Search Documents

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

Development of Cost-Efficient Environmentally Sound Technology for Enhanced Gold Recovery from Rebellious Gold-Containing Raw Materials Study of biochemical leaching performances in gold-bearing sulfide minerals processing enabled to develop environmentally sound technology of enhanced gold recovery from rebellious gold-containing raw materials. It was found that the ?-10 IMO bacteria activity contributes to increasing system oxygen concentrations and incrementing in rates of oxygen delivery onto surface of gold-bearing minerals. Bacteria activity products, ie, amino acids (?), support the formation of such heterocomplexes as [A-Au-CN]- , providing additional gold recovery into solutions. Technological properties of proposed bacteria solutions were studied. It was found that the proposed bacteria inoculants are capable to growing directly in process of raw materials leaching within a large pH range of media containing cyanides and thiosulfates. They oxidise the sulfur to the sulfate, as well as the antimony (III) and arsenic (III) sulfides to the pentads. For the first time, the hydrophobic cell properties, metabolites emulsifying efficiency, adsorption properties, wetting ability, surface tension and electro-kinetic potential of new bacteria strain solutions were studied as compared with chemical solutions. It was found that the proposed bacteria inoculants reduce surface tension at the solvent-mineral and solvent-concentrate phase boundaries. All aforementioned effects enhance mass transfer processes efficiency. IR-spectroscopy of new bacteria strain culture liquid allowed identifying available amino acids which substantially contribute to heterocomplex anion [A-Au-CN]- formation. Active involvement of heterotrophic bacteria in gold dissolving processes was identified. It was shown that the structure of metals complexes is substantially modified at intensive pulp agitation and during long-term storage. Fractional order reaction in biochemical and chemical gold leaching was identified. It evidences that the gold and impurity metals dissolving processes advance in synchronism. The both processes are running in diffusion zone. Biochemical leaching has advantages over chemical leaching, ie it provides enhanced rates of precious metals dissolving, improved gold recovery by 20 - 30 per cent, decreased cyanide consumption by 50 per cent. At the same time it allows to decontaminate dangerous substances contained in productive solutions produced in rebellious gold-containing raw materials processing. Basic parameters of flotation concentrates leaching by heterotrophic bacteria-assisted processing technology were tried and tested. Technology of gold sorption from leaching solutions was successfully tested.

Sep 13, 2010

By J. D. Law

The presence of long-lived radionuclides presents a challenge to the management of radioactive wastes. Separation of the radionuclides from the waste solutions has the potential of significantly decreasing the costs associated with the immobilization and disposal of the waste by minimizing waste volumes. Several solvent extraction processes have been developed at the Idaho National Engineering and Environmental Laboratory for the separation of transuranic elements (TRUs), 90 Sr, and/or 137 Cs from acidic radioactive waste solutions. The TRUEX and POR processes for the separation of TRUs, the SREX process for the separation of 90Sr, the cobalt dicarbollide process for the separation of 137Cs and and a universal solvent extraction process for the simultaneous separation of TRUs, 90Sr, and 137Cs have all been developed in centrifugal contactors using actual liquid radioactive waste solutions and simulated dissolved calcine waste solution. In addition, the behavior of metals with each of the solvent extraction processes was evaluated. This article summarizes the most recent results of the each of the flowsheet demonstrations and provides Information on the centrifugal contactor equipment used for the testing.

Jan 1, 1999

By Fabiano Almir Barbosa, Eduardo Alves Machado, Felipe Ferreira Cajano, Bruno Rodrigues Henriques

Spring steels are usually classified as medium to high carbon low alloy steels with very high yield strength, enabling the part to return to its original shape regardless of significant bending or twisting. Despite the fact that plain carbon steels are suitable for small springs, larger and high performance springs usually requires alloy steels such as Cr-V or Si-Mn in order to achieve an even microstructure throughout the cross section. Clutch diaphragm spring is a high performance part that requires very good cleanliness and microstructure homogeneity, thus requiring an alloy steel. In this paper was studied, in an industrial scale, the process parameters and critical characteristics for the development of a Cr and V alloyed high carbon sheet steel for the production of clutch diaphragm spring. The steel was characterized throughout the entire process (casting, hot rolling, cold rolling + batch annealing and heat treated) using tensile test, hardness test, optical microscopy (OM) and scanning electron microscopy (SEM) to assess the mechanical and metallurgical properties of the studied steel. The results have shown the material’s microstructure evolution after each main stage of the process, from a ferrite-bainite/perlite based microstructure as hot band to fully spheroidized as cold-rolled/annealed and then fully martensitic as ready-to-use part.

