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By W. Dong

This paper presents the fundamental study of the temperature distribution in a reforming planar solid oxide fuel cell (SOFC) using mathematical modeling and experimental testing approaches at Versa Power Systems (VPS). In order to investigate the on-cell temperature distribution under high rates of Natural Gas direct internal reforming (DIR), both the computer simulation approach and the experimental testing approach have been developed. In this work, comprehensive in-house DIR and SOFC models were developed and employed for the computational fluid dynamics (CFD) based 3D computer simulation. The current SOFC module has been corrected to take into account both the on-cell electrical leaking effect and the stack stage structural resistance. Meanwhile, an instrumented single-cell test jig with multiple thermocouples was built, and a series of experimental tests were performed at various conditions. The numerical results based on the single-cell jigs are in very good agreement with the physical test results.

Jan 1, 2005

The general types of industrial behaviour of liberated valuable sulfide minerals in the 0 - 10 ¦m size fraction are described and tests to explore on site at a concentrator the general nature of any deficient behaviour are discussed. In addition, the general types of behaviour of the gangue minerals in this size fraction are also described in terms of their mechanisms for recovery. These behaviours are also discussed in terms of the type of grinding device and grinding environment in which they were produced and the target grinding product size. Major recent improvements in the industrial capabilities of grinding devices are discussed.Present difficulties in characterisation of particles in the 0 - 10 ¦m range are described and desirable improvements for the future are outlined. Further, desirable improvements for industrial processing of valuable minerals in this size range are discussed along with some remedial actions.

Jan 1, 2005

By Paul J. Lewis

Estimation of the axial side shear resistance of drilled shaft rock sockets is directly related to the unconfined compressive strength of the bedrock. Commonly, the mean unconfined compressive strength value is calculated from a range of laboratory test results and is used to estimate the side shear of the bedrock. This paper presents the results from a full scale axial load test performed on an 8.5-feet-diameter drilled shaft rock socket, and compares measured side shear values to estimated values for two different rock strata. Measured side shear values correlated well with the design value calculated for the "strong" rock stratum, but did not correlate well with the design value calculated for the "weak" rock stratum. The mean unconfined compressive strength was used to calculate the side shear in both strata, but review of the laboratory data indicates that this value may not have been appropriate for the weak stratum due to a large variation in the laboratory test results. Also included in this paper is a discussion of the subsurface conditions, the laboratory test results, and the methodology used to design the drilled shaft rock sockets for axial and lateral resistance.

Jan 1, 2005

By Dale S. Preece, Matthew A. Reisenmay, Avione Northcutt

The ability to simulate the explosive effects of land mines on military vehicles is a valuable capability in the defense community. The current competency levels of such simulations, however, are in need of improvement. Experiments have been conducted to measure the explosive induced impulse of a land mine on a steel plate placed above the explosive charge. The purpose of this paper is to report the findings of a variety of simulation tests conducted in order to correctly predict the empirical impulse data gathered in corresponding experiments. The computer hydrocode, AUTODYN v5.0.01 (Century Dynamics, 2003), is the simulation code used to simulate, and process the results. The experimental data has not been made available to allow computer analysts to exercise their codes on the problem without the temptation to tweak parameters in order to match computer code predictions with experimental results

Jan 1, 2005

By Jeffrey D. Winterton

Keywords: Copper, ion exchange, sulfonic acid, bis-picolylamine, ion exchange modeling, ion exchange kinetics As part of an investigation into the feasibility of using ion exchange resins to recover copper from aqueous waste streams generated during the manufacturing of semiconductor devices, the uptake of copper onto two ion exchange resins was investigated. The resins studied were DOWEX G-26, a standard gel type sulfonic acid resin, and DOWEX M4195, a macroporous chelating resin with a bis-picolylamine functional group. The equilibrium and kinetic behavior of the uptake of copper were investigated over a range of copper concentrations with constant sulfate concentration and different levels of acidity. The homogeneous structure of the G-26 resin yields equilibrium relationships that fit the Langmuir equation, and equilibration times of less than 30 minutes. The uptake behavior of M4195 is complicated by the need to absorb co-ions to maintain electroneutrality, resulting in uptake profiles that change character with increasing copper concentrations, and extended equilibration times.

