Search Documents

By D. R. Nagaraj

Adsorption of sulfide collectors such as xanthate on pyrite has been studied extensively over several decades using a wide variety of techniques. In spite of this, there are unanswered questions as to the identity of adsorbed species on pyrite surfaces -dixanthogen vs. iron xanthate complexes. Far less is known in non-xanthate collector systems. We have used Secondary Ion Mass Spectroscopy (SIMS) successfully in the past to obtain direct evidence for the identity of the adsorbed collector species on copper sulfides, galena and Cu-activated quartz. The present study is an extension of the SIMS analysis to investigate the adsorption of xanthate, dithiovhosphate, dithiocarbamate, and modified thionocarbamates and thioureas on pyrite. Adsorption of these collectors on chalcocite was also studied for comparison. An attempt was also made to obtain SIMS spectra for pure dixanthogens at room temperature. Only in the case of dithiocarbamate (DTC) was there direct evidence for the presence of not only the collector dimer, but also iron-DTC complexes. On chalcocite, only the copper-DTC complexes were detected (no dimer). In the case of xanthate, the collector molecular ion and its S adduct -which are possible fragments from dixanthogen -were detected on pyrite, along with a fragment peak: suggesting Fe2X. For dithiophosphate, the collector molecular ion and Fe(DTP)(OH) complex were detected (no dimer). For modified thionocarbamate and thiourea, adsorption on pyrite was negligible.

Jan 1, 1997

By J. Drelich

The adsorption of oleate at the surface of titanium dioxide from aqueous solutions was examined by Fourier transform infrared (FT -IR.) spectroscopy using a germanium internal reflection element coated with a thin film of TiO2. This thin film, with a thickness of 100-200 A, was deposited on the surface of a germanium single crystal by RFIDC magnetron reactive sputtering. It was found that significant adsorption of oleate from a 0.02-0.03 mM aqueous solution on the surface of TiO2 thin film occurs at neutral pH, from about pH=5.5 to pH=7.7. Adsorption of oleate at the surface of the amorphous TiO2 thin film appeared to be reversible, involving soap-acid dimers.

Jan 1, 1997

By Andrew L. Peterson

CATOH Inc. of Weedsport, New York recently completed a very challenging Bored-In Pile project which features unique construction techniques in the installation and load testing of 45 and 100 ton capacity piles. The bored-in piles were installed on a twenty-nine million dollar New York State Department of Transportation project which began in the fall of 1995 and ended in March of 1997. The project included the construction of 5 new bridges to alleviate a very congested traffic network which had come to be known as the "Octopus" in the small city of Ithaca, New York. CATOH Inc. was awarded the piling contract by general contractor Santaro Industries in the fall of 1995. Piling installation work was completed in March of 1997. BACKGROUND The project is located at the southern tip of Cayuga Lake which lies in the heart of Upstate New York's Finger Lakes Region. This region is popular not only for wine making and vacationing, but also for its impressive geological history. The glacial activities that helped to form the deep valleys of this scenic area are also responsible for creating challenging underground conditions for deep foundations work. CATOH developed two pile designs to accommodate differing site conditions on the project. Internally reinforced piles were developed for use in the center of the valley and externally reinforced piles were developed for locations close to the valley wall.

Jan 1, 1997

By J V. Lawless

Mineralisation processes in epithermal deposits in the North Island of New Zealand are best illustrated by considering the two most productive deposits: Waihi and the Thames Bonanza Zone (TBZ), which have different mineralogies and ore shoots geometries. These two deposits can be taken as typical of certain styles of epithermal deposits worldwide, and recognition of their differences can be used to develop mineralisation models of predictive value. Waihi, the major economic producer in the Coromandel Volcanic Zone (CVZ), has laterally near-continuous ore shoots over a vertical interval of 600 m which consist of quartz, chalcedony, pyrite, base metal sulphides and electrum. They are found in the foot wall of earlier quartz veins which contain quartz pseudomorphs after platy calcite and adularia. The Thames Bonanza Zone which was the second biggest producer in the CVZ has discrete near-vertical ore shoots over 300 m vertically, which consist of quartz, pyrite, base metal sulphides, electrum and in their upper parts barite, that are enclosed in veins of quartz.   The gold mineralisation in both deposits is considered to be a co-precipitate with pyrite, with that at Waihi produced by prolonged boiling in an upflow of a hydrothermal system. That at the TBZ was produced by mixing a deep water primed for gold deposition by prior limited boiling, with an oxidised condensate of the steam released by the boiling, in an outflow proximal to the system's upflow.

