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By R. Elliott, H. Bayati

"Effect of time and temperature on microstructure and mechanical properties of an austempered ductile iron, ADI, of composition 3.6%C, 2.6%Si, 0.4%Cu, 0.2%Mn are reported. Xray analysis and. microstructural observations indicate that lowering the working temperature, aging temperature, increases the lifetime of ADI significantly. Results show· that lowering the aging temperature increases the strength and reduces the ductility of ADI. DSC traces for ADI austempered at 340°C are presented. Comparison of the DSC analysis and kinetic measurements demonstrates that the DSC traces can be· used to predict the life time of ADI successfully.IntroductionAustempered ductile iron, ADI, is one of the most significant developments in cast iron technology over the past two decades. Outstanding properties of high yield, ultimate strength, ductility, fatigue and wear· resistance make ADI suitable for a range of applications including gears, connecting rods, crankshafts and agriculture machine components. The austempering reaction in cast iron occurs in two stages, Fig. I, in contrast to the single stage reaction in steel. In stage I the relatively low carbon austenite produced during austenitising transforms into ferritic plates and high carbon austenite, a metastable structure called·ausferrite. The high carbon ailstenite and supersaturated ferrite produced in stage I decompose into ferrite and carbide in stage II: to form a structure similar to the bainitic structure in steel. This behaviour exposes a well-defined processing window, t1 - t2, over which the maximum amount of ausferrite is produced, Figure 1. Whereas the bainitic structure determines the properties of austempered steel, ADI properties are mainly affected by volume fraction of retained austenite (VRA), austenite carbon content (ACC), unreacted or martensite volume fraction (UA V), compositiori and amount of carbides, and morphology of ferritic plates[l,2]. Due to the detrimental .effect of martensite and carbides on properties of ADI, an ideal structure of ADI consists only of ausferrite [l,2]. Thus, it is common to determine the processing window for each austempering treatment in order to identify the optimized austempering time. Decomposition of austenite (stage II) signals the end of the life time for an ADI component, therefore, the aging behaviour of ADI at different working conditions can be studied by determining the t2."

Jan 1, 2000

By Seth L. Pearlman

Pin Piles are small diameter high capacity drilled and grouted piles also called minipiles or micropiles. They are ideal for building foundations on sites with poor ground conditions, sensitive surroundings, restricted vertical clearance, or difficult access. They are also well suited to foundation underpinning, arresting ground movements, and increasing the capacity of existing foundations. The major factors for selection of Pin Piles are reviewed; drilling, grouting, and design fundamentals are summarized; and a major case history is presented for the underpinning of the 43 story elevator core at the recently opened Mandalay Bay Resort and Casino in Las Vegas, NV.

Jan 1, 2000

By Andrew K. Simpson

What will this deal do to the company’s stock price? This question arises when a publicly traded mining company is presented with a new mine project, or business combination. The standard tool for addressing this question is to use discounted cash flow analysis, or net asset value(NAV), which is discounted cash flow net of liabilities. Cash flow-based analysis is invaluable for assessing project costs and other impacts on debt service capacity and internal rates of return. But cash flow analysis and NAV do not work very well for stock price analysis.