Jan 1, 2005

By R. M. S. Häggblad

The article deals with stabilisation and regeneration of Ce02 and Ce02/Zr02 based Pt water gas shift catalysts, subject to high initial deactivation. The reaction gas species effect on the catalyst deactivation was investigated by H2-TPR. Activity measurements enabled the effect of different promoters, some added to the Ce02 based catalysts and some to the Ce02/Zr02 based Pt catalysts, to be investigated. The catalysts were also characterised by BET and CO-TPR. Deactivated catalysts activity was restored by using various regeneration methods. Of the two selected carriers the Ce02/Zr02 based Pt catalyst showed the highest resilience to deactivation. For the two different carriers, Ce02 and Ce02/Zr02, Wand Re were the best promoters when the catalyst was subject to deactivation. Experiments with Hr TPR indicate a fast initial change in the platinum oxides concentration and composition. The CO-TPR was used to make conclusions about the various regeneration effects of water and oxygen on the catalyst. Finally it is suggested that not one deactivation mechanism is possible and which mechanism that dominates is dependant on the catalyst and the reaction gas composition.

Jan 1, 2005

By R. B. Nourse, R. Hundermark, B. Masters, H. Joubert

The new 30 MVA slag cleaning furnace at Waterval Smelter, Rustenburg Platinum, South Africa, has been in operation since 10 March 2003. The furnace design and operation face a number of challenges including a wide variety of feed materials and resulting bath conditions. Furnace feed varies in combinations of granulated Waterval Ausmelt Converter Slag (WACS), hot fed Peirce-Smith converter slag, concentrate and reverts. Coke is added as reductant. The resulting slag composition varies considerably and regularly. For the case feeding WACS an almost pure fayalitic slag (60%+ FeO, 30%+ SiO2) with a very low viscosity results. Due to the widely varying slag conditions, including a superheated fayalitic slag with high fluidity, a robust sidewall design is required adjacent to the slag bath. For this reason the furnace sidewall is equipped with Pyromet's MAXICOOL® high intensity copper cooling system. The design and installation of the copper coolers as well as tap holes are discussed. To cope with the variation in bath conditions and high slag superheat (350°C when tapped at 1650°C), the copper coolers are capable of removing peak sidewall heat fluxes above 500 kW/m2. Feedback is included on the performance of the Pyromet MAXICOO® copper cooling system for the first two years of operation. The paper further includes an overview on the design and performance of the tap holes, furnace shell, furnace roof and copper slag spouts.

Jan 1, 2005

By Kevin Whipkey

How is Improvement Being Achieved ? Section Equipment ?Mine Layout/Projections ? Work Schedule ? Maintenance ? Management

Jan 1, 2005

By M Xu and, P F. Wells, A N. Kerr, Y Shields

Triethylene tetramine (TETA) has been used in combination with sodium sulfite (sulfite) for pyrrhotite depression at Clarabelle Mill since 1998. This combination has been highly successful at reducing pyrrhotite levels in the bulk (Ni/Cu) concentrate. Although highly effective, the roles of TETA and sulfite are not well understood. Treating bulk samples of the circuit feeds through the miniplant enabled the effects of circuit configuration on the performance of the pyrrhotite rejection circuits at Clarabelle to be determined. Reasons for the different performance of the non-magnetic pyrrhotite rejection circuit in the miniplant were investigated and tested in the laboratory. The effect of different grinding environments in the laboratory was examined to better understand the depressing mechanisms of TETA/sulfite. Modification of the grinding chemistry improved the selectivity of pentlandite over pyrrhotite in the presence of TETA/sulfite at current plant dosages.