Jan 1, 1997

"Le présent article porte sur la diminution des rejets de concentrateurs produits durant l’exploitation et le traitement des minerais métalliques.Le minerai dilué envoyé au traitement a, très souvent, un certain pourcentage du stérile qui affecte directement la rentabilité des opérations souterraines et amplifie l’impact négatif sur l’environnement. Les essais de la séparation du stérile et du minerai effectués en milieu dense sur quelques types de la minéralisation d’or, ont démontré les deux possibilités qu’offre cette technique:• Dans le cas d’un minerai riche, il a été possible de séparer la part importante du toutvenant (minerai dilué contenant le minerai et le stérile) provenant de la dilution, tout en ayant un taux de récupération élevé (supérieur à 96%).• Dans le cas d’un minerai ayant une teneur sub-économique à cause d’une dilution importante, il est possible de produire un concentré ayant une teneur économique à l’entrée de l’usine de traitement, en éliminant une partie du tout-venant.En plus la séparation du stérile peut accroître, en outre, la rentabilité de l’exploitation minière, car le fait d’éliminer la partie de stérile le plus tôt possible diminue certains coûts (transport, traitement et autres). On conclue que la pré-concentration du minerai (séparation du stérile et du minerai) est probablement une seule solution actuellement étudiée qui diminue l’impact environnemental de la mine, sans avoir des conséquences négatives sur la rentabilité de l’exploitation souterraine."

Jan 1, 1997

By William Petruk

"Heap leaching is a developing technology for recovering native gold and electrum from low grade deposits and from tailings. Recovery depends on permeability of the rock and ore minerals, size of particles in the heap, and ore textures that influence exposure of gold grains to cyanide solutions. These ore textures include gold-bearing veinlets and microveinlets along fractures and microfractures, gold grains in porous minerals and rocks, and gold graim. occurring along grain boundaries of other minerals. On the other hand, small encapsulated gold grains arc not likely tote exposed even with fine grinding. Most gold grains that occtir along grain boundaries of other minerals can be exposed with a moderate to fine grind, but the. resulting material will be too fine-grained to be permeable in a heap. Such finely ground ore, as well as tailings from flotation operations, can however be prepared for heap leaching by agglomerating the material into porous briquettes. Oxidized and weathered zones above. orebodies are frequently amenable to heap leaching because the gold-bearing pyrite and arsenopyrite have become permeable by conversion to porous iron oxides and ferric oxyhydroxides. A review of ore textures in several types of gold deposits suggests that:(1) the gold in vein deposits would gtmerally be amenable to heap leaching of both oxidized ores and fresh non-refractory ores,(2) the gold in Carlin-type deposits and in volcanogenic massive sulfide deposits is not likely to be amenable to heap leaching fresh ore, but oxidized zones above the orebodies are generally amenable to cyanidation, and(3) the gold in porphyry copper-gold deposits and in Witwatersrand-type deposits would likely be amenable to heap leaching of both fresh and oxidized ores but with high cyanide consumption."

