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By Ryo Sasai, Takeshi Itakura, Haruki Imaizumi, Hideaki Itoh

"Emission of industrial wastewater containing harmful oxoanions is one of the serious problems on account of its toxicity and the environmental pollution, especially caused by boric, phosphinic, arsenic and antimonic species. In this study, we developed a novel treatment technique of such polluted-water by hydrothermal mineralization. The treatment is “Geomimetic” method for precipitating oxoanions in aqueous media as natural ore resources by using hydrothermal treatment with calcium salts mineralizer. The treatment made it possible not only to detoxify the polluted-water, but also to recover the calcium minerals such as Ca2B2O5·H2O, Ca5(AsO4)3(OH), etc. Concentration of each ion in treated-water was lower than that of effluent standard in Japan. Moreover, the residual concentration of each ion was independent of the initial concentration, but it depends only on the solubility of the formed mineral under hydrothermal condition. Therefore, the hydrothermal treatment could be recommended as one of the treatment techniques of polluted-water.IntroductionVarious oxoanions such as boron and arsenic oxo-anions have high toxicity against human health and the environment. They are important resources, however, for plating or advanced material manufacturing industries[1-3], from which the wastewater containing these oxoanions is generated every day. An appropriate treatment is often required for industrial wastewaters to attain national effluent standards of Japan (NESJ, B: 10 mg/dm3, As: 0.1 mg/dm3). On the other hand, there is no production of arsenic and boric resources in Japan, and they are expected to be recycled. Therefore, the establishment of a system for the removal and recycling of arsenic and boron from wastewaters is of global significance.Several methods to remove them from aqueous media have been already reported by using adsorption[4], electro-coagulation[5], membrane separation[6-8] and biological techniques[9]. However, these methods have the following problems because of their stability in water. (1) Removal yield is low, especially for tri-valent arsenite ion (AsIIIO3 3-) and borate ion. (2) The applicable concentration range is narrow. In addition, the used adsorbents or collected residues after treatments are sill hazardous wastes, so that they must be treated by a proper method. But, it is very difficult to convert them to recyclable resources at most industrial plants. These problems are caused by the difficulty to recover these oxoanions as stable solid precipitates with low solubility in water. The establishment of recycling system of these hazardous compounds will be one of the world-important issues, especially, in Japan, which is poor in natural resources. On the other hand, compounds that contain high arsenic concentrations and are insoluble in water, are often found in natural minerals, for example, as haidinglite (Ca(AsO3OH)·(H2O) or Johnbaumite (Ca5(AsO4)3(OH)). This fact suggests that nature has an ability to produce insoluble As-bearing minerals. Similar phenomena can be found in case of boron, antimony, etc."

Jan 1, 2008

Tunnelling under squeezing ground conditions poses significant challenges. There are fundamental differences in the choice of support for mining as opposed to civil engineering. This paper reviews ground support strategies that have been used to control large deformations in mining excavations based on field data from five different mines in Australia and Canada. Recommendations are made for improved ground control strategies in squeezing rock conditions.

Jan 1, 2008

By Mick Fritz, Ryan Gilmore

The Center for Disease Control [CDC] is in the midst of a twenty year project, part of which includes demolishing existing buildings and erecting taller, more modern structures within the same foundation foot print. Controlled Blasting Inc, a large and experienced construction drilling and blasting company in Metro Atlanta, was contracted to provide the drilling and blasting for the new building foundations. Working on a construction site, in this type of environment, creates many challenges for the drilling and blasting crews.

