Search Documents

By K. V. Sreenivas Rao

Solidification experiments have been conducted to study the effect of interface heat flux and air gap formation on cooling rate of the casting during solidification of Al-4.5wt%Cu alloy. The thermal history of the casting and mold during solidification is recorded using thermocouples connected to computer interfaced data logger. The measured temperatures in the mold are used as input to the IHCP (inverse heat conduction problem) algorithm for simulating multiple heat flux components at the boundary. It is observed that the filling effects induce spatial variation in the thermal field in the mold and casting regions and greatly influence the cooling rate of the casting. The study demonstrates the use of IHCP and in-situ measured thermal profile in analyzing the cooling rate and microstructure.

Jan 1, 2008

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By R. Wensel

A composite material consists of two or more dissimilar components. These dissimilar components retain their identities when mixed together and contribute to the properties of the composite. A composite usually consists of two parts, the matrix and the reinforcing material, or extender that is added to the matrix. Typical materials used as the matrix in composites are metals, polymers, and ceramics. The reinforcing material can be added for any number of reasons. For instance, if the matrix is expensive, an inexpensive filler may be added to the matrix to lower the cost of the product without sacrificing properties. An example of this is calcite (CaC03) which is added to systems such as polyvinyl chloride (PVC), to lower the cost. Reinforcements may also serve as a means to enhance the properties of the matrix material. For example, carbon fibers are frequently added to plastics to increase their strength, and glass spheres may be added to plastics to improve flexural strength. Mg(OH)z is added to polymers to give the property of fire retardancy. The latter is the focus of this paper.

Jan 1, 1995

By Atta Ur Rehman, Kwame Awuah-Offei

This paper examines the effect of bucket geometry (cutting-blade profile, floor profile and blade thickness), speed, motor power output and muckpile particle sizes on bucket penetration and draft for rubber tire loaders. The work uses a 1:16 scale model of a load-haul-dump (LHD) in full-factorial experiments to examine the effect of the variables on penetration and maximum draft. The results show that speed and motor output are positively correlated with penetration and draft, and muckpile particle size is positively correlated with penetration and negatively correlated with draft (p < 0.0014).

By Atta Ur Rehman, Kwame Awuah‑Offei

This paper examines the effect of bucket geometry (cutting blade profile, floor profile, and blade thickness), speed, motor power output, and muckpile particle sizes on bucket penetration and draft for rubber tire loaders. The work uses a 1:16 scaled model of a load-haul-dump in full factorial experiments to examine the effect of the variables on penetration and maximum draft. The results show that speed and motor output are positively correlated to penetration and draft; muckpile particle size is positively correlated to penetration and negatively correlated to draft (p < 0.0014). The results show that buckets with a semi-spade cutting nose profile yield the highest penetration (mean 118.30 mm) followed by those with the spade (mean 108.88 mm), which also yield higher penetration than those straight blades (mean 95.19 mm). Bucket floor profile and blade thickness had no significant effect on penetration or draft. Also, we determined that increasing the speed and motor power output, simultaneously, can reduce bucket penetration. Thus, operators should not waste energy for no additional gain or even loss in bucket penetration. Also, the work finds speed and motor power output each combine with muckpile particle sizes to affect bucket penetration. This research furthers our understanding of the effectiveness of different bucket geometries in improving penetration and reducing draft for rubber tire loaders.

