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By Xing Jin, Dan Graffi, Glenn MacPherson, Dan Rioux

"The complexity of a modern flotation circuit makes it susceptible to disturbances such as changes in feed, ore mineralogy, equipment degradation, poor measurements and faulty instruments. Good measurements and a robust control system are critical to create and maintain a stable and optimum flotation process.This paper focuses on the development and implementation of process control applications in the flotation circuits at Xstrata Nickel’s Strathcona Mill ( referred to as the mill hereafter ) in Sudbury, Ontario. Following the path of ‘stabilize-improve-optimize’, basic controls to stabilize process variables such as flotation cell pulp level, air and reagent addition rates, cleaning-column feed and wash-water rates have been established. Factors such as best practice in pulp level and valve position measurement, feedforward control and the application of an appropriate control philosophy, have contributed to the significant reduction in process variability. For instance, standard deviation reduction of 79% for the Ni impurity in the column Cu concentrate grade was experienced and is shown. The variability reduction of the flotation circuits’ key process-variables paves the way to further improve and optimize flotation performance. A grams-per-metal unit reagent addition control scheme has been improved upon, particularly for different operating scenarios and better robustness. In addition, following significant stabilization of the primary controls and columns feedrates, Cu/Ni separation cleaning-column bias-control (cascaded to the wash-water rate) and hold-up control (cascaded to air flowrate) have been developed and tested. This strategy – from stabilization to optimization - is expected to achieve a more consistent control of final concentrate grades and improve recoveries.INTRODUCTIONFlotation is considered the most important and value-added process in the milling metallurgical plant and is still undergoing continuous evolution to treat greater tonnage and different ores (Wills, 2006). Starting over three decades ago, with the advent of on-line slurry content analysis devices, flotation automatic control has received persistent interest and a large number of applications have been reported (Thwaites, 1983, 1986 ; Mckee, 1991). Bergh and Yianatos (2011) reviewed different aspects of process control in flotation circuits and have evaluated the applicability of model predictive control to the process. Mckee (1991) analyzed the difficulty in developing lasting/robust process control applications for flotation circuits and stated that the path of stabilization-refinement-optimization would more likely lead to successful flotation circuit process control. Best practice on column process control was discussed by Bouchard, etc. where a multi-layered approach was proposed, provided that the measurement of column process variables ( i.e. bias, froth depth, hold-up, etc. ) are measured reliably (Bouchard & Thwaites, 2008). Wills (2006) stated that the best practice for flotation automatic control starts with fulfilling basic control objectives, such as stabilized flotation cell level, air flow, pH, reagent flow etc., before considering more advanced, or even optimal, control of metallurgical targets, which are more closely linked to economic performance."

Jan 1, 2013

By Kent C. Condie

Precambrian terranes in the Rocky Mountain region decrease progressively in age from the Archean Wyoming Province (> 2.5 b.y.) to the late Proterozoic in West Texas (figs. 1,2). Within the Wyoming Province, most dates fall near 2.7 b.y. although some are recorded at 2 3.8, 2.9, and 2.6 b.y. Although Penokean (- 1.8 b.y.) deformation and plutonism are recorded in southeastern Wyoming, most Precambrian rocks south of the Wyoming shear zone, which separates the Archean and Proterozoic provinces, are < 1.76 b. years in age. Supracrustal rocks in Colorado, western Arizona, and northern New Mexico fall in the range of 1.72-1.76 b.y., those in central New Mexico about 1.65 b.y., those in southeastern Arizona and southwestern New Mexico about 1.70 b.y., and those in West Texas 1.1-1.2 b.y. The Wyoming Province is comprised chiefly of 2.7 or 2.9 b.y. tonalitic gneiss terranes intruded by 2.6 b.y. granites in the central and southern parts of the province. Supracrustal rocks are minor and include greenstone belts comprised chiefly of pillow- ed tholeiites and graywackes and remnants of quartzite-shale successions. Metamorphic grade in greenstone-gneiss terranes ranges from upper greenschist to amphibolite facies and in quartzite-gneiss terranes from upper amphibolite to granulite facies.

