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By R. J. Forzatti

The production of sulphuric acid from sulphur generates heat. The majority of this heat is recovered as steam and is often used to generate electricity. Heat not recovered as steam is rejected to cooling water systems. The design of the turbine, condenser, and cooling water systems impacts the overall water, energy, and environmental footprint of the plant. This review considers a conceptual 2000 t/d sulphuric acid plant with several alternative cooling water systems. The review utilizes Hatch?s 4 Quadrant sustainable design tool to compare the alternatives on both an economic and a weighted sustainability scale.

Jan 1, 2014

By A. Deepatana

This study compares the use of an aminophosphonate chelating resin Purolite S950 and a sulphonic acid strong cation exchange resin Purolite C160H to recover nickel and cobalt from the synthetic bioleach solutions. Batch adsorption of metal citrate is performed as a function of metal citrate concentration (15~2000 mg/L) and solution pH (0.01M and 0.1M citric acid). The adsorption mechanism as inferred from the fit to Langmuir (LM), Freundlich (FM) and Redlich-Peterson (RP) models demonstrates that nickel citrate adsorbed onto C160H appears monolayer in comparison to that adsorbed onto S950 exists multilayer. In contrast, cobalt citrate adsorption onto both C160H and S950 agrees with the LM model. The results have shown that loading capacities of nickel and cobalt citrate onto C160H are 60 and 65 mg/g whereas those observed onto S950 are 16mg/g and 6 mg/g respectively. These are achieved in metal citrate prepared in 0.1 M citric acid. Resin regeneration is conducted in using 2 M nitric acid solution. The results show high efficiency of nickel and cobalt citrate elution from Purolite C160H. Findings from this study suggest Purolite C160H is a suitable adsorbent for recovering nickel and cobalt from bioleaching solutions.

Jan 1, 2014

By E. Barsky

The composition of multi-component materials is proved to be unambiguously determined by the composition uncertainty parameter (composition entropy). At the same time, every component, depending on its content, introduces a certain value into this parameter. Quality criterion of multi-component separation is determined by the total change of this parameter for all products obtained as a result of the separation process. This parameter can unambiguously estimate both multi-product separation and complicated schemes of modern beneficiation plants. It can be used to estimate binary mixtures separation, too. During the optimization of multi-product separation, another problem arises, which is not peculiar to binary mixtures. In this case, the total efficacy depends on the order of separation boundaries, as well. In the present paper, a specific example of initial product separation into seven products by six boundaries is investigated. It is clear that with respect to a single boundary, two products only can be obtained. In this case, the separation optimum is shown to correspond to the separation of boundary-class particles equally into both products. We have also established that from the point of view of entropy, the maximal possible separation efficacy corresponds to equiprobable composition of the initial mixture, i.e., the fine product quantity in the material to be separated is equal to that of the coarse product. Three groups of experiments were carried out. In the first group, the boundaries were consecutively specified from the finest to the coarsest one. In the second group, the boundaries were set vice-versa, i.e., consecutively from the coarsest to the finest one. In the third group, no sequence was observed. At every separation stage, a boundary was specified in such a way that the separated material composition was as close as possible to equiprobable one relative to this boundary. Total efficacy was different in all the three cases. In third group of experiments, its value is the highest, which confirms the advanced supposition. The obtained results are phenomenological, ? they can be applied to any processes of solid, liquid and gaseous materials separation.

Jan 1, 2014

By Shuli Teng, Vladimir Sujansky, Matthew Rawls, Ivan Junarsa

In recent years significant advances have been made in chemical processing technology. In particular, process intensification using micro-technology has had some success in changing and improving chemical processes including mixing. Process Intensification is the miniaturization of unit operations and processes whereby a smaller compact piece of equipment takes the place of a larger one at the same given capacity or mass flow rate. This paper summarizes research into the application of the technology for manufacture of high internal phase water in oil ammonium nitrate emulsions (ANE’s) at low energy cost and with very low oil/fuel blend content. The emulsions can be used as precursors for preparation of explosives. The quality of the emulsion prepared was assessed through droplet and crystal analysis and compared with that of emulsions made by conventional large scale jet mixing technology.