Jan 1, 2008

By S M. C Verryn, K Deysel

In heavy mineral sands ilmenite, rutile and zircon are present in economic concentrations. These minerals are important sources of Fe, Ti and Zr for various industrial uses. The beach sands of northern KwaZulu-Natal, along the Zululand Indian Ocean coastline in South Africa, have been mined for 30 years. The various processes involved in mining and processing these minerals have been controlled by time-consuming and labour-intensive analysis methods which, in some cases, can be replaced by X-ray powder diffraction (XRD)-Rietveld analysis. Heavy minerals are concentrated in the plant to produce a heavy mineral concentrate (HMC). The heavy mineral extraction plant is controlled and informed of the proportions of minerals in the HMC according to their magnetic susceptibility. The different fractions are called magnetic, paramagnetic and non-magnetic fractions and quality control is based on their magnetic fraction weights combined with X-ray fluorescence (XRF) elemental analysis. This current quality control process is very time consuming and labour intensive. We have aimed to show that we can, by XRD, identify and quantify all the minerals in the HMC and also in the magnetic separations. These results are then compared with results obtained by Mineral Liberation Analyser (MLA) as well as with the results from the physical separation. It was possible to detect all minerals present in the material by XRD and use the Rietveld method for a full bulk mineral quantification. A maximum of 15 minerals can be included in the Rietveld refinement due to computational restraints. Major minerals detected are rutile, ilmenite and zircon and minor minerals are quartz, epidote, anatase, amphibole, monazite, magnetite, titanite and augite. The XRD and MLA results correlate relatively well and detailed results will be presented for HMC and magnetic fraction samples. Small differences were observed for some minerals due to the different ways in which minerals are detected or due to preparation methods within each method. Rutile seems to be more abundant in the XRD analysis and the detection of Anatase is possible by XRD, but not MLA. Leucoxene (consisting of mainly microcrystalline anatase, rutile and titanite is not detectable by XRD since it is not a mineral, but ilmenite alteration phases are observed instead. There is, however, a correlation between anatase, titanite and rutile detected by XRD and leucoxene analysed by MLA.

Jan 1, 2008

The future of the United States (US) mining industry will be affected greatly by recent coal mining disasters. These have resulted in new legislation which will have an impact on mining economic costs as well safety and health of miners. This paper discusses the changes that new legislation and regulations are making to the industry and current research that is producing technologies to make mining safer and will likely impact the future of mining.

Jan 1, 2008

By James Rowland, Richard Mainiero

When most people think of explosives transport they think of a hazardous operation. We all know that we aren’t allowed to transport explosives through tunnels and are discouraged from traveling through heavily populated areas. Popular opinion suggests that explosives transport is a very risky operation. The authors decided to look into this a little more thoroughly and found just the opposite to be true.

Jan 1, 2008

By Richard Jack De Klerk

The standard industrial method of arsenic removal from acidic aqueous processing effluents involves coprecipitation of arsenic with ferric iron (Fe/As>3) by lime neutralization in continuous circuits. To better understand current industrial practice, continuous circuit coprecipitation experiments were performed to identify industrially relevant process parameters and co-ion solutes that contribute to improved arsenic removal and retention. The coprecipitated solids were subjected to accelerated ageing at 20°, 40° & 70°C and arsenic behavior was monitored and modeled. Staging and the presence of calcium ions were found to have the most significant impact on arsenic retention. In this paper the techniques used and major results obtained are discussed.

Jan 1, 2008

By Moussa Wone

The Washington, DC Water and Sewer Authority (WASA) has implemented facility planning for the Anacostia River Projects portion of a program to bring its Combined Sewer System (CSO) into compliance with federal water quality regulations by 2025. The program includes approximately 19 kilometers (12 miles) of deep CSO storage/conveyance and flood relief soft ground tunnels, construction, vortex drop, overflow, maintenance and air release shafts, as well as near surface diversion structures and conveyances. The Project encompasses major technical and non-technical challenges including completion under a federal consent decree schedule, construction within the confines of heavily developed urban areas, difficult ground conditions, major infrastructure crossings, and close coordination with several major public agencies. This paper discusses the planning stage considerations related to the geotechnical investigation program, discusses obstructions that influenced alignment selection, and provides two examples of preliminary estimates of settlement induced ground movement due to the tunnel and shaft construction.

