Search Documents

By Carlos Frias

The lead-acid battery recycling is a major industrial activity (more than four million tonnes recycled lead per year) that generates large amounts of toxic wastes such as lead slag, mattes and acidic sludge, besides airborne emissions. This is a waste-producer industry that needs a definitive solution to avoid its negative environmental impact and getting a sustainable lead production. That is the principal target of the CLEANLEAD technology, which properly combines both hydrometallurgical and pyrometallurgical routes aiming to get zero-waste production, reducing the use of energy and resources in all phases of battery reprocessing, and consequently, greatly decreasing the operating cost. There will be no toxic emissions to land, water or air, and obtained products are pure lead metal or pure lead oxide, and commercial gypsum instead of waste sludge.

Jan 1, 2006

By D. Furrer, M. Dallaire

The arrival of Image analysis in the last 20 years has changed the world of quantitative metallography. Many standard measurement techniques which were previously manual can now be done with fully automated systems. This reduces subjectivity and operator fatigue and therefore enhances the quality of the statistical results. In many laboratories, Titanium Alloy microstructures continue to be evaluated by traditional methods, where quality of results is subject to operator fatigue and level of experience. Advances in Camera technology have tremendously improved image acquisition. One can often see clearly at 500x what can not be observed at 1000x, allowing for a larger area to be analyzed, without the inconveniences associated with very high magnification objectives. Powerful and versatile Image analysis software combined with a high precision motorized stage gives access to a multitude of applications, which were extremely challenging or impossible until now. Image Analysis tools such as Multilayer Grab, which reconstructs an uneven image into one plane of focus (ex. Observation at high magnification of texture resulting from etching) and Mosaic which builds an image from a number of fields of view (ex. Reconstruction of very large grains at low magnifications) expand even further the power and flexibility of IA systems. This presentation will describe how automated methods are applied to the point count method and grain size measurement. We will show how cameras and software work together to permit quantitative measurements of primary alpha and prior beta microstructures, as well as lamellar alpha plate thickness in titanium alloys.Automated and semi automated quantitative measurements of various Titanium microstrures have been assessed, using the Clemex Vision PE. Examples of the methods and steps used are presented.

Jan 1, 2006

By N. Bazzanella

The hydrogen desorption kinetics of pure and Nb-doped magnesium hydride film samples was investigated by using a Sievert-type apparatus. The overall activation energy and the reaction order controlling desorption are (141±5) kJ mol-1H and n 4 for Mg hydride and (51±5) kJ mol-1H and n 1 for Nb-doped (5% at) Mg hydride indicating that, in the doped sample, hydrogen desorption is controlled by the H migration in transformed h-Mg layers. Structural analysis performed by X-Ray Diffraction (XRD) and Extended X-Ray Absorption Fine Structure spectroscopy (EXAFS) show that the catalytic effect of the Nb dopant is connected with the formation of NbH0.89 nanoclusters dispersed in the Mg hydride matrix. It is suggested that the catalysis process is also connected to the presence of Mg-Nb hydride interfaces where the transfer of H atoms preferentially occurs by connecting h-Mg grains and by the role of the MgH2-NbH0.89 interface as preferential site for the dissociation of the hydride phase.

Jan 1, 2006

In order to deliver a quality shotcrete and concrete product underground for the extensions to the Cullinan Diamond Mine operations it was decided to develop a new, simpler concrete product to meet underground support requirements. The aim was to develop a concrete product that not only reduced costs but also met the performance criteria of the current range of concrete products used on Cullinan Diamond Mine, a 25, 45 and 60 MPa concrete and a fibre reinforced wet shotcrete. The concrete product batching and delivery system was to be from surface as opposed to the current underground batching systems. The operational principle was to include an automated surface batching plant with delivery of the concrete product to a borehole containing suspended pipelines delivering to an underground storage facility from where the product is delivered to the working area by further pumping or agicars. Keywords: concrete, shotcrete, full flow, frictional loss, pipeline transport, positive displacment pump

Jan 1, 2006

By James Rowland, Marcia Harris, Richard Mainiero, Michael Sapko

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 ?? 10-38 cm6 molecules-2 sec-1 for the rate equation -??d [NO]/dt = K ?? [NO]2 ?? [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