Jan 1, 2014

By M. I. Panayotova

Some of effluents released by copper smelting plants are highly acidic (pH = 0~1) and contain arsenic and copper in relatively high concentrations (10~20 g/L). Usually arsenic is removed by precipitation with different reagents, such as lime, iron salts, calcium salts, aluminium salts, etc. Precipitates (often voluminous) that require further handling are formed and copper and other valuable components are lost. A method is presented for copper and arsenic extraction from acidic effluents. Effluents are treated in specially designed closed electrochemical cell without chemicals? addition. Gases formed are collected and treated for decomposing the eventual traces of As-bearing compounds and ensuring the environment protection. Initially copper of grade of 85 % is electro-won. Further about half of the initially available arsenic is separated as low-soluble, low volume mixture of intermetallic compounds, oxides and some elemental arsenic. At the next stage the main part of the left arsenic is immobilized as low soluble stable compound. Arsenic content in the treated acid is in the range 0.20~0.25 g/L. Acidity of treated effluent after first two stages remains practically unchanged and the solution can be re-used. Physicochemical and electrochemical processes, governing copper and arsenic removal, are discussed.

Jan 1, 2014

By Darryel Boucher, Raymond Langlois, Neil Rowson, Kristian Waters

The Knelson Concentrator is a centrifugal gravity concentrator composed of a high speed rotating bowl into which a mineral slurry is fed. The rotational motion creates a centrifugal acceleration up to an equivalent of 200 G. Under this acceleration, particles enter fluidised riffles along the side of the bowl, with the fluidisation allowing for the substitution of dense material for less dense. The separation mechanism is not fully understood and questions remain on the optimal residence time, slurry feed parameters and bowl surface profile to achieve a better separation. The positron emission particle tracking (PEPT) technique has been applied to record the motion of a -1700+1180 µm particle of a quartz-gold matrix, labelled with 18F radioisotope while it undergoes concentration inside a 3" laboratory scale Knelson Concentrator (KC-MD3) operated at 60 G. The slurry used was composed of quartz and magnetite. Particle trajectories during the first stage of the concentration process where the heavier particles centrifuge through the increasingly dense slurry towards the riffles of the bowl are shown with respect to time. This work reveals new information on particle motion inside the Knelson Concentrator and the results will be used for validation of developed separation model as well as optimisation of a centrifugal concentrator’s performance.

Jan 1, 2014

By Daniel W. H. Su

Thick, massive sandstone present in close proximity of the mining horizon can create difficult longwall caving issues, which may lead to severe face loading and subsequent face roof control problems. Under deep cover, such delayed caving and overhang not only impose additional loading on the gate road pillar system, but they also increase the potential for large seismic events. Such a combination of thick, massive sandstone geology and deep cover was present over a portion of a southwestern Virginia coal mine, which was confirmed via detailed in-mine roof scoping and mapping. Large seismic events were recorded over a district of 1,000-foot-wide longwall panels. This paper presents the ground control design changes implemented to reduce longwall-induced stresses in the sandstone, to reduce longwall abutment pressures in the gate road pillars, and to reduce the magnitude of mining-induced seismic events. A series of two-dimensional finite element models were constructed and analyzed to evaluate the longwall-induced stresses in the sandstone above the gate road pillars and the abutment pressures within the gate road pillars. Results from the analyses indicated that reducing the panel width from 1,000 to 700 feet reduced the longwall-induced stresses in the sandstone by a factor of 2.0. Specifically the probability of sandstone stability improved from 29% for the 1,000-foot-wide panel district to over 95% for the 700-foot-wide panel districts. Also, the subcritical 700-foot-wide panel, coupled with a change in pillar design, considerably reduced the longwall-induced abutment pressures in the gate road pillars, which significantly increased the gate road pillar stability factor. Surface subsidence measurements conducted over the 1,000-foot-wide panel district and two new 700-foot-wide panel districts were in very good agreement with those predicted by the finite element models. In addition, results from the models indicated that wider panels with a smaller district may produce the same probability of sandstone stability. One four-panel district and one five-panel district with the new ground control design changes have been mined successfully. The panel width was found to be the most influential factor in determining the longwall-induced stresses in the sandstone and in the gate road pillars. The thickness and massive nature of the sandstone, the proximity of the sandstone, and the strength of the sandstone were also found to be important factors. Seismic monitoring over the two mining districts that employed 700-foot-wide panels confirmed the reduction of one order of seismic magnitude when compared with those measured over the 1,000-foot-wide panel district.