Oct 29, 2021

By A Nigam, K Biswas, R Sarkar

Because of the problems with 1st and 2nd generations of Advanced High-Strength Steels (AHSS), a 3rd generation of AHSS steels has become prominent and these steels have properties in between the 1st and 2nd generations of AHSS. However, although the 3rd generation of AHSS is a promising candidate as a replacement for its predecessors, there remain some challenges in processing these steels which are essentially medium Mn (Mn content ~ 5–7 wt per cent) and high Al (Al content ~ 1– 3 wt per cent) steels. The use of conventional casting powders based on the CaO-SiO2 system is unsuitable for high and medium Mn/Al steels. This work investigates the development of CaO-Al2O3- based mold fluxes for casting third-generation AHSS steel. Mold fluxes, with otherwise similar compositions but different C/A ratios, are tested and their crystallisation behaviour is examined using differential scanning calorimetry (DSC). A calcium aluminate phase having a composition Ca12Al14O33 was found to be the main crystalline phase in the mold fluxes. A decrease in crystallisation temperature was observed as the CaO/Al2O3 ratio increased from 1.00 to 1.33. The effective crystallisation rate constant exhibited an increase with decreasing crystallisation temperature, indicating a potential influence of nucleation rate on the overall crystallisation rate and suggesting an anti-Arrhenius behaviour in the crystallisation process of these mold fluxes.

Aug 21, 2024

By CHENCHEN SUN, GUOPING LUO, GUOCHENG ZHANG

Preparation of briquettes by adding CaF2 reagent into the Australian iron ore powder. The structure and morphology of iron ore briquettes during various reduction stages (i.e., Fe2O3→Fe3O4, Fe3O4→FeO, and FeO→Fe) were observed via an ore microscope and scanning electron microscopy. The results showed that CaF2 reacted with SiO2 to form CaO and SiF4 gas during the roasting process. The reduction swelling index decreased from 12.36 to 8.83% when the CaF2 content in the briquettes increased due to CaF2-mediated refinement of the hematite grains during the first stage of the reduction process. Lattice distortion resulting from the presence of Ca2+ in the FeO lattice during the second stage of the reduction process, coupled with an increase in the porosity of the iron ore briquettes and the formation of a low-melting-point slag phase, promoted the anisotropic growth of FeO lamellar crystals, which resulted in an increase in the reduction swelling index from 4.27 to 7.36%. During the third stage of the reduction process, the growth of iron whiskers was promoted by wüstite (FeO) lattice distortion caused by a solid solution of Ca2+ in the FeO lattice; the reduction swelling index increased from 15.61 to 24.72%, resulting in the catastrophic swelling of the iron ore briquettes.

May 27, 2021

By CHENCHEN SUN, GUOPING LUO, GUOCHENG ZHANG

In this study, the conditions of raw materials and fuels were simulated for Bayan Obo iron ore concentrate by adding pure calcium fluoride (CaF2) in various concentrations to Australian iron ore. The mechanism by which the fluorine (F) content of the lattice influenced the reduction swelling properties of the iron ore briquettes during various stages of the reduction process was investigated. The results provide insight into the mechanism governing the reduction swelling process in Bayan Obo ore briquettes, which could be used to direct real?world production practices, particularly those related to the rational utilization of Bayan Obo ore resources.

By S Hapugoda, H Han, L Lu

Charcoal produced from Syzygium Zeylanicum trees was widely used in ancient Sri Lankan iron smelting practices. Charcoal made from Syzygium Zeylanicum tree trunks, branches and leaves were analysed by optical mineralogy and SEM and found to contain unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOx) crystals in plant cells. Partial and full reduction tests of a high-P Brockman ore were conducted at several temperatures with coke and coke doped with CaOx and CaCO3. It was observed that CaOx promoted reduction and generated comparatively more metallic iron in reduced samples. Furthermore, CaOx encouraged phosphorous partition into slag phases than into the metallic iron, suggesting CaOx can a potential alternative fluxing material to calcium carbonate for treating high-P iron ores in ironmaking processes.

