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By Xi-chang Shi, Yun-feng Fu, Bai-zhen Chen, Hui Xu, Xiang Xiao

"Extracting boric acid from saline brine by boron specific ion-exchange resin was investigated. Effects of resin amount, temperature, time and stirring speed on boron adsorption rate were studied in the experiments. The results indicated that the XSC-700 resin showed excellent boron absorbability and it performed better property for elution. The maximum boron adsorption capacity was 6.16 mg/ml in the optimum conditions: the resin concentration of 5 ml/(100 ml brine), the temperature of 60°C, the time of 5-6h and the stirring speed of 100 r/min. Boron was eluted from the resin with HCl and boric acid was crystallized by evaporating the eluate. The product of boric acid was in pure form as confirmed by XRD and other analysis techniques.1 IntroductionBoron has a number of minerals in nature such as tincal, colemanite, ulexite, and kemite, etc. [1-2]. Boron and its compounds are chemical materials of significant value. The principal industrial uses of boron compounds are in the production of glass, porcelain, enamels and detergents. Other uses include fertilizers, metallurgy, and nuclear shielding [3-4]. In recent years, because of the large-scale mining boron ore, ore resources are drained gradually. With the development of science and technology, the boron mineral resources will be unsatisfied with the future requirement. There exits abundant boron resources in salt lakes which cover about 40% of the total reserves in China. If we can obtain boron from salt lakes, it will produce great economic interests [5-6]. Therefore, actively seeking boron from salt lake and other resources in suitable conditions has become a hot spot in the research organizations of boron resources development and utilization in the world [7].There are many methods such as acid crystallization, solvent extraction and ion exchange processes suggested effective for boron extraction from aqueous solutions. Acid crystallization method has the shortcomings of complicated procedures, the pollution caused by hydrochloric and other ingredients returning to salt lakes during the extraction process. Although solvent extraction process increases the boron acid recovery efficiency, the cost of production is high [8-9]. However, Chelating resin extracting boron has the characteristics of simple process, easy operation and no pollution. It was reported that chelating resins containing functional groups show a high selectivity for boron extraction [10-12]. Therefore, ion exchange technique which is now the most practical application of significance and most extensively used ha"

Jan 1, 2011

By R. Patterson

Tracer gas sampling methods are useful for monitoring ventilation systems, especially in remote or inaccessible areas, and can be utilized for analysis of the ventilation system immediately following a mine emergency. However, the success of this technique is largely dependent on the accuracy of release and sampling methods. Analysis of sampling methods is crucial for rapid response and dependable results during emergencies. For the purpose of this study, four well-accepted sampling techniques currently used in the mining industry were compared using solid-phase microextraction (SPMe) fibers with sulfur hexafluoride (SF6), an industry standard, as the tracer gas. Current sample collection techniques include plastic syringes, glass syringes, Tedlar bags and vacutainers. SPMe fibers are used in a variety of industries, from forensics to environmental sampling, and are a solventless method of sampling analytes. To analyze these sampling methods, samples were taken from a 0.01 % standard mixture of SF6 and nitrogen and analyzed using electron capture gas chromatography. A relative standard error of less than 10% validated results to compare the accuracy of various methods. The technical and practical issues surrounding each sampling method were also observed and discussed.

Jan 1, 2011

By Michael W. Hinds

X-ray Fluorescence Spectrometry (XRF) is used at various stages of gold refining. Initially, incoming impure gold is analysed for deleterious elements such as As, Cd, Hg, Se, and Te. Based on the levels of these impurities the material can be returned to the client or accepted for refining. XRF is also used to determine the metal concentrations after the impure gold has been melted and sampled. This information is used to assist the final Fire Assay determination of gold and silver. An energy dispersive XRF is used to determine the end point of chlorination refining step.