Oct 1, 2019

By Kazumasa Taguchi

At the Kakogawa works of Kobe Steel. Ltd., the agglomeration facilities are composed of a pelletizing plant and sintering plant. This aim is to utilize raw materials efficiently and stabilize the raw material resources. Therefore at Kakogawa works, the blast furnaces (BF) have been operated with high pellet ratio and various developments for pellet properties have been achieved to improve the blast furnace performance. These developments include dolomite-fluxed pellets, new-porous pellets and crushed pellets. As a results of these improvements, pellets have achieved almost the same performance as sinter at high temperature regarding properties such as the softening, melting and reduction behaviour. However, some problems on shape have remained to be solved. Spherical pellets flow easily into the center of the furnace and form mixed layers of pellets and cokes. Therefore, in BF operations with these pellets it becomes more difficult to keep proper and stable gas distribution.

Jan 1, 1983

By Michael Harris, David Mosch

The numerous small high grade gold and silver deposits of the Front Range Mineral Belt have been uneconomical because of the high costs of mill construction, transportation, and smeltering. Processing of these ores must be simple, cheap, with satisfactory recoveries, and be environmentally acceptable. Vat leach with direct electrolytic recovery satisfies these parameters. A battery of testing was conducted utilizing bottle and bucket tests. A five ton vat leach with direct electrolytic recovery gave excellent results while a five ton heap leach proved impractical due to channeling.

Jan 1, 1987

By V. A. Zhilina, I. V. Shadrunova, O. E. Gorlova

"The aim of the study is to develop and scientifically justify a new adaptive approach to the separating processes of deep and complex processing technogenic mineral raw materials. Technogenic mineral resources as a waste of mining and processing industry are mostly complex objects that have specific features of material composition and technological properties and make it processing ineffective with traditional schemes of mineral raw materials enrichment. Mineral wastes are regarded in this study as a complex object with a large number of signs in conditions of uncertain environment and object. However, adaptation is regarded as the process management system’ adaptation to the specific the properties of the object and the environment that has several hierarchical levels corresponding to different stages in the management of complex object. An adaptive approach is considered as a methodological basis of multivariate schemes for opening the mineral resources and creating mechanisms that could transfer these potential technogenic resources to the actual that significantly expand the mineral resource base of the country's black, coloured, rare, noble metals and construction materials. In this case, potentially the solution to the most pressing social and environmental problems associated with the adverse effects of past economic activity simultaneously with the commercial objectives. This approach to the wastes mining and related processing manufacturers meets the core idea of sustainable development as the balance of interests of State, society, business, private enterprise and each person in the areas of rational use of resources, economic efficiency and environmental safety. On the example of metal-containing raw materials in the form of slags of ferrous and nonferrous metallurgy, ferrous metallurgy sludge, mature fine tailings, the application of adaptive approach illustrates to the development of technologies of its deep and complex processing as phased, thoughtful movement from a comprehensive study of technogenic raw materials to build optimal topologies of technological schemes for processing the mineral wastes. INTRODUCTION Involving the Russian economy in the system of global economic relations significantly changes the nature of the country's competitiveness in the development of the world market and urgently requires competent management of its own natural and mineral resources. The latter at the present time in real economic processes cease to be a passive material foundation and become the producing basis in the production processes in the status of so-called natural capital. Introduced in the field of economic theory at the end of the 20th century, this term means both the flow of natural services and real natural resources. Consequently, natural objects, which act as natural resources of a certain production, today must necessarily be evaluated in a strategic sense. Modern standards of sustainable development presuppose that the economy should equally be oriented to balance the interests of the state, society, business, individual enterprise and each person in the spheres of rational use of resources, preservation of healthy ecosystems, ensuring well-being, high quality of life and environmental safety of not only the current generation, but also respect for the rights of future generations, that is, intergenerational equality. Most types of minerals are classified as non-renewable resources, therefore resource-saving in the sphere of mineral and raw materials complexes is one of the most important factors-indicators characterizing the degree of approximation to the model of rational subsoil use, and, consequently, sustainable development (State Report, 2017)."