Jan 1, 1997

By J. K. Szymanski

"RÉSUMÉPour maintenir de bonnes performances technique et économique dans l’exploitation par chambres vides (open stope) il est primordial d’assurer un contrôle efficace des limites réelles des chantiers d’abattage. C’est pour cette raison que, de plus en plus souvent, les opérateurs miniers utilisent un dispositif de laser (Cavity Monitoring System: CMS) qui permet de mesurer les dimensions réelles de chantiers en vue de calculer principalement la dilution et les pertes du minerai ainsi que d’autres paramètres. Malheureusement, il n’existe présentement aucune méthodologie commune, qui permettrait d’interpréter ces résultats selon les mêmes critères pour faciliter d’évaluations juste et précise de la réalisation par rapport à la planification en vue d’en apporter de corrections, dans les différentes opérations minières, si nécessaire. Dans la première partie du présent article on discute les principales séquences d’exploitation utilisées dans l’extraction par chambres vides. Par la suite, à l’aide des sections transversales et longitudinales on illustre toutes les phases des travaux miniers. Ceci en vue de permettre au lecteur de comprendre mieux c’est qui peut se passer effectivement dans les chantiers d’abattage. Par après on donne les définitions générales de principaux facteurs de performance technique. Finalement, l’exemple numérique, élaboré à partir des résultats de l’arpentage au laser effectué par la mine Bousquet 2 dans un chantier d’abattage, donne les détails concernant les définitions ainsi que les valeurs de nombreux facteurs de performance technique, qui pourraient être utilisés, par après, par les opérateurs miniers dans le suivi de leurs exploitations souterraines."

Jan 1, 1997

By W. G. Willson

Low-rank coal (LRC) drying processes are generally categorized by operating temperature, drying environment and type of feed (either sized or ground coal). Within these broad categories, drying processes differ according to the type of drying equipment and methods of quenching and stabilizing the dried products. This paper focuses on the produce quality of various LRC drying processes including conventional low and high temperature evaporative drying and non-evaporative, hydrothermal drying. The former may be preferred if the dried product can be utilized immediately, but moisture re-absorption, spontaneous heating and fines production during handling are problems associated with longer term storage, transportation and utilization. Methods for reducing these problems are discussed. Hydrothermal processing is an advanced technology featuring high pressure, non-evaporative drying, which solves stability problems by producing a liquid fuel.

Jan 1, 1997

By D. Lui, B. G. Thomas, B. Ho

"Results from mathematical models and plant experiments are combined to quantify the effect of transverse depressions and oscillation marks on heat transfer in the continuous casting mold. A heat transfer model has been developed to calculate transient heat conduction within the solidifying steel, coupled with the steady-state heat conduction with the continuous casting mold wall. The model features a detailed treatment of the interfacial gap between the shell and mold, including mass and momentum balances on the solid and liquid powder layers. The model predicts the solidified shell thickness down the mold, temperature in the mold and shell, thickness of the resolidified and liquid powder layers, heat flux distribution down the mold, mold water temperature rise, ideal taper of the mold walls, and other related phenomena. The important effect of non-uniform distribution of superheat is incorporated using the results from previous 3-D turbulent fluid flow calculations within the liquid cavity. Results from plant experiments confirm that transverse surface depressions and oscillation marks form at the meniscus and move down the mold. Measurements of mold thermocouple temperatures and breakout shell thickness were used to calibrate the models. The results indicate that the surface depressions and oscillation marks are filled with mold flux, but still have a significant effect on decreasing heat transfer. The predicted mold temperature fluctuations are consistent with measurements. If the depressions become filled with air, their effect is greatly increased. These results should be useful in the difficult task of interpreting transient mold thermocouple signals for on-line quality monitoring.IntroductionMany different types of intermittent surface defects on steel slabs arise during initial solidification in the mold of the. continuous casting machine. These defects include deep oscillation marks, surface depressions, and cracks. They may lead to quality problems, such as slivers, in the final rolled product. In severe cases, breakouts may occur, where liquid steel bursts through a thin section of the shell and drains over the casting machine below the mold."