Jan 1, 2006

By H. Antrekowitsch

Nowadays, the pyrometallurgical treatment in copper smelters is the common process for the recycling of metals from the electronic scrap. Furthermore the European Directive on the Waste from Electrical and Electronic Equipment (WEEE) and the Directive on the Restriction of Hazardous Substances (RoHS), increase the importance of electronic scrap recycling. Besides these a high amount of plastic and inert components in these materials leads to problems at the processing. An optimisation concerning the internal recovery and the high amount of plastic is necessary to reach the recycling quota of the European directive. The majority of the scrap is treated mechanically in order to separate in a first step plastics from metals, iron from nonferrous metals and harmful substances from valuable materials. But the quality of the different fraction often rather low and further treatment leads to higher costs. Therefore an interaction between mechanical treatment and metallurgical processing should be realised. The Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals at the Institute of Nonferrous Metallurgy at the University of Leoben carried out investigations concerning the optimisation of the metallurgical recycling and the treatment of the input materials especially of printed circuit boards.

Jan 1, 2006

By S. Kelebek

Batch flotation tests were carried out using samples from stockpiles that were up to 1.5 months old as well as fresh samples oxidized in the lab for up to six months. Head grades and size distributions of samples were equalized whenever possible. The samples from stockpiles and oxidation experiments produced inferior nickel grade-recovery compared to the fresh sample. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to complete flotation of pyrrhotite. Secondly, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite. Application of a high pH of 10 compared to the regular pH of 9.2 slowed down pyrrhotite flotation kinetics, but was not able to prevent complete flotation after 8 minutes. The samples oxidized in the lab did not match full characteristics of stockpile samples. They provided somewhat better selectivity for pentlandite. Some correlations were observed on a qualitative basis between surface characteristics such as elemental sulphur formation, activation and flotation behaviour. Oxidation conditions, which induce floatability on pyrrhotite while causing incremental loss in pentlandite floatability appear to be the root cause of difficulties in the processing of oxidized forms of these ores.

Jan 1, 2006

By Mingming Zhang

This paper describes the aluminum electrowinning in a batch recirculation cell system using 1-hexyl-3-methylimidazolium chloride and aluminum chloride (ionic liquids) as electrolyte at low temperatures. The technique proposed to deposit aluminum from ionic liquid electrolyte was a three-component electrolytic cell system. Ionic liquid electrolyte was circulated between electrolytic cell and electrolyte reservoir by ceramic piston pump. Two different anodes were used in the electrowinning and it was found the extruded carbon anode had better electrochemical stability and reusability. The cell performance variables studied were the current density and current efficiency as a function of aluminum ion concentration, electrolyte flow rate and applied cell voltage during batch recirculation operation. Results indicated that the current density was directly proportional to the applied cell voltage, initial electrolyte concentration and electrolyte flow rate. Under batch recirculation operation at applied voltage of 3.5 V and temperature of 80-90°C, 80-90% current efficiency of cathodic aluminum deposition can be achieved when flow rate is 20mL/min and initial concentration is 10 mol/L.

Jan 1, 2006

It is my great pleasure as mayor of the city of Amsterdam to welcome you today to Amsterdam, and to the 10th International Conference on Piling and Deep Foundations. The history of Amsterdam has been connected intimately with your professions of geo-engineering and geotechnology, since its very first days. It is good to be aware that you are part of a very old tradition. The knowledge that we need today to build and renew the city has been gathered over a century long process so that we fortunately can stand on the shoulders of the giants before us. During the centuries people living in this part of the Netherlands have always struggled against the water. The same waters that brought the opportunity for a seafaring country to discover the world and to build an empire in the 17th century were a threat to the low lying Netherlands.

Jan 1, 2006

By A. G. Beer

The evolution of microstructure is examined during the annealing of hot worked magnesium alloy AZ31. The influences of deformation and annealing conditions on the developed microstructures are assessed. It is found that annealing at a low temperature (300 °C), after deformation at a low temperature and strain rate (300 °C and 0.001 5-1 respectively), results in the development of abnormally large grains. With increasing values of Z (lower temperatures, higher strain rates), static recrystallization of the dynamically recrystallised structure takes place; smaller annealed grain sizes are attained and the time at which coarsening begins is reduced. Whilst both the deformation and annealing conditions influence the time it takes to reach a stable annealed microstructure, the grain size attained is governed solely by the prior deformation conditions employed.

