Search Documents

By D. Shishin

Continuous integrated experimental and thermodynamic modelling work is conducted in Pyrometallurgy Innovation Center (PYROSEARCH). The target is to develop a tool, which is capable to predict the compositions of phases, phase equilibria and enthalpy balance for pyrometallugical processes with higher accuracy. All these can be achieved by thermodynamic calculations based on Gibbs energy minimization algorithm. Recent developments made it possible to predict important factors, such as the chemical solubility of Cu in slag as a function of matte grade, temperature, P(SO2), Fe/SiO2 ratio in slag, wt% Al2O3, CaO and MgO in slag. In industrial practice, it is not only chemical solubility, but the overall amount of slag, which affects the recovery of copper and other valuable metals. It will also impact the energy balance. The presence of solids in the slag matrix influences the physical entrainment of matte in slag. Oxygen enrichment which is sometimes used to control the temperature of the furnace, may also affect the volatilization of minor elements into the gas phase. Same is true if additional fuel is used to compensate for heat balance. In other words, all key process parameters mentioned above are interrelated. Present study demonstrates the ways thermodynamic modelling can be used to link those process parameters on the example of copper smelting. INTRODUCTION Research methodology involving integrated thermodynamic modelling and experimental approach has been recently reported by the authors (Shishin, Hayes, & Jak, 2018 Shishin, Hidayat, Jak, Decterov, & Belov, 2016). Present paper reviews the updates and discusses challenges in the development of a large self- consistent thermodynamic database. The database covers the Al-Ca-Cu-Fe-Mg-O-Pb-S-Si-Zn-(Ag, As, Au, Bi, Ni, Sb, Sn) chemical system. The database works in the environment of FactSage software Bale et al., 2016 and related family of products: ChemApp (Petersen & Hack, 2007), ChemSheet and SimuSage. A list of phases, and thermodynamic models is shown in Table 1. For the copper industry, most important phases are Gas, Slag, Spinel and Liquid matte/metal/speiss. Black-colored elements represent the base system, elements in green can be considered as slag modifiers (slagging elements), and elements in red are minor. Ni is highlighted because it was included recently, in 2019, and currently under development. In addition to copper, the database covers the conditions typical for lead and zinc pyrometallurgical extraction. It is developed in consistency with the experimental results for high concentrations of Pb and Zn. Examples of applications in the present study include the thermodynamic analysis of fluxing for an agitated copper reactor to show the effect of Fe/SiO2, and calculations of copper slag cleaning using reductant.

Jan 1, 2019

By Y. Chen, D. He, J. H. Potgieter

The demand for rare earth elements (REE) is increasing rapidly owing to the emergence of new cleanenergy and defense-related technologies. China’s dominates the world production of REE. In this paper, we review the ore characteristics of four typical REE deposits in China and discuss the conventional beneficiation techniques, including gravity and magnetic separation, flotation, and hydrometallurgical processing of these ores. Some of the latest laboratory findings and industrial applications, as well as the development of novel reagents for REE processing in China are presented. The REE beneficiation technologies developed and employed in China could constitute a good case study for many other emerging projects being explored around the world.

Mar 2, 2022

Atlas Copco Construction and Mining Australia identified a number of issues in regard to the skill levels, labour turnover and productivity of our service technicians. In 1994 we were experiencing a labour turnover rate of 42 per cent per annum amongst our technicians. Exit interviews were held with each individual and one of the major areas of dissatisfaction was the degree of product training provided on our equipment, compared to what is required to be competent across the range of our products. These tradespersons were prepared to accept the reduced remuneration that an OEM offers, for the benefit of comprehensive, professional training that, in theory, could be provided. The truth is that we were achieving approximately 40 per cent of our target for training hours because of the demands of field service, pre-deliveries, etc. So, the summary was the same as the industry was experiencing at that time because of skilled labour shortages, production demands, etc people were employed and thrown in at the deep end. A recipe for failure that will be successful every time.

Jan 1, 1998

By Tom Goodell, James Cox, Scott Scovira

Resolution Copper Mining is sinking a 6943 foot (2116 m) deep shaft to access and develop a new panel caving mine with approximately 1.6 billion known tons of porphyry copper resource. This mine will take several years to ramp up to its full production level of 132,300 tons per day (120,000 tonnes per day) and is scheduled to begin production in the early 2020s. Resolution's shaft sinking contractor Cementation USA is using state of the art sinking methods combined with a largely local labor force to complete this record breaking shaft. Resolution's No. 10 Shaft has finished diameter of 28 feet (8.5m) and as of October 2013 is at the 6625 foot (2020 m) level. Upon completion in early 2014, the No. 10 Shaft will be the deepest single lift shaft in the United States.