Jan 1, 2013

By Shi Guan-Yong, Niu Li-Ping, Dou Zhi-He

"In the preset work, the viscosity model (named modified KTH model) proposed by Sichen Du and S. Seetharaman et al and extended by Shu Qi-feng was applied to the ESR slag systems. A correlation to predict the viscosities of CaF 2-(CaO)-Al203 slags using interaction coefficients of different cations in the presence of oz-and viscosity interaction coefficients between oz-and F in the presence of different cations has been developed. The interaction coefficient between oz- and F- in the presence of Al3+ was determined from the experimental data as shown in known literatures. The good agreement between the calculated viscosities and the experimental data in the CaF2-(CaO)-Al203 systems has indicated that this approach can be successfully employed to predict the viscosities of ESR slags.IntroductionReliable viscosities data of high-temperature slag melts are important for the modeling and design of high temperature metallurgical processes. Although a number of experimental measurements have been carried out, the available viscosities data is still scarce compared to the needs of today's technology, especially in the case of complex melts. In process simulations, the needs of viscosity descriptions for complex systems which could enable the extrapolation of the data as functions of temperature and composition is strongly felt today."

Jan 1, 2013

By Peter C. Hayes

"The high temperature reduction of solids through the use of reactive gas atmospheres has application in a wide range of industrially important processes. Whilst significant advances have been made in understanding and describing these processes, some key aspects of the chemical reactions and reaction mechanisms operating in these systems, for example, the transformation from metal oxide to metal, remain poorly understood. A number of different product morphologies have been identified in these reaction systems and the reaction rates have been shown to be critically dependent on the product structure.Theoretical examination of the elementary process steps taking place in the region of the gas/metal/metal oxide interface, combined with electron microscope studies of the resultant product microstructures, have enabled the key process and material variables responsible for the development of the various product morphologies to be identified. By considering i) established criteria for the stability of moving interfaces in a thermodynamic potential gradient, ii) the relative rates of chemical reactions on the oxide and metal surfaces, and iii) key process phenomena and physico-chemical properties of the solid phases, the mechanisms and conditions for the formation of various product morphologies are identified. Interestingly the analysis points to direct analogies between these phase transformations and, the phenomena and microstructures observed in metal solidification, and the potential to develop generic models of these fluid/solid reaction systems."

Jan 1, 2013

By Xicai Gao

With the intensification and expansion of deep coal mining, the surrounding rock stress environment becomes further deteriorated because of the complicated geological environment and powerful mining effect, so the major deformation of roadway appeared frequently. The proportions of floor heave are increasing and , the most serious problem is the floor heave of preparatory workings. The coal seam of Binchang coal area in Shaanxi province is at a depth of 621.6 ~ 817.0 m, the average thickness of the coal seam is 25 m, and the overburden and coal measure strata are the main regional aquifers and are highly permeable. The properties of water-weakening are obvious in the floor strata. The main preparatory workings or chambers were driven in the coal seam. The severe floor heave of the water chamber appeared during early mining and the amount was 180 ~ 910mm, and seriously affected the normal installation and use of the water chamber. Theoretical study and numerical simulation as well as the in-situ measurements were carried out to investigate the deformation and failure characteristic of the surrounding rock with non-support in the floor and the main reasons which caused the floor heave were determined. A new combined support technology was proposed which consists of overcutting, grouting, backfilling and invertedarch and bolt-grouting. The field monitoring showed that the cumulative convergence of the water chamber was 20mm, the maximum convergence speed is 1.2 ~ 2mm/d, the accumulative convergence of two ribs was 36mm and the maximum convergence speed is 2mm/d. The combined support technology will enhance the support intensity between the roof and floor, the two sides of the entry and improve the loading capacity of the floor effectively and the floor heave can be controlled effectively.

