Search Documents

By H S. Shin, H Jin, B H. Ryu, J Lee

Prospecting ice on the Moon necessitates drilling systems to obtain subsurface samples and measure the composition of ice deposits. Landers and rovers equipped with drilling equipment are essential for analysing ice and subsurface resources located at the Moon’s poles. These devices must be small, lightweight, low-power, highly efficient, and high-performance units to function properly in the extreme conditions of the lunar environment. Researchers have developed a prototype drilling apparatus capable of operating in atmospheric and cold environments. A newly developed drilling system in Korea, capable of performing not only sampling but also subsurface investigation, is introduced.

Sep 1, 2024

By S Raval

The estimation of greenhouse gas emissions from coalmines is increasingly becoming a priority for both operators and regulators. At the same time, involved scientific challenges in the methane measurements is generating significant interest from global research community. Various technology providers are also actively engaged in improving their sensors and platforms to address the measurement challenges and capitalise the market opportunities. This presentation highlights rapidly evolving multifaceted landscape of coalmine greenhouse gas emissions. It covers the advances in sensors for the detections, including ground-based, airborne, and satellite-based systems as well as models for the emission estimations, including attempts to reduce the involved uncertainties.

Sep 1, 2024

By I Mason, M van de Werken, B Zhou, J Hargreaves, W Stasinowsky

A critical step in open cut coal mining is clean removal of the overburden. This is usually achieved by drilling, blasting and digging. A key part of this process being successful is to stop drilling at the correct blast ‘stand-off distance’. The stand-off distance is the distance between the base of the drilled blasthole and the top of the coal horizon to be mined. Having this correct provides a protective cap of rock above the coal horizon so that the blast will fracture all the overburden without damaging the coal horizon or mixing it with the overburden. Drilling beyond the correct stand-off distance causes the blast to continue into the coal horizon, damaging it and mixing it with the overburden, leading to significant losses of coal product. Conversely, drilling short of the correct stand-off distance results in additional work to remove the intact overburden.

Sep 1, 2024

By C Staak, H Mischo, A Fichtner, F Reuter

In mining and remote areas of resource industry, there has been a development towards lacking emergency medical first aid response, that creates a potential disadvantage for patients after work accidents and other medical emergencies compared to standard population. This raises the question how a professional emergency medical coverage can be provided underground, taking into account lacking medical professionals in small resource companies combined with long rescue times. Aiming on the closure of this gap, a team of the mine rescue brigade from the Research and Training Mine Reiche Zeche (Forschungs-und Lehrbergwerk (FLB) Reiche Zeche) of the TUBAF Technische Universität Bergakademie Freiberg in Freiberg/Germany and its cooperating emergency departments of the Freiberg District Hospital and the Zeisigwaldkliniken Bethanien Chemnitz developed a totally new rescue concept using elements from tactical medicine and advanced emergency medicine combined with a specifically designed compact equipment and a highly standardised teaching curriculum. A fully new standardised and condensed tactical medical approach was developed including specifically adjusted equipment, and was taught in a didactically optimised way within 16 lessons in two days. Objective Structured Practical Examinations (OSPE) using manikins and simulated patients were conducted and compared to the identical exam of the reference group, which consisted of advanced paramedics. The standardised tactical medical scheme includes vital functions and body checks, advanced life support, nasal and intraosseous drug application, supraglottic airway management, artificial ventilation, thoracocentesis, bleeding control including tourniquet, fracture repositioning and splinting, transport bedding and thermal preservation. The developed Tactical Medical Mining Rescue (TMR) concept was subsequently included in the German guidelines for mine rescue services in 2022 and is already implemented in many companies in Germany and several international projects.

Sep 1, 2024

By S Gulati, N Sarkar, T Vink, S Battersby, L Okada

This paper examines a successful project implemented by BHP Mitsubishi Alliance (BMA) and the Polymathian team at Deswik, aimed at enhancing short-term scheduling processes to reduce vessel turn times in the BMA Central Queensland coal value chain. The project’s objective was to digitalise the planning process to enable planners to make data-driven insights to improve the profitability of the value chain. The strategy involved developing a digital mining system that incorporates data storage, cloud computing, and the ability to meet the integration needs of both internal and external business systems. This was complemented by a sophisticated, optimisation-based, decision-support tool to enhance the planning teams’ ability to make timely and effective decisions.