Jan 1, 1997

By A J. Eggers

With gold first discovered at Carrick in 1864, exploration and mining on the Carrick Goldfield in Central Otago, New Zealand, has now been ongoing for more than 130 years. Recorded historical hard rock production from up to 52 different mining claims from 1864 to about 1921 is 24,047 ounces (oz) of gold.   Since 1980 Amoco Minerals New Zealand Limited, CRA Exploration Pty. Limited, Amax Gold Mines New Zealand Limited and Summit Gold (New Zealand) Limited have conducted modem systematic exploration campaigns targeted at locating shear controlled gold bearing quartz lodes and stockwork deposits. More than NZ $1million has been spent by these companies on aerial photography, geological mapping, stream sediment surveys, soil and rock chip geochemistry as well as reverse circulation (RC) percussion and diamond drilling.   RC drilling by Summit Resources in 1997 has identified a 1,500 m long zone of low-grade gold mineralisation at Lower Carrick, with an average grade of 1.00 g/t Au over a 14 m average thickness. This gold mineralisation, hosted within a low angle shear zone, has analogies with the Hyde-Macraes Shear Zone in eastern Otago. Recent exploration and drilling at Carrick has revealed the potential to discover large (>0.5 million ounce (Moz)) low-grade bulk shear controlled quartz vein and stockwork gold deposits similar to those now being mined at Macraes.

Jan 1, 1997

The closure of the only professional mining school in New Zealand will mean that the minerals industry will have to explore other options to fill their mining professional positions. Globally mining is not seen as an attractive career option for young people and recruitment into mining courses is at a low level. Yet industry demands ever increasing competencies with respect to technology, environmental issues and legislation. This paper addresses this issue by first discussing the attributes required of graduate mining professionals. It then looks at alternative ways on how these can be met internationally and on the home front.

Jan 1, 1997

By Richard Klimpel

"Over the last 15 years, there has been a number of plant scale sulfide mineral flotation tests organized by this author specifically aimed at understanding how flotation rate varies with reagent type and dosage. With regard to the Interaction of collector dosage, particle size, and frother type, the eight specific trends listed in the paper (Illustrated with data from two specific case studies) are qualitatively the same for almost all plants studied in some depth. The Interaction of flotation rate K and equilibrium (Infinite time) recovery R in the plant has been denoted as the R/K trade-off. The effect of collector dosage on the rate of flotation of specific particle size intervals is particularly interesting and once understood, is quite useful In understanding how industrial flotation plants respond to changing reagent type and dosage. The location and magnitude of the R/K trade-off can be different for various ores and various plant configurations, but the RIK trade-off is almost always present. The purpose of this paper is to clearly describe and illustrate the nature of this very Important flotation system Interaction so that operating engineers have a starting reference point for beginning successful plant Improvement studiesIntroductionIt is well recognized by industrial froth flotation plant operators that improving existing sulfide circuit performance is often difficult due to the self-compensating systems nature of the froth flotation system, e.g. Klimpel (1988, 1989, 1995). Extensive plant testing with existing and new reagents by this author throughout the world has clearly shown that one of the more important self-compensating mechanisms is the Interaction between collector dosage, frother type, and particle size. The term self-compensation in flotation simply means that as the plant operator consistently changes one parameter in the same direction, the nature of the froth flotation system Is such that the circuit will eventually begin to resist this controlled parameter change by automatic (uncontrolled) changes In other parameters and the overall circuit performance will go through a maximum or minimum (hence causing the operator to stop the parameter change)."

Jan 1, 1997

By Tailoka F.

Various metallurgical residues from iron and steel making processes have been treated by chlorination in excess air with hydrogen chloride gas generated from the combustion of scrap polyvinyl chloride (PVC). The residues include dust from both the electric arc and blast &maces, hydrocyclone overflow, zinc - lead blast furnace slags and dust rich in zinc and copper from copper refining. Chlorination is achieved either directly by mixing the residues with scrap PVC or indirectly in a two furnace system. In the latter, scrap PVC is combusted between 523 and 573 K in a horizontal furnace and the resulting gases are then reacted with metallurgical residues in a vertical furnace at 1166 to 1329 K. Gas chromatography, thermogravimetric measurements, XRD and AAS have been utilised to study the reactions. The recovery of non ferrous metals is as high as 80 to 90 % and only a negligible amount of iron is carried over. The optimum temperature for combustion is between 518 and 573 K. Above 600 K, the evolution of HCI is so fast that sufficient chlorination is not achieved. Analysis showed that no dioxins were present in the gases, the residues or the chlorides.