Jan 1, 2018

By Larry G. Stolarczyk

[STATES REPORT Mining Research Mine Health and Safety Research for Period Ending 30 September 1980 PROGRAM Wireless MF Communication System DATE STARTED January 1980 TPO (USBM) Robert I. Chufo (PSRC) CO ( USBM) Alan G Bolton, Jr, (Mr. Patrick Neary RESEARCH AREA Industrial Type Hazards SCHEDULED COMPLETED Phase I 29 September 1980 Phase II 29 June 1981 Phase III 29 April 1982 Subject OBJECTIVE Development of demonstration Hardware. for medium frequency mine tireless communication system.]

By N. Aarthi, G. R. Dodagoudar

The improvement of soft clay deposits using stone columns is a well-established ground improvement technique in the western world. This technique has been well documented and has proper design codes for precise execution in the field. The sand compaction pile (SCP) method is a contemporary technique to stone columns and has limited literature related to the strength characteristics of the loose to medium dense sand deposits treated with SCP. The available studies on the SCPs installed in cohesionless deposits focused on the improvement by indirectly assessing the SPT-N values pre- and post-installation of the SCPs. The widespread implementation of the SCP technique in recent years has increased the need for a more direct evaluation of the improvement. Earlier studies in this regard have revealed that the available design solutions are based on the type of installation equipment, their working efficiency, and accumulated field data. However, it is found that there are no generic design codes for the direct estimation of the ultimate bearing capacity of the SCP improved cohesionless deposits. To meet the design requirement for the SCP treated ground, a series of experimental and numerical investigations are performed in the present study to arrive at a direct framework in the form of design charts based on the pressure-settlement response of the treated ground. The developed design charts give the ultimate bearing capacity (UBC) of the treated sand deposit for the known initial relative density (RD) of the deposit, spacing and diameter of the SCPs, size of the footing, and for the specified target unit weight required for the intended application. It is concluded that the design charts will be of preliminary use to the design engineers to directly evaluate the UBC of the SCP improved loose to medium dense cohesionless deposits as part of the SCP method of ground improvement. It is expected to have more field-scale experiments and in-depth analysis before implementing these charts for actual field execution.

Nov 1, 2022

By Kenneth Gavin

Design practice for piles installed in Irish glacial till has developed in an ad-hoc manner, based on the results of un-instrumented load tests. This had led to designers using similar design parameters for both CFA and displacement piles. To address the concerns of industry a series of instrumented pile tests were performed by two Irish Universities. These tests summarized herein, revealed that CFA piles develop higher shaft resistance than piles driven in glacial till. However, they exhibit low base stiffness and the end bearing resistance that can be mobilized at acceptable pile settlement is low. The use of simple non-linear elastic design approaches to predict the load-displacement response is considered. The methods are used to predict the capacity of two large diameter CFA piles installed in glacial till. While the predictions were reasonably accurate at predicting the initial load-displacement of the piles, significant creep settlement developed at higher load levels. The cause of the creep settlement was investigated through the use of plate load tests and the consequences for pile design are discussed.

Jan 1, 2009

By Reginals W. Burroughs

Diatomaceous or infusorial earth, also called diatomite; fossil meal, or kieselguhr, is derived from the lowest form of vegetable life, the unicellular alga:. It consists of the siliceous remains of extremely minute aquatic plants, which exist in both salt and fresh water. Light i~ a prerequisite to their development. These very small particles secrete silica in much the same way that molluscs secrete lime to form their shells. The diatoms at death sink to the bottom of the body of water in which they lived, and the organic matter gradually decays and is washed away, leaving the skeletons. Thousands of years are required by this means to develop bed5 of sufficient thickness to be of commercial value. The siliceous remains vary in size according to the species, but all are very minute and, as a general rule, they can be identified only under a high-power microscope. Over one thousand types have been distinguished and named. They are all composed of a hydrous or opalescent form of silica, with silica content ranging from seventy to ninety-five per cent. Magnified, they present an attractive sight, a very fragile structure with many interstitial openings known as cells. Many of them consist of two parts, defined as valves, held together by means of a girdle. Certain species, belonging to the Pinnularia family appear as a long comb, in half longitudinal section. The spaces between the teeth are the cells. This particular genus is very common in Nova Scotian deposits.

