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By J. A. Domenico

A safe and precise mineral separation alternative to heavy liquids is being used for mineral sands exploration on large scale orebodies. The separation process, Magstream®, uses ferro-fluids and magnetic and centrifugal forces to produce precise split points over a range of specific gravities from 1.5 to 18.0 g/cc. This paper describes a commercial scale exploration program treating, roughly, 90 samples per day in Senegal (West Africa). Separation results comparing Magstream® and conventional heavy-liquid separation are presented.

Jan 1, 1994

By W. H. Jang

Recent research has demonstrated the utility of the FTIRIIRS adsorption density equation for in-situ study of surfactant adsorption phenomena at the surfaces of reactive internal reflection elements (IREs). The FTIR/IRS adsorption density equation is given by (formula) where r is the adsorption density, A/N is the absorbance per reflection, e is the integrated molar absorptivity, 4 is the bulk concentration of the surfactant, d. is the effective thickness, and dP is the depth of penetration. Previously, the validity of the adsorption density equation had been confirmed only from solution depletion measurements with high surface area powders. Now, FTIR/IRS studies of Langmuir-Blodgett (LB) monolayer films of fatty acid transferred to the surface of a calcium fluorite IRE .clearly validate the reliability of the FTIR/IRS adsorption density equation for quantitative analysis of surfactant adsorption. In addition, it was confirmed from the observed absorption band at 1550 cm-1 that the first monolayer of the transferred fatty acid chemisorbs at the surface of fluorite.

Jan 1, 1994

By Hao Rang

The article Is specially to Introduce the recovery process of Nb, Mn, P from slags and reutilization techniques of the remaining slags. Nb-Mn-Fe alloys which contain 14-16% Nb, 40-60% Mn can be obtained after using fire refining process of " Blast Furnace-Revolving Furnace-Electric Furnace -Electric Furnace, "meanwhile, phosphorous slags which the content of phosphorus pentoxide Is 29.21%. Further going through wet metallurgical processing and electrowinning technics to recover grading 99°o metallic manganese. Finally, phosphorous slags are grinded finely to be as phosporous fertilizers to be directly used for farmlands. Small particle size (0-8mm) rich slags are mixed with slight solid additions for balling directly, and taken Into blast furnace with blocky slags all together. The remaining tall slags are fully used as constructional materials, slags cement as well as a serial of wall materials, road materials, ground ornamental materials without burning operation and steam curing. The compressive strength range of those materials is up to 15-30 MPa. There is no more solid waste slags effluent In the full technical process.

Jan 1, 1994

By Louis J. Trostel

Refractories, called the Hidden Industry by The Refractories Institute, provide the temperature and chemically resistant linings for the multitude of vessels that are used today in high temperature processes ranging from giant iron-making blast furnaces to industrial incinerators to petrochemical cracking units to the smallest furnaces used by the jewelry trade. While these refractory linings are absolutely essential to the proper functioning of these processes, the linings are almost always on the inside of the vessels and thus hidden from the eyes of the public. Refractories are defined in Standard C71 of the American Society for Testing and Materials (ASTM), titled "Standard Definitions of Terms Relating to Refractories," as "nonmetallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above 1 000°F (538°C)." This criterion of ability to withstand exposure to environments above 538OC is the critical distinction separating refractories from other ceramics, fibers, and coatings applicable only at lower temperatures. In addition to resisting temperature, the refractories must with- stand abrasion, chemical and slag attack, resist thermal shock, and carry sustained structural stresses at high operating temperatures for as long as years. The most common methods of classifying refractories are by forming method and composition. First are the traditional formed and fired bricks, batts, and the associated multitude of special shapes. These refractories are usually formed at room temperature, dried, and then fired to high temperatures to develop the final properties desired. Other formed refractories are chemically bonded or resin or tar bonded. To complete the formed refractory matrix, some fired refractory bricks and shapes are subsequently impregnated with resins or tars. Physical dimensions of these formed refractories are classified into two general categories: standard sizes and special shapes. The standard sizes are those in common usage in the United States described in ASTM Standard C909 "Dimensions of a Modular Series of Refractory Brick and Shapes" based on the 38 mm basic module as described in ASTM Standard C861 "Determining Metric Dimensions of Standard Series Refractory Brick and Shapes." The most common size is the "9-inch straight" 228 x 114 x 64 mm (9 x 4 ½ x 2 ½ in.) of the "2 ½ -inch" series or 228 x 114 x 76 mm (9 x 4 ½ x 3 in.) of the "3-inch" series. Bricks of nonstandard sizes are referred to as special shapes. Their use is required in specific furnaces for particular requirements or applications. In addition there is the large and growing group of refractories sold as unshaped mixtures that may be formed into their final shapes at the application site. These unshaped mixtures are sometimes referred to as specialties. The mixtures are prepared to be hydraulically cast, plastic or wet rammed, dry rammed, or dry vibrated into their final shapes. Some are designed to be projected through nozzles (or gunned) onto their forms. The refractory mortars used to lay up the shaped refractories fall into this group referred to as specialties. Prepared refractory grains also are sold. These are usually calcined or fused materials that are subsequently crushed and sized to a variety of specific carefully controlled grain sizes or size distributions. These grains include calcined fire clay, dead burned magnesite, periclase (fused magnesia), dead burned dolomite, kyanite, tabular and fused aluminas, fused zirconia, fused mullite, and calcined alumina-magnesia spinel. The primary composition groups of refractories are the 1) alumino-silicate refractories made largely from fire clay and high- alumina materials, 2) silica refractories made from quartzites and ganisters, and 3) basic refractories from magnesia (or magnesite) and chromia (also referred to as chrome ore), alone and in combination, and dolomite. Special refractories include carbon, zirconia, zircon, high purity alumina, mullite, silicon carbide, silicon nitride, and some borides. In addition there are groups of special insulating refractories.