Jan 1, 2006

By M. R. Coffin

Since the plant startup in 1972, the leaching and jarosite precipitation circuits at the zinc plant of the Kidd Metallurgical Division have been reconfigured several times to improve overall performance, and/or to respond to market conditions. For the most part, the circuit changes have been driven by two market factors: the price of zinc and the price of silver. Until recently, circuit modifications undertaken to improve zinc extraction and recovery came at the expense of silver recovery, and vice versa. In 2004, the plant was modified once again to produce a precious metals-bearing residue, but additional leaching circuits were added to ensure that zinc extraction and recovery did not suffer as a consequence. The development of the zinc plant of the Kidd Metallurgical Division is updated in this paper, with a focus on the recent circuit modifications and associated control strategies that were implemented to maximize zinc and precious metals recoveries, and control the quality of the jarosite residue.

Jan 1, 2006

By Tim Hughes, A. H. (Sandy) Gray, Jennifer Abols

"The selective recovery of gold and silver from solutions containing other metals such as copper is possible using AuRIX®100 resin in conjunction with the Gekko Resin Column. Selectivity is driven by controlling the solution pH, which enables activities such as loading copper, gold and silver and then selectively stripping copper before gold and silver. Alternatively gold and silver can be loaded and the copper left in solution. The selective loading of gold while reducing the silver loading has also been demonstrated opening the possibility of producing high grade gold doré from high grade silver pregnant leach solutions. This paper reviews the AuRIX®100 resin and Gekko Resin Column Technologies, discusses the uses of AuRIX®100 in the recovery of gold and silver and the chemistry relating to several projects for which AuRIX®100 is being tested.INTRODUCTIONGekko SystemsGekko Systems specializes in the design, development and distribution of innovative mineral processing equipment and systems with a particular focus on gravity separation for the gold and diamond industries. The company, which has been around since 1996, has five main products: the InLine Pressure Jig, the InLine Spinner, the InLine Leach Reactor (ILR), Gekko Resin Column and Modular Systems.The InLine Leach Reactor is an intensive cyanidation reactor that uses high cyanide (0.5 – 2 % NaCN) and high oxidant (20 ppm dissolved oxygen as O2 or hydrogen peroxide) to dissolve gold from medium and high-grade gravity or flotation concentrates. The ILR, which typically replaces a shaking table in the gold room, is available in both batch and continuous models. There are 42 installations worldwide. Further details on this technology can be found in papers written by Gray et al (2003) and Longley, McCallum and Katsikaros (2003). By replacing a shaking table with an ILR, the overall gravity and plant recoveries can be increased significantly. Other advantages include reduced security risks, lower operating costs, reduced operator involvement due to the automatic process and increased safety for gold room operators."

Jan 1, 2006

By Kazuyuki Matsuzawa

A series of plate loading tests were carried out on a loam ground in order to investigate the influences of the plate size and the loading rate on the observed load-settlement relations. Two circular plates having diameters of 0.3 m and 1.0 m were used. Three types of loading methods were employed; 1) static cyclic maintained load test, 2) static continuous load test, and 3) rapid (dynamic) plate load test. An interpretation method called non-linear damping method was used to estimate a static load-settlement relation from the rapid plate load test signals. The derived static load-settlement relations match well with the measured results from the static load tests.

Jan 1, 2006

By Hui Lu

The structural changes in solutionized AA2618 during natural aging and their effects on subsequent artificial aging were investigated by hardness measurements, X-ray diffraction, differential scanning calorimetry and transmission electron microscopy. The changes in lattice parameter and hardness during natural aging indicate that copper-enriched clusters form in the earliest stage, followed by the formation of magnesium-enriched clusters and coppermagnesium co-clusters. Prior natural aging consistently weakened the hardening during subsequent artificial aging at 180, 200 and 230 °C but had no effects on artificial aging at 150 °C. The decreased age hardening was attributed to the reversion of small clusters/zones that formed during prior natural aging. The lattice parameter exhibited erratic changes with increasing artificial aging time, reflecting the complex sequence of the reversion and precipitation.