Jan 1, 2014

By K. Takahashi

Generally speaking, wastewater coming from the metallurgical process for recovering precious metal contains precious metals such as gold (Au), platinum (Pt), palladium (Pd), Silver (Ag), etc., which concentration is about 10 mg/L. In addition, there are other metals such as copper (Cu), iron (Fe), which concentration varies from several mg/L to more than 10,000 mg/L. It should be noted that the concentration of metals in wastewater is relatively high, considering the fact that these metals of similar concentration can be found in ores. However, most of these valuable metals are not treated, due to the high processing cost and technical problems. Within this frame, the authors put forward a new process that includes neutralization/reduction, precipitation and fusion. The idea is to recover and recycle Au, Ag, and Pd metals as well as protecting the environment by saving the resources. It was found that this new process was able to recover more than 90% of Au, Ag and Pd.

Jan 1, 2014

By J. Gong

Fine mineral particles pose two challenging problems in froth flotation, i.e., ineffective recovery of fine hydrophobic particles and mechanical entrainment of fine hydrophilic particles. The first problem has attracted much research effort while the second problem has received much less attention. We have recently proposed a method to deal with mechanical entrainment, i.e., utilizing the flocculating power of polymeric depressants to flocculate fine gangue particles and making the flocs big enough so that the mechanical entrainment of these particles can be reduced or eliminated. In this paper, we report results on the use of polyethylene oxide (PEO) in controlling quartz gangue in the flotation of sulphide ores. PEO was found to flocculate fine quartz and lower its entrainment. It was also found to modify air/water interfacial properties and acted as a frother, which could increase gangue entrainment. Nevertheless, when used at starvation dosages, PEO was found to significantly improve the grades of the floated sulphide concentrates.

Jan 1, 2014

By Vasile Murariu, William Pate, John Herbst, Dilek Alkac

"Multiphysics models are essentially first principles models capable of providing very accurate micro scale predictions. The computational requirements for Multiphysics Models are extensive, precluding their direct use for flowsheet simulations. Population balance models get their form from theory but the model parameters have to be provided from experiments. The prediction errors for the population balance models are typically significantly higher than those for the Multiphysics Models but the computational effort for Population Balance Models is typically much less than that for the Multiphysics models. The hybrid model described here takes advantage of the strengths of each of the two primary model types and minimizing the weaknesses of each. The Multiphysics Model is used to perform high accuracy "experiments" that are difficult or impossible to conduct in laboratories or plants. The results of these experiments are combined with standard laboratory or plant data to parameterize and further enhance the Population Balance portion of the hybrid model. The creation of a useful Hybrid Model is demonstrated for a MP1000 secondary crusher. The validation of the hybrid crusher model is also presented. Finally the use of the Hybrid Model is illustrated in a full comminution flowsheet simulator."

Jan 1, 2014

The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores whereas oxidized molybdenum ores, being finely disseminated and difficult to process, have not been exploited and utilized effectively. In this article the beneficiation process of a molybdenum ore occurred in an oxidized ore zone was investigated in order to provide a new way for the development and utilization of the oxidized molybdenum ores in China. The molybdenum mineral in the ore was mainly wulfenite and the associated minerals included barite, limonite, quartz and small amount of cerusite. Limonite in the ore occurred in a crust and honeycomb-like colloidal state and composed the framework for the formation of the other minerals in the ore, which filled the pores in the framework. Wulfenite was mainly fine-grained and occurred in the fine porous crust and honeycomb-like framework. The finely disseminated ore structure made the separation and recovery of the molybdenum mineral in the ore very difficult. On the basis of the mineralogical study of the ore, experiments were conducted to compare the various mineral processing methods for the beneficiation of the ore, including single gravity concentration, single magnetic separation, single flotation, and a combination of high intensity magnetic separation and gravity concentration. The results indicated that with single gravity concentration a molybdenum concentrate containing 5.85 % Mo with a yield of 11.76 % and a Mo recovery of 43.5 % was produced. With single high intensity magnetic separation it was very hard to obtain a molybdenum concentrate product. With single flotation process a molybdenum concentrate containing 7.06 % Mo with a yield of 15.14 % and a Mo recovery of 62.63 % was produced. With a combination of high intensity magnetic separation and gravity concentration a molybdenum concentrate containing 6.46 % Mo with a yield of 11.81 % and a Mo recovery of 42.11 % was produced. In conclusion, compared to the other methods the flotation process can produce more reasonable technological and economical results and is the best process for the exploitation and utilization of the finely disseminated oxidized molybdenum ore.

