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By Mario A. Terceros H., K. Rainer Massarsch

"ABSTRACTThe Expander Body (EB) technology has been used successfully to increase the pile toe capacity of bored piles in loose to medium dense soil. An important advantage of the EB system is the ability to monitor the EB expansion process, which provides important information regarding soil strength and soil stiffness. This information, obtained for each installed pile, can be used to determine the actual shape and pile toe area. The expansion pressure can be used to design the pile base capacity.The Expander Body system has been recently improved by incorporating the possibility of post-grouting of the soil below the expanded pile toe. This improvement measure provides additional strength and stiffness to the pile toe and reduces pile settlement.The shaft bearing capacity of bored piles can be increased by using a soil displacement auger, which avoids soil decompression and increases lateral soil stress. This paper describes the principle of the EB system. During the past 20 years, a large number of EB piles have been installed in Bolivia and elsewhere, providing a sound database. Results from field loading tests are presented. A comprehensive study of test piles with and without EB base has been carried out which demonstrates the improvement effects that can be achieved by the EB pile system and the combination with the displacement auger pile method. A design concept for the EB pile system with the full displacement auger pile is presented. A high degree of quality control can be achieved by monitoring the entire pile installation process, including the displacement pile and the Expander Body.1. IntroductionIn many regions of South America, soil deposits consist often of predominantly loose to medium dense sands and silts, often with high groundwater table. In the Santa Cruz area in central Bolivia, such soils are frequently quaternary sediments, deposited by the river Piray. The city of Santa Cruz is located at the right bank of the river.The most common deep foundation method during the last 30 years has been cast in situ piles, augered and concreted under support of bentonite slurry. The design of such piles has been based on SPT results. However, SPT is often performed without quality control and the reliability of geotechnical data is therefore often poor. Traditional methods of pile installation with simple well drilling equipment of insufficient capacity are frequently used. Such methods lack basic requirements of quality control. Such piles have usually low toe resistance and work mainly by shaft resistance . Although the construction process and materials are cheap, the final product has variable and limited capacity. However, the most serious deficiency is that actually achieved pile capacity and pile settlement can be erratic and difficult to predict, leading to uncertainties with regard to actual foundation performance."

Jan 1, 2014

By Upali Siriwardane, Tushar V. Kudale, Naidu V. Seetala

"Cellulose acetate (CA) membranes with 25% triethyl citrate (TEC) as plasticizer were prepared with varying thickness for CO2 gas separation from water-gas-shift (WGS) reaction products. The AFM analysis of the CA membrane showed that the uniform coating had fewer and smaller pores as the film thickness increased, and corroborated by gas permeability studies. The CO2 permeability has decreased faster than CO permeability with the CA/TEC membrane thickness, and findings support that the CA membrane could be used to entrap CO2. Several CA/TEC membranes were also staked to increase the separation efficiency. Positron Annihilation Lifetime Spectroscopy (PALS) was used to estimate the nano-porosity (pore size and concentration) changes of CA/TEC films. PALS results show a decrease in pore size with increasing CA-TEC concentration in acetone, while the pore concentration increases. The PALS results are correlated with the CO2/CO permeability variations as the CA-TEC concentration change.IntroductionHydrogen is one of the main energy sources available for the future advancement of clean fuel technologies especially for fuel cells. Generation of hydrogen and CO2 from Water Gas Shift (WGS) reaction mixtures of CO and H2O is of interest to many researchers since it allows a large scale production of hydrogen [1, 2]. Once hydrogen is produced using the WGS reaction, the output products contain mixture of CO, CO2, H2, and water vapor. Metallic membranes have been used as hydrogen separation membranes [3-6]. As H2 is separated from the mixture using the metal membranes, we need to separate CO2, and find ways of sequestration of CO2 to avoid environmental problems by greenhouse gasses. Polymeric Membranes have been used for CO2 separation [7]. Plasticizer can control the micro-structural properties such as pore size and concentration of polymer membranes [8], which influence the size/molecular weight dependent diffusion rates of the gas molecules. We have used cellulose acetate with triethyl citrate as plasticizer to separate CO2 from the WGS reaction products. Positron annihilation lifetime spectroscopy (PALS) is very sensitive and able to identify different kinds of defects and their agglomerates such as vacancies, vacancy loops, and voids [9, 10]. PALS has been successful in determining the free volume in polymers that influence the properties of the polymers [11, 12]. Microscopic properties of the free volume obtained from PALS have been correlated to macroscopic properties [13, 14]. We used PALS to study the nanoporosity (pore size and concentration) and fractional free volume changes of CA/TEC films, and used to understand the variations observed in the CO2/CO permeability as the CA-TEC concentration in the membranes change."