Jan 1, 2000

By Alexander Malahoff

The most exciting frontier in Ocean Technology is represented by a new class of Marine Bioproducts, the source of which lies in marine microorganisms. The microorganisms include microalgae, bacteria and archaea. These organisms represent very diverse, adaptive life forms and in their metabolic processes use carotenoids, polyunsaturated fatty acids, ultraviolet blockers, as well as a wide range of enzymes that are pivotal in the production of new pharmaceuticals and nutraceutical products. These organisms cover a wide spectrum of ocean environments, from the shallow to the deep, from the normal to the extreme. The technological challenge is in the identification of candidate organisms, in the screening for valuable enzymes, and in the industrial production. A whole new range of collecting strategies involving submersibles, ROVs and in situ ocean floor instrumentation is emerging. New non-polluting industrial chemical processes involving the use of photobioreactors and extremophile bioreactors for breeding and monitoring these organisms in neo-farming technology is emerging. The commercial value of these candidate products is immense, as is the range of potential organisms. The dimension of this new industry is global. The Marine Bioproducts Engineering Center (MarBEC), funded by the National Science Foundation (NSF), has been established at the University of Hawaii. The vision of MarBEC is to develop a seamless research system stretching from undergraduate education to industry for the purposes of producing valuable marine bioproducts outside of the normal chemical factory production. MarBEC is uniquely and strategically placed in the Pacific to explore, find, and adapt highly bioactive marine micro-organisms found in the tropical ocean. We have watched the increasing need by the ever-

Jan 1, 2000

By Motohiro Horiguchi, Kazuo Ichii, Toshio Oishi

"As a fundamental study to prepare copper-based alloys with rare earths (RE: La, Gd, Nd, Ce and Y) without any inclusions, the solubility of rare earth in liquid copper was experimentally determined. Liquid copper alloys were equilibrated with carbon and rare earth carbide in a graphite crucible in an argon atmosphere at 1523-1873 K.Solubilities of rare earth in liquid copper were determined by approaching the equilibrium values from both the lower and the ·higher concentrations than those expected· in the preliminary experiments. They were expressed as a function of temperature. Carbon in Cu-RE alloy was also analyzed and thermodynamically discussed.IntroductionOver the past several years, the demand for highly conductive and high strength copper-based alloys, such as Cu-Cr, Cu-Zr and Cu-Cr-Zr for use in electronic materials has increased.1 -7 These alloying elements are very reactive and easily oxidized to form oxide inclusions during melting. To avoid the oxide inclusions, it may be effective to utilize the strong reducing power of carbon in conditions under which no carbides form.In this study, to provide fundamental data for producing Cu-RE( rare earth) alloys without any inclusions, the solubility of rare earth in liquid copper in equilibrium with .carbon .was determined and discussed on the basis of the experimental results and the thermodynamic data.ExperimentalSample preparation for equilibrium experimentsOxygen-free copper (99.99%), lanthanum (99.9%), gadolinium (99.9%), neodymium (99.9%), cerium (99.9%) and yttrium (99.9%), and their oxides were used as starting materials.Each rare earth carbide was prepared by mixing rare earth oxide with carbon, which is a little more than the stoichiometric composition, pressing it into a tablet form and sintering at about 2000.K for 20 ks in a vacuum furnace using a graphite crucible. Powder X-ray analysis showed that only the carbon and rare earth carbide (REC2) was present in each sample.Cu-RE mother alloys (5-20 mass % RE) were prepared beforehand by mixing metallic rare earth with oxygen-free copper, and melting in an electric arc furnace."

Jan 1, 2000

By Tony Robles

"A new process is disclosed for the recovery of gold and/or silver values from activated carbon wherein they are adsorbed as cyanide complexes. A unique chemistry allows the new process to use mill process water containing an inexpensive, non-hazardous compound as the eluant. The new process has an elution period of 5 hours at 98°C. The gold in the eluant can be recovered by electrowinning or zinc precipitation. The new elution process is simple, reliable, and provides an eluted carbon that may not require thermal regeneration before reuse. Retrofitting the new process to existing processes such as Zadra, Anglo, and others will not require significant capital expenditures.IntroductionThe efficient and reliable elution process for gold/silver from activated carbon is a very important process in the gold mining industry. The most common techniques for elution of gold cyanide from activated carbon are the Zadra and Anglo procedures.Specialized elution techniques like the Micron and Acetonitrile processes have not been commercialized to significant extent probably due to relatively complex unit operations and expensive reagents.Important functions of the gold recovery circuit are:Efficiently recover gold/silver from the loaded carbon.Carbon is in good condition for reuse for optimum recovery.The pregnant solution is amenable to electrowinning or zinc precipitation to recover gold/silver from the solution.The whole process to be simple and short to reduce gold inventories.Present Elution ProcessesTable 1 shows some carbon elution processes that are available today. The two main elution processes used in the industry are: (1) the Zadra process, in which hot cyanide solution is circulated through an elution column and electrowinning cells; and (2) the Anglo American Research Laboratory (Anglo) process, consisting of a pretreatment step with caustic cyanide solution, followed by elution with deionized water."