Jan 1, 2014

By L. M. Wang, G. P. Jiang, Y. Jiang, Liao. W. S.

ABSTRACT The authors measured porosities and permeabilities for cores from a low-permeability sandstone uranium deposit in Inner Mongolia. Features studied included fine pore structure, mineral composition, cation exchange capacity, granule appearance, and cementing features. In general, grading of the grains was relatively poor, which decreased the radii of the pore channels. The pore throat distribution was significantly heterogeneous. Pore channels ranged from small to large, but the lack of large pore channels led to low permeability. Cementation by calcite and clays, including montmorillonite, chlorite, and kaolinite, resulted in pore channel narrowing, further decreasing the permeability of the formation.

Jan 1, 2014

By Pieter de Waal

The beneficiation equipment under the control of plant metallurgists exploits the differences in the physical properties between valuable and waste mineral components. In many cases, laboratory results are too late for process control and can only serve the purpose of "post" reports, the calculation of a mass balance and the issue of a quality certificate. As a result, experienced operators regularly adjust separation equipment based on the colour and texture of the various product streams in the beneficiation plant. Metallurgists quickly learn to recognise the different minerals in their ore body. The stereo microscope has been a valuable tool used by operators to quantify known mineral species. For many years it was the only practical method available for the purpose of process control and even for quality contro1. The modem spectroscope is far superior to the human eye and can rapidly detect a change in mineral composition. New generation optical scanners and digital signal processors can provide useful signals, related to mineral composition that can readily be applied for the purpose of process control. Successful case studies, covering dry in-line and slurry applications as well as in-plant fast spot analysers are presented.

Jan 1, 2014

By P. F. Ledwaba

South Africa?s Northern Cape Province houses a variety of gemstone minerals. Diamonds remain the primary gemstone in the province, but there are also tiger?s eye, sugilite, rose quartz, jasper, amethyst, amazonite, tourmaline, and topaz deposits. This paper gives an overview of the tiger?s eye (TE) mining sector in the Northern Cape, with the objective of assessing the potential of TE to contribute to job creation and poverty alleviation in the province. Mining of TE started in 1803, but gained momentum during the 1960s. Mining is conducted on a small-scale basis, and in most cases without any legal framework. The majority of the residents are not benefiting from TE. It has been reported that an estimated R700 000 to R800 000 worth of TE is leaving the country every week through illegal trading. The potential for TE mining to contribute to socioeconomic development is hindered by illegal operations, lack of technical skills and knowledge, exploitation by dealers, lack of market information, community rivalries, and absence of value addition. A multi-stakeholder approach is needed to formalize the sector and reap the benefits. Mintek is spearheading a TE project in the Prieska area of the Northern Cape, which aims to establish a gemmological centre where TE can be beneficiated into saleable and high-value products..

Jan 1, 2014

Pyrite and Chalcocite have different crystal lattice, with different dissolution rate in the same ac-id solution, the dissolution rate of which is accelerated with increasing redox potential, they are leached simultaneously at high redox. In present work, some methods are adopted to inhibition the bioleaching of the pyrite by controlling the redox potential. Shake flask experiment shows that the dissolution of pyrite and chalcocite is slow as redox potential <700mV(Eh), but the dissolution in-creases exponentially as redox potential>800mV(Eh), they have good selectivity at redox potential between 700mV and 760mV(Eh).

Jan 1, 2014

By Anthony Spearing

There are approximately 68 million rockbolts installed annually in underground coal mines in the USA (Tadolini and Mazzoni, 2006). The most utilized is the passive fully grouted resin rebar bolt, which constitutes almost 90% of the primary support in US underground coal mines. Resin-grouted rockbolts are a very effective and safe support, but their performance still needs to be further optimized and improved. This paper investigates their performance and suggests operating conditions to optimize the performance of resin-grouted rockbolts. In addition, this paper discusses a small-scale test that can also be used to evaluate the performance of rockbolts that is quicker, easier, and less costly than short encapsulation tests.