Jan 1, 2014

By A. B. Cecala

Enclosed cabs have been used for many years to isolate workers on mobile equipment in the mining industry for health and safety reasons. These enclosed cabs create a microenvironment for workers where they can be either more protected or more vulnerable to contaminants. Over the past decade, the U.S. National Institute for Occupational Safety and Health (NIOSH) has performed substantial research efforts to improve the air quality inside enclosed cabs of underground and surface mobile mining equipment. In these efforts, NIOSH has partnered with mining companies, original equipment manufacturers (OEMs) and manufacturers of filtration and pressurization systems in a synergistic effort to reduce respirable dust and improve the air quality inside these enclosed cabs. Various field studies over this time have shown an array of results ranging from very minor to very significant reductions (protection factor: 3-89) in respirable dust levels inside these enclosed cabs. In addition to and concurrent with the field work, NIOSH also performed a comprehensive laboratory study to evaluate all the factors involved in cab filtration and pressurization systems and identified those factors that were most significant for an effective system. From this comprehensive research effort, the key components for an effective filtration and pressurization system have been identified in an effort to provide the best air quality to equipment operators inside of enclosed cabs of mobile mining equipment, thus minimizing respirable dust exposure.

Jan 1, 2014

By A. Newman, A. Brickey

Although some of the prevalence of openpit production scheduling software can be explained by the predominance of openpit mining throughout the world, other factors have led to a lag in corresponding underground software. We explain mathematically why underground production scheduling is more difficult than its openpit counterpart and provide directions for research in the underground scheduling arena.

Jan 1, 2014

By J. Edberg

"This article details the use of an alternative testing method to the 2004 "Post-Tensioning Institute (PTI) Recommendations for Prestressed Rock and Soil Anchors" manual’s recommendations for temporary and permanent rock anchors for applications in shafts and tunnels. This method was developed and used for the Black River Tunnel (BRT) project in Lorain, OH as a means to reduce testing time of rock bolts during shaft construction while maintaining a similar level of quality control and assurance. The following sections will detail the project background, subsurface characteristics, shaft construction, the 2004 PTI testing method and associated difficulties, the alternative testing method and conclusions reached.Project backgroundThe city of Lorain is located in north central Ohio on the south shore of Lake Erie, approximately 40 km (25 miles) west of Cleveland and 119 km (74 miles) east of Toledo. The city chose to build a large-diameter storage tunnel and pump station to meet its requirements to reduce sanitary sewer overflows to the nearby Black River. NTH Consultants Ltd. (NTH) was retained by the city’s prime consultant, Malcolm Pirnie Inc. (now the water division of Arcadis), to perform a geotechnical investigation, develop design and construction bid documents for the tunnel and shaft liner systems and ultimately provide oversight assistance during the construction phase of the project.The BRT is an approximately 1,700-m (5,560-ft) long, 7-m (23-ft) diameter rock tunnel to be lined with a 5.8-m (19-ft) inside diameter secondary concrete lining (Fig. 1). The tunnel is designed to accept flow at a new drop shaft (Shaft 3) located on the west side of the Black River, across from the city of Lorain Black River waste water treatment plant (BRWWTP). The tunnel will be dewatered at the south end by a large diameter pump station (Shaft 1) located in the existing Lorain Port Authority Public Boat Launch. Flow from the new pump station will be discharged into an existing shallow interceptor sewer and directed back to the BRWWTP."

Jan 1, 2014

By E. A. Brocchi

This work is dedicated to the chemical treatment of a typical EAF dust by chlorine content agents. The residue contains 48% Fe2O3 and 28% ZnO mainly in the franklinite structural form. The others less compounds are: 4.00% CaO, 2.60% MnO, 2.20% MgO, 1.08% PbO, 0.36% Cr2O3, 0.21% B2O3, 0.03% CdO and 0.01% NiO. The experiments purpose is selectively to remove zinc from the residue leaving the iron behind. Thermodynamics studies have indicated some roasting possibilities. The experimental results have shown that both HCl leaching and carbochlorination will remove iron and zinc without any selectivity. However, either the chlorine or the calcium chloride roasting seems to form, preferentially, the zinc chloride. So, it will be presented how the EAF Dust can be treated by the using of chlorine roastings process such as carbochlorination in order to separate the zinc and iron present in the frankilinite, main EAF dust content.