Jan 1, 2008

By Craig H. Olson

"A new ship dock at a Philadelphia area refinery will be capable of docking the largest tanker to travel the Delaware River, the Stena V-MAX, which will induce significant lateral loads. The loads at the dock, a system of mooring dolphins and platforms, will be resisted by over 150 pipe piles, including some 20- and 30-in diameter, reinforced, concrete-filled pipe piles and H-piles. Construction included driving the pipe piles to the required ultimate capacity, flushing the pipe pile casing clean of overburden materials, followed by drilling rock sockets into the underlying Wissahickon Formation. The Wissahickon Formation is a complex subsurface that includes variations in depth to bedrock, rock quality, degree of weathering and the presence of very hard quartzite lenses or inclusions. Because of the problematic subsurface, the designers and client requested extensive pile dynamic analysis (PDA) testing by TRC Engineers (TRC).Before beginning, the contractor requested that TRC perform the WEAP (wave equation analysis program) to evaluate the proposed hammer (APE D30-32 open-end diesel) to drive the piles into the proposed bearing strata while maintaining allowable compression stress levels. The WEAP provided a prediction of blow counts and stresses for various ultimate capacities, and showed that for the HP14x89 piles with a required ultimate capacity of 480 kips, a blow count of at least four blows per in at a stroke of 8.0 ft was necessary.New Approachway RampThe PDA testing began at the new dock approachway ramp, parallel to the existing one. The new structure is a 300-ft-long by 21- ft-wide concrete deck supported on seven bents; each has two 24- ft-diameter steel open-ended pipe piles. Every pipe received an HP 14 x 89 x 80-ft pile that was later driven beyond the pipe pile tip to create a composite pile. The pipe piles were later cleaned of overburden materials and finally filled with concrete and rebar. At each bent, a cap was installed on top of each pair of pipe piles, and then a prefabricated concrete deck was added."

Jan 1, 2008

By Kot Unrug

Mine seals are necessary in nearly every mine to isolate mined-out areas from the ventilation network. There is a large number of seals in active mines and that number continually increases as the development spreads across the reserves. The recent accident caused by the failure of seals in the Sago mine resulted in new regulations. These regulations have been set based on a principle of eliminating the risk of failure, rather than the sound engineering and understanding of the conditions that may cause seal failure during an explosion of methane in sealed areas of the mine including the probability of such occurrences. This paper discusses the following subjects related to mine seals: The potential causes of methane explosions and the dynamic effects of pressure wave propagation. Seal materials and methods of construction in view of the interaction of the seal with the host rock environment as well as requirements for gathering geotechnical data. The design of seal dimensions is based on loading conditions, therefore the probable ranges of such loading is reviewed. There is also discussion of possible methods for shielding of seals from pressure pulses following an explosion. Particular seal?s types are examined in reference to the conditions at the seals location. A novel design is presented that will be a low- cost solution for the sealing of mined out areas. Recommendations are given for further research leading to a rational engineering system for design of new seals in coal mines.

Jan 1, 2008

By Von L. Richards

Rapid Freeze Prototyping (RFP) is a novel solid freeform fabrication technology that creates parts by depositing water droplets and freezing them rapidly to form layers. An investigation into the smallest thickness that can be achieved by the RFP process was conducted. The factors that could significantly affect the thickness of the part built by this process including substrate temperature, volumetric feed rate, table velocity, nozzle frequency, nozzle standoff distance, and head pressure were considered. A shell building technique for use with the RFP system has been developed. Thin wall ice patterns have been invested using production shell building techniques and an alcohol-based slurry. The finished shells were quantitatively evaluated by inspecting their total shell thickness, mold cavity dimensional reproducibility, and shell strength. Pattern loss is influenced by not only the alcohol / water interaction but also the starting thickness as it relates to thermal mass.