Jan 1, 2006

By M. Abdellatif

Keywords: Magnesium, pyrometallurgy, Mintek Extensive testwork on atmospheric thermal magnesium production has highlighted certain important fundamental and operational factors that have a major influence on magnesium extraction and its extraction rate, the condensation efficiency of magnesium, as well as on the quality of the condensed metal. The possible impact of these factors on the selection and preparation of raw materials, recipe choice, furnace electrical energy consumption, and on the refining requirements of the crude magnesium is discussed. Selected pilot plant operational and metallurgical data are also presented.

Jan 1, 2006

By A. M. Ramalho

In the synthesis and sintering processes to obtain superhard materials, such as diamond and cubic boron nitride, deformable ceramic capsule is used as gasket to transmit and support the required high pressures and high temperatures, HPHT. The ceramics materials for these capsules should have special physics and chemical characteristics such as refractoriness, shear strength and compressibility. In this work, Bridgman?s anvil made of hard metal or speed steel was used to characterize some ceramics materials in terms of their maximum compressible thickness. Tests were also performed with different resin polymers used as binding mixture with ceramics powder. Chemical analyses and investigations through scanning electronic microscopic (SEM), X-ray and real tests for the synthesis of diamond were also performed. The results showed that local Brazilian calcite can be successfully used in the manufacture of HPHT gaskets.

Jan 1, 2006

Keywords: Stellenbosch, university, teaching, research The pyrometallurgical activities at Stellenbosch University are reviewed in this paper. The history of the activities, both in teaching and research, is outlined, as well as some of the perceived research opportunities that the University of Stellenbosch is currently focusing on. The course content, as well as its relationship to other courses in the curriculum, is discussed and the interfaces between the courses are explained to present a holistic picture of the education an engineering graduate receives in process pyrometallurgy.

Jan 1, 2006

By Ernie Holden, Chris Ringas

In the last 20 years, In Line Inspection (ILI) using intelligent pigs has become the principal tool used by pipeline operators to assess the condition of their pipelines. New pipelines are normally designed to take intelligent pigs, but many older pipelines require some modifications and special procedures for their inspection. This paper is aimed at practicing engineers and managers of pipelines, or people aspiring to those positions. The paper describes the benefits of ILI and some of the practical issues regarding pipeline preparation and cleaning, choice of inspection tool, running pigs in pipelines, and what to do with the data collected. What are the responsibilities of the Pipeline Engineer ? ? Maintain reliable and acceptable performance of the pipeline in terms of safety and product delivery at economical cost. ? Provide a defined margin of safety for operating the pipeline at its designated pressure. ? Provide timely information on all pipeline defects such that repairs can be carried out according to a managed schedule. What Defects does the Pipeline Operator have to cope with ? A useful record of actual incidents seen in pipelines can be obtained from the web site of the US Office of Pipeline Safety (OPS) - http://ops.dot.gov/stats/stats.htm. US pipeline Operators are obliged by Law to report all pipeline incidents exceeding certain threshold criteria (e.g loss of life, escape of product, cost of incident etc). These OPS statistics show that corrosion and third party damage have remained consistently the prime causes of reportable incidents in the US, with similar experience elsewhere. There are several kinds of flaws and defects in pipelines that can lead to failure, the main families being :- ? Metal loss ? Cracks or crack-like defects ? Laminations and other mid-wall defects ? Geometric anomalies

Jan 1, 2006

By P. Leo

The hot deformation behavior of a Mg-9A1-1Zn alloy produced by high pressure die casting has been investigated by means of compression tests in the temperature and strain rate ranges of 125-300°C and 10-5-10-1 s-1 and torsion tests over 150-450°C and 5, 0.5, 0.05 5-1 . The compression samples were deformed in the die-cast state or after homogenization at 415°C for 2 h to evaluate improvements. A premature fracture at 45° with respect to the compression axis was observed in samples strained at low temperatures and high strain rates. The torsion specimens were tested as received or after a predeformation-homogenization treatment. In addition to constitutive analyses suitable for modeling previously published, the results are fitted to a relationship between strain rate normalized by diffusion coefficient and flow stress normalized by modulus. The results fit well with a set of published creep experiments that were conducted in the range of 70-150°C.

Jan 1, 2006

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006