Sep 1, 2024

By K Sherry, N Shahbazi

Scope 3 emissions are a set of often overlooked indirect greenhouse gas emissions within a company’s value chain and represent the majority of emissions for many sectors. These emissions arise from activities conducted by entities beyond the reporting organisation’s ownership or direct control and are often challenging to calculate. Scope 3 emissions typically encompass purchasing goods and services, transportation and distribution, managing operational waste, downstream processing and utilising sold products. Within the mining sector, scope 3 emissions often constitute a significant portion of the overall carbon footprint. Therefore, these emissions are a significant aspect of the future of sustainable mining. As the journey towards a world committed to achieving Net Zero Emissions has started, the time to spark a transformative conversation in the mining industry has arrived. Consequently, a better knowledge of scope 3 footprints allows organisations to assess their emission mitigation projects against the total carbon impact of their operations and products.

Sep 1, 2024

By E. Matinde

Human beings have been dependent on metals and alloys for livelihoods since time immemorial. In fact, there is irrefutable evidence that successful ancient civilizations achieved supremacy over their environments through the mastery of metals and alloys (Miller, 1995; Mtetwa, 2022). Over time, metals and alloys have evolved to become ubiquitous engineering materials indispensable to mankind, with applications in industrial and residential infrastructure, agriculture, energy generation and storage, transportation and communication systems, and manufacturing, among others (Elshkaki et al., 2018; Watari et al., 2021). Population growth, technological developments, and increase in urbanization and industrialization are all intricately linked to the intensity of use of metals and alloys. With up to 5 billion people estimated to live in urban areas by 2030 (Armstrong, 2009), the demand for metals and alloys will inevitably increase in order to satisfy the increased demand for infrastructure, machinery, and other human needs (Elshkaki et al., 2018; Watari et al., 2021). According to LePan (2022), urbanization and growth of mega-cities will increase the demand for metals and alloys, such as nickel, steel, aluminium, and copper by 116%, 50%, 57%, and 26%, respectively, between 2019 and 2035. Naturally, the production of metals and alloys from natural ores, secondary resources, and/or a combination of both, to meet this increased demand will invariably lead to the increase in generation of deleterious emissions in the form of wastes. In fact, mining and metallurgical wastes currently constitute the world’s largest anthropogenic streams by mass, often containing a high concentration of elements and compounds that can cause potential damage to natural ecosystems and humans (Hudson-Edwards et al., 2011; Lottermoser, 2011; Matinde et al., 2018; Seetharaman et al., 2022). Obviously, society’s heavy reliance on new mineral resources to drive the emerging energy transition entails that the legacy of these waste streams will continue unabated for the near-foreseeable future. The scarcity of high-grade mineral reserves, coupled with deliberate efforts to solve the anthropogenic circularity conundrum, therefore introduces a high level of urgency in the metal extraction industry to develop nascent and more eco-friendly processes and technologies. Integrating circular economy principles based on intentional configurations of circular industrial ecosystems in order to maintain the value of materials and resources in the economy for as long as possible is widely accepted as a practical approach to mitigating the negative externalities imposed by

Sep 1, 2024

By Mustafa Kumral, Mehmet Balci

Strategic mine planning focuses on cutoff grade selection, capacity planning and block sequencing. Despite significant knowledge accumulated, potential value can be added to mineral sourcing by addressing various aspects. A case study on a metallic deposit with a lognormal grade distribution examines if grade/metal distribution influences cutoff grade selection. Six data sets with different shape and scale factors, but the same ore tonnage and metal quantity, are analyzed. Results indicate deposits with lower shape and scale factors are more sensitive to metal price and discount rate changes. The study also investigates the effect of economies of scale (EoS) on project value, focusing on the ratio of variable cost to total cost (capacity factor). Two regression analyses are conducted for optimal capacity planning and cutoff grade selection. The first shows capacity planning is highly sensitive to the EoS of mining and mineral-processing costs, with grade variability and metal distribution being negligible. In the second analysis, grade variability and EoS of mineral processing costs are vital for cutoff grade selection.

