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By R. Singh, C. Gong, J. Chaudhry

"Metalorganic chemical vapor deposition (MOCVD) is an ideal technique for the deposition of conducting and non-conducting oxide based thin film materials. In this paper we have presented a study of photo assisted MOCVD for the low temperature deposition of a number of oxide based advanced materials. We have used incoherent light sources as the source of optical and thermal energy in our MOCVD system. The vacuum ultraviolet (VUV) and ultraviolet (UV) photons can enhance the surface reaction of the absorbed molecules through the perturbation of the electronic state of binding between the absorbed molecules and the solid surface. Unlike plasma process, no surface damage is expected and high quality materials have been deposited. At a given substrate temperature, the performance of deposited film depends on the lamp configuration.INTRODUCTIONMetalorganic chemical vapor deposition (MOCVD) has become the standard manufacturing technique for the deposition of large area thin films of compound semiconductors. l.(.w-cost, high crystalline quality, atomically clean and sharp interfaces, atomic layer epitaxy, high throughput rates and potential for direct writing are some attractive features of MOCVD. Due to a number of potential advantages mentioned above, MOCVD is considered as an ideal technique for the deposition of various electronic and optical materials for a wide variety of applications. Rapid isothermal processing based on incoherent radiation as the source of optical and thermal energy is emerging as the key low thermal budget (integral of processing time and temperature) processing technique for the fabrication of current and next generation of microelectronic and optoelectronic devices and circuits [1]. In this paper we have demonstrated that the design of the lamp assembly plays an important role in determining the properties of the materials deposited by RIP assisted MOCVD. We have studied the growth rates, structural properties and electrical properties of Y2O3/Si structure. At a given substrate temperature, best results are obtained for the lamp assembly that provides maximum number of VUV and UV photons."

Jan 1, 1994

By P. Tsang

The stability of longwall chain pillars depends not only on the mechanical properties of coal and surrounding rocks, but also geological and mining conditions. In order to evaluate the effects of each, variable, the orthogonal experiment design was employed in this study for significance analysis. The study concluded that the stability of longwall chain pillars is mainly controlled by the ratio of pillar stress to pillar strength, the ratio of Young's moduluds of the roof to coal and floor to coal, entry width, pillar width and the internal friction angle of coal. Additionally, horizontal stress, panel width and mining height also play a significant role.

Jan 1, 1994

By W. P. Diamond, A. C. Smith, J. A. Organiscak, T. P. Mucho

The U.S. Bureau of Mines conducted a worldwide literature review of bleederless ventilation practices to evaluate their use as a spontaneous combustion control measure in U.S. coal mines. Factors that must be taken into account in the design and use of these systems include seal construction, the use of ventilation control devices, the use of methane-drainage systems in gassy mines, and the ground control plan. Monitoring for the detection of spontaneous combustion and the control of methane when methane-drainage techniques are employed is critical to the successful use of a bleederless ventilation system. This report describes the types of ventilation systems used throughout the world and the spontaneous combustion risks associated with these systems. Methane-drainage systems used in conjunction with bleederless ventilation systems are discussed. Ground control considerations such as pillar design, entry stability, and seal usage are reviewed. Monitoring systems for spontaneous combustion detection, methane-drainage control, and behind seals are examined. Finally, methods for evaluating the spontaneous combustion hazard of a mining operation to determine when the use of a bleederless ventilation system is warranted are reviewed.

Jan 1, 1994

By Shatwell DO, Hayward SB, Leach TM

Following acquisition of the Woodlark Island tenement by Highlands Gold Limited, an exploration programme using extensive diamond drilling has confirmed that the style of gold mineralisation is similar to other SW Pacific Rim carbonate base metal gold systems. The two centres of gold mineralisation at Kulumadau and Boniavat-Busai are inferred to be related. to buried porphyry centres localised on NE trending major horst bounding structures. Individual prospects are localised on NW trending cross structures peripheral to the porphyry centres.Gold mineralisation has been derived from the mixing of hot saline magmatic fluids with cool dilute meteoric waters. While the bulk of mineralisation occurs in dilational tensional gash fractures, bonanza grades resulted from fluid quenching in feeder structures. Pre-mineralisation breccias created plumbing systems for hydrothermal fluids and similar paragenetic sequences are defined for Busai and the Kulumadau areas. These include early, distal porphyry, low sulphidation mineralisation, followed by base metal gold and carbonate deposition.