Jan 1, 2005

By P. Cienfuegos, J. Loredo, J. J. Fernández, F. Pendás

This coal basin is a fore-deep basin with a lot of similarities with the Appalachian basin in the U.S.A., where throughout the 1990s, the research in coalbed methane grew rapidly due to a combination of factors, including the high prices for gas and electricity. In the Asturian Central Coal Basin 129 coal beds with thickness ranging from 0.8 to 1.5 m have been recognised in the productive carboniferous in an area bigger than 1500 km2. The maturation grade of these coals varies from the external zones of the basin where the volatile content ranges from 35%-40% to 20%-30%, to the internal zones of the basin where the volatile content ranges from 20% to 10%. In this context a sustainable exploration for fossil fuel is currently being undertaken in the most favourable areas of the basin in order to evaluate the real possibilities for coalbed methane (CBM) resources.

Jan 1, 2005

By Jessie L. Bonner, W. Stephen Blomberg, Mark Leidig, Heather Hooper

Understanding the effects of the bench on ground motion can improve the design of cast blasts and achieve improved blast efficiency while remaining below vibration requirements. A new dataset recorded in September 2003 from a coal mine in Arizona has allowed us to examine the excitation of short-period Rayleigh-type surface waves from four simultaneously-detonated explosions in and below a topographic bench of a mine. The explosions were recorded on a network of over 150 seismic sensors, providing an extensive understanding of the ground motion radiation patterns from these explosions. We detonated two separate explosions (~3 tons and ~1.5 tons ANFO) in the deepest pit of the mine, thus the explosions were shot to solid rock. Within 25 meters of these two explosions, we detonated two additional explosions of similar explosive yields in a bench, thus these explosions were shot to the free face. Radiation patterns and spectral ratios from the explosions show increased amplitudes (by a factor of 1.5 to 2) at azimuths behind the bench relative to the amplitudes in front of the bench. We compared these findings to seismic observations from two ~1.5 million pound cast blasts at the same mine and found similar radiation patterns. Modeling of these blasts shows that the variations in ground motion are caused by the topographic bench as a result of 1) horizontal spalling of the rock falling into the pit and 2) non- linear scattering near the free- face. We also note that shooting to a buffer (previously blasted rock) causes the azimuthal variations to be significantly reduced.

Jan 1, 2005

By P. M. Soupios

There is an increasing requirement for geophysical surveys carried out during geotechnical investigations to provide direct information about rock quality or other geotechnical parameters. With the paucity of information to correlate geophysical results with actual rock properties, this is still difficult to achieve and additional research effort needs to be performed to address this issue. Nowadays, several researchers have been described detailed studies which designed specifically to investigate this matter. Generally, geophysical techniques which are used to estimate seismic velocities in the subsurface focus on the low strain levels that are not large enough to induce significant nonlinear, nonelastic stress-strain behavior (Luna and Jadi, 2000), which is normally evaluated when addressing liquefaction potential of soils in the shallow subsurface. Soil parameters relevant to seismic ground response (Rechtien, 1996) are density, relative density and void ratio, permeability, shear modulus, water saturation, soil fabric and stress history. Detailed characterization of elastic properties near a major construction site (e.g. a bridge) is useful for near field dynamic analysis of soil-structure interaction (SSI) effects. The coupled effect of the bridge foundation (piles, piers or abutments) and the soil immediately surrounding these substructure elements is essential for dynamic SSI analysis of these critical bridge structures. This paper presents a geophysical investigation performed along the under construction highway of Egnatia Odos, approximately 13 km west from the town of Xanthi in N. Greece. Twelve geotechnical boreholes, drilled at the maximum depth of 75 m, approximately located 20 m from the Nestos River. The objective of the survey was to obtain the high-resolution compressional and shear wave velocities of the shallow subsurface for computation of elastic engineering properties of the unconsolidated material interposed between the investigated boreholes. Joint interpretation of borehole logs and velocity images obtained by P- and S-wave traveltime inversions outlined shallow geological anomalies.

