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By Fabio do Prado Verderano

A partir de corpos de prova de uma chapa de aço baixa liga NBR 6656 grau LNE 26, realizou-se a caracterização microestrutural, levantamento do perfil de dureza ao longo da espessura da chapa, ensaios de tração monotônicos, cíclicos de fadiga e análises fractográficas. Concluiu-se que, nas extremidades da espessura da amostra, o valor da dureza é maior, indicando que quando a chapa foi laminada as superfícies em contato com os rolos de laminação sofreram encruamento, aumentando a dureza nessa região. A microestrutura encontrada e o grau das inclusões presentes na amostra são compatíveis para o material, bem como as propriedades mecânicas monotônicas, que estão de acordo com a especificação. Por meio de ensaios de fadiga de baixo ciclo, encontrou-se uma boa correlação entre as propriedades monotônicas e cíclicas do material para a proposição da equação de Basquin, considerando-se dados seguros, quando utilizado os primeiros vinte ciclos do ensaio de fadiga para estabilização de cada corpo de prova. Verificando-se a seção transversal da fratura do corpo de prova, observa-se que o mecanismo de falha do material ocorreu a partir do aparecimento de trincas na interface ferrita-cementita com propagação transgranular até a fratura final.

Aug 17, 2017

By Mauro Araújo Medeiros

Os aços inoxidáveis dupex tem sido largamente empregado em vários setores da industria principalmente em virtude da sua boa combinação entre suas propriedades mecânicas e resistência a corrosão. Um aço inoxidável duplex DIN W. Nr. 14462 foi submetido a ensaios de torção a quente com taxas de deformação de 0,3; 0,5; 1; 3 e 5 s-1 a temperaturas que variou entre 1.000 e 1.150°C. As amostras deformadas foram analisas através de microscopia ótica. As configurações das curvas de escoamento plástico foram analisadas em termos dos parâmetros de fluxo localizado como um mecanismo de acomodação da deformação durante a torção a quente. As microestruturas reveladas mostraram que o comportamento plástico do material é influenciado pela disposição inicial das partículas de austenita na matriz ferrítica e a queda de tensão após o pico esta relacionada à ocorrência de fluxo localizado na matriz ferrítica associado à fragmentação das partículas de austenita durante o processamento, bem como aos fenômenos de recuperação e recristalização dinâmica, típicos dos aços inoxidáveis duplex.

Aug 8, 2018

By Gilvandro Bueno

Os controles dos processos de cominuição estão normalmente associados à redução de granulometria e geração de superfície específica, usualmente utiliza-se peneiramento para medição de granulometria e permeabilímetro de Blaine para superfície específica, estes métodos são largamente utilizados para este fim. O método on line por difratômetros a laser também pode ser empregado para estas medições na indústria, como se trata de uma tecnologia recentemente adaptada para ao processo de Pelotização, foi necessário validar o equipamento e determinar equações de correlação de leitura com os equipamentos existentes. O trabalho consistiu em realizar uma série de amostragens cujas amostras foram analisadas no equipamento industrial a laser, em seguida analisadas em laboratório. As equações de correlações obtidas foram inseridas no equipamento industrial de medição on line por laser tornando a leitura familiar aos obtidos pelas análises de laboratório, onde foi possível garantir confiabilidade para tomadas de decisões.

Aug 1, 2018

By Robson Aguiar de Macedo

O estudo de ligas livres de Pb envolvendo o emprego de junções metálicas sob altas temperaturas tem recebido atenção especial, sendo desenvolvidas novas ligas com qualidade e desempenho adequados. Ligas Bi-Ag consistem em alternativas promissoras para a substituição das ligas de solda contendo Pb para tais aplicações, por isso devem ser melhor caracterizadas sob o aspecto de estruturas brutas de fusão. Assim, o presente trabalho objetiva investigar a liga hipoeutética Bi-1,5%Ag (%em peso) solidificada unidirecionalmente sob regime transitório de fluxo de calor. Será analisada a influência dos parâmetros térmicos de solidificação como velocidade de solidificação (VL), taxa de resfriamento (?) gradiente de temperatura (G) na microestrutura e na evolução de dureza da liga citada. Para determinação do perfil de dureza, foram realizados ensaios de dureza Vickers. Para obtenção e caracterização das microestruturas presentes no fundido Bi-1,5%Ag, fez-se o uso da microscopia ótica e da fluorescência de raios-x. Uma estrutura de dendritas facetadas de Bi circundadas pelo eutético Bi-Ag prevaleceu ao longo do lingote Bi-1,5%Ag. Verificou-se um aumento gradativo dos espaçamentos dendríticos primário (?1) e secundário (?2) à medida que a distância da base refrigerada foi aumentada. Em geral, os valores de dureza diminuíram para maiores valores de ?1 e ?2.