Sep 18, 2023

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, David Grimsey, Denis Shishin

"An integrated nickel flash smelter is operated with Peirce-Smith converters at the Kalgoorlie Nickel Smelter. To improve the partitioning of arsenic between slag waste and matte product, an option to modify the slag–matte chemistry by addition of CaO was analysed. A combination of plant sample analysis, high-temperature laboratory experiments and thermodynamic modeling was carried out to evaluate the process options. The high-temperature experiments involved the re-equilibration of industrial matte-slag samples at 1225 °C and P(SO2) = 0.12 atm, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LAICPMS). A private thermodynamic database for nickel sulfide smelting and converting was used together with the FactSage thermochemical software package to assist in the analysis of the distribution of elements between slag and matte as a function of CaO addition. The thermodynamic predictions combined with experimental data obtained in this study can be used to characterise the effect of CaO fluxing on the slag–matte thermochemistry during the nickel sulfide converting.INTRODUCTION At the Kalgoorlie Nickel Smelter (KNS), nickel sulfide concentrate is processed in an Outotec-type flash furnace to produce nickel matte containing +47 wt% Ni. Separation of nickel matte and waste slag from the flash smelting is enhanced through settling in the electric arc -heated zone attached to the flash furnace. The flash furnace matte is further processed in a Peirce-Smith converter to produce Ni-rich matte containing +66 wt% Ni (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011). Iron silicate-based slag is used in the converting process at KNS. Most of the arsenic is contained in the final matte and very little of the arsenic partitions into the slag. Previous work by Font et al (Font, Hino, & Itagaki, 2003) shows that the distribution ratio of arsenic between calcium ferrite slag and nickel-matte (LAsslag/matte) is significantly higher than that between iron silicate slag and nickel-matte, where LAsslag/matte = (wt pct As in slag)/{wt pct As in matte} (1)"

Jan 1, 2017

By H Park, V Sahajwalla

"Due to the increasing amount of gangues in iron ores, a beneficiation process is required more as a preliminary step for ironmaking process. However, mechanical grinding and washing of iron ore needs tremendous effort that increases operating cost. Therefore, there is a necessity of a novel approach to ironmaking which can tolerate considerable amounts of silica or alumina. In the present study, a high alumina-carbon composite pellet was examined for an ironmaking process. The effect of compositional changes in the CaO-FexOy-Al2O3-SiO2 oxide system on the reduction of carbon composite pellets was investigated in a purpose built thermo-gravimetric analyser (TGA) at 1473K (1200¦C). As a result, alumina increased the reaction rate of carbon composite pellets by increasing surface area, while silica decreased the reaction rate by lowering surface area of samples. Infrared gas analysis assisted with the reaction kinetics of carbon composite pellets through measurement of CO and CO2 in off-gases. This study will assist with establishing the new pelletising method which differs from the conventional fluxed pellets.CITATION:Park, H and Sahajwalla, V, 2013. Effect of CaO-FexOy-Al2O3-SiO2 oxide system on the reduction of carbon composite pellets, in Proceedings Iron Ore 2013, pp 467-472 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