Jan 1, 2013

By Anthony T. Iannacchione

The Solar No. 7 and Solar No. 10 mines were designed to prevent mine waters from directly discharging to the surface. In January of 2004, a discharge occurred as the Solar No. 7 mine was in its final stage of flooding through a barrier averaging 456-ft in width over a 1,600-ft length (No. 1). Another barrier (No. 2) was designed to protect four municipal water wells operating 1,800- ft away and producing from within or slightly below the Upper Kittanning coalbed from the adjacent Solar No. 7 and No. 10 mine pools. These two barriers were selected for this study because of varied mine layouts, mining methods, and geology factors affecting their performance. Analysis was aided by the collection and georeferencing of 6-month mining maps from the Pennsylvania Department of Environmental Protection (PA DEP). A structure contour map of the Upper Kittanning coalbed was constructed from mine map elevation points. These data and 2-ft surface contour maps were used to measure the precise location of the coal outcrop. The actual discharge point was as little as 425-ft away from a thinpillar section and 475-ft away from a pillar recovery section. The discharge point was found to be located slightly above the coal, indicating that the drainage path was at least partially through the strata directly above the Upper Kittanning coalbed. Hydraulic conductivities and potential discharge pathways are analyzed and discussed. The possible factors influencing the performance of the down-dip barriers at Solar No. 7 and Solar No. 10 are: a) the width of the barrier, b) the applied hydraulic gradient, c) the type of mining adjacent to the barrier, d) the overburden, e) the pattern and characteristics of fractures, and f) the quality of waters contained within the mine pools. This study, part of a larger effort funded by the Appalachian Research Initiative for Environmental Sciences (ARIES), is tasked to determine the key factors responsible for the successful design of down-dip coal barriers.

Jan 1, 2013

By C. J. Tonkin

Compressed air is widely used on South African gold mines. However, due to recent and proposed future electricity tariff increases it is quickly becoming too expensive to produce and use. Boxfront chute systems at ore passes were focused on during this study, and a number of alternative power sources were examined. After comparing primarily costs, and secondarily safety and practicality, of a number of systems based on water and hydraulic oil, a system making use of either air or water was determined to be the most cost effective. A payback time of 8 years was calculated, which will be significantly less taking into account the avoidance of failures due to electricity and water shortages, which would not affect this system due to its ability to swap between either air or water. It was recommended that this system be installed at all boxfront chutes as soon as possible so that the company can begin to benefit from the cost savings.

Jan 1, 2013

By J. Labuschagne

There are a number of factors that contribute to the profitability of a mine and its associated concentrator. Chief among these is the time taken from the first hoist of material from underground to the first batch of concentrate shipped. The main aim of this project was to integrate the mining model with a concentrator production schedule to minimize the time it would take to produce concentrate (without the concentrator having to stop because of a lack of feed material) in the most capital-effective manner. A secondary goal was to ensure detailed stockpiling requirements, as the concentrator is in an area where &apos;visual pollution&apos; is to be avoided. To achieve these two goals a dynamic stockpile model was created by utilizing the mine production schedule and breaking it down to a daily production figure. Four different concentrator development models were then proposed. The difference between the mine production and concentrator consumption was integrated over the life of the mine to provide the accumulated stockpile tonnages for both Merensky and UG2 ore. To prevent a situation where the concentrator was operational without any feed, the stockpile levels were never allowed to fall below zero. When a development option was selected, the standard metallurgical performance calculations were used to derive a concentrate production schedule, which was used as a basis for commercial negotiations for the sale of concentrate.

