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By W. Stark

Many developing countries with little or no previous environmental regulation are now promulgating air quality regulations which require facilities to demonstrate compliance with both process parameter based emission limits and ambient air quality standards. For many companies with operations in developing countries, an air quality compliance program at the facility level is lacking and these companies have very little background information to work with in developing a program for assessing and maintaining compliance. This paper will present a methodology for development of a comprehensive air quality compliance program for operations located in developing countries with new environmental regulations. The experiences of the authors in developing an air quality compliance program for a mining operation located in South America will be used as a basis. A program for meeting new air quality requirements can be developed in seven steps. The seven steps are: (1) regulatory review and project scope; (2) design and implementation of a baseline air quality monitoring program; (3) site visit, (4) development of a complete air emission inventory; (5) dispersion modeling; (6) compliance analysis and compliance plan; and (7) project completion.

Jan 1, 1998

By Kot F. von Unrug

One of the major difficulties in the proper characterization of rocks surrounding excavations is the lack of data. The existing method for strength determination requires core drilling for sample collection, which, when performed from the surface is costly, and when performed underground, in addition to its cost, interferes with the mine operations. I-landling samples tested in the laboratory is troublesome and also influences the obtained results. Over several years. the author has been interested in developing a method of in situ strength determination that could rapidly generate strength data at low cost without a negative effect on mining activities. The recently developed borehole penetrometer is an improved version of the initial design ( 3 inches in diameter), which was used mainly for strength determination of coal pillars. The new penetrometer has been designed to work in 1.5 inch diameter holes. Such holes can be drilled at low cost with either hand held drilling machines or roof bolters. eliminating limitations of the previous system and opening the possibility of broad application. Strength testing of roof rock around longwall pillars is an example of an obvious benefit when designing secondary roof support. In the paper are given the principles of work of the apparatus and examples of the obtained strength data.

Jan 1, 1998

By Cliff D, Harrison P. Hester C

During 1997 two different types of coal mine inertisation equipment were trialed in separate underground coal mines in Queensland.In April 1997 tests of the Polish developed GAG-3A inert gas generator were carried out at the Collinsville No 2 Coal Mine. These demonstrations indicated that the GAG-3A device was applicable in underground coal mines and that with respect to inertisation rate the device outperformed all other currently available techniques. The unit was assembled rapidly and operated safely during surface and underground trials and no mechanical problems were encountered with the device. The GAG-3A is not suitable for every fire scenario particularly if large volumes of fresh air are being drawn into the mine(where multiple units may be required), but with respect to the selection criteria developed by the Moura Implementation Process Task Group 5 criteria, the unit performed up to the specifications required.

Jan 1, 1998

By V. P. Keran

Design of the Bajo de la Alumbrera Project started in June 1995 and concentrate production commenced early in the Third Quarter of 1997. The project is situated in North-Western Argentina and is being developed by Minera Alumbrera Limited which is owned by MIM Holdings Limited of Australia (50%), North Limited of Australia (25%) and Rio Algom Limited of Canada (25%). This paper outlines the key features that were incorporated in the design from both process and plant layout perspectives. It explains the background of flowsheet and equipment selection for the plant. A feature of the flowsheet is that it incorporates gravity gold circuits in both primary and regrind circuits for recovery of gold to dore as well as in the copper concentrate product.

Jan 1, 1998

By F. Nelson

RJB Mining is the largest coal producer in the UK. In January 1995 the Company acquired the Central North and Central South Regions of British Coal consisting of: ? 15 operating collieries -including capital equipment ? 2 care and maintenance mines ? 16 operating Opencast sites ? Interest in 26 prospective and 46 potential Opencast sites ? Approximately 417 million tonnes of proven and probable reserves and considerable mineral resource ? 9 million tonnes of coal stocks ? Long term contracts to supply approximately 90 million tonnes of coal to National Power and PowerGen to the period of 3 March 1998 ?Approximately 7,600 employees and 4,500 mining contractual labour. Up to the acquisition RJB Mining had the capacity to produce 14 million tonnes of saleable output with an approximate 1,500 strong workforce.

Jan 1, 1998

By Gerald W. Longenecker

For decades, traditional hydraulic engineering approaches have been used for sizing stream channels when stream relocation efforts have been necessary to allow for the advancement of quarry and other surface mining operations. These approaches have been based on various ydraulic models to design channel cross sections and slopes that could pass the required regulatory design storm such as the 2-, 5, lo-, 25-, 50-, or even loo-year events. Designing the stream channel to handle these more extreme ,storm events would often lead to large channel designs which required extensive bank and channel bottom stabilization techniques including concrete, rip rap, gabions, or other expensive approaches. The constructed channels often required ongoing maintenance to remove accumulated sediment and other debris which would settle out and reduce the hydraulic capacity of the channel.