Jan 1, 2005

By A. J. Makoka, B. C. Qi

Reliable monitoring of corrosion is vitally important in the combat against corrosion and over the last two decades the interpretation of electrochemical noise has received considerable attention as a means to discriminate between different types of corrosion. To this end, many different analytical methods have been proposed, such as power spectral density analysis and analysis via various other stochastic criteria. However, although many corrosion systems are nonlinear and therefore not readily interpretable by the abovementioned analytical approaches, few studies in the analysis of electrochemical noise to date have exploited advances made in the analysis of nonlinear systems. In this paper, the use of phase space methods to analyze and detect change in corrosion systems via electrochemical noise is considered. In particular, the electrochemical noise data are used to reconstruct trajectories in the so-called phase space of the system and changes in the topology of these trajectories or attractors as represented by correlation dimension curves are consequently interpreted as an indication of change in the dynamics of the system.

Jan 1, 2005

By N R. Johnson

The overland conveyor at the Los Pelambres mine in Chile is designed to move 8700 t/h of material over 12 km at a speed of 6 m/s while descending 1400 m. The conveyor, which is divided into three segments, is equipped with a braking system that must bring it to rest without producing excessive stresses in the conveyor belt. Retardation and gently stopping a mass of 250 t requires retardation times in the order of 60 seconds. Brakes that can provide this performance require sophisticated controls as well as very high heat absorption capacity. This paper describes the thermal analysis of the braking system, which required the use of novel materials to meet the arduous duties imposed on the callipers and discs.

Jan 1, 2005

By C Hall, J L. Mauk

New 40Ar/39Ar dates of vein and wall rock adularia from seven epithermal deposits and one porphyry copper prospect help constrain the ages of mineralisation in the Hauraki Goldfield. Vein adularia from the Paritu region yielded a single 40Ar/39Ar plateau date of 16.315 ¦ 0.066 Ma. Five 40Ar/39Ar plateau dates of three samples of vein adularia from the Opitonui deposit overlap within error to yield a preferred age of 13.149 ¦ 0.016 Ma. Two samples of vein adularia from the Night Reef at the Broken Hills deposit yield exceptionally flat 40Ar/39Ar plateaus, and all dates overlap within error to provide an age of 7.121 ¦ 0.010 Ma. Two 40Ar/39Ar plateau dates of one sample of vein adularia from the Wharekirauponga deposit overlap within error to provide an age of 6.318 ¦ 0.061 Ma. Four 40Ar/39Ar plateau dates of three samples of vein adularia from the Maratoto deposit overlap within error to provide an age of 6.411 ¦ 0.022 Ma. Two samples of adularia from altered wall rock at the Sovereign deposit yield three 40Ar/39Ar plateau dates that range from 6.547 ¦ 0.021 to 6.806 ¦ 0.028 Ma. This suggests that mineralisation formed around 6.6 Ma, but the results are complicated because the adularia contains minor illite that post-dates adularia formation. Results from the Karangahake deposit are complex. Two samples of vein adularia yield three 40Ar/39Ar plateau dates that range from 6.116 ¦ 0.116 to 6.901 ¦ 0.101 Ma, whereas one sample of wall rock adularia that contains minor late illite yields two 40Ar/39Ar plateau dates that overlap within error to provide a date of 5.734 ¦ 0.041. The range of dates indicates that more work is necessary to understand the history of mineralisation at this deposit. Two samples of vein adularia from the Tui deposit yield four 40Ar/39Ar plateau dates that overlap within error to provide an age of 5.714 ¦ 0.017 Ma. These results confirm previous work that indicates that the ages of epithermal deposits young southward in the Hauraki Goldfield. These results are also consistent with previously postulated different ages for deposits hosted in Kuaotunu Subgroup rocks in the northern goldfield (>10 Ma), and deposits hosted in Waiwawa Subgroup rocks in the southern goldfield (7.1 to 5.7 Ma).

