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By Jin-tao Gao

In order to recover Ti resource from titanium bearing blast furnace slag, a new technology to separate perovskite phase from CaO-TiO2-SiO2-Al2O3-MgO system by supergravity is researched. In the condition of gravity coefficient of 750g, treatment temperature of 1305°C and time of 20min, the significant layers appear in samples which are obtained by means of centrifugal treatment. Along the direction of the supergravity, the volume fraction of perovskite phase increases gradually, and the equivalent diameters of perovskite phase crystals increases with the area approaching to the bottom of the sample. It is indicated that TiO2 is enriched in the bottom of sample as concentrate with a recovery ratio of 74.05% by supergravity treatment.

Jan 1, 2014

By Shu-cai Zhou

"To understand the solidification behavior of austenitic heat-resistant stainless steel (TP34 7) in rotary electromagnetic-field, the influence of electromagnetic stirring in mold (M-EMS) on solidification structure of TP34 7 heat resistant steel in a round billet continuous casting was investigated based on industrial experiments. The results indicate that the excellent billet solidification structure of TP34 7 heat resistant steel can be obtained with appropriate electromagnetic stirring parameters. The solidification structure of TP34 7 heat resistant steel can be remarkably refmed, central porosity and shrinkage cavity can be remarkably decreased and equiaxed grains zone widens was enlarged. The industrial trials verify that the stirring intensity of TP34 7 heat resistant austenitic stainless steel should be higher comparing with plain carbon steel. Due to a higher viscosity, rotating speed of molten stainless steel was 20-30% lower than that of molten carbon steel in the same magnetic flux density.IntroductionIn recent years, the development of ultra super critical (USC) plants is accelerated by the demands of environment protection and energy saving, and USC plants with steam temperature and pressure conditions in excess of 593°C and 24.lMPa respectively were constructed. To achieve the goal, it is important to develop new materials with excellent high temperature strength, superior resistance to oxidation and corrosion at high temperature. Besides, their cost must be low enough to meet the requirement of plants [ 1]. TP34 7H steel is promising austenitic heat-resistant steel, which is used as superheater/reheater tube material and is extensively used for high temperature components and fossil-fired power plants, and suitable to be used in USC boilers plant. This kind steel contains with about 0. 7%Nb and it keeps higher allowable stress and creep rupture strength than TP304 and TP321H [1-2]. TP347H has conventionally been produced by ingot casting followed by forging and rolling. Recently, in order to decrease the production cost, challenging trials to produce these types of alloys by a continuous casting (CC) process have been attempted. However, the solidification structure of austenitic stainless steel is one of the key issues that attract more attention. Due to the low thermal conductivity of TP347H heat resistant stainless steel (much smaller than that of plain carbon steel), pronounced defects during continuous casting of austenitic heat-resistant steel such as coarse columnar, center porosity and coarse bridging, greatly influence mechanical properties of fmished products.A widely used technique in metallurgy is the inductive drive of molten metals using rotational or traveling magnetic fields. Recently, rotary electromagnetic stirring (EMS) has been applied to reducing various defects and improving increase the solidification structure of the metals in the continuous casting of steel, Al-based alloys and Mg-based alloys [3-8]. Electromagnetic stirring of plain carbon and low alloy steel in the continuous casting bloom and slab is well established for improving the quality of cast products [9-11] and is widely used in industry. However, very few literatures on electromagnetic casting of heat resistant stainless steel have reported. In this work, an industrial plant trial was performed to clarify the effect ofM-EMS on the macroscopic quality ofTP347heat resistant steel billet, in which the regularity and mechanism of the influence of EMS on solidification casting billet were discussed."

Jan 1, 2014

By B. Csoke

In a first stage of our investigations material properties of fly ash (three acidic and one alkaline type originating from combustion of various age coal) obtained from four various dumps have been characterized. In a next step systematic mechanical activation experiments??grinding??and measurements have been performed with various ashes to establish relations between grinding fineness (specific surface area), specific work input demand of grinding and activity. In a third phase utilization of a mixture of mechanically activated fly ash and lime for producing an independent binding composition has been assessed involving determination of interrelationship(s) between the degree of activation of fly ash, the lime concentration and the resultant strength of the obtained concrete. Finally, pilot size experiments were conducted and a test road section was built to explore possibilities for the production of suitable binding composition from the mixture of fly ash and lime as well as the applicability such mixture for road construction. After summarizing major achievements of the first and second stages of the work (history) the present study deals with the research conducted in stages three and four. Experimental results support the conclusion that the obtained binding material is suitable for construction of road bedding.