Jan 1, 1994

The Henderson Mine is a large underground panel cave molybdenum mine located near Empire, Colorado. Secondary blasting requirements have varied from one shot per 27 tonnes (30 tons) to one shot per 900 tonnes (1,000 tons) of ore. Geology, structure, cave abutment loads, and location of the ore in the column all affect the amount of oversize boulders (greater than three-fourths cubic meter or one cubic yard) that require secondary breakage. The primary method of breakage utilizes cone charges (plastic funnels filled with an emulsion) placed on accessible oversize rocks. Hangups in the brow area of the drawpoint are drilled with a self contained diesel hydraulic drill and loaded with gelatin dynamite. High hang-ups located beyond the reach of the secondary drill are "bombed" in with strategically placed emulsion bundles or ANFO bags loaded in place though a sectioned aluminum pipe.

Jan 1, 1994

By Dennis L. Paisley, Thomas P. Turner

Laser slapper detonators are the next generation detonator under development at the Detonations Systems Group at Los Alamos National Laboratory and function very similarly to an electrical slapper. A fiber optic transmits a laser pulse to ablate a thin metal film. This film, or flyer as it is commonly called, is launched through a short barrel to km/s speeds. The flyer shock loads or slaps a high density pressing of secondary explosive, setting off a detonation therein. Laser slapper detonators afford a number of safety advantages over other conventional detonators. Most important they require very high peak laser powers to operate, orders of magnitude larger than possible sources of natural or man-made accidental stimulus. Because light is transported over fiber optics, laser slappers avoid many of the electrical hazards associated with detonators. Use of insensitive, secondary explosives makes these detonators safer to handle, manufacture, transport, and deploy.

Jan 1, 1994

Laboratory tests were conducted in a full-scale continuous miner test gallery to evaluate resulting dust levels for changes in face airflow, spray water quantity and pressure, and mining height. The minimum and maximum values tested for each parameter were as follows: airflows between 1.42 and 6.14 m3/sec, water flows between 56.8 and 132.5 lpm, nozzles pressures between 413 and 1379 kPa, and mining heights between 1.52 and 2.74 m. Each of these parameters were evaluated for four common spray system designs. Respirable dust samples were collected in the operator's cab on the miner and in the immediate return. Second-order polynomial models were used to represent expected dust levels and multiple stepwise regression was used to identify significant control parameters for inclusion in the models. Separate models were developed for dust levels at the operator and return locations and for each individual spray system. Interaction between control parameters and curvature effects were found in most models. The analysis indicated that at the operator location, airflow and mining height had the most significant impact on respirable dust levels. In the return, airflow and water pressure were typically the most significant parameters. The models developed for each spray system design can be used by mine operators to guide application of control parameters for a variety of operating conditions and mining heights.

Jan 1, 1994

By K. A. Hildebrant, J. R. Norgate

"Synthetic lubricants have for many years documented extended service life and provided superior performance in temperature extremes. Increasing interest in synthetics' ability to reduce energy costs has resulted in laboratory and industry application evaluations. These tests have documented savings in functions such as worm gear drives, spur gears and in compressors. Energy savings data are presented as well as payback calculations as low as thirty days.The National Research Council of Canada has estimated that the Canadian economy loses over five billion dollars per year in friction and wear. Figures quoted were for 1986 during which it was estimated that nine hundred and forty million dollars were lost in the mining industry alone"" It has been further estimated that about 115 million dollars can be immediately recovered through improved tribology practices (Table I).The purpose of this paper is to present results and savings opportunities through the use of synthetic lubricants in various but common applications. Many other areas exist with the opportunity for energy savings such as in the use of more efficient drive equipment, reduced contact seals, spray mist lubrication systems and reduced friction coatings on rotating equipment such as pump impellers"

Jan 1, 1994

By A. Vien, A. J. Neale, B. C. Flintoff, R. P. Edwards

Froth flotation is one of the most widely used and effective processes for mineral beneficiation. First introduced in 1911, flotation technology has seen many developments over the past 80+ years. Innovations in reagent chemistry, equipment design, process analysis and process control have given design and plant engineers a powerful set of "tools" for process optimization. However, it does not follow that all flotation systems are optimized. As Klimpel observes: "The problem with the industrial flotation process is that it is relatively easy to get reasonable results, and relatively difficult to get excellent results" Klimpel (I 988). While reasonable was sufficient in the past, competitive forces will make excellent necessary in the future. Judging by the activities in many Canadian plants this transition is already underway. This paper examines the role of some of the optimization "tools" in effecting this change.