Jan 1, 1928

By Y. Suzuki, H. Yoshida, K. Sakaguchi, K. Matsuki, M. Minami

To estimate three dimensional in-situ stress at great depth, Downward Compact Conical-ended Borehole Overcoring (DCCBO) technique, which is one of stress relief methods, was developed. DCCBO technique can be applied to a water-filled vertical/sub-vertical borehole. In in-situ tests, the bonding device and the cleaning system were verified to work well in a water-filled borehole with cuttings on the bottom. Um dreidimensionale in-situ Beanspruchungen in großen Tiefen abzuschätzen, wurde das Downward Compact Conical-ended Borhole Overcoring (DCCBO) Verfahren entwickelt, wobei es sich um ein diese Beanspruchungen entlastendes Verfahren handelt. Die DCCBO Technik kann auf wassergefüllte vertikale und subvertikale Bohrlöcher angewandt werden. Bei den in-situ Tests wurde die Einsatzfähigkeit der Verbindungsvorrichtung und des Reinigungssystems für wassergefüllte Bohrlöcher mit Einschnitten am Boden bestätigt. La technique de Downward Compact Conical-ended Borehole Overcoring (DCCBO) ou ‘Surcarottage par sondage à extrémité conique compact dirigé vers le bas’, qui est une méthode de détente des tensions, a été développée pour calculer les tensions in-situ à trois dimensions à grande profondeur. Cette technique peut s’appliquer à des sondages verticaux/sub-verticaux remplis d’eau. Au cours des essais in-situ il a pu être vérifié que le dispositif de liaison et le système de nettoyage fonctionnaient bien dans un trou de forage rempli d’eau avec saignées au fond.

Jan 1, 2003

By A. Nieto

A dump edge and vehicle proximity warning system is being developed at the Colorado School of Mines using GPS and wireless local area networks to improve the safety of off-highway trucks in open pit mines. After two years of research, software development, and testing in the laboratory, field tests are currently being carried out at operating limestone quarries and open pit mining operations to evaluate the effectiveness of the system under rugged operating conditions. This paper describes the progress made on this NIOSH-funded project and discuss, tests carried out recently, at the Morenci open pit copper mine in Arizona.

Jan 1, 2002

By Thomas Jancic

Two of the open-pit, copper-molybdenum mining operations of Duval Corporation are located in the foothills of the Sierrita Mountains approximately 30 miles southwest of Tucson, Arizona. In March 1959, mining from a moderate sized porphyry deposit known as the "Esperanza orebody" was begun at a rate of 10,000 tons of ore per day. Some five years later, a sizeable group of mineral claims west of Esperanza became available to Duval. Earlier exploration and development drilling in this area by others indicated an orebody of greater size but lower tenor than that of Esperanza. A drilling program conducted by Duval not only verified the results of the prior drilling but in addition, revealed a continuation of the mineralization to the south and east. Thus was developed the Sierrita orebody. Open pit design delineated 414 million tons of ore containing an average copper content of 0.35 percent and a molybdenum content of 0.036 percent. In April 1966, the office of Emergency Planning authorized General Services Administration to undertake a program under the Defense Production Act to en¬courage additional domestic production of copper in the interest of national defense. Duval's Sierrita Project was brought to GSA's attention in May 1966 on November 28, 1967, an agreement providing for the development of the Sierrita Property was consummated with GSA. In March 1970, the first copper-molybdenum concentrates were produced in the 72,000 tons-per-day concentrator. Pre-production stripping exceeded the scheduled 105 million tons despite the comparatively short lead time available to equip the mine, build the mine plant facilities, and staff the technical, supervisory, and labor forces. Shortly before the first concentrates were produced, plans were being formulated for a program to increase processing capacity by approximately 15 percent, which entailed increasing overall mining capacity by approximately 50,000 tons per day. This program is scheduled for completion early in 1971.