Jan 1, 2014

By J. Kolacz

A new optical sorting system based on a complex image analysis and high definition imaging has been developed by Comex. The image analysis is based on high definition cameras of different types and advanced filtration tools for verification of waste particles. Different mineral properties are used to identify the processed material. The system is further combined with a high speed rejection mechanism based on FPGA technology and operating in real time conditions. This provides a minimal error when removing waste particles from the sorted material.

Jan 1, 2014

By M. Y. Mohassab-Ahmed

In an effort to develop a novel flash ironmaking process, the chemistry of selected slags was investigated. In different ironmaking processes, the molten bath (iron-slag bath) is expected to be in contact with gas atmospheres of H2/H2O, CO/CO2/H2/H2O, and CO/CO2. The latter was investigated to allow comparison with the blast-furnace conditions. The slag composition was selected to resemble that of the blast furnace with CaO/SiO2 in the range 0.8 to 1.4. The temperature range was 1550 to 1650°C. The oxygen partial pressure was maintained in the range 10-10 to10-9 atm. The effect of water vapor on the chemistry of the slag as well as the equilibrium reactions involving the slag has been studied for the first time. H2O dramatically affects the chemistry of the slag and strongly affect the phase equilibria in the slag as well as the equilibrium distribution of elements between slag and molten metal.

Jan 1, 2014

By P. K. Fedotov

At projecting mining-concentrating complex at the deposit ?Zapadnoye? (Russia) it was considered to enable an opportunity of refusal from conventional SAG-mills. First time a scheme of gold bearing ore destruction using Roller Press RP 5-100/90 had been developed and integrated. The plant was launched in summer 2003 and presently it has achieved designed technological parameters, processing throughput comes to 1 million tons of the ore per year.

Jan 1, 2014

By Per Svedensten

One of the most significant behaviour of a crushing plant is the constant variation in the process. The variation is caused by two major effects. The first and constantly changing is the rock material properties. During operation rock material with different strength and particle size distribution is fed to the plant which makes the performance of the equipment to vary. The second and more slowly changing variation is caused by wear on the processing equipment. These effects must be predicted in order to be able to optimise a crushing plant. This paper demonstrates how Monte Carlo simulation can be utilised to study and operate crush-ing plants. By introducing Monte Carlo simulation the varying process can be study and also optimised. To maintain the optimised process performance supervision is needed. This paper demonstrates how results from the Monte Carlo simulation can be utilised for process supervision. Charts for process measurements can for example be derived. These can then be used to guide decision making and understand how the variation and performance of the plant changes over time.

Jan 1, 2014

By Carlos de F. Gontijo

The flotation of quartz particles was studied over the particle size range from 0.5 µm to 1000 µm and for advancing water contact angles between 0º and 83º. Flotation was performed in a column and in a Rushton turbine cell. Particle contact angle threshold values, below which the particles could not be floated, were identified for the particle size range 0.5~1000 µm, under different hydrodynamic conditions. The flotation response of the particles, either in a column or in a mechanically agitated cell with a similar bubble size, was comparable. Turbulence plays a role, as does bubble-particle aggregate velocity and bubble size. The stability of the bubble-particle aggregate controls the maximum floatable particle size of coarse particles. For fine particles, the flotation limit is dictated by the energy required to rupture the intervening liquid film between the particle and bubble. Flotation of very fine and large particles is facilitated with small bubbles and high contact angles. These results greatly extend our earlier observations and theoretical predictions.

Jan 1, 2014

By J. M. N. P. C. Teles, Venda Oliveira P. J., Correia A. A. S.