Jan 1, 2014

By Gerald S. Cole

It used to be that a science/engineering presentation on "light weight" at a metallurgy conference, would relate to the materials science, processing, component fabrication and applications of aluminum, magnesium and titanium. Within the automotive industry, light weight now includes how to "lighten up", how to lightweight, or how to mass reduce vehicle components and systems. Increasingly stringent global emissions-reduction requirements require increasing vehicle fuel efficiency; mass reduction is an enabler to achieve this. While light metals certainly are the basis, a host of other materials can be used to optimize mass reduction while meeting vehicle performance, safety and cost requirements. New grades of ultrahigh strength steels and even nanosteels can be thinned down and save over 1/3 the mass vs conventional mild steels. A compacted graphite cast iron engine can be made lighter than an aluminum one. Aluminum components in vehicles were only castings; now aluminum stampings, forgings and extrusions are becoming more visible components of mass reduction. Lower mass high temperature polymers, and carbon fiber polymer composites now replace aluminum and steel. These materials often require specialized processing and manufacturing techniques to produce a component, including superplastically formed twin roll cast sheet aluminum and magnesium, and hot stamped/in-mold quenched steels. The assembly of hybrid structures requires unique joining/bonding, and corrosion-inhibiting techniques that might include sophisticated structural adhesives. This thinking "light" presentation, will conclude with a discussion of U.S. and Canadian government engineering and research support for mass reduction, including the proposed $148 M American Lightweight Materials Manufacturing Innovation Institute.

Jan 1, 2014

By Pramila Misra, Jibardhan Meher, Debadutta Das

The concentrated coal-water slurry has been receiving considerable attention recently due its ability to replace fossil fuels. Attainment of stable and concentrated slurry has been succeeded so far through several physical and chemical techniques. The present article reports the formulation and stabilization of a highly concentrated coal-water slurry formed from five varieties of non-coking coals with variable ash contents obtained from Eastern part of India, employing three varieties of starch esters, such as starch benzoate, starch formate, and starch carbamate as dispersant. The apparent viscosity of the modified coal-water slurry has been measured by varying coal loading, dispersant percentage, pH, temperature, etc. The apparent viscosity of the slurry has been found to be decreased substantially on addition of 0.8% of adsorbate in the slurry. The particle-particle interaction has been considerably decreased and stable concentrated coal-water slurry containing high weight fraction of coal (61.5-63.5%) has been achieved in each case. The slurries stay in a non-settling form for about a month with viscosity in a permissible low range. The coal-water slurry has been found to behave as a non-Newtonian liquid. Comparison of the zeta potentials of the naked and modified coals evidences that adsorption of the dispersants at coal-water interface results in inhibition of the agglomeration of coal particles through mostly steric repulsions.

Jan 1, 2014

By Derek Egan

"Abstract Construction clients want their foundation solutions to be right first time, every time; but it is often the geotechnical contractor who carries the most risk in achieving this. Robust validation to ensure that the installed geotechnical product is appropriate for the encountered ground conditions, will perform as required and be correctly measured for payment and record purposes is very important to minimise the contractor’s and the client’s risk. This paper outlines the development and operation of a robust real-time installation monitoring system which controls and validates the installation of driven cast in-situ (DCIS) piling. Using state of the art information technology the system allows the design engineer to interrogate the data acquired from the piling rig via his computer as the piles are completed. The use of the validation process, where data acquired during the driving of DCIS piles can be processed to estimate the finished pile performance, will be explained with reference to a new case study on large diameter DCIS piles. Examples of the routine use of the system will be presented to illustrate how automated monitoring of installation parameters can be used to raise the standard of reliability, efficiency and sustainability on piling projects. The conclusions to the paper will cover the key features and operational challenges characterising real-time monitoring of the execution of geotechnical works as developed from a number of years of experience of using a rig based data acquisition instrumentation system.INTRODUCTIONDriven Cast In-Situ (DCIS) piles have a long and successful history of use worldwide. The process, where a temporary steel drive tube, sealed at the bottom with a sacrificial base plate, is driven into the ground and filled with concrete before the tube is withdrawn, is well known (BS EN 12699, 2001 and Egan, 2013). Examples of large structures supported on DCIS piles installed by Keller UK include the Millennium Dome (now the O2 Arena) and the 2012 Olympic stadium in London.In recent times advances in piling rig instrumentation and telecommunications have enabled a new level of sophistication in the recording of installation parameters and the validation of pile performance. It is now possible to embed these features into the DCIS design and installation process which has improved the quality and efficiency of DCIS piling.This paper summarises the development and operation of a real time data acquisition and processing system for DCIS piling, but which is equally applicable to other forms of driven piling (for example concrete precast piling)."

