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By C. Demir, M. S. Celik, I. Gülgonul

Na-feldspar (albite) and K-feldspar (microcline or orthoclase) are major feldspar minerals with identical crystal structures and physicochemical properties. Flotation appears to be a unique method of separating these minerals. Fundamental studies on amine/feldspar system in the presence of monovalent salts showed that separation of these feldspar minerals by flotation is possible at certain concentration of monovalent salts in HF medium and natural pH. A comparison between natural pH and HF medium indicates that the latter provides a better selectivity at the expense of higher collector requirement. A general mechanism for both systems involving an ion exchange between the uncommon ions and adsorption of the common ions is proposed to be responsible for creating differences in the charge of albite and microcline unto which amine adsorbs.

Jan 1, 2002

By William I. Watson

Problems encountered in beneficiating mineral raw materials become increasingly difficult as there is a shift to lower grade and more complex raw materials, and because of the economic need to strive for ever higher recoveries, higher grade products, and lower processing costs. Methods of attacking the many problems should include not only the familiar chemical and physical tests and equipment, but such techniques as X-ray analysis, infra-red analysis, differential thermal analysis, and the use of electron and X-ray microscopes. Many people in the mineral-treating field are unfamiliar with these newer methods and techniques. The differential thermal analysis method, in particular, does not seem to be very well known, even though it offers interesting possibilities in the study of many ore treatment problems.

Jan 7, 1959

By A. J. MacRae

Metallurgical furnaces are made up of complex multi-component systems that must function either together or in parallel for safe, and reliable operation. Thermal expansion of single material components experience induced stresses during heating and cooling, which can lead to cracking or failure. Multi component elements and systems can experience significant thermally induced stresses during both steady state and transient temperature conditions. Examples pertaining to temperature effects on refractory, copper cooling blocks, furnace shells, and complete systems will be discussed. The purpose of the paper is to highlight how stresses and strains are developed due to differential thermal expansion.

Jan 1, 2015

By J. K. Whyatt, B. G. White

Various methods of monitoring slip movements on bedding planes, as well as examination of rock burst damage in stopes, suggests that rock bursts in the Lucky Friday Mine are closely associated with these movements. Slip displacements along bedding simultaneously reduce the physical dimensions of stopes and increase compressive stress along stope margins. Such changes, in turn, contribute directly to rock bursts and the sudden failure of volumes of rock and cemented sandfill surrounding stopes. The distribution of seismicity and several mining-induced and premining structures resemble those described in South African gold mines. These suggest fundamental similarities in seismic sources and mechanisms of rock burst damage.

By James J. Tansey

A Deep Foundations Institute meeting with the University of Michigan at Ann Arbor in March of 1984 featured legal rights under Differing Site Conditions. A workshop conducted by the authors and Gerard Ittig, Esq. added to the value of the symposium. This paper will be of interest to your attorneys in any subsurface disputes.

Jan 1, 1985

By Jürg Künzle

Underground construction is a matter of dealing with the inherent uncertainty of subsurface geology. If the encountered conditions are less favorable than the expected ones, the execution of excavation, support, ground treatment or lining works is likely to require more or different efforts than anticipated, thereby delaying the works and increasing the costs. The 2019 first edition of the FIDIC Emerald Book model contract (FEB) addresses many of the issues to which underground works give rise, including those related to differing site conditions (DSC). This paper examines how under the FEB disputes arising from or in connection with DSC could or should be avoided.