Jan 1, 2013

By Seyed Mahdi Abbasi, Adel Sheikhhosseini

"This research was conducted to study the changes of microstructure, chemical composition and mechanical properties ofIN718 superalloy after adding aluminum to the ESR process slag. The experiments were performed in VIM and ESR furnaces. The results showed adding 1.5 percent aluminum to the slag increase lave phase in the IN718 samples from 0.34 percent in the base sample to 3.0 percent. It also indicated that the more increase of aluminum in slag cause decrease in the aluminum absorb yield in the superalloy.it is observed that increasing aluminum from 0.7 to 1.1 and then to 1.5 percent caused a decrease of absorb from 91.4 to 76.3 and 74.6 percent respectively due to increasing of aluminum oxidation. According to the results, tensile strength increased and ductility declined in the IN718 samples mainly because of rising the amount of y' volume fraction.IntroductionIN718 superalloy is an iron-nickel base superalloy with constant mechanical properties at medium at high temperatures. For the past seven years a considerable amount of time and effort has been expended by both suppliers and users in the study of Alloy 718 [ 1]. The interest in this material stems not only from the interesting metallurgy associated with the alloy, but with the large usage of the material in numerous applications In fact many people believe that the projected use of this alloy increase significantly over the next several years, The large use of Alloy 718 is the result of its performance in respect to high strength, good ductility, good repair weld ability and from its versatility of being supplied in various product forms. This superalloy is used in wide ranges of industries such as aerospace and gas turbines [2]. In the past more than 20 years many researchers did a lot of work to improve the structure stability of IN718 at high temperatures and intended to develop a new 718 type alloy to be used beyond 650 °C. One of the methods is to control and phase precipitation behavior by means of adjustment of Al, Ti and Nb contents. The other idea is to strengthen the matrix by altering the content of solid solution elements such as W and Co. The adjustment of these alloying elements can change phase precipitation behavior [3]. If detailed information dealing with phase precipitation behavior can be obtained before experimental work for alloy development, a lot of time can be saved and the development cost can also be reduced. In recent years, computer modeling based on experimental data plays an increasing role in alloy design and development. Adding Al to the Iron and Nickel increas the strength of superalloy by formation of y phase and subsequence formation of n phase. Ti in IN718 superalloy also helps the formation of MC carbides and gamma prime phase. Increasing Al/Ti and (Al + Ti)/Nb will lead to form finer particles of y'. More uniform distribution of the precipitates and enhancing stability of y' in IN718 superalloy [ 4]. Adding Al to slag of ESR process can reduce the oxide inclusions because of the strong tendency of Al to oxidation. In addition, tensile properties of IN718 superalloy improve. The most significant inclusions in IN718 superalloy are Alz03 and TiN that were found in agglomerate forms. Thermodynamic calculation results indicate that the effect of increasing Al shows a strong increase in solvus while phase solvus shows mildly decrease when Al level is less than 2%, after that it dramatically decreases [ 5]. Laves phase precipitation and the appearance of phase are occurred when Al content reaches 2%. In fact, when Al content is beyond 1.5%, phase has already precipitated in a considerable scale. Shows the fraction of increases greatly while the fraction of phase decreases remarkably with the increment of Al content. Based on thermodynamic theory, if these particles were not existed in the melt during cooling agglomeration would not accrue and the superalloy will be cleaned By adding Aluminum to the slag, the metal reacts with oxyge"

Jan 1, 2013

By Phil Thwaites

"The mining industry uses many types of mineral and metallurgical plants to produce saleable product from ore mined. Plant design history has left current operations with a mixture of manual operation and various forms of automated process controls. Consequently, we typically see high variability in the continuous operations together with a shortfall in the attainment of full capacity, or higher utilization of consumables.At a level of best practice, “Operational Performance Excellence” focuses on process control, using automation and control systems to deliver process optimization. This more sophisticated delivery is a great deal more difficult than the first stage of equipment selection / installation. It includes the appropriate selection of the right instrumentation, control system, key process knowledge, individuals with a solid control engineering background/experience, and the essential backing/ support of the operations management team together leading to higher value delivery. Robust solutions can be realized, considerably minimizing process variation, thus leading to process optimization. This approach results in an easier, efficient and safer process while providing considerable returns for the plant owners.How variable are your processes, and do you maintain optimized process performance with dedicated resources, modern instrumentation, ‘best practice’ control systems and performance monitoring tools? In this lecture, these questions and their possible answers are discussed.357"