Jan 1, 2005

I once read an æarticleÆ in FHM Magazine entitled æThe Coolest Jobs There Ever WasÆ. It was about a group of guys who were pursuing careers that any person on the planet would just kill for. I distinctly remember drooling over the pages, thinking how much I would love to be Michael SchumacherÆs Chief Engineer at Ferrari, or the Principal Designer and Tester for one of the big Dutch rollercoaster companies. From that moment on, I decided that I wanted a career that was cool enough to make it into the pages of that article. Throughout my time at university, I always had that article in the back of my mind. As a result I constantly wondered about what sort of job I could end up with once I left university. More importantly, I wondered if FHM would be banging down my door to put me in the magazine! After a long and stressful job hunting process (in between completing a thesis and studying for exams) I finally managed to land myself a job with Orica Mining Services. I can honestly say I didnÆt know what to expect when I first joined Orica. Most of my friends ended up working for big mining companies, while I was offered a position with one of the biggest suppliers to these mining companies. However, I had a feeling when I was discussing the role with my future supervisor during the interview process that the job was going to be awesome. I have now spent a year working for Orica and I absolutely love it! While I feel that my job is worthy of being in that FHM article, unfortunately, I donÆt think I am going to get my opportunity to be in the magazine. Apparently I donÆt look too good in a bikini! However, I would love to have the opportunity to discuss the journey that I have taken so far û from my time as an environmental science graduate, then moving on to mining engineering, to now, being part of the Orica Mining Services Graduate Program. My suggestion is to use this paper as a resource. I have learnt during my time at university, as well as my time in the workforce, that the best people you can learn from are your peers. Take what you feel is relevant from the paper; hopefully it will help guide you in shaping your own career.

Jan 1, 2005

By Dave Capstick, Ken Garner, Jim Porter

Technologies and systems used in the management of energy consumption in the mining and metal processing industry are well understood and documented from the supply side of the business. It is our contention that in many instances, through a more complete understanding of the demand side of the business, based on the detail of the operations plan, will provide greater lead time in terms of the design, implementation and utilisation of power supply infrastructure. Thus, optimal management of demand in a proactive manner, based on production requirements, will ensure both security of supply as well as continuity of operations. This paper describes the technology and methodology that is being developed to enable the above statement to be achieved. We use a case study to demonstrate the ability of the tools and methodology and conclude by outlining the business benefits achievable as well as the future developments emanating from this initiative.

Jan 1, 2005

By Mark Dangerfield

[Power-Point Presentation]

Jan 1, 2005

One of the most important factors leading to the success of a cement plant is its location. A multicriteria decision-making method is used to rank alternative plant locations. The set of criteria is established and corresponding criteria should be established for each case study, although this multicriteria decision-making approach has broader applicability. In this paper, the analytic hierarchy process (AHP) with 5 criteria is used to develop a location evaluation hierarchy for an alumina?cement plant in East Azerbaijan province of Iran. Five alternatives for the plant location are evaluated. The main criteria are transportation, water supply, power supply, fuel supply and land. Other criteria have the same importance as these five alternatives. The alternatives are ranked by a multicriteria method and the best site is proposed. Keywords: plant location; multicriteria decision-making

Jan 1, 2005

By G Tsatouhas, R Newell, K Y. Wong

A sulfide ion selective electrode was used to control sulfidiser addition in the flotation testing of a synthetic and a naturally occurring ore containing malachite in order to compare the behaviour of sodium sulfide and calcium polysulfide. Both slug and controlled potential sulfidisation methods of addition were used. Under defined optimum CPS conditions, calcium polysulfide was a more effective sulfidising agent than sodium sulfide on the basis of both capital and operating costs. Surface and solution studies were used to compare the mechanism of each sulfidiser. For calcium polysulfide, XPS showed that polysulfide ions are adsorbed, whereas for sodium sulfide it is the hydrosulfide ions that are adsorbed on the mineral surface. For calcium polysulfide, the CuSx layer was believed to form on the malachite surface, which promoted the flotation of the malachite, by xanthate. Studies of surface morphology of the sulfidised malachite showed that a fairly uniform sulfidised layer is formed with both reagents. The use of sodium sulfide resulted in a thinner initial sulfidised layer compared to polysulfide at equivalent initial sulfur concentration.

Jan 1, 2005