Sep 1, 2024

By J Wen, P Hou, W Yu, M Hu, Z Jiang, C Bai

Vanadium titano-magnetite (VTM) is one of the important iron ore resources in the world. High viscosity and low fluidity are the basic characteristics of hot metal containing vanadium and titanium during the ironmaking process. Clarifying the influencing mechanism of the melt viscosity would be a significant issue for the high efficiency smelting of VTM. In this paper, a self-developed melt viscometer based on the principle of torsional vibration theory was employed to measure the viscosity of hot metal accurately. Simultaneously, the thermodynamic calculations and some modern detection methods were also used to investigate the precipitation behaviour of high-melting-point phases in hot metal containing vanadium and titanium. The measuring results show that the viscosity of molten iron gradually increases with the increase of titanium content when the mass fraction of titanium is between 0.09 wt per cent – 0.50 wt per cent. Meanwhile, the viscosity of the hot metal was affected significantly by the vanadium content. When the vanadium mass fraction was higher than 0.30 wt per cent, the viscosity of hot metal increased sharply, which will have a serious impact on the fluidity of the hot metal. Furthermore, it was revealed by thermodynamic calculations that an increase in titanium and vanadium content would result in the precipitation of high melting point phases such as TiC, TiN, VC, and VN in the molten iron, ultimately resulting in a decrease in its fluidity. Meanwhile, it was confirmed by Scanning Electron Microscope (SEM) observation that the precipitates in the hot metal were compounds consisting of V, Ti, C, and N elements, which agrees well with the thermodynamic analysis results.

Aug 21, 2024

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

By K Saito, M Hasegawa

In steelmaking processes, it is known that P2O5 in dephosphorisation slags often exists in solid solutions between Ca2SiO4 and Ca3P2O8, <C2S-C3P>SS, and thus the solid solutions play an important role in the dephosphorisation reaction. Hence, the knowledge of thermochemical properties, ie phase relations and activities of components, in slags containing <C2S-C3P>SS are necessary for the effective removal of phosphorus from hot metal. In this study, the P2O5 activities in <C2S-C3P>SS were measured through the gas equilibrium method. In the present experiment, oxide samples were equilibrated with Cu-P liquid alloys at 1573 K under a stream of Ar + H2 + H2O or Ar + H2 + CO2 gas mixture in which oxygen potential was fixed and then equilibrium phosphorus concentrations in the Cu-P alloys, [mass%P]Cu, were analysed with ICP-OES.

Aug 21, 2024

By M Ranjan, C R. Borra, P Palai, P P. Sahoo

Change in mould slag composition during casting of medium alloy steel is caused by the redox reaction between molten steel and mould flux. Mould flux generally contains a certain amount of SiO2, but elements such as Al, Mn and Ti in high/medium alloy steels reduce SiO2 in the mould flux, causing remarkable changes in the composition of the mould slag. As a result, the properties of the mould slag change greatly as continuous casting proceeds. This causes casting instability, process abnormality and casting defects. Effect of Ti as an alloying element in steel on mould slag is studied extensively through high temperature laboratory measurements and plant measurements. TiO2 gets picked up by the mould slag up to 3 per cent during casting a steel grade containing 0.1 per cent Ti. This changes the mould slag composition and results in decreasing the slag viscosity by up to 10 per cent and decreases slag break temperature by 30–40°C.

Aug 21, 2024

By R G. Reddy, A Yahya

The sulfur distribution ratio (Ls) is an expression of the amount of sulfur in slag to the amount of sulfur in molten metal. The sulfide capacities calculated from Reddy-Blander (RB) model were used to calculate the sulfur distribution ratio (Ls). A new Reddy model for sulfur distribution ratio (Ls) was developed for modelling Ls for ironmaking, steelmaking, and secondary steelmaking conditions. Besides calcium oxide, the major component in the ladle furnace (LF) slags is alumina. The Ls was calculated for typical LF slags as a function of temperature and composition. The model calculated Ls values are in good agreement with the experimental and industrial slags data. The extremely low oxygen potential in these furnaces after fully-killed steel is favourable for desulfurisation. For any given slag’s composition and temperature, its sulfide capacity can be calculated a priori. The equilibrium sulfur distribution ratio between this slag and liquid metal in a particular vessel can also be calculated a priori. The Ls for ladle furnace (LF) slags is about twice those for blast furnaces (BF) slags and ten times those of basic oxygen furnace (BOF) slags. The desulfurisation of pig iron in BF and desulfurisation of steel in LF during secondary steelmaking are recommended. Steel desulfurisation in steelmaking furnaces is not effective. Since the model used to calculate the sulfur distribution ratio (Ls) is a priori, it is a useful tool for the iron and steel makers in improving the product quality and optimisation of the industrial furnace operations.