Jan 1, 2014

By H. Bouzahzah

The field of quantitative mineralogy has evolved significantly through the development of image analysis techniques and information technology. Quantitative mineralogical characterization can now be routinely conducted for determining ore compositions and understanding the behaviour of minerals within mineral separation processes. The characterization of mine tailings is another important application of quantitative mineralogy. The estimation of acid and neutralization potential as well as the interpretation of kinetic leaching test results are often based on quantitative mineralogical knowledge (mineral abundance, texture, metal distribution amongst minerals, etc.). The objective of this paper is to determine and compare the accuracy of four mineralogical characterization techniques that are often used for environmental sample analysis: (1) X-ray diffraction, (2) normal analysis from chemistry analyses, (3) normal analysis from specific gravity measurements and (4) SEM-EDS image analysis. For this purpose, three artificial samples were assembled by mixing pure minerals in proportions often observed in mineral processing plant tailings. BILMAT, a statistical data reconciliation software, was applied to reconcile the chemical analyses with the results of other mineralogical analysis techniques and to estimate the acid and neutralization potential of actual mine tailings samples. The acid mine drainage was qualified from the acid potential and neutralization potential equilibrium as determined through quantitative mineralogical analysis. The statistically reconciled data made it possible to predict the metal deportment as a function of their bearing minerals and therefore, in the case of neutral contaminated drainage, to assess metal leaching potential.

Jan 1, 2016

By R. M. Powers

The Florida Institute of Phosphate Research (FIPR) has funded a four-year research project to develop a computer model 'which will predict the hydrologic impacts of phosphate mining on surface and groundwater systems. The core of the model is an analytical geographic information system (SPANS) which integrates EPA's Hydrology Simulation Program Fortran (HSPF) surface water model with the McDonald-Harbaugh groundwater model (MODFLOW). The hydrologic model conducts both event and continuous annual Simulations driven by variable precipitation and temperature data. The model is currently being calibrated and will be ready for distribution to the user community in mid-1991.

Jan 1, 1990

By Selim Coskun

In this study, tungsten matrix composites reinforced with 2 wt% TiC particles were mechanically alloyed (MA?d) for 3h, 6h, 12h and 24h. 1 wt% Ni is used as sintering aid which is added before and after mechanical alloying. Microstructural and phase characterizations of composite powders and sintered samples were carried out via SEM and XRD analyses. Furthermore, density and hardness measurements of as-consolidated and sintered samples were carried out. Additionally, DSC experiments were conducted to investigate the sintering behavior of the MA?d powders.

Jan 1, 2009

By T. Abu Leil

A new class of ternary Mg-Sn-Ca alloys is being developed to address the dual demands of corrosion and creep resistance at service temperatures. While tin has proven to enhance the corrosion resistance, calcium is expected to significantly increase their creep resistance of binary magnesium alloys. Their effects in ternary magnesium alloys are not yet known. The series of alloys studied has Sn and Ca in the ranges 3-6% and 1¬2%, respectively. The results indicate that these alloys have two-phase structures with CaMgSn phase dispersed in a matrix that is predominantly a solid solution of magnesium. The corrosion behavior of these alloys has been investigated by means of salt spray tests and potentio-dynamic measurements. Creep behavior of these alloys was measured at a temperature of 135 C under an applied compressive stress of 85 MPa. Scanning Electron Microscopy with Energy Dispersive X-ray facility and X-ray Diffraction techniques were used to characterize the microstructures. The results indicate the prospect of designing alloys that can provide optimum combinations of corrosion and creep resistance by adjusting the relative compositions of Sn and Ca in the system.

Jan 1, 2006

By Ananda Moreira Vaz Ourique de Avila

High and intermediate temperature fuel cells (FC) are power generators characterized by high efficiency and their use in cogeneration systems. The single fuel cells are connected in series by the use of interconnects to form a fuel cell stack. Ferritic stainless steels have been used in the making of high and intermediate temperature operation solid oxide fuel cells interconnects. However, at high temperatures, on the order of 700-8500C, these steels can present significant oxidation and degradation processes, promoting increased electrical resistivity and corrosion losses that result in contamination of the electrodes and reducing the performance and the useful life of the FC. Intensive R&D activities have been made to minimize these problems and the use of composite coatings on metallic substrate has been considered. This paper evaluates the use of coatings of copper and nickel, with particles of La2O3, Y2O3, CeO2, LaCrO3 and doped chromites applied on ferritic stainless steels AISI 430, AISI 441 and Crofer22APU produced by electrodeposition. The produced samples were evaluated by microscopy techniques, gravimetric analysis and by electrothermal characterization. The most significant results were obtained with chromites coatings (LaCrO3 pure, mono- and multiple-doped) showing the combination of the best features of metal coatings, substrates and ceramic particles with semiconductor properties.