Jan 1, 2014

By R. J. Hundermark, L. R. Nelson

The critical importance of tap-hole design and management to furnace performance and longevity is explored through examining some of the specific matte, metal and slag tapping requirements of non-ferrous copper blister and matte converting and smelting, ferroalloys smelting and ironmaking systems. Process conditions and productivity requirements and their influence on tapping are reviewed for these different pyrometallurgical systems. Some critical aspects of the evolution of tap-hole design to meet the diverging process and tapping duties are examined. Differences and similarities in tapping practices and tap-hole management are reviewed. Finally core aspects of tap-hole equipment and maintenance are identified that are considered important to securing improved tap-hole performance and life, so pivotal to superior furnace smelting performance.

Jan 1, 2014

By Partha Patra

Numerous proteins of varying properties are available in extracellular bacterial proteins (EBP) isolated from Paenibacillus polymyxa. EBP was fractionated through ammonium sulfate precipitation in a controlled fashion and characterized through SDS-PAGE technique. Different groups of proteins, (Group A~D) exhibited varying degrees of surface affinity to minerals such as quartz, pyrite, chalcopyrite, galena and sphalerite. Interaction with mineral specific bioproteins rendered pyrite and chalcopyrite hydrophilic while surface of quartz, galena and sphalerite turned more hydro-phobic. Specific groups of proteins could thus be used for selective separation of galena, sphalerite and quartz from pyrite and chalcopyrite (as a mixed sulfide) through microbially-induced flotation or selective flocculation.

Jan 1, 2014

By Jacqueline Satur, Yoshiaki Kon, Buenaventurada Calabia, Xiao Sheng Yang, Arvo Naumanen, Kenzo Sanematsu, Sayaka Morita, Tetsuichi Takagi

Granite ores are composed of silicate minerals and a variety of valuable REE (rare earth elements)-bearing minerals, however the processing technique to recover these valuable minerals is not yet developed. In this study, the recovery of REE-bearing minerals by dry magnetic separation and wet high intensity magnetic separation (WHIMS)-settling from surface sample and from drill core sample, respectively, of a granitic REE-Zr-Nb ore deposit was investigated. The two samples have different mineralogy however in both samples, light REE are commonly contained in REE carbonate minerals while Y and heavy REE are commonly contained in zirconium silicate minerals and pyrochlore. The liberation size of the REE-bearing minerals in the two samples ranges from 10-250 ?m. Previous flotation testwork conducted on the drill core sample reported high recoveries of La2O3 (88%) and Ce2O3 (88%) but low recoveries of Y2O3 (42%), ZrO2 (17%), and Nb2O5 (29%). The objective of this study was to obtain higher recoveries of Y2O3, ZrO2, and Nb2O5 by dry magnetic separation and WHIMS-settling. Both processes implemented the application of a low magnetic intensity to initially separate the ferromagnetic minerals then a high magnetic intensity to recover the REE-bearing minerals. The results showed higher recoveries of Y2O3, ZrO2, and Nb2O5 by dry magnetic separation and WHIMS-settling indicating the potential of magnetic separation and gravity separation in recovering the heavy REE-bearing minerals. WHIMS-settling is more recommendable than dry magnetic separation because of its applicability in treating a wider range of particle size. In the WHIMS-settling, the light REE, Y, and Zr minerals were recovered mainly by applying four stages at high magnetic intensity of 21,500 gauss while the weakly magnetic pyrochlore was recovered mainly by decantation of the nonmagnetic slurry after a short settling time of 0.25 to 0.50 h. (MAX.300 words)