Aug 7, 2018

By Caroline Gomes de Oliveira

As fibras lignocelulósicas representam vantagens econômicas, técnicas e ambientais em comparação com as fibras sintéticas, como fibra de vidro por exemplo, quando se considera as alternativas de reforço aos compósitos. A fibra natural usada no presente trabalho é a fibra de eucalipto, que é largamente cultivada em território brasileiro. Este trabalho tem como objetivo avaliar uma análise estatística da correlação entre o diâmetro e a densidade da fibra de eucalipto. Para isso, foi aplicado o método de Weibull. O diâmetro foi obtido por meio de medições em projetor de perfil, enquanto a densidade utilizou determinações precisas da massa e do volume de fibras. Os resultados revelaram uma dependência inversa entre o diâmetro da fibra de eucalipto e sua densidade

Aug 17, 2017

By Catia Casagrande

O processo de pelotização foi desenvolvido com a finalidade de aproveitar as partículas finas e ultrafinas geradas nas operações de exploração e tratamento do minério de ferro. Os principais minérios que alimentam as usinas de Pelotização de Tubarão/Vitória/ES são provenientes das minas Brucutu, Fábrica Nova, Alegria, Conceição e Cauê. Os estudos de caracterização mineralógica e testes tecnológicos são realizados para auxiliar o processamento de minérios. Entretanto, alguns minérios possuem grande variabilidade de participação de minerais em sua composição, gerando necessidade de ajustes no processamento dos mesmos. Ter a previsibilidade mineralógica dos minérios é muito importante para atuar no processo com antecedência, realizando ajustes operacionais caso necessário, a fim de ganhar qualidade e reduzir custos. O método de cálculo normativo mineralógico é uma técnica nova que utiliza os resultados de análise química como base para quantificar minerais presentes no minério de ferro. O objetivo principal deste trabalho foi avaliar a aplicabilidade da metodologia de cálculo mineralógico normativo por meio de correlação com a microscopia ótica. As amostras analisadas foram pellet feed das minas de Fábrica Nova, Alegria e Brucutu. O estudo mostrou que existem diferenças entre as técnicas, entretanto os resultados foram promissores e satisfatórios.

Aug 17, 2017

By Agnes Ágata Fróes Martins

Placas ósseas metálicas são componentes utilizados para correção ou cura de fraturas ósseas. Em se tratando de implantes ortopédicos, é fundamental conhecer o comportamento dos materiais quando submetidos a esforços mecânicos. Para isto ensaios são realizados baseados em normas técnicas, que no caso específico de placas ósseas, são utilizadas as normas ASTM F382 e ABNT NBR 15672-2. Na execução do ensaio para determinação da rigidez à flexão, de uma placa óssea, pode existir o efeito da flexibilidade do dispositivo de ensaio. Para verificar a magnitude desse efeito, foram realizados três ensaios de flexão estático e um ensaio de flexibilidade do dispositivo de ensaio, onde o ensaio foi interrompido ao final da fase elástica. As propriedades mecânicas da placa foram avaliadas, aplicando a correção da flexibilidade do dispositivo. Os resultados mostraram que para os níveis de carregamento alcançados, as cargas de prova apresentaram pouca influência na flexibilidade do dispositivo, e consequentemente pouca influência na rigidez após os cálculos de correção.

Aug 8, 2018

The captions to Figs. 1 and 2 of the paper by B. J. Parry entitled 'High-strength cold-rolled steels' should read as follows:

Jan 1, 1984

"After the non-destructive testing is completed, the data must be compiled, evaluated, and interpreted. During this process, the data may indicate that there is an anomaly warranting further investigation, which may eventually be determined to be a flaw or defect. The definitions of an anomaly, flaw, and defect can be described as follows (after Amir, 2002):Anomaly - Any irregular feature identified in the NDT graphic results. An anomaly may be due to the testing instrumentation (such as noise), to the means used to perform the test (e.g. access tube debonding in CSL) or to the shaft itself. It is the responsibility of the NDT practitioner to gather and analyze all relevant data and try to resolve every anomaly before it is declared a flaw or defect.Flaw - Any deviation from the planned shape, size and/or material of the shaft.Defect - A flaw that, because of either size or location, may detract from the shaft’s intended performance or durability. The geotechnical engineer and the structural engineer are jointly responsible to decide which flaw comprises a defect.This section describes the process of evaluating the data, determining if an anomaly exists, and if so, deciding whether the anomaly is actually a flaw or a defect. If the anomaly is determined to be a defect, its effect on the performance of the shaft must be evaluated, and if necessary, the can be re-engineered, repaired, or replaced."