Aug 7, 2018

By Paul S. Korinko, Simona E. Hunyadi Murph

To address a radiological contamination event, a materials and process project was initiated. During the course of this project, processes and materials were developed that successfully captured zinc vapors physically and chemically, respectively. However, the physical traps were placed in an undesirable area and it was determined that the chemically captured zinc reactions was reversible. Consequently, advanced nanomaterials are being developed to capture zinc vapors. The current state of the art of the science and engineering of these materials and their efficacy for zinc capture and retention is discussed in this paper.

Jan 1, 2015

By S. P. Sandoval

In 2002 the Freeport-McMoRan Technology Center undertook research to develop a lower-cost alternative to guar for cathode smoothing in copper electrowinning. The work was conducted at the Technology Center?s SXEW Test Facility located in Morenci, Arizona. Bench-scale copper electrowinning cells were designed and implemented to screen a number of potential polymers for cathode smoothing. These included modified polysaccharide polymers that were nonionic, cationic, and anionic in nature.

Jan 1, 2010

By P. Schilizzi, A. Jarosz, M. Karmis

This paper is concerned with subsidence prediction methods and in particular with two techniques, one based on profile functions and the other on influence functions. Profile function methods provide a tool for a fast calculation of subsidence on a line across a mine panel. Influence function methods, on the other hand, allow for a more detailed calculation of ground movements, in any mode and at any depth, on a grid or at any specific point. In more detail, the hyperbolic tangent profile function, as developed by VPI&SU from field data pertaining to the eastern U.S. coalfields, and an influence function method currently being adapted for the same region, are presented and discussed. The applicability, advantages and limitations of these techniques are examined and comparisons are presented with field measurements. Computer software developed for the application of these prediction methods, for two widely used personal computer systems, are also discussed and a number of examples are presented demonstrating the potential of such programs.

Jan 1, 1986

By Matt Schuett

Antamina Mine Facts • Surface Water Design Principles • Drainage Areas • SEDCAD Modeling • Impacted Runoff Collection • Clean Runoff Collection • System Flexibility • Outfall Construction

May 1, 2004

By A T. Yuniar, C A. Brannon, N D. Pascoe, H H. Firdausi

This paper describes the key components of the Grasberg Block Cave (GBC) mine design and the development and construction status of the mine. Drawpoint production from GBC will be initiated in 2018 following the closure of the Grasberg open pit. Full production of 160 000 t/d is planned for 2024, which will make it a 20-year time period between initial access development in 2004 and full production.Diluted ore reserves are about 1 Bt at a grade of 1.0 per cent Cu and 0.78 g/t Au. The mine plans some 2400 drawpoints on a 20 m × 30 m drawbell spacing in a 700 000 m2 footprint using the El Teniente layout. The drawpoint opening sequence includes five production blocks, the first two of which are scheduled to be undercut simultaneously in 2018. Ore is transported using diesel-powered load-haul-dumps to a series of orepasses and then delivered via loading chutes to a rail haulage system, which delivers the ore to a three gyratory crusher complex. Crushed ore is transported to the mill stockpiles via dual inclined conveyors.Development and construction of the substantial fixed facilities are now well underway. Primary access for personnel and materials is via the 6 km Ali Boediardjo (AB) adits. A service shaft will hoist personnel and materials from the AB adits level to the various operating levels. Shaft commissioning is scheduled for late 2015. The rail haulage system installation and construction is in progress and is due to be commissioned in 2017, which is timed to coincide with the commissioning of the ore handling system. Ventilation is provided through a series of large intake and exhaust drifts, and two of the four main fans have been commissioned. A 1600 L/s pumping system will manage drainage from the mine.Other key facilities include separate shops for rail and rubber-tired equipment, warehousing, a powder magazine, a main control centre and an underground concrete batch plant.CITATION:Brannon, C A, Firdausi, H H, Pascoe, N D and Yuniar, A T, 2016. Development and construction update of the Grasberg block cave mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 625–634 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By F. A. Myzenkov