"In the present study, the reduction behavior of composite pellets comprising of iron oxide, synthetic graphite and slags were investigated in a laboratory-scale horizontal tube furnace. Two different types of slags indicating silicate base and aluminate base slags were chosen to examine the effect of slag chemistry on the reduction behavior of pellets. Slag composition of binding materials has influences on the reactions occurring in composite pellets during direct reduction. In-situ high temperature visualization approach was used to observe the slag / iron / carbon interactions at 1773K (1500°C). The off-gases were measured by means of infrared analyzer to determine the reaction rates of the pellets. Different physical appearances during the in situ reaction inferred a strong correlation between the slag composition and internal reactions. In addition, compression tests were conducted to examine physical strength of the pellets. This investigation was carried out to establish feasibility of physical property control of pellets by selecting optimum slag compositions of binding materials INTRODUCTIONCurrently, most of the iron ore mines have facilities that make an ore more usable for the blast furnace operation by improving its physical properties (e.g. pelletizing and sintering). However, during the process, a large amount of fuel is supplied to indurate materials which consequently deteriorate energy efficiency and produce more CO2 emission. Along with increased interests, direct reduced iron (DRI) making process; simply without coke oven or sintering process, has opened the era of clean and environmental friendly iron making process. While some of the established DRI technologies such as Midrex and HYL were restricted to certain locations where natural gas is abundant, coal based technologies using Rotary Hearth Furnace (RHF) such as FASMET and ITmk3 have been developed with regardless of expensive fuel deposit. In addition to the direct use of pulverized non coking coal and fine iron ore, RHF process also has advantages of utilizing waste materials such as EAF dust, biomass and recycled plastics. Nevertheless, there are still many challenges in the coal utilizing technologies as the unprocessed coal and the waste materials contain huge volatiles and ashes. Although recent investigations on volatiles in a RHF process (Sohn and Fruehan, 2005, 2006) have indicated the benefits of coal in terms of iron oxide reduction and have shown feasibility of multi-layer process, carbon composite pellets still have disadvantages because of its weak mechanical bonding strength. As the mixed system with carbon and oxides generates intermediate gases (e.g. CO and CO2) between solid particles, it is difficult to keep its physical state without the help of binding materials. In this reason, industries have been tried to use various binding materials such as bentonite, kaolinite and Portland cement. However, they are still struggling to find out new materials that provide not only sufficient mechanical strength but also metallurgical properties, such as porosity, reducibility and swelling throughout the reduction reaction. Recently, Canadian researchers (Aota et al, 2006) observed enhanced mechanical strength of pellets by using high alumina cement as a binder and concluded that the method could be used to recycle EAF dust as well, but in depth mechanism of reinforced strength has not been concerned. Most of the ashes coming from binders formulate certain type of slag during the reduction process due to its incombustibility. Thus, observation and regulation of slag property is an essential for the control of carbon composite pellet. Yet, only a little thermodynamic consideration from the perspective of slag chemistry has been adapted in the iron and steel making industries as ash has been easily ignored for its tiny proportion. In this study, effect of CaO-SiO2- Al2O3 slag system on the reduction of iron oxide was investigated in terms of"

Jan 1, 2012

By Z. Q. Chen, M. H. Loretto, Y. G. Li

"As-cast, As-forged, as-solution-treated, and solution treated and aged microstructures of Ti-15Mo (IMI205) with and without carbon were examined using optical microscopy, scanning electron microscopy .and transmission electron microscopy. Tensile testing was carried out at room temperature. It was found that carbon acts primarily as a titanium carbide former: Titanium carbides increase slightly the tensile strength, but decrease the ductility of IMI205. These observations are interpreted in terms of the titanium carbide morphology observed using SEM and TEM and the phase diagrams of Ti-Mo, Ti-C, and Mo-C.IntroductionIn a recent study on the development of a burn-resistant 13-Ti alloy, carbon was introduced· into the Ti-V-Cr system in order to optimise the mechanical properties. Research results[1, 2] demonstrate that carbon addition can refine the 13 grain size and improve the stability of the 13 phase in Ti-V-Cr alloys. The most attractive result is that carbon addition produced a marked improvement in the ductility of alloys when the carbon content is over 0.1 wt.% in this alloy system. Even after long exposure, the alloy with carbon addition maintains good ductility. One of the main reasons for the ductilising of the alloy is that titanium carbides can getter the oxygen from the 13 matrix.In view of the success of carbon addition in improving the properties and the stability of the Ti-V-Cr alloy, it is of interest to investigate the behaviour of carbon addition in other beta Ti-base alloys. The objective of the present work was, therefore, to assess the microstructures and mechanical properties of IMI 205, a metastable beta titanium alloy, with and without carbon addition using optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), wavelength dispersive X-ray (WDX) analysis, room temperature tensile testing."

Jan 1, 2000

By García B., Wolff E.