Jan 1, 2011

By Donald Voit

"The reaction between zirconia/zircon, coke, and chlorine involves a slow reaction between the coke and the zirconia/zircon and a fast reaction with chlorine. Because of the fast chlorine reaction, the reaction rate for zirconia/zircon is nearly independent of chlorine concentration for most conditions. The reaction between zirconia/zircon and coke is particle size controlled and related to the degree of physical contact between the zirconia/zircon and the coke. Since particle-particle contact is critical, compaction of finely ground coke and zirconia/zircon produces the highest reaction rates. Uncompacted, coarse coke and zirconia/zircon has the slowest reaction behavior with static bed tests.SummaryZirconia reacts with chlorine in the presence of carbon to form zirconium tetrachloride, carbon monoxide, and carbon dioxide. A similar reaction occurs with zirconium silicate with the additional formation of silicon tetrachloride. The reaction rate depends primarily on temperature and the intimacy of contact between the zirconia and the coke. The reaction is multi-stepped with a slow reaction between coke and zirconia to form an intermediate that reacts rapidly with chlorine, causing the order of the reaction for chlorine to be near zero. Chlorination rates in the range of 1 µmole/hr/cm2 are seen for fluid bed reactors. Plug flow, and static bed reactors have reaction rates of the order of 1 mmole/hr/cm2, where the area is based on the zircon surface area in plug flow and fluid bed reactors and the boat cross sectional area in a static bed. Chlorination rates measured in zirconia/coke briquettes are higher with rates as high as 400 mmole/hr/cm2 reported. High chlorine diffusion resistance, not accounted for in the analysis of experimental results, has led to a lot of confusion in the literature interpretation of chlorination data.In general coke and zirconia/zircon particle size, coke and zirconia/zircon intimacy, coke to zirconia/zircon ratio, chlorine concentration, and temperature are important variables for chlorination. Decreasing the coke and zirconia/zircon particle size generally increase the reaction rate. The coke to zirconia/zircon ratio affects the reaction in a more complex way. Increasing the chlorine concentration generally increases the reaction rate, but the effect appears to be more related to the concentration dependency of diffusion than to its role in the kinetics. The reaction rate increases with temperature but the exact behavior is complicated by temperature effects on diffusion."

Jan 1, 2011

By R. Benito

This paper describes the development of a life of mine schedule (LOM) for one of the world?s largest known sedimentary Copper-Cobalt districts located in the Katanga Province, Democratic Republic of Congo (DRC). A particular feature of the Tenke Fungurume LOM schedule is the considerable number of pits/phases for scheduling, each competing to provide the best ore available to a capacity constrained process facility. This paper discusses the main scheduling objectives and constraints, data pre-processing as a scheduling aid, the mine scheduling approach, and results and conclusions.

Jan 1, 2011

By M. Hamarat

Freeport-McMoRan Copper & Gold (FCX) is committed to preserving and enhancing biodiversity in the areas in which we operate. As a member of the ICMM, FCX is committed to implement the 10 Sustainable Development (SD) Principles throughout our business. FCX is also a member of the Wildlife Habitat Council (WHC), a nonprofit coalition dedicated to protecting and enhancing wildl ife habitat. In alignment with ICMM SD Principle 7 and our Environmental Policy, FCX has set a performance goal to prepare a biodiversity inventory in 2010 and land management plan by end of 2011 for all active mining sites. In 2010 FCX established a Biodiversity Task Force to assist sites in biodiversity management; optimize use of resources around the globe; implement FCX goals and targets; and align biodiversity programs with ICMM principles and guidance. The task force consists of Environment and SD Department management, scientists and engineers from FCX sites, and WHC staff. The Task Force recently issued a biodiversity inventory guidance document to set expectations and provide consistency across the sites when developing a biodiversity inventory and land management plan.