Jan 1, 2014

By V. A. Luganov

The processing of pyrite concentrates may be accomplished with a preliminary enrichment due to withdrawal of iron sulfides from initial concentrate. The withdrawal of iron sulfides is possible with the help of magnetic separation when the magnetic iron sulfides (pyrrhotites) separate from non-magnetic fraction?the sulfides of non-ferrous metals. The conversion of non-magnetic pyrite to magnetic pyrrhotites of adjusted structure occurs because of roasting with the withdrawal a part of sulfur. The resultant pyrrhotites are strong ferromagnetic with hexagonal structure. This paper contains results of studying magnetic properties of pyrrhotites, findings of the de-composition of initial pyrite with the consequence homogenizing of product and hardening of product of decomposition in liquid nitrogen. Define the type of pyrrhotites super lattice structure, was established that at increasing of sulfur contention the magnetic properties of pyrrhotites are change ? pyrrhotite begin evince the properties of antiferromagnetic material and magnetic susceptibility of material is interruptive changing from 0 to 1.7×10-3~1.9×10-3 SI units/g system. The paper contains results of technological researching of pyrrhotizing-magnetizing roasting of pyrite concentrates in different condition: in unoxidizing, with the decreasing contention of oxygen and in autogenous regime in air atmosphere. Established that the magnetic susceptibility of products depend of pyrite degree dissociation and achieve 2×10-3~3×10-3 SI units/g system at 40%~45% desulphurization. Defined the conditions of steady regime autogenous roasting, at resultant products possess coefficient of magnetization, and this can be used magnetic separation for separating ferromagnetic pyrrhotites from gangues and non-magnetic sulfides of non-ferrous metals. This technology of pyrrhotizing roasting is recommended for effecting in industrial condition. The initial materials and products of roasting subjected to chemical, thermogravimetric, Moss-bauer spectroscopy and X-ray analysis, defined the magnetic properties.

Jan 1, 2014

By O. Kökkilic

This study covers the tests to develop separation process for production of clay and colemanite rich concentrates, and aims to serve the clay and colemanite concentrates extracted from the tailing dams to the industrial applications. For this purpose, samples from the tailing dams in Kestelek Boron Plant (Turkey) with an average B2O3 content of 8%~11 % were subjected to the investigations. The separation process of hydrocyclone--to make clear the way to obtain either clean clay or cole-manite--was initially discussed. Therefore, following the gentle scrubbing (to keep the bimodal size distribution between clay and colemanite) of the tailings to disperse the slurry, two alternative multistage hydrocyclone processes; allowing to recycling the overflows or underflows to concentrate clay and colemanite were respectively tested. As a result of the preliminary tests, the multistage hydrocyclone separation in direction to the clean colemanite concentrates (recycling the underflows) gave the better separation efficiencies. So, all the parameters such as apex and vortex finder diameters and feeding pressures were examined with the multistage hydrocyclone process allowing the recycling the underflows. The detailed multistage hydrocyclone separation process of the tailing dam wastes yielded with colemanite concentrates (approx. 12 % of the feed, w/w) with B2O3 content of 35.0 % and the clay concentrates (approx. 42 % of the feed, w/w) with B2O3 content of 2.1 %. Colemanite concentrates were found good enough either to re-feed in to the separation process or to keep upgrading for final product ready to use in Industry whereas the attempts on production of light bricks from clay concentrates has failed. But it is worth to point out that these clay concentrates can be used for agricultural purposes just in the form as it is.

Jan 1, 2014

By R. Pelton, Z. Dai, S. Yang

ABSTRACT Hydrophobic polystyrene nanoparticles were evaluated as potential flotation collectors for pentlandite. The flotation of hydrophilic glass beads demonstrated the nanoparticles’ ability to induce flotation. Deposition of nanoparticles on glass surfaces increased the contact angle and enhanced adhesion of the beads to air bubbles. High flotation recoveries were achieved when 5–10% of the bead surfaces were covered with nanoparticles. Surface functionalization—the addition of vinylimidazole to polystyrene nanoparticle surfaces—caused the nanoparticles to selectively deposit onto pentlandite surfaces in the presence of Mg-Si slimes. Ongoing work includes attempts to identify specific applications where nanoparticle collectors might be cost effective. _ KEYWORDS Flotation, Nanoparticle collector, Coverage