Jan 1, 1994

By M. E. Poad

In 1986, a cooperative effort by the Homestake Mining company, the U.S. Bureau of Mines and the University of Utah was initiated to determine shaft stability while recovering high grade ore in a nearby pillar. Premining finite element simulations indicated the shaft would remain in elastic ground. Six years have elapsed and, despite some initial concern during the first lifts, it appears that the bulk of the original reserve will be safely and profitably recovered. An integrated application of rock mechanics tools from laboratory testing through numerical modelling to mine measurements and observations contributed substantially to the operational success of the project.

Jan 1, 1994

By Szwedzicki T

Uniaxial testing was performed on model pillars to determine the effect of width to height ratio on pillar and surrounding rock mass stability. Samples were modelled in a shape similar to that of dumbbell weights, with the centre representing

Jan 1, 1994

By B. W. Cavender

Innovative mining and metallurgical operating techniques or processes can be identified and developed by systematically analyzing change as it occurs within the mine, plant, technology, or industry. Sources of change to be monitored for innovative opportunities include unexpected successes or failures, incongruities between perceived and actual events, process needs, changes in perceptions, and the development of new knowledge. Innovation can be effectively organized, practiced, and managed. The perception of change as an opportunity rather than a threat is mandatory, as is the systematic measurement of innovative performance. Innovation is enhanced by specifically-designed policies regarding organizational structure and staffing, daily management practices, and compensation and incentives.

Jan 1, 1994

By Marcello M. Veiga

Informal gold mining operations in the Amazon emit about 100 tonnes of mercury annually because of poor amalgamation practice. Lack of information and the complexity of mercury transformations hinder effective action to prevent such pollution and/or monitor its extent. In the past, mathematical equations have been formulated to deal with the correlation of natural variables and mercury in biota but often, the error range is too great to provide useful models. Projection of physico-chemical variations in an environment subjected to mercury emissions onto the extent of bioaccumulation is fraught with many uncertainties and unknowns such as internal correlations between variables and the site-specific nature of biota contamination. Often assumptions about closed systems are invalid when applied to natural environments. This work presents a heuristic approach to this problem in which amalgamation methods and natural variables are dealt with using an IF-THEN rule-based system that concludes about levels of emission and risk of bioaccumulation. The system is able to handle uncertain or vague data and yet still provide useful output. Belief in mercury oxidation or dangerous conditions are examined using Fuzzy Logic techniques and Inference Equations. These belief levels are derived from thermodynamic equilibrium data together with field observations of natural variables. This procedure can reduce the need for sophisticated analytical equipment and can provide information and diagnosis to non-technical people.

Jan 1, 1994

Intrusion related Cu/Au mineralisation is localised in Pacific Rim island arcs by arc parallel, termed accretionary structures; or arc normal, termed transfer structures. In Papua New Guinea, NE trending transfer structures, evident on Landsat imagery, represent deep crustal fractures which have facilitated dextral rotation of the mainland during oblique plate collision. Major structures localise intrusion centres, and by rotation, develop ore hosting dilational environ-ments in subsidiary structures. While transfer structures localise the Porgera, Wafi and Yandera porphyry centres, the Frieda Porphyry and associated Nena high sulphidation Cu/Au mineralisation are localised by accretionary structures. The Bulolo Graben, which hosts the Morobe Goldfield, developed during intra arc rifting aided by movement on transfer structures. Crustal thinning has initiated magmatism with which diatreme breccias and fracture controlled mineralisation are associated.

Jan 1, 1994

By Farouk T. Awadalla

The presence of humic species in spent Bayer liquor causes many processing problems in the production of aluminum hydroxide. Ozonation of spent Bayer liquor was found to be an effective process to destroy the colored humic species. The kinetics of the decolorization in spent Bayer liquor was found to be slower than in the alkaline humic acid solution containing no alumina. However, the reaction kinetics ware enhanced by heating the solution during ozonation above room temperature. Copper ions which are used as catalyst to enhance the ozonation reaction were found to be ineffective due to the presence of large quantities of aluminum hydroxide in the liquor. Ozonation was a more favorable process than membrane separation as it achieved about 92% separation of color and produced lower amounts of organic material. The treated spent Bayer liquor can be recycled to the upstream process without causing any difficulties and the purity of aluminum hydroxide product would also be improved. A comparison of preliminary cost data indicated that ozonation compares very favorably with membrane separation in this application. Key words: ozonation, Bayer liquor, aluminum hydroxide, humic species, copper ions, membrane separation, purity and economic.