Jan 1, 1994

By E. M. Williams

The U.S. Bureau of Mines is investigating the use of in-seam seismic methods to monitor stress-induced changes in coal near the working face of longwall mines. Seismic surveys performed through a longwall panel and pillars near the face can provide valuable information on geologic anomalies, high stress regions, tailgate support performance and other conditions that could endanger miners or interrupt production. This paper describes the details of the equipment and data analysis techniques used, and the significant results obtained and their implications for ground control. Using seismic tomography, it is possible to conduct measurements on the pillar and reconstruct an image representing the internal velocity distribution. Successive measurements over several days identify changes in velocity attributable to changes in stress. Several field measurements were conducted at a western U.S. longwall mine to observe stress induced changes within the panel and pillars during mining. A permissible data acquisition system was designed to meet mine safety requirements for operation in gassy air. Certification from the Mine Safety and Health Administration (MSHA) was obtained, and this approved system was used to monitor stress changes in several pillars as the longwall face passed during first panel mining. Tomographic surveys were completed across the longwall panel to map the apparent abutment stresses ahead of mining. Velocity distributions show an increase in vertical stress across the panel from the headgate to the tailgate. Additionally. a yield zone along the face near the tailgate and the forward abutment approximately 100 feet outby the face in the tailgate side of the panel were detected. These results agree well with data obtained from other instrumentation emplaced in the panel near the tailgate. Using velocities for both compressional and shear waves, the Poisson's ratio was calculated for the panel.

Jan 1, 1994

By Claude Cunningham

Ths oonoept of precise. eooursts timing with Elsotronic Delay Detonators (EDD’s) was first ssriously sddresssd in ths mid 80’s end much wss made of the cheapness end profusion of digital wstohes in terms of the likelihood of EDD’s also being cheap and essyto produce. Ten years Iater. with every major explosives group end many elsotronios groups having instituted projects to capitalize on the promise of these devices, production devices are still to come into asneral use.

Jan 1, 1994

By P. Rusin

A new bacterium, Thiobacillus cuprinus, can extract copper from chalcopyrite as rapidly as T. ferrooxidans. On solution with and without nutrient amendments and bacterial growth media were supplemented with T. ferrooxidans or T. cuprinus in shake flask studies. Both species extracted -42% of the copper using growth media. In one case, T. cuprinus solubilized approximately twice as much copper as T. ferrooxidans utilizing a seeded On solution. Thiobacillus prosperus also oxidizes chalcopyrite and tolerates high chloride concentrations. These sulfide-oxidizing bacteria are representatives of the mixed microbial community found in sulfide dumps. Rates of biological copper extraction from sulfide ores, using the native microbes, have been significantly enhanced by amending On solution with PGM.