Jan 1, 1997

By P. E. Sperry, R. E. Heuer

The United States Bureau of Reclamation is constructing the $200 million Navajo Indian Irrigation Project to irrigate 110,000 acres of land on the Navajo Indian Reservation in northwestern New Mexico. Water from the San Juan River is impounded by Navajo Dam and will be conducted for 26 miles along a series of tunnels and canals to the area to be irrigated. Tunnel No. 3 is the third in a series of six tunnels along the route. Bids for construction of Tunnel No. 3 were received by the Bureau of Reclamation in September, 1970. Fluor Utah was low bidder at $8.7 million. Ten of the 12 bids were based on excavation by tunnel boring machine. The consulting firm of A. A. Mathews, Inc., was retained by the contractor to advise on geologic and rock mechanics conditions after support problems developed in the tunnel. Tunnel No. 3 is 15,264 feet long, has an 18 foot lined diameter, rises approximately one-half inch per 100 feet in the direction being excavated, and is 6,000 feet above sea level. There is one short curve in the alignment. Minimum concrete thickness is 12 inches with eight inches from 'A' to 'B' line making a pay diameter of 21 feet, 4 inches. The tunnel is supported with rock bolts and steel pans. Mole excavation began on May 13, 1971 from a blasted starting chamber. After 46 feet were excavated the mole was shut down and the trailing muck handling equipment was pulled into place. After advancing 1,700 feet in 34 days, unanticipated ground water conditions and ground support problems were encountered slowing moling so that the next 1,000 feet of advance consumed 97 days until December

Jan 1, 1997

By R. Padilla

A thermogravimetric study has been conducted to follow the decomposition and volatilization of arsenic from enargite concentrate in nitrogen and slightly oxidizing atmospheres. Temperature has a large effect on the rate of volatilization of arsenic. Fractional volatilization of arsenic as high as 98% were obtained in less than 60 min at 650°C in nitrogen atmosphere, while in slightly oxidizing atmosphere the same volatilization could be achieved in 30 min. It was found that arsenic volatilizes as sulfide in nitrogen atmosphere and as 4xture of sulfide and oxide in atmospheres containing 1% oxygen. By using the pore blocking and the first order kinetic models, apparent activation energies of 213 and 200 kJ/mol for the temperature range of 780 - 900 K and 205 and 184 kJ/mol for the temperature range of 900 - 985 K were determined for enargite and copper concentrate, respectively.

Jan 1, 1997

By Kuda R. Mutama, Allen E. Hall

A wind tunnel investigation into the fundamental characteristics of jet fan performance is described. The effects of varying fan positioning in a square tunnel cross section are reported for two fan outlet diameters and velocities. Tests were conducted, also for a jet fan placed in a flow developed by an external fan operating in the same direction as the jet fan. The position of the jet fan relative to the tunnel walls was found to affect its performance. Performance parameters were determined and used to formulate theoretical equations based on momentum and energy considerations. The results identified a range of flow ratios which can be used to design an effective jet fan ventilation system and provide a basis for the selection of jet fans for practical mining applications

