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By L. Paulino, C. E. Zangiacomi, J. Yamamoto

"This paper presents the learning from Alcoa Po9os de Caldas Smelter in Brazil, after several energy restrictions resulting from the failures of three rectifier units at its power switchyard. Starting on December 27th, fuses and diodes failed in three rectifier units of Potline #1, causing a long and dangerous power interruption. Even after current was reestablished, amperage was only 70% of the line target leading to a bath freezing process that lasted for around 48 hours. The process engineering team played with several potroom parameters as pot resistance, bath and metal levels, alumina feeding and bath chemistry in an attempt to minimize impact on the potline metal output and energy consumption. As it will be illustrated, the first battle was to keep the pots running on a ""survival"" approach. After that, several changes took place on the procedures used to run at reduced current which were considered rather successful. Finally, some recommendations will be given to foresee and prevent transformers and rectifiers from undesirable failures."

Jan 1, 2006

By Padmavathi V. Sagi

In this paper, effect of cyclic loading on the behavior of a long, flexible, unrestrained vertical pile loaded laterally in soft clay is examined. For cyclic loading, the analysis is carried out using a new method for the construction of p-y curves and for static loading conditions, p-y curves proposed by Dewaikar and Poonam (2005) are used. An iterative analysis is employed with secant modulus approach using a matrix method known as moment area method developed by Sawant et al. (1994). For pile top deflection of 20% of pile diameter, the load values are computed for both static and cyclic conditions. The comparison of results with the field test results reported by Matlock (1970) shows a good agreement. A parametric study is further carried out to examine the effect of load eccentricity, pile embedment length, diameter and the number of cycles on the pile response. The results of this study are discussed in the paper.

Jan 1, 2006

Keywords: Pyrometallurgy, Wits University, research Wits Metallurgy celebrated its centenary in 2004. The department has been at the forefront of education and research and has contributed greatly to the metals and minerals industry, both in South Africa and abroad, in terms of human resources and knowledge generation. A significant number of industry and academic leaders worldwide are Wits Metallurgy graduates. Since its early beginnings, pyrometallurgy has always been part of the curricula and research offered by the department. Pyrometallurgical activities started to expand tremendously from the middle of the 1960s, especially by the formation - together with Mintek - of the Pyrometallurgy Research Group, which continues its internationally recognised research activities today. The research efforts have been concentrated on problems associated particularly with ferroalloy, steel, stainless steel production, and PGM/Cu-Ni sulphide smelting. In recent years, research has been further expanded to physical modelling of pyrometallurgical reactors. Almost all of the specific research projects were handled from a fundamental point of view, and hence a large number of MSc(Eng) and PhD degrees were achieved by candidates under the supervision of the Pyrometallurgy Research Leaders. Moreover, a significant portion of the research results were published in internationally recognized journals and conference proceedings. Among these, Infacon and the Molten Slags, Fluxes and Salts Conference series are worth mentioning. The studies from a fundamental point of view include thermodynamics, phase equilibria, transport phenomena, kinetics, and process dynamic aspects of high temperature processes and systems, both in the solid and liquid states.

Jan 1, 2006

During operations, mining and metallurgical processes may generate effluents such as tailings water, acid mine drainage (AMD) and seepage and process acid streams. Depending on the type of ore and the metallurgical process, these effluents may contain one or more toxic compounds (eg acidity or alkalinity, cyanide, ammonia and/or nitrate, heavy metals, total suspended solids (TSS), sulfate) in elevated concentrations requiring treatment before their discharge to the environment or recycle/reuse in the process. Natural oxidation of sulfide minerals present in mining wastes (eg tailings and waste rock) at mining sites may generate AMD, which is characterised as a low pH, high acidity effluent containing heavy metals and sulfate. If generation of AMD cannot be controlled and/or prevented, AMD needs to be collected and treated for neutralisation of acidity and reduction of metals and TSS to meet regulated water quality standards. It is important to note that some of these compounds may persist in run-off from mine sites, even after the mine and processing facilities are decommissioned. Treatment of mining and metallurgical process effluents can be accomplished by means of various physical, chemical and/or biological methods. The mode of process application may vary from the use of either specifically designed, controlled and automated facilities or passive systems. Lime neutralisation and precipitation is the most common method used in the mining industry to treat AMD. To reduce the problems associated with disposal and long-term storage of the resulting sludge, the use of a high-density sludge process (HDS) has become a preferred option. The use of other chemical reagents, waste or by-products from other industries, and biological sulfate reduction methods can also be considered as viable options for site-specific situations. Recently, several passive treatment systems have been designed and successfully operated, even in the cold North American climate. This paper will discuss available options and provide insights for selecting a suitable method for a given situation using case studies from projects conducted by Golder Associates around the world over the last decade.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By Frank Rausche