Jan 1, 1994

By C. L. Karr

The efficient management of the distribution of goods and services is important throughout the minerals industry. From the scheduling of processing plant operations, to the routing of work crews in mines, to the planning of product development, vast amounts of time, energy, and money are wasted due to poor planning and scheduling. Thus, the U.S. Bureau of Mines is investigating computational algorithms that can be used to minimize the economic losses related to scheduling and allocating resources. Although there is commercial software available for tackling many scheduling problems, there has been little relief provided for solving the difficult traveling salesman with time windows problem (TSTW). The TSTW problem is a "derivative" of the classic traveling salesman problem, and can be used to minimize the distance traveled by vehicles or personnel to visit all points on a tour, with the additional constraint that each point on the tour must be visited within a specified time window. This paper is a survey of published work in which genetic algorithms have been used to efficiently solve the traveling salesman problem and its more difficult derivative, the TSTW problem. A genetic algorithm is a search algorithm based on the mechanics of natural genetics, and has been used to solve a broad spectrum of engineering optimization problems. Results indicate that the versatility, searching power, and simplicity of genetic algorithms can be used to provide substantial improvement in the area of scheduling and resource allocation.

Jan 1, 1994

By Y. Xi, T. M. Yegulalp

An availability approach for determining the capacity of a major Bucket Wheel Excavator (BWE) system to be used in the Yuabaoshan Surface Coal Mine in China is presented in this paper. Based on previous studies on other BWE systems for delay times due to internal and external causes and a four-level maintenance and repair schedule, a model was developed, taking into account all random failures, to present a fast and simple solution to this highly complex problem. A procedure employing the Markov renewal theory for determination of the distribution of random failure times and failure rate of the whole system, as well as some other factors useful for calculation of the overall system capacity, are discussed.

Jan 1, 1994

By M. P. Hoffman

The U.S. Bureau of Mines is developing a roof bolter with a computer-controlled drill head that will increase the safety of roof bolting in underground coal mines by allowing miners to be relocated to a safe area. To ensure secure anchorage, acceleration and strain data are broadcast from an instrumented drill steel to a data acquisition system. These data are analyzed, correlated, and transformed to pro-vide information about roof strata, then are sent to a supervisory computer executing National Institute of Standards and Technology's real-time control software. The supervisory computer sends setpoint commands to proportional-integral-derivative control loops to control drill thrust, position, revolutions per minute, and torque.

Jan 1, 1994

By S. J. Ristorcelli

Historically, geologic data has not been adequately considered in resource estimation. More recently, with the use of computers and sophisticated estimation algorithms and geostatistical justifications, geology has been downplayed further. Many reasons are given for not using geology including cost, time and irrelevance. None are valid. Boundaries defining mineral domains should be used in computer-generated resource estimates. Selected case histories show how the failure to honor geology has caused discrepancies in resource estimates of actual in-place resources. After-the-fact differences have included decreases in tonnage of up to 50% and increases up to 300%; partial to complete recategorization of material; and 50% decreases in grade. The costs of gathering and using geology are trivial compared to the potential consequences.

Jan 1, 1994

By N. A. Barcza

DC plasma-arc technology using a hollow graphite electrode (cathode) has been successfully implemented in the primary metallurgical industry in South Africa up to the 30 MW scale. Mintek has applied its expertise base, established over the past fifteen years, to testing the treatment of metallurgical wastes such as carbon- and stainless-steel plant dusts, lead- and zinc-containing slags, and residues from the base-metal industry. Favourable results have been achieved, and disposable products were produced. The evaluation of numerous wastes indicates that recovery of zinc as metal gives the best economic return from these sources. Direct recovery via a splash condenser or electrolytic zinc extraction from fume are the two preferred alternatives under review. In both instances dehalogenation is an important issue, but can be achieved by suitable treatment processes. The Enviroplas technology provides a flexible, commercially viable approach to the treatment of a wide variety of wastes. Mintek, together with its associate Pyromet CC, are installing a plasma- arc pilot-plant facility with both an ISP lead-splash condenser of about 5 t/d condensed zinc capacity and a combustion chamber to burn zinc vapour to zinc oxide. This will demonstrate the suitability of the Enviroplas technology for treating specific metallurgical wastes, so that customized industrial plants can be engineered based on large-scale testwork.

Jan 1, 1994

This report on the Venezuelan coal industry is the seventh in a series of studies on coal exporting countries requested by the House Appropriations Committee, The committee asked that the basic differences in mining costs for U.S, and foreign mines be identified, especially those costs incurred in complying with health, safety, and environmental regulations.1 Basic costs in extracting raw coal are analyzed in this report for surface operations, This report also provides a limited analysis of the relative market competitiveness of selected Venezuelan and U,S. steam coal mines in three electric utility markets: New England and the east coast of Florida in the United States, and western Europe. Although some Venezuelan coal has coking characteristics, all coal-producing regions of Venezuela sell coal in steam markets.

