooling rates, and the holes mainly distributed in three zones, i.e. the interface between the horizontal and vertical columnar grains, top vertical columnar grains and the final solidification region. Additionally, higher ferrite fraction was obtained with lower cooling rates.IntroductionDuplex stainless steels (DSS) have a dual-phase microstructure consisting of ferrite (d) and aus-tenite (?). Due to the combined advantageous properties of d and ? phase, their application rapid-ly increased in industry [1, 2]. Super duplex Stainless Steel (SDSS) is the third generation of du-plex stainless steels, of which the alloy elements Cr, Ni and N content are higher than the stand-ard 2205 DSS. Because it has high contents of alloy elements, the SDSS has better mechanical properties, and its pitting resistance equivalent number (PREN) reached a point 43. Hence SDSS has been used in petroleum chemical industry, the marine equipment and harsh corrosion environments [3]. SDSS contains ferrite stabilizing elements, such as Cr, Mo and Si, and austenite stabilizing elements like Ni, Mn and N [4]. Many researchers have studied the effects of these elements on the stabilization of d and ? phase and the ratio of the two phases. High nitrogen con-tent is another prominent feature of SDSS. Nitrogen addition to SDSS is very effective for improving its mechanical properties [5] and corrosion resistance [6], such as pitting resistance in NOx environment. To increase the nitrogen content in steels, a lot of work had been done. N. Nakamura and S. Takaki [7] examined the behavior of nitrogen absorption in Fe-23Cr alloy powder by sintering in nitrogen gas atmosphere, they found nitrogen content easily up to 1.0 wt. %. Using devised NH3 gas injection system, W. Park et al. [8] successfully produced austenitic Fe–23.5Cr alloys containing over 3 wt. % of nitrogen. Further-more, W.P. Tong et al. [9] stated that nitrogen percent was extraordinary high (about 10 wt. %) in pure iron plate. However, the above methods are difficult to be applied to large-scale industrial production."

Jan 1, 2012

By J. P. Beukes

South Africa holds approximately three-quarters of the world?s viable chromite ore resources and dominates the global production of ferrochrome. Albeit completely unintended, small amounts of Cr(VI) are formed during ferrochrome production. Certain Cr(VI)species are regarded as carcinogenic, hence making the treatment of some ferrochrome waste materials necessary. In this paper, the Cr(VI) treatment strategies currently employed by the South African ferrochrome producers are investigated by means of a literature review and a questionnaire survey. From the discussion, it is evident that various treatment strategies are available to deal with Cr(VI)-containing waste in the ferrochrome industry. However, by far the most commonly applied treatment strategy remains the aqueous reduction of Cr(VI) with ferrous iron. The advantages and the correct application of this strategy, together with the disadvantages and pitfalls, are argued. Innovative improvements on historic practices are also discussed

Jan 1, 2012

By Xiaodi Huang, Matthew Andriese, Zheng Zhang, Jiann-Yang Hwang, Zhiwei Peng

"A simplified finite-difference time-domain (FDTD) algorithm for modeling microwave propagation in magnetic dielectric materials was developed and employed to study the microwave dissipation in magnetite. Heat transfer during microwave heating of magnetite was subsequently investigated by solving heat transfer differential equation using explicit finite-difference (EFD) method. It is observed that temperature of magnetite surface increases rapidly in the first minute due to the rapid strength decays in both electric and magnetic fields within a short distance along the path of microwave dissipation. A temperature peak, initially formed at the surface of the sample slab, migrates inward as heating time extends and microwave power increases.IntroductionAs one of primary materials in iron and steel industry, magnetite exhibits excellent microwave absorption capability, which leads to great energy conservation in microwave assisted steelmaking [1,2]. The fast temperature increase in microwave heating of magnetite can be attributed to both dielectric and magnetic losses [2]. Although much experimental work has confirmed this observation, detailed computational studies for modeling of microwave field dissipation in magnetite at commonly used frequencies, such as 915 MHz, has not been well addressed [1,3].Finite-difference time-domain (FDTD) method is widely used in computational electrodynamics modeling to simulate the dynamics of electromagnetic wave scattering from various media [4,5]. This approach requires modeling algorithm to be formulated with integration of specific characteristics of each medium. An extensive literature survey indicates that current formulations are only suitable for modeling electromagnetic waves propagating in normal dielectric lossy materials [5,6]. Since magnetite is a magnetic dielectric material in which both dielectric and magnetic properties contribute to the heating process under microwave irradiation, a specific algorithm should be developed for the simulation."