Jan 1, 2013

By Tianzu Yang, Weifeng Liu, Lin Chen, Deyu Wang

"Due to the gradual exhaustion of easily extractive gold ores, it is vital to make efficient use of refractory gold ores which hold 30% gold storage of the world. However, the disadvantage of current processing technologies for refractory gold ores consists of severe pollution, low gold extraction ratio, high investment, etc, thus great research interests were attracted during recent years. This article provides an overview of the distribution and categories of the refractory gold ores in the world. The state of art in processing refractory gold ores by pyrometallurgy, hydrometallurgy and biometallurgy techniques and their industrial applications are highlighted. Potential environmental conservative techniques for efficient gold extraction are also reviewed.IntroductionResources of Refractory Gold OresAs easily extractive gold ores are going to be exhausted with the large scale mining nowadays, refractory gold ores are becoming more and more important. Gold in the refractory gold ore cannot be fully extracted using conventional method (cyanidation) even with fine grinding. The amount of gold in the refractory gold ores is about 1500~2000t in China, which occupies 30~40% of the total gold storage [1]. Therefore, it is vital to make efficient use of refractory gold ores."

Jan 1, 2013

By Vincent Tirolo

The proposed Second Avenue Subway is a new two-track subway line running from 125th Street and Park Avenue at the north, east along 125th Street to Second Avenue and south along Second Avenue to the Financial District in lower Manhattan, NY with 16 new stations and 13.6 km (8.5 miles) of track. The project has been broken into four construction phases. The initial Phase 1 operating segment includes three new stations (96th, 86th and 72nd Street stations) with a connection to the existing Broadway line at the 63rd Street Station at Lexington Avenue. Rehabilitation of the 63rd Street Station is also included in the scope of Phase 1. Subsequent phases extend service north and west to 125th Street (Phase 2), south to Houston Street (Phase 3) and finally to Hanover Square (Phase 4). The DMJM Harris/Arup Joint Venture (DHAJV) prepared the Contract Documents MTA for Phase 1. Parsons Brinckerhoff is providing the MTA with construction inspection services for Contract C-26002. In April 2007, NYCT awarded first Phase 1 for $337 million to S3 Tunnel Constructors, a tri-venture comprised of Skanska USA Civil, Schiavone and Shea. Contract C26002 is for the construction of the tunnel boring ma-chine (TBM) launch box and the mining of the TBM tunnels from 92nd Street to 63rd Street. The major part of the contract is to construct a shaft, commonly referred to as the launch box, from East 92nd Street to East 95th Street having dimensions of 244-m- (800-ft-) long by 18.9-m- (62-ft-) wide and a depth of 19.8 m (65 ft), including more than 91,000 m3 (119,000 cu yd) of soil and rock contained within its walls. The launch box will ultimately become the southern half of the 96th Street Station. The focus here is geological conditions at the launch box and existing structures along the launch box. These geologic conditions and existing structures had a major influence on the selection and design of the support of excavation system (SOE), the SOE bracing system, construction staging, the ground movements, dewatering and other challenges of constructing the launch box (Fig. 1).

Jan 1, 2013

By Dakota D. Faulkner

Cable bolts anchored with traditional two component polyester resin cartridges have successfully supported difficult roof conditions in underground mines. Resin cartridges provide a costeffective cable bolt anchoring system with consistent anchorage performance characteristics when properly installed. The most commonly used cable bolts in the U.S. mining industry are 270 ksi (1,862 MPa), 0.7 and 0.6 inch (18 and 15 mm), seven-strand smooth cable with resin mixing bulbs (also known as bird cages), and 40- and 30-ton nominal capacity, respectively. However, there are other types of cable bolt anchoring systems aside from bird cages. Recently, many questions have been raised regarding the anchorage characteristics of various types of cable bolts. Keystone Mining Services, LLC (KMS), the affiliated engineering company of Jennmar Corporation, conducted a variety of controlled tests developed to closely model actual underground installations. These tests compared the performance of three commonly used cable bolt varieties, including plain, bird caged and indented seven-strand cable. Details of the laboratory testing and comparative analysis of the results are provided.