Jun 13, 2021

By J. Ling, L. Racine, P. Cousin, A. R. Laplante

"The problem of gold recovery by gravity from high density gangues is first discussed from a fundamental perspective. Three potential difficulties are presented: poor liberation and fine gold particle size, concentrate bed erosion by coarse dense particles, and slow percolation of gold particle through the high density gangue bed. Two case studies are presented to illustrate the impact of these three problems on circuit performance and the feasibility of gravity recovery. It is concluded that careful testing can determine the scope of the first problem and feed preparation can limit the extent of the second. The third problem is clearly the most serious and results in lower gravity recoverable gold recoveries than would be achieved with the same recovery effort on a low density gangue application.IntroductionSince the commercialisation of the Knelson Concentrator in 1980, gold gravity recovery has experienced a surge in interest, in Canada and the United States first, then Australia, Zimbabwe and Russia, and finally worldwide. Table I details number of units sold in various countries, which corresponds approximately to their importance as gold producers 1. Exceptions. such as the low rank of South Africa or the importance of Zimbabwe, despite the much higher gold throughput of the former, are generally the result of differences in the effectiveness of the local marketing strategies, as well as a reflection of the ""philosophy of recovery"" prevalent in the country.The impact of the Knelson has not been felt equally in all plants. Typically, a highly successful application falls into the following categories: (a) alluvial or hard rock recovery for which gravity is the sole recovery method, (b) hard-rock free gold milling with ores which have a very high gravity-recoverable gold (GRG) content, (c) low grade sulphide copper-gold ores which include flotation ahead of cyanidation and (d) free-milling gold ores ahead of Other applications can be successful, but are not as common. The ""explosion"" of centrifuge concentration, of which the Knelson is the most successful but by no means the sole model, has created a certain euphoria which can be summarized as ""gravity recovery will improve the profitability of gold milling, no matter what."" This presentation is about applications that are not so successful, or even downright unsuccessful. The rationale is not to down-play gold gravity recovery, but to set it in its rightful position: metallurgically, it is not appropriate all of the times; it can become inappropriate if poorly designed; and it can be metallurgically possible but economically unjustifiable. In this paper, this will be illustrated and explained rather than demonstrated, with the use of both industrial plant surveys and laboratory test work. Alternate gravity approaches will be suggested."

Jan 1, 1997

By J. Ling, J. Xiao, A. R. Laplante

"The most challenging gold gravity separations occur when gangue has a high s.g., gold is fine, or a combination thereof This paper examines such separations, and evaluates the performance of a 3-in Knelson Concentrator at various rotation speeds, a 4-in SuperBowl, and a laboratory Mozley Multi-Gravity Separator (MGS). Synthetic feeds, primary cyclone underflows and flash flotation concentrates are tested.It is concluded that higher rotation speed are mostly useful for very fine (< 3 7 µm) gold recovery, with potential loss of recovery in the 37-212 µm range. This problem is traced to the collapse of the flowing film at higher Gs, which hinders the percolation of particles of intermediate size. Increasing fluidization water flow can alleviate this problem, but the recovery of very fine particle then drops. The MGS does not operate with the same principles, and can achieve good to very good recoveries of very fine to fine gold particles, but the unit has a high cost to capacity ratio, and there is no evidence yet that it can yield smeltable concentrate grade or a concentrate that can be upgraded with a shaking table.IntroductionThis presentation is a sequel to similar CMP presentations of the past eight years; all focused on practical aspects of gold recovery. The first hard rock application of the Knelson Concentrator (Laplante et al, 1990), studies of the grinding and classification behaviour of gold and other malleable metals (Banisi et al, 1991; Laplante et al, 1995), the development of a 3-in Knelson based methodology to study gold gravity circuits (Laplante and Shu, 1992), a comparison of the Knelson and Falcon (Laplante, Laplante et al, 1993), the presentation of a test to determine the amount of gravity recoverable gold, or GRG (Laplante et al, 1996), and the use of synthetic materials, in particular tungsten, to mimic gold (Laplante et al, 1995) were presented. A summary of many practical implication of the McGill research was presented in 1994 (Laplante). Whereas gold gravity recovery was less popular and largely jig-based (in North America) at the beginning of the eighties, many gold plants now incorporate a gravity circuit, and the Knelson Concentrator is the most commonly used unit."