Jan 1, 2014

By Carlos M. Fontes Vieira, Ruben J. Sanchez Rodriguez, Carlos E. Gomes Ribeiro

"The worldwide demand for ornamental stones in building construction is motivating the use of their wastes, generated during fabrication, to produce compound stones. This work has as its objective to investigate the production of an ornamental compound marble (OCM) under vacuum and compression processing of a polyester matrix composite with addition of marble waste as load and as filler. Square OCM composite plates were subjected to compression and flexural mechanical tests. Samples were analyzed to obtain the density and water absorption. The OCM composites presented properties within the expected range of an artificial stone.IntroductionMarble is a limestone, composed mainly of calcite, more or less crystallized by metamorphism that ranges from granular to compact in texture. It has a density 2.7 g/cm3 and its porosity is approximately 0.4%. The UNI 8458 standard defined marble as: ""every crystalline rock constituted mainly by minerals with a Mohs hardness equal to 3-4"". In marble production around70 - 75% of whole extract material is lost in byproducts generation [1,2].In function of large volume of residues generated, the ornamental stones industry has attracted ever more the attention of environmentalists [3].Actually the marble can be pulverized to obtain calcium carbonate for industrial applications. It is also possible to obtain a thinner powder to produce concretes [l]. Some authors study the use of stone residues in concrete mortars and ceramic bricks, getting better properties to these materials [3,4].The marble residues can be also used in engineered stones, or ''agglomerated"" stones, production. The most common engineered stones in the market consist, like a polymer concretes, in polymer matrix composites incorporating petreous components. In the formulation of the engineered stones, the particulate or granular petreous components are the result of fragmentation or trituration processes to which natural stones were submitted to [ 5]."

Jan 1, 2014

By Michael Murphy

A multi-stage triaxial procedure has been developed for the enhanced servo controls and feedback systems at the National Institute for Occupational Safety and Health (NIOSH) rock mechanics laboratory. Due to the difficulty of preparing multiple rock specimens for single-stage triaxial tests at different confinements, multi-stage testing provides a huge advantage if only a few samples of coal measure rocks can be prepared from the drill core. A multi-stage test can provide mechanical properties, post-failure properties, and a complete failure envelope for a single specimen. For the multi-stage test procedure, a parameter used to define the slope of the stress-radial strain curve was developed and monitored in real time in order to successfully predict peak strengths at different confining stages. For this paper, multi-stage tests have been conducted on sandstones of varying strengths, including Berea sandstone which has well-documented properties, and fine-grained and coarse sandstone from a western US coal mine. For the tests conducted on the fine-grained sandstone, it was found that the ramp rate was an important factor in the success of obtaining peak strengths during the multi-stage tests. For each rock type, a table including Young?s modulus, Poisson?s ratio, unconfined compressive strength, friction angle, cohesion, residual friction angle, and residual cohesion are reported. The values from these tables have been used as input parameters for projects at NIOSH requiring numerical model input parameters.

Jan 1, 2014

By Gulsen Tozsin, Ekrem Kalkan, Taskin Oztas, Elif Agirman Akturk, Ercument Koc, Ali Ihsan Arol

Marble wastes are generated by quarries (marble quarry waste-MQW) and processing plants (marble cutting waste-MCW). The large amount of marble wastes is becoming serious problem for industry and environment because of discarded into rivers and lagoons, without any treatment. Marble wastes can cause environmental problem and economic loss if the waste is not used. However, this type of wastes has a good potential to be used as an amendment for the neutralization of acid soils. In this study, MQW and MCW were applied to an acid soil at different rates and their effectiveness on neutralization was evaluated by a laboratory incubation test. The results showed that soil pH increased from 4.71 to 6.36 and 6.84 by applications of MCW and MQW, respectively. It was suggested that MQW and MCW could be used as soil amendments for the neutralization of acid soils, and thus the negative impact of marble wastes on the environment could be reduced.

Jan 1, 2014

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By M. Bryson, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho

Mkango Resources Limited is developing the Songwe Hill Rare Earth Element Project in southeast Malawi. Since being awarded the exclusive exploration licence for the project in January 2010, Mkango has completed an extensive work programme including detailed mineralogical studies, geological mapping, geochemical sampling and trenching, environmental and social studies, two phases of diamond drilling, and extensive metallurgical test work. In October 2012, the company announced a NI 43-101 compliant mineral resource estimate comprising an Indicated resource of 13.2 million tonnes grading 1.62% total rare earth oxides (TREO) and an Inferred resource of 18.6 million tonnes grading 1.38% TREO. The Indicated mineral resource estimate formed the basis for commencement of the Preliminary Feasibility Study (PFS). The mineralogical program identified the fluorocarbonate mineral, synchysite, and the phosphate mineral, apatite, as the primary rare earth element (REE) bearing minerals. Extensive flotation testwork conducted at Mintek in South Africa has resulted in an effective regime to increase the REO grade 2.6 times. Initial leaching testwork by Mintek identified that a selective hydrochloric acid (HCl) leach can target the gangue minerals with minimal REE dissolution. Recent testwork undertaken at Nagrom in Western Australia has expanded on this work to develop a two stage HCl leach process incorporating HCl recycling. A downstream processing route of purification and cerium rejection to produce a cerium depleted high grade REE concentrate suitable as feed to a separation facility is proposed.

Jan 1, 2014