Jan 1, 2004

By Tobin GJ

Testwork carried out in the cooling water circuit at the Yabulu treatment plant of the Greenvale Joint Venturers (Metals Exploration Queensland Pty. Ltd. and Freeport Queensland Nickel Incorporated) since 1980 has resulted in significant improvements to both fouling and corrosion control. At the same time corrosion inhibitor costs have been reduced.Acrylate-type silt dispersants were identified as the most effective means of sediment control in the circuit. An increase in the cathodic component of the corrosion inhibitor coupled with a relatively minor adjustment to water pH has yielded a two to three fold reduction in corrosion rate. It has been established that these lower corrosion rates can be sustained in the face of a 20% reduction in corrosion inhibitor addition rate. Further improvements are indicated with a change of raw water algicide.

Jan 1, 1985

By Tatiana Kotrikova, Steven Kolarz, Alan Kolodne, James Parkes, Matthew Goff

The WMATA Yellow Line is the section of steel segmentally lined tunnels that have experienced leakage and significant corrosion in isolated areas. A three part rehabilitation design has been developed for curtain grouting, structural repairs, and corrosion protection to provide continued performance. As WMATA’s first Construction-Manager-at-Risk (CMAR) project, the design development benefitted from collaboration with the Contractor through the final design development process. Rehabilitation work started in Fall 2022 and will be completed by late Spring 2023. Details of the project, the remediation design, and the process and benefits of the CMAR approach in the design development are presented.

Jun 13, 2023

By N. O. Taylor

THE failure, by swelling, of several cast aluminum-zinc, spiral, pump rods, used to circulate water in a constant-temperature bath, brought up the question as to whether the presence of tin in varying quantities would have any appreciable influence in controlling this action. Previous workers had found the same difficulty with aluminum-zinc alloys, due to their swelling in water or solutions of electrolyte^.^ It was known that pure aluminum was practically insoluble in concentrated sulfuric and nitric acids, presumably due to the formation of an oxidized film on the surface. Concentrated sulfuric acid had little or no effect on pure zinc and tin and concentrated hydrochloric acid would attack all three metals. These facts aroused curiosity as to the probable reaction of the ternary alloys of these metals, and tests were made to determine their resistivity to the action of common laboratory reagents. Samples, covering the entire range of the ternary series of aluminum, zinc and tin alloys, were made up from good grades of the commercial metals.2 The materials were melted, at as low temperatures as possible, in graphite crucibles in a gas-fired crucible furnace. Graphite crucibles were used in preference to clay, to prevent the absorption of silicon by the aluminum, as found by previous workers. The melted materials were stirred thoroughly with pine sticks in order to ensure complete mixing and the greatest possible freedom from oxidation, and were cast in sectional, iron molds giving bars % in. in diameter and 5 in. long.