Jan 1, 1997

By Samantha Beeson, Collin Poole

"This paper examines the development of two new selective flocculation techniques for recovering KCI values from low grade carnallite potash ore.Direct recovery of KCI was achieved using one of two mid-range molecular weight polymers, one non-ionic and the other strongly cationic, in conjunction with the same selective anionic dispersant. From initial response studies on pure minerals and selective flocculation tests on synthetic mixtures, investigations were extended to recover KCI values from a natural carnallite potash ore. A single-stage process achieved products grading up to 61.3% KCI at recoveries up to 85.4% for the cationic flocculant suite and up to 64.8% KCI with recoveries as high as 90.3% for the non-ionic flocculant suite, with dispersant and flocculant dosages of 150-250gr1 and 10-75gr1, respectively. These results clearly demonstrate not only the feasibility of treating such problematic ores at low reagent dosages, but also the potential elimination of desliming prior to froth flotation.The experimental results presented are considered in terms of the reagent adsorption phenomena present in the system and various aspects of floe formation and cleaning.IntroductionAs high-grade sylvinite potash ores become scarce, lower grade sylvinite and carnallite potash ores are becoming more attractive. However, these ores often contain large amounts (up to 15% by weight) of water-insoluble slimes which must be removed prior to KC! flotation, owing to their high adsorptive capacity for the amine collectors used. The slimes are generally removed by scrubbing followed by hydroclassification and any residual material not eliminated is blinded with reagents such as guar gum or starch to inhibit interference in subsequent KC1 flotation.An alternative approach used commercially in Canada by Agrium Inc. involves water-insoluble slimes flotation prior to KC! flotation. In this process, the slimes are selectively flocculated and then separated by froth flotation. Losses of KC! to the slimes product and associated brine requirements are both reported to be less than those encountered in conventional desliming, but the technique is somewhat limited in its application at present."

Jan 1, 1997

By J. A. L. Napier

This paper presents an overview of work carried out by the CSIR Division of Mining Technology and formerly by the Chamber of Mines Research Organization (COMRO) to quantify the behaviour of the stope fracture zone near deep level goldmine stopes. The motivation for this work is first reviewed in the context of the unsatisfactory status of current mine layout design criteria. Numerical methods to represent failure processes are reviewed briefly. Specific studies of microfracture processes are described as well as physical modelling experiments that can yield insights into deformation mechanisms. Modelling of stope scale deformation mechanisms are presented and considerations relating to elastodynamic modelling of the rock mass are described. The implications of this understanding in relation to prospects for active fracture zone ?engineering? are outlined and finally, the directions of future research work are proposed.

Jan 1, 1997

By W. Blake, J. K. Whyatt, B. G. White

In situ stress on the scale of a tunnel or mine may be distorted by geologic structures. The resulting variations in in situ stress have a direct bearing on the potential for mining-induced seismicity. New evidence collected from the Lucky Friday mine by US Bureau of Mines researchers, as well as a review of previous case studies, demonstrated that in situ stress variations affect the [spatial] distribution of mining-induced seismicity. Although overcore stress measurements have been useful in these studies. they are too expensive and, depending, on conditions, may be too difficult to collect. However, information on borehole and raise breakouts: deformation of mine openings: and patterns of seismicity, ground-control problems and rock-burst damage can be used to build a stress database. In conjunction with maps of mine structure and geology and models of rockmass behavior, this database can then be used to build a map of in situ stress variations. Such a map could provide a means of anticipating patterns of mining-induced seismicity and. Thus, could be the basis for planning appropriate measures to ameliorate rock-burst hazards.

Jan 1, 1997

By A. G. Jackson, S. J. P. Laube

"Control of thin films during the growth process is dependent on several parameters that are difficult to monitor, including flux of film material, pressure, substrate temperature, composition, and thickness. One means for easing this difficulty is to take advantage of emission spectra associated with the process and the film. For pulsed laser deposition (PLD), the ion cloud generated by the laser has characteristic emission spectra that can be used to control the flux and, hence, the film. For chemical vapor deposition, the species present can be determined using mass spectroscopy and specific peaks can be used to control the deposition. Raman spectroscopy affords the possibility of real-time control by sensing characteristic peaks associated with film composition and thickness. These spectroscopic methods offer a real-time alternative to process control that is very attractive, because of the ability to accurately control films to achieve the engineered structures and properties sought. Examples are presented to illustrate the capabilities of these methods for thin film preparation.IntroductionThe drive to reduce costs and improve efficiencies of operation sets the tone for much of research, basic or applied. Basic research is limited by the ability of sensors and associated instrumentation to measure parameters accurately and reproducibly. Applied research has the same limitations and also the added constraints of time and costs. Hence, there are strong incentives to explore means for refining existing sensors with respect to performance and cost, as well as finding new sensors and techniques for more accurately and rapidly measuring quantities of interest in experiments and in various processes."

Jan 1, 1997