Aug 21, 2024

By A Nigam, K Biswas, R Sarkar

Because of the problems with 1st and 2nd generations of Advanced High-Strength Steels (AHSS), a 3rd generation of AHSS steels has become prominent and these steels have properties in between the 1st and 2nd generations of AHSS. However, although the 3rd generation of AHSS is a promising candidate as a replacement for its predecessors, there remain some challenges in processing these steels which are essentially medium Mn (Mn content ~ 5–7 wt per cent) and high Al (Al content ~ 1– 3 wt per cent) steels. The use of conventional casting powders based on the CaO-SiO2 system is unsuitable for high and medium Mn/Al steels. This work investigates the development of CaO-Al2O3- based mold fluxes for casting third-generation AHSS steel. Mold fluxes, with otherwise similar compositions but different C/A ratios, are tested and their crystallisation behaviour is examined using differential scanning calorimetry (DSC). A calcium aluminate phase having a composition Ca12Al14O33 was found to be the main crystalline phase in the mold fluxes. A decrease in crystallisation temperature was observed as the CaO/Al2O3 ratio increased from 1.00 to 1.33. The effective crystallisation rate constant exhibited an increase with decreasing crystallisation temperature, indicating a potential influence of nucleation rate on the overall crystallisation rate and suggesting an anti-Arrhenius behaviour in the crystallisation process of these mold fluxes.

Aug 21, 2024

By Z Li, Z Yan, T Htet, S Zhang

During the pyrometallurgical processes, a substantial quantity of high-temperature ironmaking and steelmaking slags, generated at temperatures ranging from 1400 to 1600°C, is wasted, as the heat contained in these slags is released into the environment during the tapping process without effective utilisation. On the other hand, a significant amount of energy is required to reheat the cold materials for the manufacturing of glass and mineral-wool, often necessitating the addition of high-silica materials to facilitate the production process. In this study, an innovative approach is presented to harness the heat present in molten metallurgical slags to directly produce new raw materials for glass and mineral-wool manufacturing while simultaneously reducing energy consumption and mitigating CO2 emissions. The theoretical amount of waste glass that can be effectively added in the process has been estimated via thermodynamic calculation. Experimental assessments were conducted to examine the impact of high-silica waste materials on the dissolution, melting and fluidity. Potential recipes for glass and mineral-wool manufacturing were suggested and an assessment of the energy savings, and reduction in CO2 emissions with manufacturing of glass and mineral-wool using this innovative approach were included. It was determined that the processes could lead to a reduction of over 26 kg of CO2 emissions per 100 kg of new material used, primarily due to the utilisation of heat from slag and the accelerated smelting process.

Aug 21, 2024

By Y D. Jeon, K S. Kim, C-H Eom, C M. Yoon

The carbon neutrality continues to require reduction of carbon usage in ironmaking and steelmaking processes. Specially, it is expected that the hot metal ratio (HMR) in the steelmaking process should be reduced essentially. Unfortunately, the reduction of the HMR in converter can bring about poor environment for nitrogen removal from molten Fe. From this situation, nitrogen prediction model has been developed to understand the fundamental of behaviour of nitrogen and quantitatively interpret its content changes in the converter process. Thermodynamic and kinetic approaches were improved based on existing mathematical model and attempted to predict nitrogen content in realtime by combining process data. In present study, heat supply from the oxidation (mainly carbon and silicon) and CO evolution in the converter are considered, and scrap melting due to the heat transfer from the molten Fe to the solid scrap charged in the converter also be considered.