Jan 1, 1927

By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017

By Anja Pfennig, Axel Kranzmann, Phillip Zastrow

"Properties of pipe steels for CCS technology require resistance against the geothermal corrosive environment (heat, pressure, salinity of the aquifer, CO2-partial pressure). To predict the reliability of two different injection pipe steels with 13% chromium and 0.46% carbon (1.4034, X46Cr13) as well as 0.20% carbon (1.4021, X20Cr13) steel coupons were heat treated by comparable routines prior to long term corrosion experiment (60°C, 100 bar, artificial brine close to a CCS-site in the Northern German Basin, Germany). In general higher carbon content exhibits better corrosion resistance with respect to corrosion rate, amount of pits and maximum intrusion depth in the case of local corrosion. At 100 bar hardened steels with martensitic microstructure have the lowest corrosion rates with an average of 0.003 mm/a after 2000 h exposure time. At ambient pressure normalized steels show the lowest corrosion rates, indicating that the corrosion is driven by grain boundaries.IntroductionEngineering a geological on-shore saline aquifer CCS-site (CCS Carbon Capture and Storage [1-3]) corrosion of injection pipe steels may become an issue when emission gasses, e.g. from combustion processes of power plants, are compressed into deep geological layers [4-8]. Typically 42CrMo4 (1.7225, AISI 4140) is used for casing, and for injection pipe the steel X46Cr13 (1.4034, AISI 420 C) or X20Cr13 (1.4021, AISI 420 J) is used. Saline formations are the most favorable storage sites in Germany [9], because of their large potential storage volume and their common occurrence. Leakage of CO2 back into the atmosphere may be a problem in saline aquifer storage, especially around the water level within the borehole. Carbon dioxide corrosion may cause failure of pipelines and wells as known from the oil and gas industry [4,6,10,11, 12].From thermal energy production it is known, that the CO2-corrosion is sensitively dependent on alloy composition, contamination of alloy and media, environmental conditions like temperature, CO2 partial pressure, flow conditions and protective corrosion scales [6-8,13- 20]. Considering different environments, aquifer waters and pressures, the analyzed temperature regime between 40 °C to 60 °C is a critical temperature region well known for corrosion processes as shown by Pfennig et al. [21-23] and various other authors [10,24-28] (figure 1). Here a maximum around 4.7 mm/year was found for the pit intrusion depth of 13% Cr steel X46Cr13. Still this may be predicted by the rather conservative Norsok-Model used in the oil and gas industry to calculate surface corrosion rates of carbon steels [29]."

Jan 1, 2014

By P. Gautier

Current feedstock in the aluminum hot forging processes can be used in the cast or extruded forms. The microstructural variation between as-cast and extruded materials could result in different mechanical properties and corrosion resistance for hot-forged products. Corrosion performances were examined for forged parts produced by two AA6082 feedstocks at different conditions using the following corrosion tests: open circuit potential, anodic polarization, salt spray exposure and corrosion fatigue. With the help of optical and scanning electron microscopes, metallographical investigations were carried out on cast-forged and extruded-forged materials before and after corrosion. The corrosion behavior of both materials was compared in both as-forged and aged tempers. Results show that there is no significant difference in the corrosion performance for final cast-forged and extruded-forged products.

Jan 1, 2011

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By C. Liu

Corrosion behavior of the stir zone in a friction stir weld of dissimilar A12024/AZ31 alloys was investigated in the immersion test in distilled water (pH=6) for different times. Microstructures and the distribution of chemical elements were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Due to the difference in the corrosion potentials between A12024 and AZ31, the AZ31 alloy constituent in the stir zone was susceptible to the corrosion attack in the distilled water. The corrosion attack was found to occur in the narrow region of the AZ31 alloy adjoining the A12024 region, where there was a low ratio of anode-to-cathode surface area. The corrosion attack became more severe in the AZ31 alloy regions with increasing immersion time. The A12024 alloy region in the stir zone of the weld was protected by cathodic reactivity due to sacrificial anode AZ31 alloy.

Jan 1, 2007

By Ham. Y. M.

The corrosion behaviour of Al-B4C metal matrix composites immersed in 2500 ppm boron-containing H3B03, 0.5 M K2SO4, and 3.5% NaC1 solutions was investigated. Effects of B4C particle volume fraction on the corrosion behaviour of composites were studied using potentiodynamic polarization and electrochemical impedance spectroscopy techniques. Scanning electron microscopy was employed to study the surface morphology of the material before and after corrosion. Results show that all materials investigated are more corrosion resistant in 2500 ppm boron-containing H3B03 than in other solutions. No appreciable corrosion was observed in boric acid and sulfate solutions in contrast to an obvious pitting in NaC1 solution for both base alloy and composites. The preferential pitting sites are the interfaces of Al/Fe intermetallics for the base alloy, and the A1/B4C interfaces for the composites. Increasing the volume fraction of B4C particles in the composite decreases its corrosion resistance of Al-B4C composites.

Jan 1, 2011

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

By F. Charette

The paper reviews recent investigations of the impact of corrosion on the performance of both plain and coated Swellex rock bolts. It addresses the problems associated with estimating and predicting corrosion rates of friction bolts, and based on field data it suggests an empirical relationship to predict corrosion rates. A review of the necessary qualities for a protective coating leads to recent experience with coated Swellex bolts that suggest that they can contribute to extending the useful life of Swellex bolts in potentially corrosive environments.

May 1, 2004