Jan 1, 2011

By D. Q. Cang, G. Duan, H. X. Li, H. Bai

"Life cycle assessment (LCA) is a valid environmental evaluation method and enterprise environmental management tool used in industrial ecology areas. In this paper LCA was newly used to evaluate the environmental impact of manufacturing of alumina by Bayer process in china from two aspects of logistics and energy flow, GaBi software acted as analysis tools with evaluation model established, and several environmental impact assessment criteria were selected based on the actually typical date of Bayer alumina producing process. Evaluation results show that alumina manufacturing by the Bayer process has a great impact on the global warming and human health of respiration, even roasting process gives rise to the greatest impact of winter fog index. Scenario analysis proposed ways of reducing environmental load caused by Bayer process including: (1) the economic and efficient use of mineral processing technology; (2) optimization of energy use, saving power consumption or the use of new more economical source of energy; (3) actively promote the use of innovated technology and equipment in alumina manufacturing and waste such as red mud utilization process.1 IntroductionSince 2002, China is already the world's biggest producer of aluminium, in 2007, China aluminum production has accounted for above 1/3 all over the world, 2009 for 13 million tons and to the end of 2010, China aluminum production is expected increased to be over 15 million ton [1,2,3]. While as the raw material for producing aluminum the alumina production in china has up to 19.46 million tons of the world's total quarter in 2007, by the end of 2009 China alumina production has achieve to 23.78 million tons [4,5]. China has rich bauxite resources with proven reserves about 23 million tons, but the great majority of china bauxite is hard monohydrate diaspore type with low ratio of aluminium silicon, high impurity content and poor aluminum dissolution performance, that cause high energy consumption, long and complex process, high production costs and heavy environment load[6,7]. Before most used alumina production was sintering process rather than Bayer method in china, over the past decade Bayer method has been widely applied instead of sintering process or combination both forming joint process, premise is improving bauxite quality by mineral processing or adding imported rich bauxite mineral[6,8]. In general each ton production of alumina needs bauxite 1.6~2.20t, limestone 0.7~1.7t, soda 0.250kg, fresh water 12.30 cubic meters, in addition to consume large amounts of energy, and emission waste water over 8.0 cubic meters, dust 2.3~5.7 kg, red mud 0.8-1.5 tons. In china Red mud yield nearly 30.0 million tons every year, accumulated stock is approximately 0.2 billion tons, by 2015 accumulative total red mud is expected to reach 0.35 billion tons [9-13].We know aluminium industry and alumina production have produced large waste, make large energy consumption and its environmental impact could not be ignored. Expecting to optimize production processes and achieve resource recycling for this industrial process the proper environmental assessment is very necessary. Currently Life Cycle Assessment (LCA) is generally recognized as the approved tool to achieve the purpose. The essence of LCA tool is to examine, identify and evaluate a kind of materials, product, process, or a system of environmental impact in their whole life cycle. The life cycle of materials or products includes whole process from raw materials obtained to the final disposal, or more ideal with original or other forms of the whole process of recycling [14-17]."

Jan 1, 2011

By D. Sediako

Excessive residual stress in Al engine blocks may result in cylinder distortion which reduces engine operating efficiency. As such, neutron diffraction was used to measure residual strain along the Fe liners and Al, in the hoop, radial and axial orientations with respect to the cylinder axis, at the cylinder interbore region. Residual stresses were subsequently calculated using generalized Hooke's law and related to the microstructure along the cylinder bridge. The results suggest that the residual stresses in the Al interbore region are tensile and increased with depth in the axial direction of the cylinder. The increase in residual stress at the bottom of the cylinder coincides with a finer and more uniform microstructure in this region of the cylinder. The refinement in microstructure at the bottom of the cylinder likely increased alloy strength, thereby decreasing this section's susceptibility to distortion. This study successfully quantified the residual stress profiles in a heat treated engine block and related the stress profiles to an as-cast engine block.

Jan 1, 2011

By C. C. Pretorius

3D seismic surveys have become a well-accepted method of imaging sub-surface geology in the Bushveld Basin. Because both the seismic sources and receivers are placed at surface, most surveys are limited to imaging faults with >=7 m throw. However, some areas such as shaft infrastructure can benefit from the ability to detect smaller structures prior to shaft sinking. Borehole radar and logs such as the acoustic televiewer can identify these structures in the shaft barrel, but not within -200 m from the shaft. Therefore, Anglo Platinum has developed the method of high-resolution 3D vertical seismic profiles (VSPs) for structural sterilization of shaft sites prior to shaft sinking. VSPs utilize a surface source and sub-surface receivers deployed down a borehole. This means that seismic energy goes through the near surface only once, and therefore suffers less frequency loss than when both source and receivers are on surface. Furthermore, VSPs can record 3 component (3C) data which comprises P wave, Sh (horizontal) and Sv (vertical) wavemodes. Because S waves travel at about 0.6 of the velocity of a P wave, shorter wavelengths and therefore higher resolutions are possible using S wave data. VSPs were first used in their one dimensional, zero offset, mode to correlate borehole geology with seismic stratigraphy within seismic surveys. This showed that VSPs record -30% higher frequencies than surface seismic surveys. The program then applied two dimensional VSPs to the problem of imaging geological structure close to a borehole. 2D VSPs confirmed that high frequency results could be achieved, and that this enabled a more accurate image of the Merensky Reef than could be achieved by surface seismic data. Finally, the program has achieved the successful recording and processing of 3D VSP data, with both compressional and shear wavemodes giving a high resolution structural result. Although P wave data gives -30% frequency improvement over surface seismic surveys, S wave data can give as much as 80% improvement, further improving the structural image achieved. The high fixed costs of VSP surveys mean that they should ideally be run in multi-client batches, which can reduce the per borehole cost by up to 50%. Their application is anticipated to be on high value capital infrastructure with a geological risk from faults which are not imaged by surface seismics-generally in the sub-7 m range. Keywords VSP, 3D seismic, bushveld, platinum, resolution, imaging, shear waves, shaft sinking.