Jan 1, 1998

Vale Inco?s Coleman Mine 153 Orebody is a narrow vein deposit with a dip that varies from 30 to 70 degrees. It has a strike length of 1200-feet and the current mining extends from the 4250 level to 5100 level. The primary mining method is mechanized cut-and-fill although drift-and-fill is also used in wider sections of the ore zone. The ore body is divided into six main mining horizons with an average of three mining blocks on each cut. There are some interesting rock mechanics challenges related to mining upward from the 4550 level and these challenges are increasing as the mining front progresses toward the 4400 level. The mining of the 4550 block is currently at cut 13 whereby the crown pillar thickness is approximately 60-feet. Significant factors including increased stress levels in the crown pillar, the change in the orebody dip at this level and a recently indentified geological structure in the footwall, have all combined to introduce seismic activity in the footwall of 4550 level. Closer studies revealed a consistent trend of seismicity that was further examined with core logging and Acoustic TeleViewer technology. The data from these assessment tools disclosed a geological structure that is influencing the mining environment. This paper reviews the seismic analysis for the 4550 level mining zone and the subsequent procedures used to locate the new geological structure. The paper also discusses the key mining practices used to successfully mine cut 13 of 4550 level and briefly reviews the studies that are underway to up-date the mine design for continued extraction of high-grade ore in a safe and productive manner.

May 1, 2009

By Cary Moffat, John Kita, Rick Walker

The Lac des Iles Mine, in an isolated area of NorthwesternOntario is a relatively new open pit platinum and palladium mine. They were encountering problems with the equipment and production scheduling when ramping down to begin production on the subsequent benches. A co-operative effort between Lac des Iles Mine operation people, ICI Explosives, and the mines drilling and blasting contractor - Consbec Inc., resulted in a decision being made to use full depth sinking cuts to provide access to the next bench.

Jan 1, 1996

By William Gleason

"Ed Rapp is among those who believe in the saying that necessity is the mother of all invention. Rapp is the president of Caterpillar’s mining group. As such, he is tasked with leading the world’s largest mining equipment maker, and its customers, through this time of lower commodity prices, while also positioning his company to be prepared for better days that lie ahead.The decade-long mining boom fueled by growth in emerging markets and demand for commodities that led to record prices for some metals paused in 2008 with the global financial crisis. However, according to Rapp, thanks to stimulus packages around the world, and in particular the stimulus from China that was focused on infrastructure, the mining sector recovered fairly quickly, and from 2010 to 2012, mining was strong.And then the stimulus stopped. Credit dried up and global growth began to slow down and, in the three years since, commodity prices have declined by an average of 60 percent. Caterpillar expanded during the boom, acquiring Bucyrus, and investing billions into the mining sector. It has felt the pinch of the slowdown as much as any mining company in the world. These pages, and those of other mining publications as well as mainstream media, have been filled with stories of doom and gloom about the industry. But Rapp, while acknowledging that the difficult times have been painful, also said Caterpillar sees opportunity in the slow down and reaffirmed his company’s commitment to the mining industry as absolute."

Jan 1, 2014

By Orlando Oliveros

The Los Bronces Mine and Concentrator, one of the three operating units of Compania Minera Disputada de Las Condes S.A. (an Exxon Minerals Co. affiliate), is located in the high Andes of East-Central Chile approximately 70 kilometers northeast of Santiago at an elevation of 3,650 meters above sea level. (Figure 1). Santiago, the capital city of Chile, is located at an elevation of about 500 meters above sea level and enjoys a very mild climate, similar to some areas of California. At the mine site, however, extremely heavy winter conditions prevail occasionally, with very heavy snow and the resulting snow avalanches endangering installations and people. At the same time, ideal skiing conditions are found at the nearby ski resort of Portillo and Farellones. Mount Aconcagua, the highest mountain in the western hemisphere is only about 55 kilometers further to the northeast of the Los Bronces mine.