Jan 1, 2013

By Qingchun Yu, Bin Yang, Yong Deng, Heng Xiong, Fei Wang, Minxiu Chen

"Metal aluminum produced by non-electrolysis process received much attention due to its lower energy consumption. In this paper, carbothermic reduction and carbothermic-chlorination of alumina in normal pressure and vacuum were studied. The products were examined by means of XRD, EDS and SEM. During the carbothermic reduction process using carbon reductant in normal pressure, no metal aluminum was found. However, when coal was used as reductant, a mixture containing metallic aluminum, A14C3, and silicon was obtained, but metallic aluminum couldn't be separated from the mixture. During the carbothermic-chlorination process in vacuum, Al404C and Al4C3 were produced by the reaction between alumina and carbon, and Al Ch gas reacted with Al404C and Al4C3 to produce Al Cl gas. Metallic aluminum was produced due to the disproportionation of A!Cl gas and condensed on the collecting plate. Meanwhile, the initial temperature of carbothermic reduction of alumina reduced in vacuum compared with that in normal pressure.IntroductionIndustrial production of primary aluminum is carried out in alumina cell by the so-called Hall- Heroult process, necessitating the use of very high currents of low voltage. The alumina from which metallic aluminum is gained must be chemically pure, otherwise impure metal results. The main drawbacks of the electrolytic production are its very high energy consumption, the release ofperfluorocarbons, and the high specific C02 emissions [1]. During the past years, there were a lot of attempts to produce metallic aluminum by carbothermic reduction of A1203 [2, 3]. Cox [4] determined the vapor pressure over the A1203-C system and performed X-ray diffraction analysis of condensed products. It was demonstrated that an increase in the carbon content in the system leaded to the sequence of transitions: A1203~Al404C~A1zoc~A14C3 ~AI [5]. In any carbothermic reduction process for aluminum, extremely high temperatures (2000 °C ) were required [6]. In spite of considerable effort, the carbothermic reduction of alumina to aluminum remains a formidable technical challenge, due to the high temperatures required, and to the formation of aluminum carbide and oxycarbide byproducts [7]."

Jan 1, 2013

By W. van der Merwe

ABSTRACT With the gold industry processing more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more critical. This paper compares the two commonly employed ‘free’ cyanide online analysis methods (amperometric and potentiometric endpoint silver nitrate titration) with the rhodanine endpoint silver nitrate titration and ion selective electrode methods common at site laboratories. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared using these measurement techniques.

Jan 1, 2013

By B. G. Cousins, B. O’Rourke, C. Spence

"Some non-flotation chemistries are added to flotation circuits directly and indirectly to control issues such as scaling and dust. Since the dosage levels are generally not very large, a standard laboratory float test may not be able to determine the effect a specific chemical has on the productivity of the flotation circuit. Hudbay and Ashland Water Technologies developed a laboratory testing protocol that uses kinetic float studies to test the effect of normal to extreme doses of antiscalant and dust chemistries (5 ppm to 500 ppm). Laboratory results indicate that this protocol helps to predict the potential interference that a particular chemistry will have on the flotation circuit.INTRODUCTIONFrom a chemical perspective, flotation is a very complex system involving more than the reagents used for flotation. Along with collectors, frothers, modifiers, suppressants and activators, there can be antiscalants for water treatment, dust suppressants used in the mining process, residual flocculants from recycled thickener overflows, grinding aids, and many other types of chemicals that are added upstream of a flotation circuit. Although these other chemicals are usually used at very low doses, it is important to know if they affect the flotation process detrimentally in the event of a spill or a build up from recycled water.Laboratory flotation testing of these chemicals characterizes their effects, but testing at expected doses in the float can mask the effects of the chemicals in the plant. Also, simple tests that do not measure the kinetics of flotation do not reveal the effects the other chemicals have on the flotation circuit. Thus, a new flotation protocol was needed to expose the full effects of chemical additives and to assist in choosing the chemical with the lowest potential for a negative effect.FLOTATION KINETICSMeasuring recovery kinetics in a laboratory flotation cell is a well-established procedure: analyzing concentrates taken in a timed sequence to determine the recovery rate of individual cells in a flotation circuit. The recovery from the early flotation cells are a true measurement of how well a flotation chemical is performing. The principles of kinetics can be mathematically determined by the following functions (Houston, 2006):"

Jan 1, 2013

By D. Van Tonder, C. Edwards

ABSTRACT Solvent extraction is used in many acid leach uranium circuits to upgrade and purify the uranium-bearing solution prior to final product precipitation. A number of strip options are available to recover the uranium from the loaded organic. This paper compares seven of these options on the basis of typical capital and operating costs for the solvent extraction circuit and downstream uranium processing and also considers other related issues. The aim is to provide an objective comparative assessment of these options that could be used as a qualitative guide in process selection or improvement.