Jan 1, 1971

By H. Paudyal, K. Ohto, H. Kawakita, S. Alam, B. Pangeni

The orange waste after lime water modification was converted into promising adsorbents for fluoride by metal loading reaction. The effectiveness and mechanism of fluoride adsorption on metal loaded orange waste gel from synthetic and real plating solution were investigated. Amount of zirconium(IV), aluminium(III), cerium(III), lanthanum(III), titanium(IV), vanadium(IV) and tin(IV) loaded on orange waste from aquearegia dissolution were evaluated to be 1.62, 1.16, 0.93, 0.95, 1.20, 1.12, 0.97 mmol/g respectively. The maximum adsorption capacity (qmax) of zirconium(IV), cerium(III), lanthanum(III), iron(III) and aluminium(III) loaded orange waste for fluoride ions were evaluated to be 1.74, 0.91, 1.07, 0.98 and 1.01 mmol/g from aqueous solution. The mechanism of fluoride adsorption by metal loaded orange waste was inferred to be ligand exchange reaction. Application of zirconium(IV) loaded saponified orange juice residue(SOJR) for real plating solution showed effective removal of trace concentration of fluoride down to the accepted standard. The negligible interference of co existing anions like nitrate, carbonate, sulphate and chloride makes zirconium(IV) loaded SOJR a promising sorbent for waste water treatment. The adsorbed fluoride from fluoride loaded zirconium(IV)-SOJR was effectively desorbed by using alkali solution for its regeneration. This work shed light on the potential application of metal loaded SOJR to remediate fluoride contaminated water for environmental relevance.

Jan 1, 2012

By W L. Daniels, C Stilson, C Zimmerman

Mineral sands mining for ilmenite, rutile and zircon has disturbed over 1000 ha of prime farmland in Virginia (USA) since 1997 and additional areas are likely to be disturbed in Virginia and North Carolina (USA) over the next 15 years. Full-scale mining operations at the Old Hickory Project in Virginia were initiated in 1997 by Iluka Resources Inc. and restoration protocols have continued to evolve in response to a variety of economic, technical and social issues. Early on, the return of these lands to agricultural row-crop production was complicated by vertical stratification of tails + slimes and lateral variability in soil physical conditions in the reclaimed pits and by limited topsoil return. Virginia Tech and Iluka have worked cooperatively with all stakeholders for over 20 years to review the pre-existing research base, conduct new and innovative site-specific research and thereby provide reasonable expectations of post-mining soil productivity levels. In 2004, Virginia Tech, Iluka Resources and a local leaseholder (Carraway-Winn family) agreed to jointly manage a 45 ha research demonstration farm where the long-term effects of alternative soil reconstruction practices are being rigorously monitored for both row crops (corn and wheat) and forage production. All mined land crop yields are also compared to an adjacent undisturbed exceptional quality prime farmland soil. Row crop yields between 2005 and 2010 were significantly above county average yields (regulatory target level) and approximately 75 - 80 per cent of undisturbed adjacent prime farmlands. The state regulatory authority has recently relaxed its position on the necessity of topsoil return versus use of topsoil substitutes based on appropriate on-site research results and the ability of the reclaimed soils to meet comparative local county crop yield targets. This cooperative effort allows all clientele groups to objectively assess the post-mining productivity of these mined lands while providing an invaluable educational opportunity for the mining industry. CITATION:Daniels, W L, Stilson, C and Zimmerman, C, 2012. Development of effective rehabilitation protocols for mineral sands mining in Virginia, USA, in Proceedings Life-of-Mine 2012 , pp 97-104 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By Mikhail I. Khersonskaya, Mark I. Mantsevich, Andrey V. Tarasov