The pellet qualities primarily depend upon the thermal profile and gaseous environment during induration. During the induration of the pellet, it undergoes physical as well as chemical changes. Physical changes are mostly due to sintering and chemical changes are due to carbon burning inside the pellet. The effect of carbon on sintering is investigated on a single pellet scale using an optical dilatometer. Sintering is a complex process that involves transportation through various mechanisms. Sintering is quantified in terms of sintering ratio and the kinetic parameter, exponent ‘n’, under isothermal conditions is deduced using the power law equation. The value of n can be used to estimate the sintering mechanism at different isothermal temperatures. Also, the activation energy is calculated using the empirical Arrhenius equation. The activation energy of 0 per cent coke and 1 per cent coke-containing pellets are 531.0 kJ/mole and 552.6 kJ/mole respectively. The order of magnitude of activation energy suggests the same mechanism in both cases. Although the mechanism of sintering is the same, 1 per cent coke-containing pellet sinters more at any isothermal temperature.

Jun 17, 2024

By S Lakemond, L I. Ku, J Vaughan

Conventional processing of poly-metallic gold containing flotation concentrates are challenging for a number of reasons. One reason is that substantial copper and zinc in the cyanide leach solution compete with gold and silver for carbon adsorption sites. In this study, metal-cyanide adsorption kinetics and equilibrium are measured on three samples of coconut derived activated carbon and one sample of synthetic carbon. Loading selectivity was confirmed to be in the order gold&gt;silver&gt;copper&gt;zinc for all carbon samples. The synthetic carbon tested showed promising results in terms of loading kinetics and capacity for precious metals.CITATION:Lakemond, S, Ku, L I and Vaughan, J, 2013. Effect of carbon type on adsorption of Cu, Zn, Ag and Au from mixed cyanide solution, in Proceedings World Gold 2013 , pp 411-418 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Peter Zhang, Daniel Su, Bo Hyun Kim

Shale gas wells drilled in longwall chain pillars are influenced by longwall mining. Longwall mining on each side of the chain pillars can create overburden movements and induce deformations in gas well casings. If the deformations result in a casing breach, intrusive shale gas could leak into the longwall mine with serious safety consequences. This study concerns five shale gas wells in the chain pillars between two adjacent longwall panels in the Pittsburgh coal seam under a cover depth of 670 ft and a mining height of 7 ft. The gas wells were constructed with typical casing design, but a casing cementing alternative with uncemented production casings was practiced. Four production casings were uncemented, and one production casing was unintentionally cemented with good quality cement to a 535-ft depth and low-quality cement stringers from a 444- to 535-ft depth. The longwall faces passed by the shale gas wells as each adjacent longwall panel retreated. Production casings were surveyed by a multi-finger caliper after each panel was mined. No deformation was detected in the four uncemented production casings, but small deformations were detected in the partially cemented production casing. The maximum measured deformation in the cemented production casing was 0.05 in. after first panel mining and 0.06 in. after second panel mining. The casing deformations were also predicted by the FLAC3D model set up on site-specific overburden geology. The predicted deformations were in good agreement with the measurements in terms of deformation locations and magnitudes. All five shale gas wells resumed normal production after being temporarily plugged during the period of mine-by. This study provides a successful demonstration of the effectiveness of a casing cementing alternative for decoupling production and intermediate casing, and thus minimizing the influence of longwall mining in the shale gas wells drilled through longwall chain pillars.

Jul 1, 2023

By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By Xiang-ning Meng, Miao-yong Zhu