Jan 1, 1998

Mineral ownership determination is not always straight forward as in many cases the relevant details are not recorded on the latest Land Transfer title held in the local Land Registry Office. To determine mineral ownership can be difficult, time consuming and expensive especially in a confused sector. Non statute minerals can be owned by the Crown, Land Owner or other persons. Statute minerals (Gold, Silver, Petroleum, Uranium) are always owned by the Crown and thus present no problems. In simple terms the only accurate and reliable method of determining the mineral ownership under subject land is to historically search back to the first registration when the land and minerals were definitely intact. Then carefully ascertain from the evidence gathered along the way to the present day whether any legislation or private agreement altered or affected the status quo.

Jan 1, 1998

Following a short review of selected literature, a back analysis of stress measurements of stress regeneration in a closed mini-longwall is shown. The agreement is good, lending confidence to the parameters used in the proposed numerical model. Foundation yielding was modelled in the absence of total stope closure. A ?Prandtl? wedge was formed, coinciding with the yield point of the pillar/foundation system. Some theoretical work is used as a starting point for the formulation of a new design methodology for strike or dip stabilizing pillar/foundation systems in deep level goldmines. The existing guideline for the stability of foundations (APS< 2.5UCS) is critically examined. Finally, the advantages of the new approach, and the work required to substantiate the proposed new design methodology, are outlined.

Jan 1, 1998

By T. B. Szwilski

The paper gives an account of the development of a mine health and safety program in China from 1987 to 1996. The project was funded by the United Nations Development Program and managed by the International Labor Office (ILO). The objective was to strengthen the capability of the National Safety Training Center (NSTC), located near Beijing to train more than 2,000 engineers per year, and provide consulting and informational services to 39 safety training centers and coal mines. Presently China has the highest mortality rate in the world for coal mine operations, the greater incidence occurring at the many thousands of small, unlicensed underground mines.

Jan 1, 1998

Laboratory tests were conducted to evaluate the silica collection efficiency of flooded-bed scrubbers with six different filter panel designs and at two operating velocities. Test results indicated that reductions in filter density negatively impacted respirable dust collection. Silica collection efficiency for the least dense filter was as much as 33 % lower than the collection efficiency of the densest filter. At the low operating velocity, the least dense filter allowed over 40% of the respirable silica dust in the scrubber intake air to pass through the unit, where it would be discharged back into the mine environment. Operation of the scrubber at the higher test air velocity increased silica collection efficiency, regardless of the filter panel tested. The density of the filter panels also impacted the quantity of air that is moved through the scrubber, with higher density filters reducing scrubber airflow. For each filter, the relationship between dust collection efficiency and air moving capacity must be considered to determine overall effectiveness for specific mine applications.

Jan 1, 1998

By W. J. Schlitt, J. H. Templeton

The chemical reactions that occur within a copper-leach recovery system are discussed, and the impact on the overall acid balance is evaluated. Both oxide and sulfide mineralogy are addressed, and their effects on acid consumption, generation and solution buffering are presented. Two case studies that apply the discussed chemistry show the practicality of using a computer spreadsheet acid-balance model for the early planning and design of copper-leach systems.

Jan 1, 1998

The nature of adsorbed calcium carboxylates (oleate and stearate) has been investigated by in-situ/ex-situ Fourier transform infrared internal reflection spectroscopy (FTIR/IRS). Previous spectroscopic studies in alkaline solution have shown that adsorbed carboxylate is characterized by a C-O stretching vibration at about 1550 em?1 for less than monolayer coverage. Similar results were found in this study. More specifically, in this study such a singlet at 1550 cm-1 was found for LB monolayers of calcium distearate transferred as a condensed layer at a high film pressure to the surfaces of fluorite and germanium. Normally the spectrum of bulk calcium distearate reveals a doublet at 1575 and 1540 cm-1, characteristic of a three dimensional 7-fold coordination for calcium carboxylate complexes. This doublet is generally found for carboxylate multilayers formed by spontaneous adsorption at the surface of calcium minerals. In this regard, the spectral evidence suggests that whenever the calcium dicarboxylate is constrained at a surface as a condensed layer, the 7-fold coordination can not be satisfied and the surface carboxylate is forced into a two dimensional symmetrical coordination with a singlet at 1550 cm-1. On the other hand, if the Langmuir-Blodgett (LB) monolayer calcium distearate film is transferred at a low film pressure the doublet is observed. This analysis is further confirmed by the spectral results for LB transferred calcium distearate monolayers at a hydrophobic silicon surface. Even though these are condensed monolayers formed at high film pressure, the carboxylate group, oriented away from the surface, is no longer constrained by the surface force field, and thus exhibits the characteristic doublet of the bulk calcium distearate salt.