Without doubt, driven piles are the most economical deep foundation element for a nearshore environment, providing for high bearing capacities and stiffness, quick installation times, assured quality by simple monitoring and inexpensive dynamic load testing during restrike testing. However, when the pile top elevation is several meters below water surface, questions often arise as to the most reliable and economical pile installation method. Frequently encountered, yet relatively expensive, solutions include driving inside a dewatered cofferdam, driving long piles that are later cut off below water surface, or using an underwater hammer. Arguably, the most economical solution is driving the piles with a follower or chaser. However, many foundation engineers shy away from this solution because of the uncertainty associated with the transfer of energy through the interface between follower and pile, the associated potential driveability problems and maybe the limited fatigue life of the follower. This paper will demonstrate how the driveability of a hammer-follower-pile-soil system should be analyzed prior to installation and how to model the pile-follower interface both for steel and concrete piles. As an example, results will be presented which were obtained for both steel pipe piles and precast concrete piles, driven by a single-acting diesel hammer through a steel follower for a pre-construction test pile program in Venice, Italy. While analysis of the steel pile-follower system was straightforward, for the concrete piles, the presence of a soft cushion material whose material properties changed continuously posed some difficulty. Pile Driving Analyzer® measurements and CAPWAP® analysis yielded not only realistic stresses and transferred energy values in the pile, but also reasonable model parameters for further use in a pure wave equation analysis. As a side note for clarity, the dynamic measurements and analysis results herein presented are based on the GRLWEAP and CAPWAP software. GRLWEAP is commonly used all around the world for the preparation of pile driving jobs. The program either yields a bearing graph that relates bearing capacity and pile stresses to blow count or set per blow or it predicts blow counts and pile stresses as a function of pile penetration. These results allow the contractor to estimate driving time and select an economical hammer and driving system for a safe and efficient installation. CAPWAP on the other hand is the analysis of choice once a pile has been installed and records of pile top force and velocity have been acquired during installation or during a restrike test. CAPWAP is a signal matching program which calculates for one particular impact (for example at the end of driving) the static and dynamic soil parameters. Its final results include the calculated resistance distribution, the complete stress history in the pile and also a simulated load set curve. The CAPWAP calculated dynamic soil parameters can also be used in a Refined GRLWEAP analysis to generate a calibrated bearing graph."

Jan 1, 2006

By L. St-Georges

In aerospace and transportation industries, severe problems are related to fatigue failure. Aluminium is frequently used in these industries to optimize the solidity and minimise the weight of the structures. Nevertheless, the fatigue life of aluminium alloys is limited and specific efforts have to be made to reduce the vibratory stresses in the mechanical parts. When riveted, the life of the sheet metal structures can be increased compared to welded structures, due to the energy dissipated by the friction between the rivets and the sheet metal and the sheets themselves. In the past decade, a new tool was developed to assemble aluminium structures; the friction stir welding. With this new technique, fatigue life of the aluminium welded joints can be increased by a factor from two to ten. However, less energy can be damped by the friction between the components and increased vibratory stresses may occur. In this investigation, the potential of the friction stir welding to create damped aluminium sheet metal structures is evaluated.

Jan 1, 2006

By R. Sullivan, K. Joiner, B. Emery, M. de Vries, F. A. Stober, L. R. Nelson, J. M. A. Geldenhuis

Keywords: Pyrometallurgy, smelting, converting, furnace design, furnace retrofit, high-intensity smelting, copper coolers, plate coolers, waffle coolers, tap-blocks, lower sidewall air-cooling, wall hold-down system, platinum group metals, ferroalloys, ferrochrome, ferrocobalt, ilmenite smelting, ironmaking, operational readiness, operational support The paper describes the development of furnace designs by Hatch in conjunction with the smelting plants in Africa to meet the intense process requirements in certain applications; continued improvement in operating efficiency through increased throughput from existing crucibles; and improvement in campaign life and furnace integrity. The era of Hatch in Africa has seen the doubling of furnace power in retrofit projects using existing crucibles to developing the highest intensity immersed electrode operations in the world. This has resulted in minimized OPEX and CAPEX per unit of production. Through the continued development of its cooling, binding and furnace power supply technologies and working with the experienced and knowledgeable personnel at the smelting facilities in Africa, Hatch has managed to meet the challenges of ever increasing furnace process requirements associated with increased power density and superheats prevalent in the operations. In addition to developing furnace crucible designs, Hatch has also intensified its ?after sales service and support? with the construction, commissioning and start-up technical assistance and operational readiness and operational support for ramp-up to nameplate capacity and beyond. The key areas of furnace risk associated with high superheat molten material tapping has also seen the development of diagnostic systems to mitigate risks and produce early warning signals for the operators.