Jan 1, 2011

By M. A. Marois

This paper proposes an improved temporal stability condition for the implementation of an inverse heat transfer method for predicting the time-varying bank thickness of the phase change protective bank inside a high temperature furnace. The direct problem is handled with the enthalpy method. The inverse method rests on the Adjoint Problem and the Conjugate Gradient Method. It is shown that the temporal stability condition for the inverse phase change problem relies on the time delay of the temperature measurements. Results indicate that this time delay is proportional to the heat diffusion time including heat diffusion through the mushy zone.

Jan 1, 2011

By D. Rahal

All ores have an economic optimum particle size (Wills and Napier-Munn, 2006). This optimum value is often a compromise between the need to achieve adequate liberation for the efficient separation and recovery of valuable minerals and the energy consumed by the crushing and grinding process. It has been recognized for nearly three decades that grinding is the most expensive and least efficient stage in mineral processing (El-shall and Somasundaran, 1984). At that time it was estimated that grinding consumed between 25 and 70% of the total power required in mineral processing. This recognition drove the development of new stirred mill fine grinding technology in the 1990s (Jankovic et.al, 2003; Enderle et. al., 1997; Massey, 2008). These milling technologies have a reduced energy consumption compared to traditional fine grinding using ball mills. In the ?coarser? fine grinding applications this improvement is approximately 30%. The benefits increase to above 50% in ultrafine grinding applications (Lichter and Davey, 2006). Despite these gains, the US Department of Energy reported that an additional energy savings of up to 37% is possible in the minerals industry. They identified continuing research and development and implementing best practices in both grinding and materials handling as the primary avenues for the additional reduction (BCS, 2007).

Jan 1, 2011

By Rajesh Sonkar, Sanjeev Kumar

The deployment of Dragline machines in opencast coal projects involves huge capital expenditure as well as operating costs. The mine operators always endeavor to ensure smooth excavation of material by the Dragline machines while meeting the major objectives of safety, minimal disturbance to environment and optimal operating costs. Optimization of fragmentation through well designed blasts is fundamental in meeting part of the objectives is good fragmentation of rock or mineral proposed to be lifted by the Dragline machine. If the overburden lying over mineral is not properly fragmented, it may result in formation of ‘Toe’ the removal of which is the most arduous task in opencast coal mines. The mine operators always endeavor to achieve best possible results in blasting to ensure smooth operation of the high cost Dragline Machine. However, despite continuous efforts by the blasting engineers involved in bench blasting for the machine, the formation of ‘Toe’ is an ever nagging problem faced in large opencast coal projects eventually reducing the overall operational efficiency of mining.