Jan 1, 2000

By Michael Kelly

Longwall mining is the principal method of underground coal mining in Australia, with 70 million tonnes being produced by longwall mines in 1999. However, the mechanisms that control longwall geomechanics are still not clearly understood resulting in stoppages costing several hundred million dollars per annum The CSIRO has been investigating longwall geomechanics with consultant groups and minesites through several ACARP supported projects since 1994. The research has aimed to improve longwall support design and control methods by defining strata failure mechanisms and their occurrence about underground extraction panels, It also aimed to develop better predictive tools bur a broad range of underground environments. As a result of site studies at more than 8 locations some of the aspects that have been touted to control longwall geomechanics, especially from a 3D aspect are highlighted. These aspects include stress controls, geometry, faulting, depth. longwall width and changes in lithology.

Jan 1, 2000

By M. Mets

Pile foundations have been used in Estonia since the beginning of 1960's. To evaluate the capacity of piles nearly 2,500 pile tests and 1,800 pile loading tests Have been carried out. The pile foundations of nearly 150 houses are under settlement observations.

Jan 1, 2000

By Scott R. Giese, Lucas Dix

"Recently, there is a growing trend in the aluminum foundry industry to develop· improved melting and casting processes to produce lightweight, high-strength, and thin-wall castings for the aerospace and transportation industry. One casting method that has demonstrated industrial potential for producing clean, thinwall castings is vacuum-assisted, counter gravity casting. This process has the benefit of expeditiously and quiescently filling the casting cavity with a dramatic reduction of furnace related and reoxidation inclusions. Additionally, lower casting temperatures can be utilized because the application of vacuum during filling overcomes the resistive internal cavity pressure resulting in a finer, as-cast microstructure. The paper explores and discusses the processing and design conditions in improving the mechanical properties of A206 casting alloy using the vacuum assisted, counter gravity casting process.IntroductionThe process of metal casting has been, over the centuries, the chief production technique for components used in everyday life. However, the casting process has certain inherent problems that can adversely effect the properties of a finished product. These problems are directly attributable to the gravity pouring technique used to transfer molten metal to the mold and to fill the mold cavity.A recent study for the American Metalcasting Consortium demonstrated reoxidation products created during the casting process are five times more likely to cause product rejects than entrapped molding aggregates, melt slag, or furnace lining materials1. Formation of nonmetallic and intennetallic compounds are more prevalent in aluminum and titanium alloys because of their reactiveness to furnace lining materials and their high affinity for oxygen. The incorporation of undesirable compounds can be attributed to four areas of the casting operation. The sources are charge materials, melting technique, pouring methodology, and casting cavity filling. Aluminum foundry men have addressed the first three areas by selecting high quality melt stock, non-stirring melting equipment, and the use of porous ceramic filters. Unfortunately, little consideration is given to the last, but yet tl.1e most important part of the casting operation, the actual fill mg of the casting cavity.The generation of inclusion defects during the casting process can be described by two methods. As the liquid metal flows in the gating network and casting cavity, abrupt changes in flow d1rect10n cause the metal to become agitated. This mechanism liquid metal splashing, is generated by instability of the advancing liquid metal interface from turbulence effects as schematically illustrated in figure 1a2 . The surface oxide film bursts under high velocity conditions, folds over, and becomes dispersed and incorporated in the bulk liquid. Additionally, fragmented liquid droplets ejected from the disturbed interface oxidize and become dispersed in the metal stream."