Jan 1, 2008

By Bill Stormes

This paper will discuss implementation of the Hilti OneStep rock anchor technology to improve face bolting operations during the May 2008 longwall move; increase rock anchor installation capacity; and improve safety by reducing employee exposure periods by utilizing the Hilti OneStep rock anchors.

Jan 1, 2008

The Gordonsville Operation of Pasminco US Inc. along with the Center for Advanced Mineral and Metallurgical Processing (CAMP) at Montana Tech studied, developed and implemented a pilot-scale hydrometallurgical facility for the industrial recovery of germanium and gallium. This paper describes the joint testing and engineering programme that culminated in this successful process.

Jan 1, 2008

On Nov 1, 2007 House Resolution 2262 ? The Hardrock Mining and Reclamation Act of 2007 ? was passed by the U.S. House by a vote of 244-166. HR-2262, among other things, would impose a 4-per-cent royalty on existing mines with commercial production and an 8-percent gross royalty on all new claims. Not surprisingly, this possible new law was one of the hottest topics of discussion at the Northwest Mining Association?s conference that this year returned to Spokane, WA for its 113th annual meeting on Dec. 3-7. More than 1,800 delegates attended the conference that was held under the banner theme of ?Mining ?. For today and tomorrow.? Northwest Mining Association executive director Laura Skaer was one of many speakers during the three-day conference to respond to the threat to the industry posed by HR-2262 with a presentation titled ?Potential changes to the 1872 Mining Law.? In the presentation that she first unveiled at the Alaska Miners Association?s convention and trade show on Nov. 8, Skaer laid out a comprehensive list of problems with HR-2262. In addition to the association?s obvious concerns about the proposed royalty, Skaer noted that the bill includes a mine veto provision that would allow the Secretary of the Interior the authority to deny an operations permit to a project if the secretary determines that the operation would cause undue degradation to public lands and resources. Potential massive withdrawals from mineral entry are also included in HR-2262. Among the lands that could be off limits to miners under HR-2262 are wilderness study areas, areas of environmental concern and 23.6 hm2 (58.5 million acres) identified as Roadless Rule. States, political subdivisions and Indian Tribes would also have more authority to withdraw lands, she said. To combat the proposed changes, Skaer made 10 trips to Washington D.C. on behalf of NWMA members in 2007. In her presentation at the annual meeting, she also objected to provisions that include no life-of-mine permits and uncertain permit renewals and new and duplicative environmental standards that she said are vague, ambiguous and inconsistent with current federal and state environmental laws. Debra W. Struhsacker, an environmental permitting and government relations consultant, also spoke on the issue of HR-2262 with a presentation titled ?The House mining law bill ? Rip van Winkle is back ? and he?s meaner than ever.?

Jan 1, 2008

By Paul Downing

When was the last time the documents and paperwork were cleaned out of the glove boxes, door pockets, under the seats and above the visors in your company vehicles? Insurance cards that expired three years ago and vehicle registrations from 1999 through 2003, for instance, don’t do any good and just take up space

Jan 1, 2008

By K. V. Sreenivas Rao

Solidification experiments have been conducted to study the effect of interface heat flux and air gap formation on cooling rate of the casting during solidification of Al-4.5wt%Cu alloy. The thermal history of the casting and mold during solidification is recorded using thermocouples connected to computer interfaced data logger. The measured temperatures in the mold are used as input to the IHCP (inverse heat conduction problem) algorithm for simulating multiple heat flux components at the boundary. It is observed that the filling effects induce spatial variation in the thermal field in the mold and casting regions and greatly influence the cooling rate of the casting. The study demonstrates the use of IHCP and in-situ measured thermal profile in analyzing the cooling rate and microstructure.