Jan 1, 2011

By Michel Ruel

"PID loops – also known as base layers or regulatory controls – form the foundation of any plant’s control layer and it is generally accepted that PID loop health has a direct impact on the plant’s bottom line. Keeping these thousands of control loops in good health has a direct impact on the plant’s bottom line: it reduces variability, improves quality and throughput, and decreases energy costs and raw material usage. This has been well proven and documented in many articles. In the last ten years, technology has evolved: control engineers can now keep track of control loop performance and link it to the root causes of variability. However, they lack industry-wide best practices and criteria for determining what can be considered as excellent, good, fair, or poor performance. To ensure that PID control loops continue to perform well and meet their objectives, control engineers need a combination of (a) an appropriate monitoring technology and (b) best practices for doing the maintenance of base layer controls.Most plants have limited resources and operate with an increasing number of constraints; therefore, using the right tools and including reports in daily workflow is key for success. This paper suggests roles and responsibilities of key players needed to work toward control performance best practices and discuss organisational changes to succeed.INTRODUCTIONAlthough PID controllers are reliable workhorses in the process industry, they are often underrated. Since the 1980’s, computer control has evolved and the control algorithms used by control engineers have become increasingly complex. However, PID controllers still handle over 90% of the control loops in operating plants. Table 1 shows the savings that can be realized by achieving best-practice in several different process control categories (Brisk, 2004). The savings are expressed as a percentage of production costs."

Jan 1, 2011

By Gary E. Sherman

Preliminary economic mining feasibility studies were conducted by the Bureau of Mines to estimate mining costs in the Juneau gold belt area of the Juneau Mining District, southeastern Alaska. Investigations were conducted on the economics of two mineral deposit types: (1.) Berners Bay vein gold deposits, and (2.) stockwork gold deposits containing gold, silver, and lead. Cost estimates were developed using the Bureau of Mines Cost Estimating System (CES). Discounted cash flow return on investment (DeFROI) was calculated using the Bureau's MINSIM computer program. Underground mining of a Berners Bay vein gold deposit was found to be economic (15 pct DCFROI) at a recoverable metal value of $353.67/mt for a 100 mtpd shrinkage stoping mine with a 10 yr mine life, $324.76/mt for a 20 yr mine life, $138.63/mt for a 500 mtpd longhole stoping mine with a 10 yr mine 1 ffe, and $127.50/mt for a 20 yr mine life. Block caving mining of a large stockwork gold deposit was found to be economic at a recoverable metal value of $15.28/mt for a 18,000 mtpd mine with a 20 yr mine life.

Jan 1, 2011

By M. Rufli

Until not so long ago most ring geared mills were operated with fix speed motors only. By using the latest generation of medium voltage frequency converters, new possibilities have arisen to improve the grinding process. Beside all the direct and indirect advantages, several dedicated functions have now been implemented for ring geared grinding mills in the minerals industry. The sophisticated operational functions ensure a smooth, safe and reliable operation with minimum stress for the mechanical equipment and therefore utmost availability of the mill. Several papers have already been presented concerning the benefits of using this state of the art technology for mill drives. Now this paper is focusing on the experiences gained with this kind of sophisticated ring geared mill drive system rather than only show and explains the operational benefit of the different functions. Several measurements of different operating conditions, starting, frozen charge remover, controlled roll back, backlash, etc., made on an installed and commissioned 2 x 5 MW dual pinion ring geared mill drive system will be shown and discussed. The accuracy of the load sharing between the two 5 MW motors during starting, normal operation and stopping will be demonstrated using real measurements from an operating system. Finally the inherent features of these drive systems are briefly discussed.

Jan 1, 2011

By A. K. Smith

Overexposure to noise remains a widespread, serious health hazard in the U.S. mining industry. Most other categories of illnesses and injuries associated with mining have improved, with the exception of hearing loss. U.S. Mine Safety and Health Administration (MSHA) coal noise data from 2000-2004 show that the continuous mining machine (CMM) is first among all equipment, accounting for 35% of noise overexposures. Joy Mining Machinery, in collaboration with the National Institute for Occupational Safety and Health (NIOSH), is conducting research to reduce noise generated by continuous mining machines. This paper describes a "JOY Designed for Noise Reduction" (JOY DNR; patent pending) tail section as a noise control for reducing the noise overexposures of CMM operators. Underground testing shows a 45% to 65% noise exposure reduction for the operator when comparing the JOY DNR tail section results to those for a standard machine. Utilizing this newly developed noise control, along with previously proven controls, will provide CMM operators an opportunity to be within the MSHA permissible exposure limit (MSHA-PEL). Mining Engineering, 2011, Vol. 63, No. 7, pp. 83-85. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By T. D. Chatwin

While new jobs and taxes are major incentives for support of mining, stakeholders must also be assured that current jobs, resources and environment will be protected. Mining companies can help achieve stakeholder support by frankly addressing Acid Rock Drainage CARD) issues. To prevent ARD, miners must begin early in the mine life-cycle to develop an ARD management plan and integrate it into the mining operation. As this proactive preventative program is initiated, mining companies also need to engage and collaborate with stakeholders to insure that their expectations and needs are met. Stakeholder engagement is enhanced as mining companies emphasizes the value of clean and available water for current and future generations.