"AbstractA laboratory work was performed to study the mechanical behavior of a Portuguese soft soil chemically stabilized with binders and reinforced with metallic fibers when subjected to tensile stresses. To this end and in order to compare the tensile strength results done by two different tests, there were conducted two types of experimental tests: Tensile Split Strength Tests (TS) and Direct Tensile Strength Tests (T). The samples tested had the same binder quantity and different fiber contents, which allowed the characterization of the tensile behavior of the stabilized and reinforced soil, as well as the definition of the best fiber content. Results show that the binder is the main parameter controlling the behavior of the stabilized and reinforced soil until failure, while the influence of the fibers is noticed mainly at the post-failure behavior. The comparison between the tensile strength done by T and TS tests shows that the tensile split test can be used to estimate the tensile strength, although its results are lower than those obtained by the direct tensile tests in general.IntroductionDue to its poor mechanical characteristics, the construction on soft soils presents difficulties that require the use of soil improvement techniques such as chemical stabilization. However, even when mixed with binders, the tensile strength of the stabilized soil is poor, requiring, in certain cases, the use of expensive steel reinforcement or metallic beams, with obvious impact on the final cost of the work. Thus, for the cases where the tensile strength is a design requirement, the soil stabilization should be design with another element, whose primary role is to give tensile strength to the improved soil (Teles 2013).To fill the lack of published studies focused on soft soils both chemically stabilized and reinforced with metallic fibers, the present research aims to analyze the behavior of the improved soil when subjected to tensile stresses. To support the research there were conducted direct tensile tests (T) to directly measure the tensile strength of the samples and tensile split tests (TS) or Brazilian tests to obtain it indirectly. The samples tested had the same binder quantity but five different fiber contents in order to study the influence of the fibers in the improved soil behavior. In addition, a comparison between the results of both tests was made."

Jan 1, 2014

By V. Yahorava

Efficient recovery of precious metals from process solutions is essential for improving process economics. Traditionally, precious metals are relatively effectively recovered from waste streams via precipitation or cementation. However, these approaches have a number of drawbacks, including poor water balance, creation of environmentally unfriendly waste streams, and losses of precious metals. Ion exchange technology is an alternative for the recovery of precious metals from waste or low-grade streams. This technology allows the recovery of the precious metals to extremely low levels (micrograms per litre) with relatively high upgrade ratios from the solution onto the resin without major water balance concerns, while the impact on the environment could be minimized or avoided. Research was conducted on the recovery of platinum group metals and gold from different low-grade and waste streams from one of the precious metals refineries in South Africa by means of ion exchange. Various functionalities and matrices (granular and fibrous) of ion exchange materials were evaluated. The results from these studies indicated that in some cases ion exchange could be very effective for the recovery of precious metals, and that the PGM concentration could be reduced to < 1 mg/L. The upgrading ratios of the various PGMs onto the specific fibres were relatively high for the specific streams evaluated, which might in some cases justify incineration of the loaded material instead of stripping and recycling the adsorbent. The cost of direct incineration for one of the waste streams tested would be less than 1% of the value of the PGMs recovered. However, the adsorbent has to be carefully selected and the process design optimized for each specific stream.

Jan 1, 2014

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By M. M. Oosterveld

"In South West Africa diamonds are mined from ancient beach deposits by the Consolidated Diamond Mines of South West Africa, Limited.To improve the control of mining production, a computer is used for the calculation of statistically more accurate and homogeneous ore blocks. Geological and sampling information has been digitized and stored on magnetic files.The figures derived for each block entail the calculation of the diamond size frequency distribution, the diamond density distribution and the ore reserve by using the density distribution.The diamond size frequency distribution is used for estimating the revenue in an ore block.A description is given of how a linear programming system can be used for production planning."

Jan 1, 2014

By S. L. Gao

Based on the differences in hardness and density of diaspore and aluminosilicate minerals which usually exist in Chinese diasporic bauxite, It is analysed that bauxite of this kind is difficult to be separated effectively by classification and normal gravity separation, and cyclonic centrifugal field was thus proposed to be carried out, in which classification can take place according to the size difference resulted from selective grinding, what?s more, the separation function according to density difference is expected to take effect at the same time, and then cyclonic separation tests for diasporic bauxite of A/S 4.39 and grinding 61.90% -0.074mm were carried out tentatively. The results showed that the accretion of feed pressure can offer strong enough centrifugal force for cyclonic separation with result that separation function according to density difference is effectively intensified, by the increasing of this parameter, underflow and overflow of A/S 7.64 and 2.18 can be processed at the same time, and the recovery of Al2O3 in underflow is 71.78%; judging by the flow ratio, the spatial locality envelope of zero vertical velocity do constringe to the vertical axis by the enlarging of diameter ratio of apex to vortex, overflow and underflow of A/S 2.08 and 6.5~7.0 can be processed by controlling this structural parameter, which is possible to offer a technological method for low-grade bauxite to de-sliming beforehand.