Jan 1, 2008

With a growing concern over mine fires, prevention and suppression are hot topics. NIOSH researchers Michael Trevits, Alex Smith and Edward Thimons discuss their research in the area. The leading causes of US mine fires include flame cutting and, welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions and spontaneous combustion. From 1990 through 2007, there were 1601 reportable fires that occurred in the US mining industry -an average of 89 fires per year. The fact that mine fires are occurring with alarming regularity reinforces the importance of recognizing and eliminating the potential hazards. These statistics also show the need for improved control and suppression technology to ensure worker health and safety if a mine fire does occur.

Jan 1, 2008

By Matthew Janes

The new Bow office complex will become the new headquarters of EnCana Corporation, a leading Canadian oil and gas company. The shoring system, encompassing nearly two city blocks and excavated to a depth of 20.5 m, supported surrounding utilities and buildings in downtown Calgary. Past excavations in the area experienced large amounts of rock movement, the mechanics of which were poorly understood. The focus of this paper is the design process and construction results concerning rock movement and the effectiveness of the shoring structure. A lack of information regarding the local in-situ stresses and shear band propagation in the bedrock led to research of case studies in the Calgary area and a peer review from local experts. Several geotechnical scenarios were analyzed using FLAC to account for varying residual rock stresses and the location and composition of weak rock layers suspected of causing shear band movement. Movement characteristics were predicted that would identify the rock deformation mechanic throughout the construction process. A detailed monitoring programme composed of precision monitoring targets, inclinometers, and extensometers was established to provide accuracy and redundancy in establishing the movement of the rock and excavation support structure. The results of the programme were used to identify the rock deformation mechanics and further refine the FLAC analysis. To date, monitoring indicates that localized shear band effect is the leading cause of rock movement. The phenomenon appears to be directionally dependent and strongly correlated to excavation extent.

Jan 1, 2008

By A. Eslami

In recent development of piled raft design, the contribution of both raft and piles to tolerate the loads is taken into account, depending on the stiffness and contributions of involved elements i.e.; piles, raft and surrounding soil. The piles are usually required not to ensure the overall stability of the foundation but to act as settlement reducers. One alternative method of foundation design is therefore to introduce piles purely as a means of improving or enhancing the stiffness of the base soil by structurally disconnecting the piles from the raft. In this paper, two and three dimensional finite element analysis of disconnected pile-raft systems are performed on three case studies including a 12-storey residential building in Iran, a 39-storey twin tower in Indonesia, and the 256m height of Messeturm tower in Frankfurt, Germany. The analysis include different geometrical parameters, e.g., pile spacing and embedment length, arrangement and raft thickness for foundation system to obtain the optimized design functions and to clarify the role of each parameter and method of analysis. The parametric study results and comparison to a few field measurements indicate that by concentrating the piles in the central area of the raft foundation leads to the optimum design with the minimum total length of piles. This achievement can be considered as a criterion for project cost efficiency. On the other hand, disconnected piled-raft systems can significantly reduce the settlements and raft internal bending moments. Finally, the comparison indicates that simple and faster 2D analysis has almost the identical results to 3D analysis which is complicated and time consuming.

Jan 1, 2008

By M. I. Brittan

Cyanide leaching of two West African gold ores was studied in multiple laboratories to provide process-engineering data for plant design purposes. Unusually slow leach extraction kinetics were observed using routine cyanide leach test procedures with pregnant solution monitoring. Carbon-in-leach testing, however, showed normal rapid kinetic behavior, with the same ultimate gold extractions being reached in much shorter elapsed times. Kinetic curves based on washed solids assays also exhibited more typical leaching characteristics. The results bore all the hallmarks of some equilibrium inhibition of the leaching. It was surmised that ore gangue components were responsible for weakly adsorbing gold-cyanide complex reaction product, thereby holding up soluble gold in the solid phase. The term ?preg-borrowing? was coined to describe the reversible phenomenon and distinguish it from irreversible preg-robbing. The two ores investigated may represent an extreme form of a more general effect that in most instances might pass unnoticed. The effect can lead to misinterpretation of kinetic leach curve data and underestimation of calculated ore head grades.

Jan 1, 2008