Jan 1, 2006

By Dinesh Agrawal

Microwave energy has been in use for variety of applications for over 50 years. These applications include communication, food processing, wood drying, rubber vulcanization, medical therapy, polymers, etc. In the last two decades microwave heating has been also applied very effectively and efficiently to heat and sinter ceramic materials. Microwave heating is recognized for its various advantages, such as: time and energy saving, very rapid heating rates, considerably reduced processing cycle time and temperature, fine microstructures and improved mechanical properties, better product performance, etc. The most recent application of microwaves has been in the field of metallic materials for sintering, brazing/joining and melting. Several common steel compositions, pure metals and refractory metals have been sintered in microwaves to nearly full density with improved mechanical properties. Many commercial powder-metal components of various alloy compositions including iron and steel, copper, aluminum, nickel, Mo, Co, Ti, W, Sn, etc., and their alloys have also been sintered in microwaves producing better properties than their conventional counterparts by using a 2.45 GHz multimode microwave system. This work has been further extended to join and braze bulk metal pieces, especially super alloy based turbine blades. Further, in a specially designed microwave cavity, even the bulk metals can be made to couple with the microwave field and melted. The implications of these findings are obvious in the field of powder metal technology.

Jan 1, 2006

By P. A. Mahanwar

Flyash were melt mixed with nylon 6 at a 30wt% concentration. TYZOR® TPT, a coupling agent, was used to facilitate the link between filler and matrix. The morphological characterization, using SEM, revealed sufficient matrix residue on the filler surfaces thus confirming the strong interfacial bonding between the filler and the matrix on treating. Tensile, impact and the flexural properties of the composites were also improved with the incorporation of coupling agent. As flyash particles tend to impart a grayish color to the plastic, TiO2 pigment was employed to make the formulations aesthetic. The pigment was added to the filled system in 0.1, 0.5, 1.0, 1.5, 2.0 wt/wt ratios. Scattering of incident light and spectral reflectance was higher for smaller particle size flyash. Moreover an increase in the scattering with increase in pigment concentration indicates better dispersion of the pigment, which again is due to the presence of coupling agent.

Jan 1, 2006

By Paul M. Wiltcher

This paper discusses how benefits in engineering design can be achieved from combining existing GRP concrete design guidelines with carbon steel design codes primarily made possible due to the increase in the constitutive properties of modern composite rebar or GRP. It also examines the technical and practical considerations necessary to both construct and ensure the integrity of composite rebar during transportation and handling on site and the measures taken by Franki-Cementation Joint Venture to ensure the safe deployment of the GRP in the workplace on the Noord/Zuidlijn Project in Amsterdam between 2003 and 2006.

Jan 1, 2006

By L. J. Gardner

Ore pass systems play a critical role in moving broken rock from the workplace to surface, and the integrity of the ore pass excavations is crucial. Over the life of the mine, ore pass integrity deteriorates, which may eventually result in the ore pass no longer being fit for purpose. This paper presents several case studies of successful ore pass rehabilitation exercises.

Jan 1, 2006

By Junfeng Shen

Geosynthetic clay liner (GCL) is a kind of waterproofing material used widely in engineering. The waterproof mechanism is understood in terms of bentonite particles becoming a water-obstructcolloid layer after they absorb water and swell. The swell stress, however, has not been determined directly till now. In our experiment, the swell stresses of the GCL under saturated and water absorbing conditions are measured directly using a custom-made instrument. The results show that (1) the instrument designed by the authors performed satisfactorily and the test results are reproducible; and, (2) The trend line of swell stress variation with time can be divided into three segments. The first segment is characterized by a quick increase of the swell force in the first 0?50 hours. The swell stress increases by 7.00×10-4?1.00×10-3 Mpa / hour. The second segment shows a slow increase of the swell stress during the 50?1730 hours. The swell force increases by 7.54×10-6?2.02×10-5Mpa / hour. The third segment is characterized by little variation in the swell stress after 1730 hours. In this segment, the average value of the swell stress measurements is 0.0719Mpa and the maximum value is 0.0729Mpa. It is suggested that the swell stress is mainly raised by water entering the pores among montmorillonite particles and the interstitial layers in individual montmorillonite crystals, leading to an increase in volume and manifested as a stress on the surrounding materials.

Jan 1, 2006

By Jong-Jin Pak

The present work reports the commercialization of a recycling process of spent acid to recover molybdenum. The process consists of ammonia gas neutralization of spent acid containing molybdenum, crystallization and filtration of ammonium molybdate, roasting and hydrogen reduction of molybdic oxide to produce a commercial grade molybdenum metal powder. The mother liquor, highly nitrogeneous residual solution after the filtration of ammonium molybdate, can be utilized to produce chemical fertilizers.

