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By A. Tikhonov, D. Kipper, V. Korovin, A. Olifirenko, Yu. Shestak

The present paper deals with vanadium and molybdenum sorption from industrial wastes and intermediate processing products using Cybber macroporous strong- and weak-base anionites. Vanadium and molybdenum recovery by Cybber anion-exchange resins as well as desorption processes were studied in static and dynamic modes; their efficiency was demonstrated for that purpose. The results of the work may be used to design technologies for complex processing of both ores and industrial wastes containing vanadium and molybdenum.

Jan 1, 2011

In a gravity separation device, particle shape, size and density all play a role. The combination of these determines where each individual particle reports to in the viscous fluid, where particle crowding (solids to water ratio) also plays a role. To understand the performance of gravity separation devices in the heavy mineral industry, these particle characteristics need to be measured. There are various challenges in analysing particle density and particle size simultaneously for the purpose of quantifying gravity separator performance, not to mention particle shape. These analytical challenges include the high cost of high-density sink-float fractionation, toxicity of high-density sink-float media, inability of sink-float media to fractionate at densities greater than 4.0 g/cm3, and the time-intensive nature of these fractionations. The use of the detailed particle-by-particle output from Qemscan® particle mineral analyses (PMA) as a fast and cost-effective alternative is evaluated. The size and density outputs from the Qemscan® were employed to characterize the performance of a heavy mineral spiral concentrator as an example. Critical analytical requirements are to be addressed before the Qemscan® output data can be utilized. Keywords Gravity separator, performance, heavy minerals, Qemscan® particle mineral analysis

Jan 1, 2011

By T. J. Goff

Keywords: accurate control, matte level, smelting operations, process control, tapping, sounding bar, electromagnetic measurement [ ] Accurate control of matte levels during primary matte smelting operations is desirable in order to improve process decision-making. High matte levels in the vessel could have to disastrous consequences, particularly in the new generation of intensive smelting furnace with deep-cooled copper coolers. Knowing when to commence tapping and a better understanding of melt times can only be improved if the furnace levels are monitored correctly. At Lonmin Marikana Smelter Division it has long been understood that the matte level information being provided by the manual sounding bar is only as good as the operators? following of measurement procedure, their skill in assessing what the sounding bar is displaying, and their individual interpretation of what they are looking at. This paper sets out to show how this problem was identified as an area of major concern to the plant, how a solution was sought and how an electromagnetic measurement system was installed as an alternative measurement to the matte sounding bar system. Other areas discussed in the paper are the difficulties to be overcome when first installing new equipment and how these teething problems were solved by close co-operation between Lonmin and equipment suppliers, which led to some design modifications to the delivery system. In conclusion the paper discusses the results between the electromagnetic measurement and the manual sounding measurement and how best to integrate the generated data into the plant?s process control system for improved decision making.

Jan 1, 2011

By Zong-Xian Zhang

In sublevel caving mines, serious eyebrow break usually gives rise to lower ore recovery, higher dilution, and worse safety for the people working in the field. For example, chargers must go near the caving region and stand under the damaged eyebrow where a hanging stone may suddenly fall down or rock fragments may quickly roll down.

Jan 1, 2011

By A. McLean, Q. R. Yang, Y. D. Yang, G. F. Zhang, P. Wu

A considerable amount of waste slag from the pyrite roasting process is discharged every year. Recovery of iron from the waste slag is of great interest for comprehensive use of mineral resource, reduction of environment impact and improvement of economical benefit to related companies. The objectives of the present work are focused on: (1) Compare various procedures for recovery of iron from the waste slag and select a best procedure for industrial trial which is roasting of the waste slag under reducing condition followed by magnetic separation; (2) Investigate the optimum conditions for maximum recovery of iron from the waste slag. The experimental result shows that under the treatment condition found in this work about 36 to 40% of the iron oxide was recovered from the waste slag, where the iron content in the concentrate is 57%. The total recovery ratio of iron, up to 70%, from the waste slag was achieved. After the treatment, sulphur content in the waste slag was reduced significantly and gangue materials, such as SiO2, Al2O3 and TiO2, were reduced effectively.