Jan 1, 1994

By I. Gaballah

The chalcopyrite ore's anodic and cathodic electrodissolution are studied using a Porous Pulsed Percolated Electrode (3PE) reactor. Stationary solid electrode experiments are also performed to explore the mechanism of electrochemical dissolution of chalcopyrite. Experiments with a low - grade natural ore have been carried out at 25 "C in solutions containing 1 M NaCl and 1 M HCl. Galvanostatic and potentiostatic conditions are employed. The influences of current and potential on selectivity of the chalcopyrite ore dissolution are assessed. Anodic oxidation of this ore leads to a preferential dissolution of iron bearing minerals, whereas cathodic reduction is more selective with respect to chalcopyrite. However, in both cases the electrochemical dissolution is incomplete and the current efficiency is low. Design of the actual reactor has to be modified to increase the bed conductivity and to allow continuous experimentations.

Jan 1, 1994

By Henry E. Hilliard

The production, use, and emission of vanadium in the United States has been traced for the year 1991. Consumption was 3,300 tons2, exports 1,285 tons, and imports 2,013 tons. About 98% of production was used in metallurgy; the remainder was consumed in chemicals, including catalysts. Total emissions to the environment in 1991 were estimated at about 3,100 tons, including emissions due to the combustion of coal and petroleum products. Emissions resulting from the production of ferrovanadium were 130 tons, and emissions from the production of steel about 6 tons. Dissipative losses, defined as losses that occurred during use or as a result of wear, were estimated to be no more than 3 tons. Disposal losses were estimated to be about 4,600 tons. Most of these losses were steel products that contained 0.1% or less vanadium and mayor may not have been recycled. When these products are recycled by the steel industry, vanadium ends up in the steelmaking slag and does not return to vanadium use cycle. Worldwide emissions due to anthropogenic and natural sources were briefly reviewed. It was concluded that industrial emissions were about three times greater than emissions from natural sources.

Jan 1, 1994

By H. Hahn, B. H. Kear, K. Kan, S. C. Danforth, G. Skandan, W. Chang

"A new chemical synthetic process for the production of non-agglomeratednano structured ceramic (n-ceramic) powders, starting from metalorganic precursors, is described. The process combines rapid thermal decomposition of a precursor/carrier gas stream in a hot tubular reactor with rapid condensation of the product particle species on a cold substrate. Critical to the success of this Chemical Vapor Condensation (CVC) process are (1) a low concentration of precursor compound in the carrier gas, (2) rapid expansion of the gas stream through an uniformly heated tubular reactor under a reduced inert gas pressure of 1-35 mbar, and (3) rapid quenching of the gas phase nucleated clusters or nanoparticles as they exit from the reactor tube. A wide variety of metal organic precursors is available commercially, all of which can be utilized in the CVC process to produce n-ceramic powders, including single phase, multiphase and multicomponent systems.The CVC process has been used to synthesize non-agglomerated n-SiCxNy and n-ZrOxCy powders, with controlled particle size in the range 2-20 nm. Heat treatment of the assynthesized n-powders in various high purity gas streams causes compositional and structural modifications, including particle purification and crystallization, as well as transformation to a whisker-like morphology. Thus, as-synthesized amorphous n-SiCxNy particles transform to (1) cubic n-SiC particles, when heated in flowing argon at temperatures> 1350 °C, (2) hexagonal n-Si3N4 whiskers, when heated in flowing NH3IH2 at 1400 °C, and (3) cubic nSiC whiskers, when heated in flowing H2 at 1400 °C.Non-agglomerated n-ceramic powders form uniformly dense powder compacts by cold pressing, which can be sintered to theoretical density at temperatures as low as 0.5 Tm' For example, full densification ofn-Zr02 powder compacts under free sintering conditions can be achieved at 1125 °C."