Jan 1, 1994

By G. R. Palmer

The success of future electric vehicles will depend greatly upon the power supply choices made today. Research is presently being conducted by automotive engineers and electrochemists to determine what battery type may be the most promising. Not only are product production and application efficiencies being evaluated but also environmental concerns of reclamation and recycling. Rechargeable batteries using nickel-metal hydride electrodes are strong candidates for these electric vehicle applications. The U.S. Bureau of Mines is investigating hydrometallurgical technology that separates and recovers purified metallic components present in nickel-metal hydride battery scrap. Sulfuric, hydrochloric, and nitric acids are all capable of dissolving the battery electrode alloys given the proper operating conditions. Solvent extraction of the leach solutions using D2EHPA removes iron, and selective precipitation shows promise of recovering the other metals in the H2SO4 and HNO, systems.

Jan 1, 1994

By T DePetris, B B. Beamish

There has been a gradual increase in the volume of internationally traded thermal and coking coal, with emphasis on blending of coals rather than single coal usage. New Zealand can take advantage of this situation, especially with its low ash and sulphur content coals. However, there is a need to clarify the thermal and coking behaviour of these coals as they relate to other market players, to benefit both the consumer and supplier. The high volatile matter contents of New Zealand coking coals are due to their high vitrinite content, which causes them to demonstrate stronger coking properties over a wider rank range than Gondwana coals. These same high vitrinite levels appear to correspond with lower initial softening temperatures than for Gondwana coals of similar rank. Preliminary results using thermogravimetric analysis also suggest that New Zealand high volatile bituminous coals can be used to substitute for higher rank Gondwana coals in combustion processes.

Jan 1, 1994

By S. A. Richards

Business planning in the coal' industry revolves around the production and quality forecast. It is difficult to accurately estimate costs and revenues until the production forecast is made. At mines where production comes from multiple sections, quality is tied to each section's production. Blending becomes a part of the planning process. In order to respond to rapidly changing business climate, a reliable program is needed to accurately forecast the effects of changes in key parameters affecting the production. This paper discusses an efficient, intuitive, and economical approach to underground coal mine planning program which uses a PC-based relational database as the programming platform to forecast production and quality. The program was developed at a major coal company. The relational nature of the production planning data, the programming algorithm, and the underlying principles are discussed in this paper.

Jan 1, 1994

By M. T. Ityokumbul

The liquid phase mixing in Western Research Centre (WRC) pilot plant flotation column with diameter of 0.76 m has been characterized using a salt tracer. The process variables studied were gas and liquid flow rates. The response of the column to a tracer pulse input was monitored at three axial and two radial locations. For all the experimental conditions investigated in the present study, radial and axial concentration gradients were not observed. It is thus concluded that the 2 tph flotation column is behaving as a well mixed tank. This finding is consistent with the observed poor recoveries of coarse fractions in the column flotation circuit. Based on the findings of this report, it is recommended that several schemes of reducing the backmixing be implemented and evaluated for their effectiveness in improving the column recoveries.

Jan 1, 1994

By David R. Lentz

At True Hill in southwestern New Brunswick, low-grade porphyry-style Bi-8n-Mo greisen mineralization is associated with the cupola of an epizonal granite porphyry (granite) that also exhibits three episodes of brecciation. The first episode of brecciation is an in situ, 8 m to 10 m wide transitional zone of net-veined to coarse-grained "blocky" endogranitic mesobreccia that is chloritized and greisenized and hosts weak disseminated minerali.zation. In a zone closer to the host rockgranite contact, angular fine- to coarse-grained endogranitic mesobreccia with greisenized matrix is superimposed on the earlier transitional breccia. The latest episode is fault-controlled and consists of quartz- and chalcedony-hosted sub-angular to rounded fine-grained "pebble" mesobreccias that crosscut and brecciate the other breccia types, as well as the adjacent altered metasedimentary country rocks. The first two episodes of brecciation are magmatic-hydrothermal in origin related to hydrofracturing of the granite carapace and are accompanied by greisenization and mineralization, whereas the post-mineralization, silica-hosted, "pebble" mesobreccias related to hydromagmatic, low-temperature fluid circulation and/or boiling along faults near the contact. These magrnatichydrothermal and hydromagrnatic mesobreccias are similar to those associated with W-Mo-Bi porphyry-greisen mineralization at the Mount Pleasant deposit.

Jan 1, 1994