Jan 1, 2011

By R. Gunda

Due to the rapidly increasing production rates and deepening of mine working areas, there is a drastic rise in the number of thermal issues to be addressed for maintaining a safe mine environment. As high temperatures and humidity in underground mines could affect the health and performance of workers, and ultimately the production rate, it is necessary to provide a properly controlled safe environment. The backfilling of stopes in metal, non-metal mines results in different thermophysical properties for the hanging, side and foot walls, modeling of which is not provided by any existing mine climate simulation software. This paper presents the modeling of such a single stope using the MULTIFLUX (MF) software, developed at University of Nevada, Reno. A special case is presented in this paper, where a case study from the Homestake mine in the US with a drift and ramp connected to a stope with high Virgin Rock Temperature (VRT) and various spot heat sources is modeled in MULTIFLUX and CLIMSIM, and the results are compared against each other. Another case is presented in which the stope of the previous cases is modeled with walls, each having a different set of thermophysical properties. These results are compared with the former results to analyze the effect of anisotropic properties.

Jan 1, 2011

By J. Kang

There is increasing demand to utilize aluminium alloy sheets and their spot welds by the automotive industry. While traditional uniaxial tensile tests only determine mechanical properties to small strain, direct measurement of the constitutive behaviour of aluminium alloy spot welds at large strain remains a challenge. A technique was successfully developed using digital image correlation coupled with shear tests to directly measure the constitutive behaviour of an AA6022-T4 spot weld to large strains. The results show that the spot welding process not only decreases the yield strength but also lowers the work hardening rate of the nugget versus the base material. Details of sample preparation, experimental approach and results will be discussed.

Jan 1, 2011

By T. Hudaverdi

Several studies have been conducted on blastability and prediction of fragmentation. The term blastability is used to refer the susceptibility of the rock to blasting and is closely related to fragmentation. Parameters that determine fragmentation by blasting may be divided into two groups. The first group consists of blasting design parameters. The blast design parameters are controllable parameters and determined by the explosive engineers. The burden, spacing between holes, bench height, drillhole diameter, stemming height and explosive density are all design parameters. The second group consists of rock mass parameters that are referred to as uncontrollable parameters. The uncontrollable parameters are physical and mechanical properties of rock and rock mass structure. The strength, modulus of elasticity, density of rock, number of joint sets, joint orientation and joint spacing are among uncontrollable parameters. The rock mass parameters and blast design parameters should be considered together to explain fragmentation process. In this study, a blast database was accumulated to use for multivariate analysis. The blast database contains the blasts performed near Istanbul region quarries and the blasts that were preformed in various mines in the world by the blasting researchers. The cluster analysis was used to separate the blast data into different similarity groups. Group memberships were analyzed and checked by the discriminant analysis. Then, the multivariate regression analysis was used to develop a prediction equation for blast fragmentation for each group. Finally, a validation of the suggested models was performed for various mines. The model comprises blast design parameters, mechanical properties of rock and rock mass structure.

Jan 1, 2011

By R. Gunda

Due to the rapidly increasing production rates and deepening of mine working areas, there is a drastic rise in the number of thermal issues to be addressed for maintaining a safe mine environment. As high temperatures and humidity in underground mines could affect the health and performance of workers, and ultimately the production rate, it is necessary to provide a properly controlled safe environment. The backfilling of stopes in metal, non-metal mines results in different thermo-physical properties for the hanging, side and foot walls, modeling of which is not provided by any existing mine climate simulation software. This paper presents the modeling of such a single stope using the MULTIFLUX (MF) software, developed at the University of Nevada, Reno. A special case is presented in this paper, where a case study from the Homestake mine in the US with a drift and ramp connected to a stope with high Virgin Rock Temperature (VRT) and various spot heat sources is modeled in MULTIFLUX and CLIMSIM, and the results are compared against each other. Another case is presented in which the stope of the previous case is modeled with walls, each having a different set of thermo-physical properties. These results are compared with the former results to analyze the effect of anisotropic properties.