Jan 1, 2000

[Scott Aberle Western Energy Co POB 99 Colstrip, MT 59323-0099 Randy L. Acre Joy Mining Machinery 2569 Silver Oak Ct. Grand Junction, CO 81505 Brian L. Acton Oxbow Carbon & Minerals Inc 1601 Forum Pl-#P2 West Palm Beach, FL 33401 Laine W. Adair Genwal Resources Inc POB 1420 Huntington, UT 84528-1420 Thomas D. Aderman The North American Coal Corp 14785 Preston Rd #1100 Dallas, TX 75240-7891]

Jan 1, 2000

By Dennis R. Dolinar

A room and pillar coal operation in central Pennsylvania was experiencing roof cutters and long running roof falls caused by high horizontal stresses. The roof conditions created hazards for the miners, and caused several production panels to he abandoned prematurely. The mine requested assistance from the National Institute for Occupational Safety and Health (NIOSH) in applying the "advance and relieve" mining to reduce the affects of the horizontal stress during panel development. The "advance and relieve" plan that was developed called for removing a pillar on one side of the panel as it was being advanced, thus creating a cave. The caving then relieved a portion of the horizontal stress across the panel. Because the horizontal stress direction is key to the success of this method, stress mapping as well as mining experience was used to establish the direction of the horizontal stress. Subsequent field measurements provided an estimate of the stress magnitude. Three panels were mined using this technique, and good roof conditions were achieved in all these panels. Instrumentation was used to monitor the stress changes in the roof created by the cave. Stress relief of over 1.000 psi was measured 120 ft from the cave and to depths of 20 ft into the roof. The lateral extent of the stress relief zone across the panels appears to be about 400 to 500 ft. This case history has provided much insight into the practical application of the "advance and relieve" method discussed in this paper.

Jan 1, 2000

By Nobuhiro Shinihara, Makio Naito, Keizo Uematsu, Tadashi Horta, Hiroya Abe, Masataro Okumiya

"A significant variation of strength was noted in silicon nitride ceramics made through the powder compaction processing with minor processing changes. The relevance of the fracture strength to the microstructure was examined in these ceramics. In the examination of microstructure, the ceramics were made into thinned specimens, and their internal structures were observed with an optical microscope in the transmission mode. This technique can distinguish a difference in microstructure associated with the minor processing changes. The strength of all ceramics examined in this experiment was qualitatively correlated with the -pore size distribution in the specimens. Clearly, the elimination of these detrimental defects will enhance the reliability of ceramics.IntroductionIn ceramics made through powder processing, a variation of properties is often encountered [l ,2]. This brings a major problem on producing reliable and cost-effective ceramics. The variation is often ascribed to the changes in the characteristics of defects. However, there is no clear evidence f\)r this explanation due to the lack of an adequate tool for identifying the defects determining the properties. Details of the origin of the variation have still been poorly understood.A new technique is very promising for clarifying the origin of the variation [3,4]. This has very high potential in detecting minor differences in structure for .engineering ceramics. With this technique, ceramics are made transparent with its thinning down to about 50 µ m and their internal structures are observed with various types of optical microscopes in the transmission mode. The characteristics of the defects determined through this approach were found to be directly related to the strength of the ceramics [4-6].The objective of this study is to clarify the ongm of fracture strength of silicon nitride ceramics. This material is representative of high performance ceramics, and the origin is of great practical interest. For this study, silicon nitride ceramics with minor changes in processing condition were prepared. Specific feature focused in this study is the difference of large pore structure determined with the new technique and its relevance to the strength of the silicon nitride ceramics."