Jan 1, 2014

By W. Y. Liu

A sulfate reducing bacteria strain (named SRB-A) is isolated from sanitary wastewater by using anaerobic technology of Hungate. The studies of physiological, biochemical and phylogenic of the isolated strain are carried out. The colonies of the strain are circle. Cells that are slightly curve, rod-shaped with the size of 1.0~3.0µm in length and 0.8~1.0µm in width. The optimum temperature for growth of the organism is 30~35°C. The optimum pH for growth is 7.0~7.2. Strain SRB-A can use sodium lactate, sodium citrate, sodium acetate, ethanol and acetone as electronic acceptor but can not use glycerol, glucose, sucrose and sodium oxatate. The isolated strain reduces sulfate, sulfide, sulfur, DSMO and FeCl3, then nitrate and nitrite can not be used. The strain has higher tolerance of NaCl, and the optimum growth occurs in the presence of 5%~8% (w/v) NaCl. The result of 16S rDNA sequence analysis indicates that the isolated strain SRB-A is the most similar to Desulfo-vibrio halophilus, and the level of the similarity was 98.4%. The isolated strain has a stronger ability to reduce sulfate, and the level of sulfate reduction reaches about 90% at pH 7 in the liquid medium. 0.6 to 0.8 is the optimum COD/SO42- in the medium for the isolated strain to show better ability to reduce sulfate. At pH 2.5 the level of removal of Cu2+ reaches 96.3%. Under the condition of pH 3.5, the level of removal of Zn2+ reaches 92.6%. When the value of pH reaches about 7, the Fe3+ is precipitated by the formation of Fe(OH)3, and Fe3+ is removed up to 89.4% at last.

Jan 1, 2014

By E. Alldén Öberg

In 2004, LKAB decided to start a basic engineering study in expanding its existing production lines at the Malmberget mine site. It was expected that some of the production lines would become bottlenecks with reference to capacity. In this study, the sorting plant is examined and the results show that several unit operations will be limiting under current operating conditions. An additional purpose with the study was to investigate how replacement of some machines would influence performance and if production plans for the coming years might be achieved. Steady-state simulations using the software Modsim? were extensively used to study process performance for different operating conditions, such as iron content and size distribution in run-of-mine ore. Model parameters were derived from pilot plant data and when possible from ex-isting circuits. A complication for the simulations was the lack of relevant data and therefore some of the initial results were only indicative. The result shows that installation of new screens would give a much better operation, but also new crushers would be an improvement. This, since they can be run with full crusher chamber and tighter CSS. During 2007, most of the proposed remedies were implemented and the result is that the bottle-necks are gone, and the grades and material balances are even better than what was envisioned from the simulations.

Jan 1, 2014

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

The mining industry worldwide is currently facing a significant restructuring process. In most underground mines, widespread mechanization of the mining processes increases production while reducing staff numbers. At the same time, mining depths as well as the lateral spread of the mine workings are increasing. This ever-changing mining environment requires sophisticated solutions for the design and operation of underground mines. In fact, a reduced number of mining engineers is taking responsibility for everincreasing mine operations. This applies not only to the excavation of the minerals, but also to all other aspects of the mining operation, including health and safety, disaster management, and mine rescue organization. Most mining engineering graduates entering the industry lack experience in mine emergency management. Young engineer trainees must learn mine emergency management and rescue work in addition to their normal training experience on the job. Often, and unfortunately, emergency and rescue training at different mining companies is not carried out to the highest level and standard and with the best possible training outcomes. The tasks and challenges a young engineer faces while being trained in a new position do not leave much room for additional training in mine rescue and emergency management. At the same time, experienced, ?old hands? are retiring and cannot easily be replaced due to limited graduation numbers. Strategies are being developed at mining universities worldwide to train mining engineering students in handling mine emergency situations and to provide hands-on experience for managing potential accident and disaster scenarios underground. Two of these strategies, from the USA and from Central Europe, are presented in this paper. These specific strategies have to be seen under special consideration of the local and regional boundary conditions, but might serve as case studies for mining schools and universities in other countries.

Jan 1, 2014