Jan 1, 1983

By James T. Ludwiczak

Drilling and blasting in a Karst (sinkholes and mud seams) environment has long been a problem for blasters, miners, quarry operators, contractors, and developers. While one cannot change the geological conditions, one can take some measures during the bidding process and the initial preparation of the blasting program to help reduce some of the problems. During the geotechnical investigation and developing the test/core drilling grid, the owner/developer needs to take some additional measures that will provide important data to the blaster to help reduce the problems associated with blasting this type of geology. The owner/developer must also understand that, due to the geologic conditions, the results of the blasting will not be ideal and there may be additional blast-related costs. If provided the proper geologic data, the blaster can develop drilling patterns and blast designs that will help reduce some of the more problematic areas.

Jan 1, 2005

By P M. Outhwaite

Everyone present today is especially aware of the need for minerals in this society of ours. The words &apos;especially aware&apos; were deliberately chosen because this is a meeting of the NZ Branch of The Australasian Institute of Mining and Metallurgy not a dilettante group such as some of our critics. Members of the Australasian Institute of Mining and Metallurgy knew that our great farming industry, our shelter, our transport and our energy supply, are largely dependent on a flow of minerals into this country despite the presence of large coal and natural gas reserves. Flow in was said because New Zealand imports most of its mineral requirements with all the consequential strategic and economic disadvantages. If the above statements are accepted by this gathering it would be a premise fairly stated that New Zealand has a great need to discover and develop minerals.

Jan 1, 1976

By Y. K. Rao

In the carbonyl process for the refining of crude nickel CO(g) reacts with nickel in the 310-370K range producing nickel tetracarbonyl, Ni(C0)4(g). Iron and cobalt impurities also form gaseous carbonyls but their partial pressures are low. The carbonyl is led to a decomposer plant wherein the gas disproportionates in the 500-600K range depositing pure metal on nickel pellets that move countercurrent to the gas-flow. This system serves to illustrate the fundamental principles involved in the vapor phase mass transport of elements, against temperature-gradient, under the influence of chemical potential gradient. Unlike in the crystal growth, the source is at a lower temperature (say 350K) whereas the seed is in the hot-zone (say 550K) of the closed ampoule-type reactor. By assuming virtual gas-solid equilibria in the end zones, with diffusion of gaseous species between them acting as a slight perturbation, the quasi-steady- state mass-transport rates are computed for a range of CO-pressures and temperatures.

Jan 1, 1993

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By Lev Levin, Sergei Lesokhin

"The formation of titanium carbide during hot filament assisted carburizing of NiTi alloy was investigated. Phase content and morphology of the diffusion zone were examined by X-ray diffraction, X-ray microanalysis, SEM, and Auger electron spectroscopy. The growth of stable and adherent TiC film was observed. A non-planarity of interphase boundary was noticed. The applicability of the chemical diffusion approach to the analysis of the experimentally observed interface instability is discussed. A criterion, taking into account the influence of growth stresses on the stability of the flat interface, is developed by means of linear perturbation analysis.Introduction.Equiatomic intermetallic NiTi belongs to a class of materials exhibiting the shape-memory effect. The unusual property of this compound promotes its application in many fields, from aerospace technologies to medicine. The relatively high ductility ofNiTi also permits its use as a matrix material in metal-ceramic composites. The objective of this work was to investigate the possible incorporation of a ceramic material (titanium carbide) into NiTi by gas carburizing.Free energy calculations indicate the potential to obtain TiC by carburizing Ni-Ti binary phases. The main obstacle to such a process is the high affinity of titanium to oxygen. At moderate temperatures the formation of TiC is preferable to titanium oxidation only if the partial pressure of oxygen is extremely low [1]. This problem was overcome in this work by the use of hot filament assisted gas carburizing. Due to chemical reactions occurring near the hot filament, the gas mixture, initially consisting of methane and molecular hydrogen, was enriched by atomic hydrogen [2], drastically decreasing the content of free oxygen in the carburizing atmosphere.The second part of this article concerns the theoretical analysis of reasons that lead to the development of the experimentally observed morphology of the diffusion zone. In particular, the influence of the growth stresses on the morphology of an interphase boundary is investigated."