Jan 1, 2014

The traditional technological flow sheets for processing of ferrous quartzite (magnetite ores) al-low production of the iron concentrates with Fe content of 65%~68 % and recovery level about 55 %. The losses of iron with the tails of wet magnetic separation are related to hematite and quartz-magnetite particles, which are not extracted under low magnetic field employed. This work presents the results of the application of reverse cationic flotation for production of hematite concentrates with weak silica content from the tailings of wet magnetic separation of mag-netite. Fine particle size, complex mineralogy and presence of locked particles determine the impos-sibility of direct production of hematite concentrate by flotation or magnetic separation. The gravity concentration allows obtaining of iron concentrate from the well-prepared feed (size fraction -53+20 µm) but with very low recovery. Thus, hematite concentrates with weak silica content and satisfactory iron recovery were obtained by reverse cationic flotation, when it was fed with iron pre-concentrate produced by high gradient magnetic separation. The best flotation results were obtained by the use of formulations based on amines of different molecular structure that modulate the structure of adsorption layer, and favour a shifting of hydro-philic-hydrophobic balance on the surface of silicates with adsorbed starch and their preferential transfer into the froth product.

Jan 1, 2014

By Ping Fang, Dezhou Wei, Zichuan Guan, Wengang Liu, Yanbai Shen

A new cationic collector, bis(2-hydroxy-3-chloropropyl) dodecylamine (N23), that can be dissolved in water easily was synthesized successfully. Its flotation performance to quartz was investigated compared with dodecyl amine in hematite reverse flotation system. It was found that N23 showed stronger collecting performance to quartz than dodecyl amine. The maximum recovery of 98% to quartz was obtained at a collector concentration of 43.3 mg/L in the pulp pH range of 6-9. This collector can be used to float quartz from hematite when starch was used as depressant. Optimal separating results with 90.06% iron recovery and 66.3% iron grade to artificially mixed sample were achieved at a collector concentration of 43.3 mg/L and a starch concentration of 23.3 mg/L at neutral pulp pH when hematite and quartz were mixed at a mass ratio of 3:2. The adsorption mechanism of the collector on quartz surface was investigated by infrared spectroscopic analysis and zetapotential measurements, which revealed that electrostatic attraction and hydrogen bonding adsorption occurred between the collector and quartz surface.

Jan 1, 2014

By Thomas Mütze, Anja Hirte, Ursx Peuker, Thomas Kuhn

"The comminution behavior of two ferromanganese nodules samples of the equatorial northeast Pacific has been examined as a basis for the separation of two kinds of metal-rich layers. Those layers were finely grown together during nodule formation and are one reason that the exploration of deep-sea minerals calls for the development of new mineral processing concepts. Therefore fundamental analyses of the fracture behavior have been made under compressive and impact stress. Further experiments took focus on the crushing behavior in a jaw crusher and a small scale impact crusher as well as the milling behavior in a dry vibrating mill, a wet planetary ball mill, and a wet agitated ball mill. The comminuted products were characterized by PSD, particle shape, particle density, and porosity. The experiments show a low stress resistance of the ferromanganese nodules. Compared to compressive stress, impact stress turned out to be the more effective for crushing. Both samples showed no significant difference in the comminution behaviour which makes differing mechanical treatments unnecessary. In both cases particle sizes below 1 µm were achieved by wet grinding. This particle size is necessary to separate the two kinds of metal-rich layers which is part of continuative studies."