The technology developed by the authors uses new methods for raw material smelting in electric furnaces, a new autogenous method and apparatus for subliming smelting for antimony trioxide production and separation of antimony and gold. Concentrate produced from the ore deposits in Yakutia has the following average contents of main constituents, % by weight: 29.4 Sb, 1.2 Fe, 13.1 S, 40.0 SiO2, 0.2 As, 2.6 CaO and 45 g/t of Au. Unlike the technology used abroad a new autogenous method makes it possible to increase considerably specific capacity and reduce gold losses with antimony trioxide by several times. At the same time mineralogical composition of trioxide has improved considerably ? it has mainly a cubic base with prevalence of senarmontite. The content of a main component (Sb2O3) in the final product has increased from 99.0% up to 99.6% which means better quality and makes it suitable for use in special technologies. Despite a lower antimony content of the concentrate (29.4% as compared with over 33% as common in the world practice), an antimony recovery of 85.3% into a commercial-grade product has been achieved, as well as a gold recovery of 96.65% into a gold-antimony alloy. The technology for processing gold-antimony materials developed and introduced at the Ryaztsvetmet plant is unique in the world with respect to gold recoveries.

Jan 1, 2006

By J. E. Quinn, S. Wolstencrof, K. H. Soldenhoff

Ion Exchange (IX) using Strong Base Anion Exchange (SBA) resins is conventionally used to purify uranium from sulfuric acid pregnant leach solutions (PLS), particularly when uranium grades are relatively low. However, the presence of chloride in the PLS interferes negatively with conventional SBA based IX processes, by reducing the uranium loading on the resin. Chloride can be present in the PLS due to the use of saline bore or seawater in leaching, or chloride containing leach/IX reagents. ANSTO has been examining strategies to combat this problem for several years. ANSTO previously reported that a recently developed high-capacity SBA resin was capable of extracting uranium efficiently from saline leach liquors produced at Boss Resources’ Honeymoon in-situ recovery mine in South Australia. The resin was tested successfully in a 2017 Field Leach Trial carried out onsite in the existing wellfield area. While the piloting was extremely promising, the elution was more challenging, with eluate tenors limited to 2 g/L U3O8 using NaCl. This is due to the resin’s strong affinity for the uranium complex, which makes it difficult to elute efficiently by standard methods. In this paper, we describe a novel elution process developed for strong base resins that significantly improves upon conventional methods. The process, developed by ANSTO, is based upon conversion of the extracted uranyl sulfate species to uranyl carbonate, followed by elution with sodium chloride. The loading and elution process was demonstrated in continuous locked-cycle piloting conducted at ANSTO in 2019. The results were excellent, with eluate tenors of 8–9 g/L U3O8 achieved from Honeymoon PLS containing 50 mg/L U3O8, with very little transfer of impurities. In subsequent test work, the eluate was shown to be amenable to uranium peroxide precipitation. The results represent a huge step forward for the purification of uranium from saline leach liquors.

Jan 1, 2020

By S. Hadley, M. Placha, M. Mishra, V. Choudhry

Under a DOE-funded project, four advanced flotation technologies (the Jameson cell, the Outokumpu HG Tank Cell, an open column and a packed column) were evaluated at the benchscale to identify the technology or combination of technologies that best improved fine coal recovery and reduced processing costs. The results indicated that two-stage application of the Jameson and packed column cells provided the optimal performance. Subsequently, proof-of-concept scale testing was conducted at the Cyprus Emerald Coal Preparation Plant. The results confirmed that levelized production costs were lower using two-stage cleaning with the Jameson cell followed by the packed column.