Jan 1, 2012

By Youzhen Zhang

The drilling boom is the key component of a roof bolter, and it has significant impact on the performance, safety, and reliability of the overall working device. In this paper, the experimental modal parameters of a drilling boom at low frequencies are identified with the Laplace wavelet correlation filtering method. Based on the obtained experimental parameters, a finite element model of the drilling boom is revised using an optimization algorithm to improve its accuracy. The dynamics of the drilling boom are analyzed through its modal and harmonic response. As a result, an improvement for the drilling boom is proposed to fix the weak links and enhance the dynamic performance.

Jan 1, 2012

By Vince Saporito

Miners work in dangerous terrain, around the clock, with heavy equipment. Is there room for improvement in safety and standardization in the mining industry? Recent history would suggest there is a need for action. At a 2011 Spring Thaw conference in Denver CO, one speaker commented, ?We are having a number of incidents with workers getting ?pulled? into rollers or ?trapped? at transfer points when trying to manually clean (it) while the conveyor is still in motion.? It?s a troubling thought. These actions are specifically prohibited under U.S. Mine Safety and Health Administration (MSHA) regulation 57.14202. Another official from MSHA earlier this year indicated with today?s technology and policies presently in place, ?we should not be repeating the same incidents and violations year after year as we currently do.? But we are doing exactly that.

Jan 1, 2012

By C. Lottering

Copper sulphate solutions are produced during the pressure leaching of first-stage leach residue in a typical base metal refinery process. Apart from impurities such as selenium and tellurium, this leach solution also contains other precious metals (Rh, Ru, and it) due to dissolution in the pressure leaching stage. Selenium and tellurium are removed from the leach solution by precipitation with sulphurous acid, since these elements negatively affect electrowinning. This study investigates the feasibility of modifying the Se/Te precipitation process step to achieve significant rhodium precipitation in addition to selenium and tellurium precipitation, in order to reduce the rhodium inventory of the process. Thiourea, S02, formaldehyde, formic acid, and sodium thiosulphate were evaluated to determine which of these reagents would achieve the highest Rh precipitation. Based on these screening tests, SO2 and thiourea were selected to be used as precipitation reagents in optimization tests. During these optimization tests, the operating temperature (80 to 150°C) and the amount of reagent added (80 to 140 per cent excess) were varied to evaluate the effects that these operating conditions have on the precipitation behaviour of Rh as well as Se, Te, Cu, and Ni, and to propose appropriate operating conditions. It was found that thiourea resulted in good Rh and Se precipitation (typically in excess of 90 per cent), but precipitated noticeably more copper and nickel from the solution than when SO2 was used. In addition, thiourea had poor Te removal characteristics. SO2 achieved a maximum of 70 per cent precipitation of the rhodium. Faster kinetics and a larger extent of Te precipitation were, however, observed when using SO2 compared to thiourea.

Jan 1, 2012

By Yuanbo Zhang, Zhixiong You, Daoxian Duan, Guanghui Li, Tao Jiang

"Manganese is mainly consumed by steel and battery industries. In recent years, it is essential to utilize the low-grade manganese oxide ores with total manganese grade below 25%, as the high quality manganese ore resources are becoming scarce with the rapid development of the steel industry. Conventional pyro-metallurgical processes for utilizing manganese oxide ores are characterized by high production cost and energy consumption, low productivity, serious environmental pollution, etc. In this study, reduction thermodynamic of MnO2 reduced by sulfur was firstly carried out. Then, a novel process of reduction roasting with sulfur followed by acid leaching was developed to recover manganese from the very low-grade manganese oxide ores. Effects of main factors, including temperature, reduction time and S/Mn mole ratio, were investigated, and a high leaching efficiency of Mn above 95% was obtained under optimal conditions.IntroductionHigh/middle-grade manganese oxide ores are generally used in the metallurgical industries, particularly in steel plants and ferro-alloy units. The consumption of metal manganese in the ferro-alloy industry accounts for 85- 90% of the total Mn demanded [1]. Therefore, high quality manganese ore resources are becoming scarce with the rapid development of steel industry. It is essential to make good use of large quantity of low-grade manganese ores (TMn < 25%) presently available."

Jan 1, 2012

By D S. Preece

The aim of the present work is to investigate the effects of shooting multiple explosive charges, in the same borehole, on the amplitude and frequency content of the generated seismic wave. The work also investigates the effect of the coupling medium used in the borehole on the quality of the generated seismic wave. The delay period between the shots is on the order of months and up to a year. The investigation utilizes a numerical modeling approach which is capable of modeling the detonation of explosives as well as shock and stress wave propagation in solids.