Jan 1, 2014

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By C. Kruger

Anglo American Platinum has adopted a strategy of best practice principles (BPP) for sampling, mass measurement, analysis, and metal accounting for more than a decade now. When new plants are designed, the most suitable sampling equipment and sampling protocols are implemented and material flows and plant layouts are designed around sampling strategies. A few years ago, a crushing plant for a high-grade matte stream was commissioned. The design called for the high-grade material to be crushed to 95% passing 2 mm, and the design allowed for a single-cutter primary Vezin sampler taking increments from a gravity flowing stream at regular intervals while filling a tanker for pneumatic offload at the base metal refinery. This was a single point of sampling and analysis that would measure the wanted output from the smelting complex and the input to the refineries. In addition, the design incorporated the functionality to collect increments in an ?interleaved? fashion from the Vezin sampler for internal precision checks. The metal accounting strategy for Anglo Platinum involves the ongoing measurement of all inputs, outputs, and stock levels for all operations for platinum group metal (PGM) and base metal (BM) content. Included are yearly stocktakes, usually done on 1 February, across the smelters and refineries (at least the base metal refinery). In the accounting period immediately following the introduction of the new crushing and sampling facility, a trend was developing whereby the absolute difference between the physical stock and theoretical stock (PGMs predominantly) increased for the two respective sites on an ongoing basis. The smelter showed an increase in physical stock compared to the theoretical stock (sender) and the base metal refinery showed an increase in theoretical stock against physical stock. Because of this anomaly, an additional stocktake was held in September for the period in question, and it was confirmed through the physical stock measurement results that the PGM accounting problem was indeed pointing towards the evaluation of the high-grade matte stream. This paper showcases parts of the process that took place to explain the poor accountabilities for the two sites. Previous results from the sampler ratification process (of the interleaved sampling design) were reanalysed, a physical inspection was carried out on the sampling system again, and the sampler performance was monitored (quality control parameters) for the period. From these investigations, it was found that airflows inside the Vezin introduced the sampling bias. A change in sampling protocol was introduced, as well as certain physical changes to the sampling equipment, to eliminate the airflow and thus the bias conditions significantly. The accounting period that followed the phased upgrading process showed that the accounting between the smelter and base metal refinery had been restored to within statistical limits (difference between physical and theoretical stock below 5% relative to theoretical stock). Keywords sampling, metal accounting, Vezin sampler, sampler bias.

Jan 1, 2014

By Ali Naeimipour

Availability of accurate geological information about the rock mass surrounding a tunnel or mine working is the key to enhance and optimize the required ground support measures. Various approaches have been used to obtain data on ground conditions, including the possibility of characterizing the ground while drilling for roof bolts, by the Measurement While Drilling (MWD) system, via optical, sonic and acoustic televiewers, and using various types of gamma probes. While there are many different systems for characterizing the ground in longer, larger-diameter holes drilled downward, the options for using probes and logging systems in short, small-diameter holes drilled in horizontal or an upward direction are very limited. This paper will present the results of recent field tests using optical televiewer (OPTV) to analyze the joints and voids in boreholes drilled in different directions. The studies show that OPTV is a promising tool; however, getting a good quality image from the upward drill holes still need to be studied. Meanwhile, estimated in-situ strength of the intact rock is needed to complement the jointing pattern for rock mass classification. For this purpose, preliminary steps for the development of a borehole scratcher to estimate rock strength will be discussed in this paper.

Jan 1, 2014

Compressive crushing is applied in crushing plants used in mineral, mining, and aggregate in-dustry for fragmentation of rock materials. From a global perspective, the total volume of crushed rock is massive and corresponds to several billion tons. All societies have to fulfil a daily need of rock material products and its derivatives such as metals and minerals. The business for metals and minerals is global while the aggregates production is mainly a local industry. This paper presents a broader overview of optimisation with respect to product yield, use of natural resources and energy consumption. High level plant optimisation of compressive crushing plants is covered as well as real-time optimisation and optimisation of single production units. Each of three optimisation areas are presented and a discussion around how these three areas will be able to communicate with each other is given. Several models, e.g. process performance behav-iour with respect to wear, as well as fitness functions can be common for all three areas. Well-defined and representative fitness functions are of the utmost importance in order to assure that the optimisation results reflect the production targets. It is concluded that great benefits can be achieved by linking together different areas of optimisa-tion. The future for compressing crushing lies, without a doubt, in tailored processes both with re-spect to machines optimised for each customer, plant parameters and operation routines as well as an on-line adjustment, which takes into account current information and control possibilities.

Jan 1, 2014