Jan 1, 2006

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By André C. Zingano

The coal pillars in room-and-pillar mining method are subjected to vertical stress due to overburden rock mass and horizontal stress relieve due to entries excavation around them. Some coal mining companies are applying rock bolts and steel straps to improve the pillar strength, consequently to reducing the pillar size and increasing coal recovery. This kind of approach deserves some discussion, whether it is pillar reinforcement or just rib support. The efficiency of pillar reinforcement (or rib support) is directly related to the initial load capacity of coal pillar, the type of excavation, and the width to high ratio of the pillar. The objective of this paper is to understand the mechanism of pillar reinforcement (or rib support) using rock bolts and steel straps on pillar ribs. Numerical simulation taking into account the relations listed above. The results showed that the increase of coal pillar strength is very short, and there is no influence on improvement of load capacity of pillar. However, the rib support avoids block falling, rib failure, and displacement, reducing the pillar failure propagation into the pillar center. Keywords: coal, pillar reinforcement, room and pillar.

Jan 1, 2006

By John Capers

•The IME is the Safety and Security Association of the commercial explosives industry in the United States and Canada. •Founded in 1913 •Board of Governors •5 Standing committees- 1. Technical 2. Environmental Affairs 3. Legal Affairs 4. Safety & Health 5. Transportation & Distribution

Jan 1, 2006

By Alfonso Nájera

Turbulent flow of liquid steel and its control is studied using different geometries of turbulence inhibitors. Four designs of turbulence inhibitors were characterized through experiments of tracer injection I a water model and mathematical simulations using the Reynolds Stress Model (RSM) of turbulence. Geometries included octagonal-regular, octagonal-irregular, pentagonal and squared. A layer of oil was used to model the behaviour of tundish flux during steel flow. Fluid flows in a tundish using these geometries were compared with that in a bare tundish. Experimental and simulation results indicate that the flow in the bare tundish and a tundish using turbulence inhibitors open large areas of oil due to strong shear stresses at the water-oil interface but the squared inhibitor. These phenomena are explained by the high gradient of the dissipation rate of the turbulent kinetic energy using the squared inhibitor. Using this device the kinetic energy reports a high gradient from the tundish floor to the free bath surface as compared with other geometries.

Jan 1, 2006

By G. J. Hasenfus

Although theoretical and conceptual knowledge regarding the impact of horizontal stress on underground coal mining excavations have existed since at least the mid-1900s, it wasn?t until the late 1970?s that the theory and practical understanding began to mesh. Since that time, particularly over the last 25 years of this Conference, increased empirical study, as well as advances in measurement technology, computer simulation, and bolt design, has significantly improved our understanding of horizontal stress impact, and provided coal mine operators with tools to reliably predict and manage it. This paper provides a retrospective review of some of the more important horizontal stress-related advancements made during the 25 years of Conference proceedings, particularly those for predicting and controlling horizontal stress impacts within underground coal mines. Relevant and significant CONSOL experiences and studies will be presented in context, with particular attention to horizontal stress considerations for longwall faces and gateroads. The significance of horizontal stress will also be placed in context with respect to local geology and structure, ground support measures, and mining configuration, method, and sequence.

Jan 1, 2006

By J. C. Gathje

Newmont&apos;s Phoenix Project is located near Battle Mountain, Nevada and is scheduled to produce copper concentrates containing high precious metal values. High temperature pressure oxidation (PDX) of the concentrates was considered as a treatment option during process development. The metals content in Phoenix concentrates range from: 15-25% for Cu, 1-10% for Zn, 0-2% for Pb and ?27% Fe. The precious metals content of the Phoenix concentrates can range up to ?300 g/t Au and >3,000 g/t Ag. As a consequence it was necessary that any process for consideration should have the capability of recovering both the copper and precious metal values. Typically, gold can easily be leached from the autoclave discharge solids, but silver is chemically bound with the jarosite formed and cannot be directly leached. Laboratory investigations led to the development of a patented PDX process that minimizes the formation of jarosite so that the silver can be leached easily along with the gold. The process was confirmed with extensive pilot plant testing. Excellent solution extraction of copper and zinc was achieved, and both iron and lead were precipitated in the PDX residue. The process produces clean PDX discharge liquors with very low iron concentrations. As an example, conventional PDX techniques resulted in pregnant liquors containing ?5 g/L Fe. However, the Newmont process, which controls the iron and sulfate species, achieved high iron precipitation in the PDX solids and pregnant liquors containing <0.5 g/L Fe. High gold and silver recoveries were achieved by direct cyanidation of the PDX solids. This process has the added benefit of producing PDX solids that demonstrate superior settling and filtration characteristics.

Jan 1, 2006