Jan 1, 2012

By Daniel Scott

Mines have used explosives for economical fragmentation for many years. It can therefore be expected that the mining industry has thoroughly researched how to achieve the most efficient blast. However, there is still a large amount of iteration that must be undertaken before blasting at a mine site can be refined enough to allow for consecutively successful blast results. And then the geology changes. This paper will present an approach to blast design that considers production goals, geology, budget, and safety, and will contrast the proposed method with well established blasting theory.

Jan 1, 2012

By R. Mathur

Cu isotope fractionation in low-temperature aqueous environments has been well documented. Here Cu fractionation was applied to two distinct, yet related, mining problems. First, an exploration geology application, where copper isotope fractionation was measured in oxidized leach caps, chalcocite enrichment blankets and hypogene mineralization in three porphyry copper deposits located in the southwestern U.S. Cu isotope patterns exist in a vertical distribution within the mines, coupled with distinct relationships with the Cu grade. Second, a hydrometallurgical application, where copper isotope fractionation was measured in leach fluids, feed and residues from a quick leach test (QLT) on Cañariaco, Peru ores. The results indicate the relative proportions of the minerals providing Cu during leaching. Interpretations of the QLT test measurements indicate covellite is the dominant ore mineral providing Cu during leaching. Both applications clearly demonstrate the use of the Cu isotope technique to understand low-temperature aqueous processes involving copper.

Jan 1, 2012

By B. Genc

Improving student success rates without compromising the quality of graduates is one of the biggest challenges expanding university programmes are facing in South Africa. By establishing a new Mine Design Laboratory (MDL) for higher learning in Mining Engineering, the School of Mining Engineering at the University of the Witwatersrand (Wits Mining) has achieved one of the important goals in its five-year strategic plan, i.e. to improve throughput in all years of study. Although the establishment of the laboratory has been a costly exercise, results so far have shown an improved success rate in most subjects taught in the facility. This paper outlines the design and equipment of the laboratory, the facilities incorporated, a comparison with the old laboratory, and the performance of students?all of which indicate how important it is to have proper facilities to improve the teaching of, and learning by, large classes. Through this initiative, Wits Mining has taken an important step that will contribute to addressing the skills shortages in the mining industry.

Jan 1, 2012

In its largest product launch in company history, Cummins Engines welcomed more than 200 customers, vendors and media to witness the unveiling of its new QSK95 engine at its Seymour Engine Plant in Seymour, IN on Nov. 1. It took the efforts of 150 engineers to design the QSK95 and more than $100 million in investments to establish a new production line and test facility at Cummins? Seymour Engine plant. The result of these efforts is a new platform of engines that Cummins says will provide as much as 2,983 kW (4,000 hp) and will be the most powerful, high-speed diesel engine ever built.

Jan 1, 2012

By James McGough, Lawrence Mirabelli, Ran Tamir

The paper will demonstrate how automated fragmentation photo analysis is being used at the Lafarge North America, Ravena NY quarry as part of an ongoing drill, blast and primary crushing continuous improvement process. Using on-line fragmentation photo analysis systems at both the primary crusher feed point and crusher discharge belt, data is collected to: benchmark the drill/blast process; monitor the work being done by the primary crusher; measure gradation changes in the crusher feed resulting from changes in drill/blast and measure the subsequent changes in further size reduction done by the primary crusher.

Jan 1, 2012

By L. Furtenbach, T. Möller

"Grinding mills are the heart of the mineral processing plant, and are production-critical machines which are required to achieve high availability. Liner wear life and a liner design that promotes ease of installation are important variables to achieve a high level of mill availability. Increased mill size results in more mill internal surface to protect, and more liner components to install and remove. This drives designers toward an increase in liner size to minimize the number of components to be installed by the liner handler. The liner attachment method can also have a large impact on mill availability as well as safety during installation.This paper outlines the experience from the development, installation and follow-up of liners installed in two 38&apos; x 45&apos; AG Mills at Boliden Aitik in Sweden. A new Poly-Met shell liner concept has been developed to minimize the number of liner components. The new Poly-Met shell liner components are made much larger than conventional Poly-Met or steel liners. This reduces the number of components to be installed/removed by the liner handler and helps to minimize installation time and consequently down- time. A new attachment system has also been developed to eliminate the need for the installation crew to be in the “drop-zone” of the shell liners while installing the liner bolts.One interesting aspect of this project was the requirement to predict liner life for these new large format AG mills. The existing 22&apos; diameter mills at Aitik provided a base-line reference for this purpose, and DEM studies were used in the project development stage to predict the wear life of shell liners for the new 38&apos; diameter AG mills. The results from this study are included."