"Due to depletion of the existing ore deposits the content of non-ferrous metals in produced ores has an inevitable tendency to decrease. Processing of low-grade ores is associated with production of low-grade selective concentrates and poses serious problems for the non-ferrous industry relating to increasing losses and expenses for waste treatment and disposal.The main component contaminating selective concentrates is iron sulphides.Copper-nickel, copper-zinc and polymetallic ores have been discussed as most important types of ores requiring removal of iron sulphides.One of the promising directions for development of selective flotation technology is the use of lowmolecular organic depressors. An advantage of organic compounds is in the possibility of multi-variant structure of organic molecules, which permits selection of a most efficient reagent for the given conditions. Another way for improving the grades of concentrates is concentration of valuable constituents associated with iron sulphides in an intermediate product and upgrading of the latter by chemical and metallurgical techniques.In order to remove iron from nickel concentrates, specific process conditions have been developed for selective flotation of pentlandite with the use of an organic depressor for pyrrhotite. The use of a depressor for flotation of high-grade copper-nickel ores ensures an increase in the nickel content up to 14% in the nickel concentrate produced as compared with 7% when using conventional process conditions, along with a nickel recovery improved by 2-3%."

Jan 1, 2003

By Akio Ohta

The Hyuga smelter has been producing ferronickel by a rotary kiln-electric furnace process in Miyazaki, Japan. Several approaches to improve our operation have decreased the electrical energy consumption. A new process was developed to decrease the cost of energy even further. Oil and technical oxygen are injected through lances to heat up the calcined ores (calcine) instead of the electric power. Main problems during the development of the process were the short life of the water-cooled lances, the check on security of the safety system and the eruption of combustion gases through the calcine bed. These problems have now been overcome successfully, and stable operation can be maintained. The addition of 1 Litre of heavy oil per tonne of ore can save the electrical energy requirement by 8.6 kwh per tonne of ore. The new process has resulted in a reduction of the electrical energy consumption by more than 10 percent

Jan 1, 1992

By Pravin Kumar

Goldcorp Inc.?s Red Lake Mine (RLM) is situated in the Red Lake Mining District, a history rich North Western Ontario mining community. Red Lake Mine formerly known as the Dickenson Mine has experienced various degree and type of bursting since the 1960?s. During the 1960?s burst were common in shrinkage stope box hole pillars. After discovering the High Grade Zone (HGZ) between its 30th and 39th levels, the mine has changed its mining method to mechanized cut and fill with cemented paste fill. The rock mass at RLM is mainly massive basalt-ultramafic and behaves in a manner consistent with massive brittle rock. This paper presents the use of empirical and numerical design techniques. The use of the Span versus RMR graph to determine critical stope spans at RLM and the use of numerical design techniques to determine the stability of the sills and post pillars. Selecting of a sill pillar dimension is illustrated using four different failure criteria?s. The four failure criteria are m & s failure criteria, the Pillar Stability Graph, deviatoric stress ???-?3), and induced stress level criteria ?1 /UCS, which are calibrated to RLM?s ground conditions. A wide range of case histories has been studied ranging from stable to highly burst prone ground conditions in order to calibrate the failure criteria to observed conditions and quantified to local micro seismic system.

May 1, 2002

By Hyunsuk Yoon, Kiho Lee, Juhyng Lee, Younghoon Jung, Junboum Park

"The environmental double pile method is presented as a device to improve the engineering properties and to clean up contamination of low-permeability soil. This method is one of the novel technologies based on the concept of one step process. It can be applied to low permeable contaminated ground for site reuse. It uses piles to improve drainage, contaminant remediation, and bearing capacity of the ground. To evaluate the on-site applicability of this technology, drainage and strength properties of the environmental double pile were assessed by a series of experiments and numerical analysis. Environmental double pile was found to be a feasible alternative method to improve contaminated soft ground.Korea is a peninsula with many coastal industrial zones. These zones are located in regions mostly underlain by soft ground with low permeability and adjacent to industrial areas that can be contaminated. Therefore, a new region-specific remediation method is required to achieve environmentally sustainable development. This research introduces the Environmental Double Pile (hereinafter, refer to as EDP) for the lowpermeability contaminated ground and focused on both contaminant remediation and soft ground improvement. Basically, the EDP is quite similar to sand compaction pile (SCP). The SCP has been studied extensively to improve soft ground (Braja 1999; Hansbo 1994; Madhav and others 1978; Taylor 1948). But unlike SCP, EDP is filled with oyster shells instead of sand and an inner pile is inserted in the center of this oyster shell filled-zone. Therefore, it is a double pile consisting of the oyster shell pile and the inner pile, as depicted in Fig. 1."

Jan 1, 2005