Jan 1, 2011

By B. K. Mishra

In order to maintain higher grinding efficiency in tumbling mills the mill interior and dynamics must be known. For this purpose, several different types of non-intrusive methods have been proposed and are being tried in the industry. We have made an effort to develop a diagnostic tool based on vibration signal. Here we discus results of our experiments pertaining to ball as well as SAG mill. In each case, a triaxial accelerometer was used to capture mechanical vibration generated due to the tumbling action of the charge. The vibration signal was transmitted to a remotely placed computer and the signals were analyzed by standard signal processing technique. In case of a ball mill (5m diameter), qualitative mill information could be obtained by correlating the vibration signal to feed rate and mill filling. An effort was also made to identify different motion characteristic of the charge by analyzing its vibration signal. In case of the SAG mill (10m diameter), liner wear was estimated by comparing the vibration signal emitting out of a freshly lined mill with that of a worn out mill.

Jan 1, 2011

By R. Heath Forbes

The route of a new, 4-mile long, electrical transmission line passed through residential neighborhoods and commercial areas of a small town in the South Carolina Coastal Plain. The new line consisted of 54 new poles and a one-mile underground section. Most of the new poles were constructed within 50 ft of existing structures, and in some cases, within 8 ft to 20 ft. A widely-space subsurface exploration consisting of 20 cone penetration test soundings indicated the subsurface conditions along the alignment generally consisted of saturated, loose to medium dense, fine slightly silty to silty sand. The pole foundations consisted of 20 to 30 ft long, prefabricated ?caissons? (essentially an open-end pipe pile with a prefabricated connection system at the top) with diameters of 28 to 56 inches. The steel caissons were installed with vibratory pile hammers. To help prevent damage and defend against possible allegations from nearby property owners, vibration and settlement monitoring was performed during all foundation installation activities. Limited structural condition assessments were also performed before and after foundation installation. For 53 of the 54 foundations, the ground vibrations recorded at distances coincident with the nearest structure locations ranged from 0.05 inches per second to 1.46 inches per second. With consideration of the dominant frequency, the majority of these values were below the commonly used USBM vibration limits. For a foundation installation that was only 8 ft from the nearest structure, a peak particle velocity of 3.06 inches per second was recorded, which exceeded the USBM limits. For all cases, the measured ground surface settlement was negligible (i.e., less than ¾ inch). Several spurious claims alleging vibration-induced damage were made, but the monitoring program provided an adequate defense. One claim involving artwork that fell to the floor during foundation installation at a distance of 8 ft from the house was deemed legitimate.

Jan 1, 2011

By S. F. Diehl

Weathered mine waste consists of oxidized primary minerals and chemically unstable secondary phases that can be sources of readily soluble metals and acid rock drainage. Elevated concentrations of metals such as Cd, Cu, Fe, Mn, Ni, Pb, and Zn are observed in deionized water-based leachate solutions derived from complex sedex and Cu-Pb-Zn mine wastes. Leachate (USGS FLT) from the Elizabeth mine, a massive sulfide deposit, has a pH of 3.4 and high concentrations of Al (16700 ug/L), Cu (440 ug/L), and Zn (8620 ug/L). Leachate from the sedex Faro mine has a pH of 3.5 and high concentrations of Al (2040 ug/L), Cu (1930 ug/L), Pb (2080 ug/L), and Zn (52900 ug/L). In contrast, higher-pH leachates produced from tailings of polymetallic vein deposits have order of magnitude lower metal concentrations. These data indicate that highly soluble secondary mineral phases exist at the surface of waste material where the samples were collected. Sulfide minerals from all sites exhibit differential degrees of weathering, from dissolution etched grain rims, to rinds of secondary minerals, to skeletal remnants. These microscale mineral-dissolution textures enhance weathering and metal leachability of waste material. Besides the formation of secondary minerals, sulfide grains from dried tailings samples may be coated by amorphous Fe-Al-Si minerals that also adsorb metals such as Cu, Ni, and Zn.