Jan 1, 2000

By G C. Reed, J M. Murray

During more than 100 years continuous mining of the lead-zinc orebody at Broken Hill, an immense amount of geological data has been collected about shear zones related to the orebody. The challenge to current mine geologists is to synthesise and interpret these data sets in a way that is applicable to production demands. Precise knowledge of the locations of major shear zones is important not only for the determination of ground conditions but also to develop an understanding of ore remobilisation along these structures. Traditionally, geological information has been collected from drill core and back and wall mapping underground, and interpreted on sections that are approximately 20 m apart. The recent introduction of MaptekÆs Vulcan software has enabled the shear zones to be modelled in three dimensions. The new three-dimensional shear models have been combined with seismic data from the Southern Cross area. The seismic data is collected from a microseismic monitoring system installed in the Pasminco Southern Operations in August 1996 (Rauert and Tully, 1998). The addition of seismic information to the shear zone models has led to a greater degree of certainty about the shear zone locations and has provided information about shear zones in areas yet to be drilled.

Jan 1, 2000

By Erik M. Westerberg

The Soilex Pile combines a slender shaft, for quick and easy installation, with an enlarged pile toe, for high capacity. The key component is the Expander Body, which is inflated by injecting cement grout when in position. The latest development in the Soilex Pile System results in a reduction of the total cost of Soilex Piles, in many cases values that are competitive with pre­cast concrete piles and displacement piles. Soilex Piles can now be installed on top of a bearing soil layer, instead of 3 to 4 m into that soil as previously required, further minimising the ground disturbance. Soilex Piles achieve high capacity in relatively loose soils, with ultimate loads typically between 1000 and 2000 kN in a sand with CPT qc = 5 to 10 MPa or SPT N= 10 to 20. It is possible to pre-load and proof-load all piles with dynamic testing up to 2000 kN or using built-in jacks, thereby verifying the capacity. The vibratory installation method, which is extremely quick and causes very little soil disturbance and noise, is exemplified by two case histories.

Jan 1, 2000

By M. Grodner

Underground excavations exhibit different hangingwall conditions in response to varying geotechnical and mining situations. These differences need to be quantified so as to accurately determine the effectiveness of the mining and/or support strategies. A useful tool for the quantification of these differences is hangingwall profiling. Two methods of hangingwall profile measurement are described?termed irregular and periodic methods. Several data analysis techniques are reviewed for these methods and the suitable ones are discussed in detail. For irregular data the suitable techniques are the determination of the length, the average of the profile and the average absolute deviation from the mean of the profile. All of these techniques as well as determination of the moving average of the height and examination of the spectral image of the profile can be successfully applied to regular data. The effect of preconditioning on the hangingwall is discussed as an example and it is quantitatively shown that it results in improvements of conditions. The techniques described allow the engineer to quantitatively identify the appropriate support type or mining strategy and thus represent a valuable decision-making tool. It is suggested that these techniques should be employed on a routine basis by the rock engineers on the mines as part of their geotechnical classification, as well as support manufacturers to quantify the effectiveness of various support types.

Jan 1, 2000

By Thomas M. Barczak

The decade of the 90's brought an unprecedented increase in the development of innovative technologies to provide more effective and easier to install roof support in underground mines. To facilitate the application of these technologies to improve mine safety. National Institute for Occupational Safety and Health (NIOSH) developed the Support Technology Optimization Program (STOP). STOP is a windows based software program that provides mine operators with a simple and practical tool to make engineering decisions regarding the selection and placement strategy of these various standing roof support technologies. This program includes a complete data base of the support characteristics and loading profiles obtained through safety performance testing of these supports at the NIOSH Safety Structures Testing Laboratory. Support design criteria in the form of the required support load density at a specified convergence can he established from four options: ( 1 ) a data base of measured ground reaction data from various mines or ground behavior information inputted by the user. (2) determination of loading requirements based on a detached roof block or rock failure height. or (3) criteria based on the current roof support system, and (4) arbitrary criteria set the by user. Using these design criteria, the program will determine the installation requirements for a particular support technology that will provide the necessary support load density and convergence control. Optimization routines are also available to determine the most efficient support design for a user specified support installation- In addition to these performance measures. STOP can be used to compare material handling requirements and installation costs. Comparisons among the various support technologies are easily made including graphical analysis of relevant support parameters. This paper describes the STOP and its application to optimize standing secondary roof support systems.