Jan 1, 1999

By A. Hotta

Reduction of CO2 emissions is the key driving force behind the development and implementation of new solutions for energy production. One solution is circulating fluidized bed (CFB) combustion technology combined with a high-efficiency once-through water-steam cycle. Foster Wheeler's CFB technology is today commercially available in capacities up to 800 MWe with ultra-supercritical steam parameters. Simultaneously, the Flexi-Burn® CFB technology is being developed to provide capability of flexible operation in air firing and oxy-combustion for carbon capture. CFB technology can offer an attractive solution for the reduction of CO2 emissions, owing to advantages such as fuel flexibility and low emissions that the air-fired CFB technology offers today. Pilot test facilities provide information about the performance of CFB oxy-combustion technology, and the acquired knowledge is being incorporated in boiler modelling and design tools. One of the European R&D initiatives on carbon capture and storage (CCS) is the Technological Centre for CO2 Capture and Transport, which is supported by the Spanish Government through the Fundación Ciudad de la Energía (CIUDEN). CIUDEN is a research and development institution created by the Spanish administration in 2006 and fully conceived for collaborative research in CO2 capture, transportation, and storage. The Technology Development Centre for CO2 Capture and Transport comprises two technologies on oxy-combustion: pulverized coal (PC) and circulating fluidized bed (CFB). This paper will focus on the design and main characteristics of the 30 megawatt-hour thermal capacity (MWth) oxy-CFB boiler. Foster Wheeler is the technology provider of the Flexi-Burn CFB unit, for which commissioning has been completed in the first quarter of 2011. The CFB unit design allows operation either under conven¬tional combustion with air or under oxy-fuel conditions. The size of this experimental boiler is sufficient to allow the scaling of the results to commercial units. In this way, multiple fuels and operating conditions can be tested economically. The results will validate the design of a future 330 MWe supercritical Oxy-Combustion Power Station (OXY-CFB-300 Compostilla Project) intended to demonstrate the CCS technology at commercial scale. The Compostilla OXY-CFB-300 Project is one of the six CCS demonstration projects funded under the European Energy Programme for Recovery (EEPR) of the EU. The project is based on a future 330 MWe CFB supercritical oxy-combustion plant, with CO2 storage in a deep geological formation. The first phase of the project, granted by the EEPR programme and led by the Spanish utility ENDESA, includes all studies and characterization work needed on CO2 capture, transport, and storage, as well the costs, financing, and regulatory and permitting required, prior to the final investment decision for the construction phase of the plant by the end of 2012.

Jan 1, 2012

By Joseph T. Duncan, Syd Peng, Larry G. Stolarczyk

The mining business has numerous risks: equipment availability, labor disruptions, foreign exchange rate, etc., but one of the more important risks is assessing the geology. Improving the “intelligence” of geology can and will have significant positive effect on reducing mining risk and thus enhancing operational and financial performance. The use of the advanced Radio Imaging Method (RIM-IV) on coal seams and ore bodies can create useful two-dimensional (2-D) and three-dimensional (3-D) high-resolution images that provide mining engineers with additional intelligence to better plan and improve operations. Improved operational performance will reduce costs and enable mining companies to meet market and financial commitments. For the past decade the underground coal mining industry has been moving toward “super panels” in long-wall mining, and “super sections” for room-and-pillar mining. These mining conventions employ wider faces, longer gate roads, greater room-and-pillar density, and an increased scale in the amount and complexity of mining equipment. An obvious economy of scale exists: amortization of setup investments over greater volume of coal enables mine management to reduce fixed cost per ton. Restricted by equipment considerations, face widths have currently reached about 1,100 ft. Wider longwall panels are planned, with 1,400-ft widths, but this requires an incremental step in hardware that the original equipment manufacturers will soon bring to market. However, longwall panel length has not yet reached its limits, with some panels planned up to 25,000 ft. While longwall panel length is generally dictated by reserve size and extent, practical restrictions in mine planning also include seam thickness, ventilation requirements, or restrictions involving methane drainage. Super panels have certainly enabled the industry to keep pushing the limits of productivity improvement. However, important considerations in mine planning, now and especially in the future, will be driven in large part by geological factors. While larger developments improve productivity and capture economies of scale, the fact that super panels can contain at least four times the area or coal volume means that the probability of encountering serious anomalies is at least four times greater than with the “conventional” panels. Given the increased probability of encountering anomalies, improved assessment of geology is important for super panels and super sections. Proper due diligence requires a thorough and competent evaluation of a mining property and its ore reserve. Using improved geostatistical techniques is most important, and improving the base data for the analysis is equally important. The old cliché “garbage in, garbage out” certainly applies. Also, the quality of coal reserves is (or has been) declining, so, in the future, mining will be in deeper and most likely thinner seams—and these seams appear to contain greater anomalies that threaten efficient operations. To counter the impact of reserve deterioration, the industry is moving toward greater use of geophysical tools and services. Fortunately, tools such as the Radio Imaging Method™ (RIM-IV) system have been improved and can provide the industry with enhanced 2-D and 3-D images of coal seams and ore bodies. To identify and profile the best areas of a coal reserve, geologists, engineers, and mine managers need greater intelligence in the form of RIM-IV tomographic maps of longwall panels and room-and-pillar sections. These images have enhanced the understanding of in-seam features, which in turn has improved operational plans and performance.

Jan 1, 2005

By R Edwards

Greater efficiency of capture of minus 6 mm to fine micron size particles of free gold is achieved with the Knelson Concentrator. The development, principles of operation and recent innovations relating to this enhanced gravity concentrating device are described by the inventor, followed by a description of application and consequent economic benefits in low grade alluvial gold deposits by a large scale user of Knelson Concentrators in the Northern Territory of Australia.

Jan 1, 1990