Jan 1, 2011

By Jian Li, J. Miles, P. Liu, W. Cook, W. Zheng, Alvin Qian

"High temperature corrosion resistance is one of the key challenges in water-cooled nuclear reactor material development. Iron based materials with low Cr content exhibits superior high temperature mechanical properties. However, due to the relatively low Cr content, their corrosion resistances under supercritical water (SCW) conditions are generally poor. High-Cr alloys, despite their much improved corrosion resistance, often suffer from embitterment due to the precipitation of sigma phase in the microstructure. In this study, corrosion resistance of an in-house produced high Cr steel (25%Cr) showed much better corrosion resistance compared to that of low Cr alloy (14%Cr). This high-Cr steel can potentially be used as a corrosion-resistant coating for structural materials in sew applications.INTRODUCTIONThe supercritical water-cooled reactor (SCWR) concept is one of the promising designs for the next generation nuclear reactor, in which the water coolant is designed to be at about 625°C and 25 MPa at the outlet of the reactor core. Under these relatively high-temperature and high-pressure conditions, the cooling water is at supercritical state. High-temperature mechanical properties, corrosion resistance and radiation damage are some of the key challenges. At present, no single commercial material can meet all the requirements of the severe SCWR in-core conditions. Canada supports research in several key areas of SCWR development, including materials selection. A major focus is on materials development, selection and evaluation for both in-core and out-of-core components.Allen et. al. [1] carried out a comprehensive study on the SCW corrosion resistance up to 600 °C on commercially available high temperature materials including Ni-based super alloys, various types of stainless steels and ferritic/matensitic steels. They concluded that ferritic steels develop a relatively thick but mechanically stable oxide layer, while austenitic alloys develop a thinner oxide layer that has been found to spall in some cases. Of the three types of alloys examined, the Ni-based alloys exhibited the lowest oxide thickness, however pitting was observed in the vicinity of intermetallic precipitates."

Jan 1, 2011

By N. Sahin, K. Baris, A. Ozarslan

This paper aims to assess the current and future role of coal in energy strategy of Turkey and evaluates the compatibility of the policies to the EU energy policy and strategy. The Turkish government set targets to utilize more coal reserves of the country in next decades. However, the country is also in the process of becoming an EU Member State, hence, it is expected that the energy policies have to comply with the EU. Moreover, Turkey ratified Kyoto Protocol, thus the country should limit greenhouse gas emissions. Clean Coal, Carbon Capture and Storage (CCS) technologies are expected to become an important instrument for the mid-term reduction of CO2 emissions from coal-fired power plants. An alternative technique to the conventional CCS methods is CO2 sequestration by mineral carbonation. Turkey has significant resources of magnesium silicate minerals (olivine, serpentine) deposits which can be utilised in CO2 sequestration by mineral carbonation method.

Jan 1, 2011

By Saeed Salehi Malekshah

In hybrid foundation system or piled raft foundation (PRF), the raft has adequate bearing capacity and piles are usually required to ensure overall stability of foundation and also to act as settlement reducer for high rise structures. When piles are connected to the raft, a high axial stress may develop and one alternative is to disconnect the piles from raft and consider them as stiffeners for supporting soil. This system is known as disconnected piled raft foundation (DCPRF). Cushion, a compacted coarse grained soil layer, can be used beneath the raft to redistribute and adjust the stress ratio of piles to subsoil and plays an important role in mobilizing the bearing capacity of subsoil and modifying the load transfer mechanism of piles. In this study, finite element method (FEM) has been employed to investigate the effect of different parameters such as cushion stiffness, gap height, raft thickness and piling configuration on the behavior of disconnected piled raft foundation. The analysis is performed on different foundations of hypothetical and real case histories. Results indicate that increasing the raft thickness reduces the differential settlement and pile head axial stress. Concentrating the longer disconnected piles similar to connected ones beneath the central area of raft, decreases settlement of raft. With increasing cushion stiffness, vertical stress ratio of piles to subsoil increases, but settlement decreases. Increasing gap height from 0.1 m to 1 m decreases the vertical stress ratio of piles to subsoil.

Jan 1, 2011

By Z. Hyder

Simulation and modeling is powerful tool to analyze real time data and can be used to analyze different scenarios using appropriate software that may reduce need of infield data collection process and can predict reasonably accurate results. In this paper the real time data of a mine is used to simulate and model the stresses on the pillars and evaluate the pillar strength and safety factor. The material properties assigned to the model are obtained by testing the representative samples taken from the selected locations of the mine. The mine under investigation has 50 ft wide pillars and 50 ft wide rooms under an average overburden of 650 feet. The effect of reduced pillar dimensions and increased roof span on overall stability of mine and extraction ratio is analyzed using LaModel [1] software. The predicted results of the reducing pillar size are analyzed to compares the current mining practices with the optimized room and pillar size to get better extraction ratio without comprising the safety.