Jan 1, 2000

By K. Severin, B. Flanigan, P. Marion

“Plutonic-related” gold deposits in Interior and SW Alaska (Tintina Gold Belt) vary significantly in size, grade, vein/deposit morphology, depth of emplacement, distance from causative pluton and metal association. Metal associations such as Au-Bi and Au-As-(Sb-Hg) are a good empirical indicator of depth of emplacement and distance from causative pluton and have been used successfully in exploration. Results from a variety of analytical techniques also suggest a phenomenological cause for these metal associations, e.g. gold and bismuth have linked metallogenesis at high temperatures and thus are best correlated at deposits that are deep and/or close to causative intrusions.

Jan 1, 2000

By Hitoshi Iijima, Fumitaka Tsukihashi

"Fine powder of tantalum is used as materials of electric condenser. It is important to control the distribution of particle diameter of tantalum fine powders for the commercial use. In this study, fine powders of tantalum were produced by reducing tantalum chloride vapor with hydrogen gas at 1673 and 1773K. The tantalum chloride vapor was reduced with hydrogen and the produced fine particles of tantalum were collected to observe the distribution of particle diameter. The effects of reaction temperature, partial pressure of hydrogen gas and vaporization temperature of tantalum chloride on the distribution of particle diameter and reaction efficiency of reduction were determined. The mechanism of reduction reaction of tantalum was discussed.IntroductionThe ultra fine powder shows various different physical properties from that of bulk materials. Therefore, the application of ultra fine powder to various fields such as magnetic material, electric material, catalyst, etc is anticipated. The control of shape of powder, size distribution, property of agglomeration, purity is required for the practical use of ultra fine powder. Although the ultra fine powders of ceramics are produced by various methods, the ultra fine powder of metals are produced by the evaporation in gas atmosphere, plasma evaporation process, chemical vapor deposition process, and reduction and precipitation in liquid phase depending on the metal and productivity. The chemical vapor deposition process has features that pure metal powder can be obtained and the control of the distribution of powder size is easy. [1,2,3,4,5]"

Jan 1, 2000

By Paul F. Ph. D. Ziemkiewicz, Courtney D. Black

According to the American Coal Ash Association, 105 million tons of coal combustion products (CCP) were produced by the power generating utilities in 1997. Of that total, 1.68 million tons were used in mining applications (ACAA, 1997). Results have ranged from the environmentally beneficial to neutral and, in some cases, detrimental. Twenty years ago coal ashes: bottom and fly ashes constituted nearly all CCPs. With the shift to new emission control technologies at power plants, however, large volumes of new products are being generated. Many do not lend themselves to traditional ash applications such as cement formulation. Many CCP disposal sites are not documented with reliable pre and post application monitoring. In this report we discuss types of CCP, their relevant characteristics and the mining environment. We have attempted to identify a range of documented applications and to draw conclusions about their environmental effects including benefits and adverse impacts.

Jan 1, 2000

By Raj P. Singh

Applications of cementation in the recovery of metal ions from process solutions have been known for a long time. Cementation reactions involve electrochemical precipitation of a noble metal from solutions of its salts on a more electropositive metal which, in tum, progressively dissolves. For example, addition of zinc metal powder in a solution containing zinc and cobalt ions would allow for the precipitation (separation) of cobalt according to the following chemical reaction. This paper pertains to the recovery of cobalt from cobalt process solutions via a cementation reaction on aluminum shavings (metal scraps from cans etc). Specifically, we report on the characterization of cobalt process solutions, a by-product obtained from cobalt chemicals, and the kinetics of cobalt, nickel and manganese cementation from process solutions on aluminum shavings.

Jan 1, 2000