Jan 1, 2012

By E. Keskinkilic

Drying, calcination, prereduction, and smelting are the main steps in conventional crude ferronickel production. Industrially, these steps are conducted using the rotary kiln-electric arc furnace (RKEF) process. In this paper, calcination characteristics of Sivrihisar laterite ores from the Central Anatolia region are investigated. The extent of elimination of chemically bound water and other volatiles was studied by experiments conducted at various temperatures in the 250?800°C range. Phase changes were examined using X-ray diffractometry. For the particle size used in the study, 300°C was determined to be almost sufficient for complete transformation of goethite to haematite, and 700°C was required for effective elimination of all volatiles in the ore.

Jan 1, 2012

By Jason Baird, Braden Lusk, Dominique Nolan, Allen Stults

Conical shaped charges have been used to penetrate rock for many years now. Examinations have been made looking at shaped charge liner geometry, material, and standoff, as well as explosive composition, confinement and initiation. Most of the testing conducted towards penetration rather than cratering has fallen within the realm of the petroleum industry and as such been confined to specific rock types, with test apparatus that include simulated down hole (subterranean) environments. The testing conducted within this experimentation is conducted at ground level, in small scale samples, using a single standoff, against multiple rock types. The data collected from that testing is examined here and relationships between physical properties of the rock and the liner are analyzed. The analysis of that data raises the possibility of a relationship that may lead to new empirical methods of penetration prediction in rock.

Jan 1, 2012

By Run Huang, Xuewei Lv, Songli Liu, Chenguang Bai

"Titanium alloy was prepared from titania-bearing blast furnace slag (Ti-BF slag) by aluminothermic process in an induction furnace. The effects of aluminum amount on the titanium silicon yield and titanium recovery ratio were studied. The phase transformation and chemical composition of the prepared alloy were investigated by X-ray diffractometry (XRD) and X-ray fluorescence (XRF) respectively. It was found that the mass fraction of silicon and aluminum increased with increasing the aluminum amount, however, the mass fraction of titanium increased first and then decreased with increasing the aluminum amount. Furthermore, both the titanium alloy yield and titanium recovery ratio increased with the increase of aluminum amount. The main phases of the alloy were TixSiy and AlTi3. The titanium alloy samples prepared in various conditions had a composition (wt.%): 38–50% Ti, 29-34% Si, 4-11 Al%, 1.6-2.2 Mn%.IntroductionPanzhihua and Xichang regions in the southwest of China are rich in vanadium-titanium magnetite containing iron, vanadium, titanium and gangue. According to the characteristics of the resource, iron and vanadium are successfully recovered with a blast furnace process and a converter process. However, most content of titanium are entered in the blast furnace slag with TiO2 22% -26% and metallic Fe 2%–6% called Ti-BF slag. Due to the dispersed distribution of Ti in various fine grained mineral phases with a complex combination between Ca, Al and Si, it is difficult to recover the Ti components[1]. This slag is generated at a current rate of 3.6 million tons per year, which adds to the existing 70 million tons of slag produced so far[2]. The slag has had to be piled as large as the mountains, which not only waste of resources but also cause a pollution of the environment. Therefore, the study of integrated utilizing Ti-BF slag has become very significant."

Jan 1, 2012

New developments in the pipe conveyor and belt are advanced to address the growth in the capacity, length and complexity of pipe conveyor systems. Improved belt construction can offer better stability during horizontal curves and resistance to twist. Low rolling resistance rubber compound can significantly lower the power consumption and belt tension, producing capital and operation cost savings. Dynamic analysis, when used to analyze the conveyor?s starting and stopping behavior, can improve the design and reliability of long overland pipe conveyor systems. For these three aspects, technical backgrounds and field installations as examples are discussed in this paper.

Jan 1, 2012

By Gungor Tuncer, Ali Kahriman, Abdulkadir Karadogan, Alper Celtikci, Serdar Celik, Yucel Karakus

This paper presents bench blasting designs based on results of vibrations analysis on test shots organized in an open pit coal mine located near to Soma district at Manisa province in Turkey. There are some structures which can be adversely affected by blasting at the coal mine. The one of the main goals of this study is to perform a preliminary assessment of possible damage effect of ground vibrations induced by blasting at these structures by risk analysis based on ground vibration measurements. During this investigation, the data pairs of scaled distance and particle velocity obtained from the 36 event records belong to 9 test shots were statistically analyzed and a PPV prediction equation specific to this site with 95% prediction line were obtained. And also, this equation was used in the derivation of the practical blasting charts specific to this site as a practical way of predicting the peak particle velocity and maximum charge per delay for future blasting. A risk analysis was performed by using this equation. In the light of this analysis, preliminary blast design model was proposed to be used in this coal mine for overburden excavation.

Jan 1, 2012