Jan 1, 2011

By A. Kale

A chlorination pilot plant having capacity to produce 5?10 kg/hr of titanium tetrachloride is in operation at the chlorination facility in Mintek. The bubbling fluid bed chlorination plant can be operated in batch and/or continuous process to study the chlorination kinetics of various feedstocks. The chlorination of titaniferrous ores to produce titanium tetrachloride (TiCl4) was carried out during the commissioning of the pilot plant and also as part of the titanium programme carried out at Mintek. TiCl4 is a basic raw material for producing commercial titanium dioxide pigment and titanium metal. This paper discusses the challenges faced during the commissioning and operation of the chlorination pilot plant. It also discusses the effect on the auxiliary facilities and instrumentation as a result of the harsh operating conditions of +1000°C and use of corrosive gases like chlorine and titanium tetrachloride. It discusses the effect of physico-chemical properties of the titanium tetrachloride and iron chlorides. The effect on the chlorinator refractory lining due to heating and cooling of the chlorinator is also discussed. Besides the special provisions made during the design of the chlorinator, this paper also discusses the operational experience and possible solutions to be implemented in future. Keywords Fluid bed chlorination, titanium ore chlorination, titanium tetrachloride (TiCl4) production using fluid bed technology.

Jan 1, 2011

By Les R. Chernauskas

Driven pipe piles are commonly used for near and offshore structures due to their omni-directional bending resistance, large surface area, and ease of installation. However, these piles typically cannot be driven deep enough to develop significant and sustained uplift capacity, and in some cases do not generate enough end-bearing resistance before being overstressed during driving. When driven closed-ended, their relatively light weight to cross-sectional ratio, and when driven open-ended their tendency to prematurely plug, are some installation short comings. Spin Fin® piles are traditional pipe piles fitted with flat, steel plates (?fins?) attached at a slight angle over the lower few feet of the pipe. Their design development dates back several decades for projects associated with harsh, limited weather window, offshore Alaskan oil field work. These projects required a pile type that could generate high and sustained capacity in both compression and tension, at relatively shallow depth. During pile driving, a relatively short, high capacity pile translates into more rapid installations with smaller and more efficient equipment. In this type of environment, where pile capacities are large, cyclic loading is typical, and relatively high pile movement is tolerable, the Spin Fin® pile is a superior solution. This paper describes the experience of using Spin Fin® piles on several recently completed Massachusetts Steam Ship Authority projects.

Jan 1, 2011

By I. J. Barker

Keywords: Submerged-arc furnace, plasma furnace, d.c. furnace, scale up, Søderberg electrodes, smart grid, demand side management, load shedding This paper argues that the scale up of furnaces and the supply of electricity are going to be two major issues that will affect the ferro-alloy industry in the near future, and that economic factors will drive this development. The most common type of furnace for producing ferro-alloys at present is the submerged-arc furnace with three electrodes, fed from a three-phase a.c. electrical supply. The scale up of this technology has now reached a fundamental constraint, which is caused by the electrical reactance of the secondary circuit. If the economy of any further scale up is to be achieved in the future then a different technology will have to be used. The supply of electrical power in future is likely to become a more complex issue than it is at present. Existing submerged-arc furnaces tend to run at fairly steady loads, but the ability to swing the load under demand-side management may offer advantages, and may allow a furnace to get cheaper power from the organisations that supply this power. This will have to be counterbalanced against the nuisance factors incurred by having a varying load in the operation of the furnace. Various options are therefore discussed in this paper. The possibility of scale up of Søderberg electrodes is discussed, as well as the use of d.c. power and multiple electrodes. Some of the issues with load swinging are also examined. A particular scenario is also briefly presented to show that considerable further scale up of ferro-alloy furnaces is still possible.

Jan 1, 2011