Jan 1, 1998

By D. Pohl

The past decade has seen rapid expansion in the West African mineral exploration environment. This expansion has been largely driven by changes in ?Political climate ?Fiscal and legal regimes ?Exploration approaches ?West African geology. Major regional mapping and geochemical surveys by the UNDP, and the BRGM in the late 1970s and early 1980s laid the foundation for the rapid development of mineral exploration and resources during the past decade. An additional driving impetus was the discovery by native artisanal miners of many significant new gold occurrences at Libiri, Essakan, Bouda and Tirahori, during the great droughts of the late seventies and early eighties.

Jan 1, 1998

By N. Kanari

Kinetics of the carbochlorination of Cr2O3 has been studied with C12+CO gas mixtures between 500 °C to 900 °C using thermogravimetric analysis. The apparent activation energy is about 100 kJ/mol. Mathematical fitting of the experimental data suggests that the shrinking sphere model is the most adequate to describe the carbochlorination mechanism of chromium oxide and that is controlled by the chemical reaction. In the temperature range of 550 "C to 800 OC, the reaction order is about 1.34 and is independent of temperature. Changing the C12+CO content from 15 pct to 100 pct increases the reaction rate and does not affect the reaction mechanism. Similarly, changing the ratio of C12/(Cl2+CO) from 0.125 to 0.857 do not modify the carbochlorination mechanism of Cr203. In these conditions, the reaction rate passes through a maximum when using a chlorinating gas mixture having a Cl2/(C12+CO) ratio of about 0.5.

Jan 1, 1998

By Yong J. Kim, J. M. Park

"Solid/melt interface shape during continuous casting process has a strong influence on the resulting microstructure of the ingot. The interface shape is primarily governed by the heat flow condition between the molten metal and mold (or container). The roll of the microstructural transition resulting from various solid/melt interface shapes is discussed using the Sn-22.6wt%Pb alloy. Three different types of mold such as cold mold, resistantly heated mold, and electromagnetically heated mold were used to generate those interfaces having different curvatures. Experimental measurements of complete temperature profile along the axis and surface of the ingot during downward continuous casting are presented to determine the solid/melt interface geometry. The results provide an explanation of the ingot property with emphasis on microstructure.IntroductionA large scale of continuous casting process of alloys often has a rather deep V channel type of solid/melt interface resulting from a limited heat flow condition. As a result, the deep V type solid/melt interface shape entraps defects such as pores and inclusions and also creates canter segregation. In order to reduce the defects concentration, electromagnetic stirring(EMS) mechanism has been applied to the melt in the channel[l]. Speith and Bungeroth introduced first experimental EMS device to the continuous caster in 1952.[2] Today, with wide ranges of benefit, a large variety of such technique is available. Electromagnetic field on the melt can be divided into three aspects. First, eddy current is induced on the metal surface by alternating magnetic field with high frequency, which results in heating the metal. Second, electromagnetic body force which is generated by the magnetic field and the eddy current reduces the melt pressure on mold or support the melt not to contact with the mold[3,4,5]. This force is used for electromagnetic casting process(EMC). Finally, it causes stirring in the melt. Many research efforts have been done on the EMC process to improve surface quality of slab[6] and control meniscus shape where three phases such as melt, solidified metal, and mold powder coexist[7,8]. However, the eddy current heating effect on the surface of the ingot was less considered. It is worth noting that induced eddy current on the surface of slab melts the solidified shell and thus changes the heat flow condition between the mold and melt. Mold heating effect was first proposed by A. Ohno[9] and its processing conditions were identified in details[ 10, 11]. The so-called Ohno process is based on the fact that by keeping the mold temperature slightly above the melting temperature of the liquid, no grain can be nucleated on the mold wall[12]."

Jan 1, 1998

By R. M. Enick

A novel liquid-liquid separation for the recovery of free or liberated gold from mixtures of fine particles was evaluated. The separation, conducted at ambient temperature and a pressure of about 1000 psi a, was based on the difference in wettability of precious metals and minerals. Contact angle results indicated that in the presence of water and liquid CO2, gold, platinum and silver had intermediate wettability. Minerals such as quartz and magnetite, however, were hydrophilic. Therefore fine gold particles. -325 mesh, that were mixed with water and liquid CO2 dispersed in the CO2 or agglomerated at the H2O-CO2 interface while the minerals tended to remain in the aqueous phase. Best results were obtained when these fine gold particles were liberated, were not agglomerated in slimes, were not adhering to minerals, and were not coated with minerals.