Aug 21, 2024

By D Stepanenko, G Stovpchenko, L Lisova, D Togobitskaya, L Medovar

Classical electroslag remelting of consumable electrodes is a drop-by-drop melt feeding through a slag layer into a renewing molten metal bath, slowly solidifying into a homogeneous, dense, defectfree ingot in a copper water-cooled mould. The new look at the additive nature of the electroslag remelting (ESR) process in a protective atmosphere allowed us to formulate the principles of a comprehensive thermodynamic-based model that can predict dynamic changes in slag and metal composition at certain ingot remelting. The model considers drastically different slag-to-metal mass ratios at the beginning and end of remelting and predicts gas, slag and metal composition in a chain of thermodynamic subsystems. Despite consisting of calcium fluoride and stable oxides, the ESR slag can oxidise main and active elements from steel and alloys (primarily aluminium, titanium and silicon) due to chemical reactions between slag and metal. ESR is not an electrochemical process in its nature. However, slags are ionic melts and deviation in their composition causes a change in their properties, affecting both operation mode and ingot quality. Another important understanding derived from the modern metallurgy technological route is that the ability to refine metal from impurities is not a priority for the ESR because consumable electrode has already passed all stages of refining and deep degassing at ladle treatment that changes ESR slags engineering principles. The critical importance became slag’s ability to generate process heat and keep the melting composition in the metal bath unchanged (except for non-metallic inclusions assimilation). Slag engineering for ESR required a compromise between chemical inertness to a metal composition and desired physical properties deriving from technological reasons. The Directed Chemical Bonds Concept (DCBC) in a multicomponent oxide system was used to build predictive models of electric conductivity and the melting temperature of fluoride-oxide slag based on their chemical composition. Both models help to design a customised composition of effective slags for steel and alloy groups or individual grades, and they are significant steps in the development of a comprehensive model of electroslag remelting.

Aug 21, 2024

By B A. Webler, P Su, P C. Pistorius

Advanced high-strength steels (AHSS) typically have much higher aluminium concentrations (by an order of magnitude or more) than conventional low-carbon aluminium-killed steels. The resulting lower oxygen activity at the steel-slag interface changes the kinetics and thermodynamics of steelslag reactions. Previous work showed that the rapid transformation of alumina inclusions to spinel inclusions, and spinel to periclase, occurs because of the relatively high concentration of dissolved magnesium. In this paper, experimental results on nitrogen removal by ladle slag are compared with predictions based on the available thermodynamic databases. As in previous work, the kinetics was modelled by assuming mass transfer control, with steel or slag mass transfer limiting. The results show that significant removal of nitrogen by steel-slag reaction is possible.

Aug 21, 2024

By H Kim, M J. Sun

Global steel companies are actively combating climate change by reducing carbon emissions. Traditional steel production, using the blast furnace (BF) – basic oxygen furnace (BOF) process, heavily depends on coal and emits substantial CO2. To mitigate this, companies are transitioning to the more eco-friendly DRP (direct reduction plant) – EAF (electric arc furnace) process, which lowers CO2 emissions. This study quantitatively evaluates the impact of increased hydrogen consumption on the carbon footprint of product (CFP) through an analysis of direct reduction process heat and mass balances. The study prioritises a comprehensive material balance based on mass conservation principles. The heat balance is calculated using differences in enthalpy through state energy properties, avoiding heat consumption. Validation using operational data from Hyundai Steel Dangjin works’ blast furnaces shows close alignment between calculated results and actual data, with less than 1 per cent error. This methodology facilitates a detailed analysis of the direct reduction process, offering insights into its feasibility and efficiency. Analysis of the operational impact by increasing the hydrogen ratio demonstrates reduced CO2 emissions and increased heat requirements due to the endothermic nature of hydrogen reduction, in contrast to the exothermic CO reduction. Possible solutions include raising reducing gas temperature or enhancing flow rate. The study effectively utilises designed heat and mass balances to assess material quantities and thermal balance under different operational conditions. It lays the foundation for the initial direct reduction process design, aiding in deriving and optimising operational parameters. Additionally, it provides valuable insights into the challenges of increased hydrogen, contributing to the production of greener steel by addressing these issues.

Aug 21, 2024

By A Vickerfält, J Huss, J Martinsson

The European Union has listed vanadium (V) as one of the critical raw materials for the transition to a future green society, as stated in the Critical Raw Material Act, written by Grohol and Veeh (2023). In the steelmaking industry based on V-containing iron ore, V is a possible by-product from the slag. A requirement for slags to be suitable for V extraction is a V content preferably above 8 wt per cent as V2O3 and a phosphorus (P) content below 0.1 wt per cent as P2O5. Hence, it is important to keep V in the slag phase while the P is moved to the metal phase during the steelmaking process.

Aug 21, 2024