Jan 1, 1994

By Edward P. Hagarty

The Hazardous and Solid Waste Amendments (HSWA) of 1984 added Subtitle I to the Resource Conservation and Recovery Act (RCRA), authorizing the Environmental Protection Agency (EPA) to develop and implement a new regulatory program for Underground Storage Tanks (USTs) containing petroleum and other regulated substances. Technical standards required for release detection, prevention, and correction as necessary to protect human health and the environment were promulgated as described in 53 Federal Register 37082 (September 23, 1988). Virginia State Regulations (VR 680- 13-02) and U.S. Army Regulations require that a Corrective Action Plan and a Site Clearance Report be prepared to explain the details of remediation of any contaminated media. Construction of new buildings is proposed in two different areas at Fort Myer in Arlington, Virginia, where USTs containing gasoline, diesel and heating oil were located. Tightness testing performed on these USTs in September 1991 indicated that some of the tanks were leaking. Many of the tanks were removed for permanent closure. Initial Abatement (excavation of contaminated soil) was &ed out immediately. A detailed Site Characterization Study which included Hydropunch", field screening using immunoassay, and pilot test - dual phase (water and soil gas) extraction was conducted. Environmental media were analyzed for volatiles, semi-volatiles and metals. A detailed risk analysis (RA) was performed to determine risk-based clean up levels for benzene, toluene, ethylbenzene, xylenes (BTEX); polycyclic aromatic hydrocarbons (PAHs); and methyl-tertiary butyl ether (MTBE). The RA also discussed the presence of lead in the soil. Before constructing any buildings in these contaminated areas, remediation must be conducted in accordance with the State, Federal and other applicable regulations. The remedial alternatives evaluated included Vapor Enhanced Groundwater Extraction, Soil Vacuum Extraction, Soil Washing, Soil Steaming, Active and Passive Ventilation SolidificationlStabilization, Vapor Barrier Construction, and Excavation with Off-site Disposal. This paper discusses: (a) delineation of soil contamination @) risk analysis (c) evaluation of remedial alternatives and selection of the most appropriate technology and (d) consideration of various regulatory issues.

Jan 1, 1994

By S. J. Jung

The stability of underground openings for deep mines is critical, since incorrect orientation or geometry of shaft, stope, and accessways often results in the failure of openings due to high stress concentrations. Current state-of-the-art procedures for the design of underground openings are largely based on rules of thumb, experience, and trial and error. Rules of thumb are invariably based on the past experience of the designer and may not remain optimal as the depth and complexity of mine workings increase. Often, as conditions change, and as the interaction between geology, in-situ stress conditions, and mine openings grows more complex, the cost of maintaining structural integrity becomes prohibitive. Existing design procedures for deep mines are rapidly becoming inadequate as mines are worked at greater depths. For example, in the Coeur d' Alene Mining District, several million dollars are spent for inspection, repair, and maintenance on a regular schedule, largely as a result of inadequate design. In these types of situations, it is of critical importance that a new design methodology be developed for the layout and design of underground openings.

Jan 1, 1994

American Barrick Resources Corp. has come farther, faster in the last 11 years than any mining company in recent memory. Acquisition of Lac Minerals Ltd. in August 1994 now makes Barrick the largest gold producer in the world outside South Africa. In terms of market capitalization, the company is the world's most valued gold producer. American Barrick's 28.3-km2 (7000acre) Goldstrike property on Nevada's Carlin Trend, the primary engine for past growth, was purchased in 1987 for $62 million. Regarded as an attractive exploration target, Goldstrike instead propelled American Barrick to the front rank of world gold producers. In 1993, the company produced 50.75 t (1,631,988 oz), 44.78 t (1,439,929 oz) from Goldstrike. Reserves on the property totaled 905 t (29.1 million oz) at the end of 1993, the largest in North America.

Jan 1, 1994

By C. Cheung, U. Erb

"Over the past few years, nano-processing of magnetic materials has received considerable attention, because many magnetic and other application-specific properties have been shown to be enhanced in materials with ultrafine grain size. This paper reviews recent advances in the production of nano-processed soft magnetic materials such as pure nickel and cobalt as well as binary nickel-iron and ternary nickel-iron-chromium alloys by electrodeposition. Magnetic, electrical and mechanical properties of these materials are presented and discussed in terms of their microstructural defects.IntroductionIn recent years, nano-processing of materials to enhance their magnetic properties has received considerable attention [1-23]. Thin films, compositionally modulated thin films, granular films and bulk materials have been produced by many different techniques. These include gascondensation [1-6], ball-milling [7,8], chemical processing [9,10], metal-organo complex routes, solution reduction and co-precipitation [11], sol-gel methods [12], sputtering [12-14], rapid solidification [15], devitrification of amorphous alloys [16-19] and electrodeposition [12,20,21]. The potential application of nano-engineered materials with enhanced magnetic properties has been specifically discussed for soft magnets [18,19,22,23], hard permanent magnets [15] as well as for layered materials showing giant magnetoresistance effects [13,14] and nano-composites for magnetic refrigeration [11,12].The purpose of the present paper is to review recent advances in the development of nanocrystalline soft magnetic materials by electrodeposition methods. These materials could find applications in areas such as magnetic recording heads, high efficiency electric motors, transformer cores, etc."

Jan 1, 1994