"A three-dimensional finite-element heat-transfer model is conducted to predict temperature of hot copper plate in a slab continuous casting mold and the effect of casting speed on temperature difference between copper plate and solidifying shell is simulated in combination with process data. The results show that centre temperature of hot copper surface at casting speed 1.8 m·min-1 and 2.0 m·min-1 are higher than that of 1.6 m·min-1 casting speed 4.7-5.2 °C and 11.2-12.2 °C respectively and temperature is not increased linearly with casting speed. Temperature difference in meniscus between mold and shell is influenced obviously by casting speed and increased 4.0- 6.0 °C with increment of casting speed 0.2 m·min-1• Fluctuation of temperature difference in meniscus is a main reason to deteriorate casting quality as increasing casting speed.IntroductionIn conventional continuous casting of steel, a large amount of sensible and latent heat of molten steel dissipates in primary cooling zone and mold becomes a critical component of caster to govern steel quality, meanwhile, thermal load on mold is increased constantly and environment is also more abominable since high productivity and quality are required and high-effective technologies are applied. So, an in-depth understanding of thermal behavior of mold at high casting speed is essential to design cooling structure and maintain casting stability. Many studies have been carried out to shed light on thermal behavior in mold. Chow et al. [l] applied a mathematical model to heat transfer in billet mold at a high casting speed to give a new taper in order to minimize mold-strand interaction. Thomas et al. [2] researched relation between mold geometry and temperature distribution based on a finite-element heat-transfer model. Lu et al. [3] indicated that slab mold temperature are mainly affected by thickness of copper plate and nickel layer by a heat transfer model. Samarasekera et al. [4, 5] researched temperature of copper plates for both billet and slab molds and effect of a large number of factors ranging from water quality to casting speed. Park and Thomas et al. [6, 7] developed a finite-element thermal-stress model to determine temperature and thermal distortion and stress in both thin and slab molds and O'Connor et al. [8] applied an elastic-plastic-creep finite-element model in a funnel shaped mold to achieve same goals. Cicutti et al. [9] evaluated heat transfer and temperature fluctuation in a slab mold and proposed an expression to predict global heat flux as a function of process parameters and an index to quantify thermal instability. All mentioned above shown that thermal behavior is not only important to casting stability, it is also premise to further understand mechanical behavior in mold."

Jan 1, 2011

Four catalytic converters for diesel exhaust systems were tested to determine their effectiveness in reducing the amount of harmful substances discharged into the air. Tests were conducted with four different catalytic converter designs, using two diesel engines as exhaust gas generators. (Of the four noble metal catalytic converters, three are commercially available.) Testing showed that the catalysts varied widely in oxidation efficiency at light to intermediate engine loads, but that all were very effective in reducing emissions of CO, HC, aldehydes, and odor intensity at heavy loads (engine operating modes resulting in high exhaust temperatures). Particulate loading, particulate size, and NOx emissions were generally unaffected by any of the catalysts. The catalysts had one ad-verse effect on exhaust quality--increased sulfate emissions. Because of the potential problem of sulfate emissions, the exclusive use of catalytic reactors for emissions reduction does not appear to be satisfactory. However, when used with a means for subsequent removal of sulfates, a catalyst can function as a key component in an emissions control system for diesel engines operated in underground mines.

Jan 1, 1978

By D. W. Feng

Thiosulfate leaching has been considered as the most promising alternative to cyanidation for the recovery of gold from ores. The chemistry of the ammonia-thiosulfate-copper system is complicated due to the simultaneous presence of complexing ligands such as ammonia and thiosulfate, the Cu(II)-CU(I) redox couple and the stability of thiosulfate in solution. However, acceptable gold leaching rates can be achieved by maintaining suitable concentrations of thiosulfate, ammonia, cop-per and oxygen in the leach solution. The leaching of gold in thiosulfate solution is an electrochemical reaction involving the oxidation of gold to gold thiosulfate and the reduction of Cu(II) to Cu(I). Previous studies have shown that the reaction rate of gold was much higher in the presence of am-monia thiosulfate than corresponding sodium thiosulfate. This indicates that cations may affect the anodic oxidation of gold in thiosulfate solution. The present study utilises electrochemical tech-niques to study the anodic oxidation of gold in thiosulfate medium in the presence of the different alkali metal and alkaline earth metal ions. It has been shown that the presence of the heavier cations such as potassium, calcium, and caesium enhance the oxidation of gold in thiosulfate solution. Leaching tests also indicated the improved recovery of gold from a sulfide ore with the addition of heavier cations. XPS results demonstrated that the binding energy for gold shifted to lower values in the presence of the heavier cations, indicating the ready formation of ion-pair with gold thiosulfate at the gold surface during adsorption.

Jan 1, 2014