Jan 1, 2013

By Jerry C. Tien

The rare earth elements (REEs) are a group of 17 chemical (metallic) elements. REEs are used widely in high-technology, clean-energy products as well as weapon systems. China&apos;s dominant position as a producer of over 95% of the world REEs output and the world&apos;s increasing reliance on REE products have highlighted concerns about the future availability of rare earths in recent years. This paper briefly reviews the REEs world reserves, production, consumption, the impact of our heavy reliance on REEs products and China&apos;s changing policies on REE export on world supply chain.

Jan 1, 2013

By Marcelo Mourao, Adolfo Pillihuaman, Alberto Nogueira, Cyro Takano

"The self-reduction is an alternative and promising process for production of pig iron because offers decisive benefits such as enhancing the reaction kinetic with decrease in fuel consumption and C02 emissions. The self-reduction mixture of iron ore fines, carbonaceous reducer and additives for slag forming components, without agglomeration, was tested in a laboratory rotary kiln. The additives for slag were defined for presenting two different estimated liquidus temperatures (1623 Kand 1773 K) to verify the effect of these temperatures on the iron-carbon nuggets coalescence process. These mixtures were tested at 1673 and 1773 Kin an experimental rotary kiln. After reduction-melting and coalescence processes the samples were disaggregated and the iron nuggets were classified by size. It was considered that nuggets larger than 7,93mm would be a good reference for coalescence index. Low liquidus temperature slag presented 37% of this larger fraction against only 13.5% for high liquidus temperature one. The low liquidus temperature slag would facilitate contact between the particles of iron-carbon in a rotary kiln, enhancing the coalescence.IntroductionThe slag composition usually depends on the reducer ash composition, the ore gangue, the binder composition and any fluxing material [l], and the mechanism of carbon transportation in slag that contains iron oxide reducible by carbon can be explained by the oxide reduction and the metal carburization. During carbon transportation, the carburized particle is transported to slag-metal interphases by the gravity effect, being assimilated by the metallic phase [2]. When the slag's iron oxide comes in contact with the solid carbon, it is immediately reduced, forming Fe particles and CO bubbles as it is shown in the figure l(a). The Fe particles are carburized by carbon particles; they are liquefied simultaneously in the carbon-slag interphase. The Fe-C liquid particles are transported from the slag-carbon interphase to iron-slag interphase as a result of slag flow, based on the surface tension difference (Marangoni effect), figure l(b). The Fe-C liquid particles coalesce on the iron surface and the carbon is immediately diffused in the iron as it is shown in figure l(c). The reduced iron is carburized continuously by repeated sequences [3]."

Jan 1, 2013

By Xinyang Wang

It is believed that sulfur and volatile matter contents in coals are the main intrinsic properties to cause the self-heating of coal. Their oxidation at lower temperatures than that of fixed carbon to initiate coal&apos;s self-heating should be quantified. This study is aimed to improve the previous mathematical model developed by the authors for studying the coal&apos;s propensity for spontaneous combustion. It enhances the model&apos;s ability to consider the effects of sulfur, volatile matter and moisture contents in the coal - three important factors affecting the coal&apos;s self-heating process. Sulfur exists in coal primarily in the form of pyrite which will be oxidized rapidly under suitable conditions. Volatile matters, higher in low rank coals, are more easily to be oxidized. Heat of water condensation provides initial energy for low temperature oxidation. Heat release rates for pyrite oxidation and moisture condensation are built in the model. Finally, the simulation results in terms of time versus temperature on pyrite oxidation and moisture condensation are validated with the adiabatic testing data respectively.

Jan 1, 2013