Jan 1, 1998

By Courtney A. Young

All cyanide species are considered toxic and can be found predominantly in industrial effluents generated by metallurgical operations. For example, cyanide&apos;s strong affinity for metals makes it favorable as an agent for metal finishing and treatment and as a lixivant for metal leaching, particularly gold. These technologies are environmentally sound but require safeguards to prevent water contamination. Various methods of cyanide remediation by separation and destruction are available, but certain methods are more effective than others depending on the cyanide species being remediated. Photolytic destruction is regarded as the one technique that is independent of the cyanide species involved. The destruction of various cyanide species by several photolytic techniques has been investigated for the past few years. A literature survey suggests heterogeneous photocatalysis with anatase (TiO,) should behave similarly to homogeneous photolysis with hydrogen peroxide (H,O,) since proposed reaction mechanisms for both processes involve hydroxyl radicals. However, experimental evidence on a suite of cyanide species suggests otherwise. A new mechanism for the photocatalytic destruction of cyanides, especially SAD species, is therefore proposed.

Jan 1, 1998

By Wenxian Zhu, Patrick R. Taylor

"The small dimensions of nano-sized materials leads to novel and enhanced mechanical and physical properties. A thermal plasma reactor has been developed to study the formation of nanometer sized metal powders. A supersonic nozzle and a powder filter were designed and built. By vaporizing coarse metal powders in the plasma flame, and quenching the metal vapors through the nozzle at the rate of 107 K/sec, nanometric sized powders have been produced. The powders were collected in an airtight secondary quench-filter system. The particle size of the product power is 5 -20 nanometers, obtained through TEM analysis. The XRD analysis showed that the powder did not oxidize after the filter was handled in an inert atmosphere glove box.IntroductionNanostructured materials have been shown to exhibit improved physical and mechanical properties compared to conventional materials with larger grain sizes (1,2). There have been several methods proposed for preparing nanometer size materials. Thermally induced vapor-phase reactions have been used to produce a variety of powders. A common feature of these processes is the rapid production and cooling of condensable reaction intermediates and products, by gas-phase reactions, leading to the formation of a large number of very small particles. Thermal plasma synthesis of ultra-fine size particles has been attracting increasing interest (3,4,9-11), because it offers many advantages, especially in refractory materials processing, compared to conventional processes: (a) thermal plasma temperatures are very high(> 5000 K); (b) the rates of chemical reaction are much faster than those encountered in conventional processes; (c) high-purity materials may be obtained using fewer processing steps by collecting the product at temperatures where the by-products are in the vapor phase; ( d) the mean particle diameter can be controlled; (e) unifom sized particles may be produced with clean surfaces (these particles are particularly suitable for pressureless sintering); and, (f) high throughput per reactor volume can be achieved. In addition, the process used for generating particles determines the degree of sintering ability of the powders, since the process dictates the morphologies, the purity and its size distribution. In the future, thermal plasma synthesis nanometer size particles may play an important role in vapor phase reaction techniques and might be expected to be one of the first full scale commercial installations in the future."

Jan 1, 1998

A Mark IV surface force apparatus (SFA) was used to conduct direct force measurements between mica surfaces in dodecylamine hydrogen chloride collector solutions at varying pH levels. It was found that long-range hydrophobic forces reach a maximum at pH 9.5, which also corresponds to the maxima attained by the contact angle and flotation recovery of quartz. The charge densities are comparable on both mica and quartz surfaces (0.40 to 0.48 nm2), making it possible to draw conclusions on the flotation of quartz from the direct force measurements conducted on mica. Therefore, it may be suggested that, in the pH range of 8.0 to 10.3, the maximum flotation recovery of quartz may be attributed to the appearance of a long-range hydrophobic force, which, in turn, can be related to the formation of a close-packed monolayer (or hemimicelle) in the presence of neutral amines formed as a result of hydrolysis.

Jan 1, 1998

By A Clark

When production targets are not being reached it is essential to determine what the operating problems are so that remedial action can be taken. It is also imperative that all persons who are part of the production stream within a mining operation know and understand what the operating difficulties and delays are so that corrective action is effective. This includes the supervisors, superintendents, planning team members and managers. A new approach recently adopted at Hilton Mine to help identify these operating difficulties has been to use short-term schedules and reports known as the Daily Shift Schedule Controls (DSSC), and the Daily Weekly Operating Reports (DWOR) respectively. These control elements have enabled management and supervisory staff to accurately identify labour inefficiencies and ultimately determine capital resources.

Jan 1, 1998