Jan 1, 1996

By L. S. Darken

THE manufacture and treatment of metals comprises operations whose effectiveness depends in large measure upon diffusion phenomena. The significance of such phenomena has, for a few simple cases, long been understood, but in more complex cases it has not been adequately recognized. This paper presents a mathematical analysis of some of the cases in which diffusion leads to the formation of a new phase within the metal, and this analysis provides a basis for interpreting quantitatively many apparently diverse experimental observations recorded in the literature, some of which are outlined in the following pages. OBSERVATIONS RECORDED IN LITERATURE An outstanding instance is the general type of phenomenon in which diffusion of an element into an alloy is followed by a phase change, which most frequently is a reaction (precipitation) of the diffusing element with one or more components of the alloy to form a compound. Thus in certain alloys heated in contact with oxygen not only the usual oxide scale appears but, in addition, beneath the surface, a well-defined zone in which free oxide particles are dispersed with notable uniformity. This zone, commonly referred to as the subscale or zone of internal oxidation, is remarkable in that the visible boundary between it and the unaltered metal is usually sharp. Such a subscale, which appears to have been recognized first in oxidized copper alloys, has been described and studied by C. S. Smith,1 by Rhines,2 and by Rhines, Johnson and Anderson;3 but it appears also in other alloys when they are exposed to conditions that bring about the precipitation of some compound, not necessarily an oxide. Another clear case of this same kind is the diffusion of carbon into a steel containing an element such as molybdenum, chromium, vanadium or tungsten, whose carbide is less soluble in iron than iron carbide, the result being that some part of that element is precipitated as a dispersed carbide. A similar phenomenon may occur on the welding of two alloys each of which contains one of a pair of elements that react to form a compound or a new phase of any sort. But in addition to the precipitation of a compound formed from the diffusing element, other effects may result merely from the presence of the diffusing element. For instance, if homogeneous austenite, nearly saturated with respect to carbon, is heated in contact with silicon in the absence of oxygen, one would expect to find, behind the several iron-silicon phases analogous to a scale, a zone of austenite containing dispersed carbide, because of the fact that silicon decreases the solubility of carbon in iron. As still another example, oxidation of an alloy may result in diffusion toward the surface of one or more of the constituents; for instance, during oxidation of a steel containing an element such as copper, which is less prone to oxidation than iron, there is a notable enrichment of copper just beneath the scale-metal interface. As an example of a yet more

Jan 1, 1942

By Robert Mehl

IN examining the progress of metallurgical science, the critic must remember that most of our present knowledge of metals and alloys has been accumulated through the needs of industry and commerce rather than through the desire and efforts of a large body of scientists interested primarily in developing a science of metals. The progress of metallurgy, scientifically speaking, has been irregular, and little given to the exhaus-tive exploitation of important scientific fields. The experienced engineer now recognizes the need for the development of the basic science upon which his engineering rests. In addition to the increase in knowledge which results from the normal requirements of industry, a development of the basic science of the behavior of metals and alloys is as desirable in metallurgy as in any other branch of science and engineering. The continued growth of the science of metals-as of every other science-requires studious attention to the principles that underlie the behavior of matter, with the result that knowledge in the several fields of interest should continue to increase. Among the various subjects recognized as important in physical metallurgy few have a wider significance than that of diffusion in solid metals. The phenomena of diffusion are intimately related to many basic problems of the metallic state, but in addition to this, the process of diffu-sion is of first importance practically. The formation of alloys by the annealing of mixed powders, first practiced by Faraday and Stodart81 in 1820 and in more recent years investigated by Masing187,189 and others, has led to the development of special alloys like Carboloy, Vascoloy-Ramet, Genelite, Elcon68, and has recently been applied to the production of noble-metal alloys for electrical contacts"&apos;.

Jan 1, 1936