Jan 1, 2011

By W. H. Schiffbauer

The protection of miners, equipment, and infrastructure is discussed. While the primary focus of the described technology is to prevent miners from being injured, struck-by, or crushed by heavy equipment; another major benefit realized is also the protection of equipment and infrastructure. An attempt is made to define and classify the systems used to provide proximity detection and warnings as well as collision detection and avoidance. Information about the speed of vehicles and human operator response time can be a factor in the choice of what type of system and what features are needed to properly address the needs. How the technology adjusts to compensate for various vehicle speeds, while maintaining the same level of protection is noted. The statistics which justify the need of miner protection are provided. The primary system components required, what attributes they feature, and how they respond in the environment, is briefly highlighted. The physics behind the danger zone marker technology and what makes it so robust and reliable is established. Examples of a few mining applications and specific operational modes are provided for both surface and underground.

Jan 1, 2011

By F. Rashchi, N. Naseri Joda

Recycling of electronic wastes is an important subject both from an environmental point of view and also the recovery of valuable materials. In this research, PC board scraps were leached to recover Cu, Ag, Au and Pd. Due to the high cost of the shredding process and to avoid secondary pollution from odors and dusts, board scraps were cut into 5X5 cm2 pieces. To determine the most effective leachant, aqua regia, nitric acid, hydrochloric acid, ammonium persulfate and potassium persulfate were tested. The effect of the leaching parameters, the leachant concentration, temperature, leaching time and liquid to solid ratio were studied and optimized using response surface methodology.

Jan 1, 2011

By S. Heukelman

Zinc or, a zinc refinery in South Africa, uses oxygen enrichment of up to 26% O2 in its fluidizing air to increase concentrate-throughput in its fluidized bed roasters. The aim of the study is to determine whether O2 enrichment can be reduced by introducing micro-pelletized concentrate into the feed blend, while maintaining concentrate throughput rates and calcine quality. A laboratory scale fluidized roaster was used to determine the strength and oxidation kinetics of suitable micro-pellets. The strength of the pellets was determined by the extent of attrition during roasting. It was found that micro-pelletization decreases the fines in the feed to the roasters; the ?500 µm fraction decreased from 87% to 10%. The micro-pelletized particles do break down during roasting, which increases the -500 µm fraction to 31%. The general morphologies of the roasted particles are similar to those found by previous workers. Micro-pelletized concentrate particles require more time than non-pelletized concentrate particles to oxidize in the roasting step, although this is less than the mean residence time of the Zincor roasters. Roasting micro-pellets in O2-enriched fluidizing air increased the reaction rate.

Jan 1, 2011

By A. Muller

The magnesia-carbon refractories used in the ConArc process experience severe wear as a result of the varying slag composition during the blowing phase. This work determines the basicity range in which minimum as well as maximum refractory wear was experienced by the magnesia-carbon refractories during service. In order to determine an optimum slag composition, the crucible test in an induction furnace was used. The magnesia-carbon refractory bricks were cut into cylindrical crucibles to which a synthetic slag in the form of pellets was added. The basicity (B2) of the slag was varied from 0.5 to 3. Tests were done at 1 600°C for one hour. Apart from the crucible test in an induction furnace, visual inspection and SEM analysis were also done to investigate the corrosion mechanism. FACTSage® predictions about the interaction between refractories and slag were also done. These predictions were compared to the actual results attained. It was found that the extent of corrosion by slag attack decreases as the basicity increases. The most severe corrosion of the MgO-C refractories occurred at a basicity of 0.5 whereas the optimum basicity is above 2.0. SEM analysis indicated severe slag attack at the lower basicities with no visible refractory-slag interaction at higher basicities. TheFACTSage® predictions supported most of the actual findings. Keywords Magnesia-carbon, ConArc, blowing phase, slag resistance, induction furnace, crucibles.

Jan 1, 2011