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By Bahaa Alyosif, Turan Uysal, Muhammet Kürsat Aydemir, MURAT ERDEMOGLU

 The paper investigates the effect of intensive milling on the conversion of microcline to potassium chloride during chlorination roasting. The study aims to improve potassium recovery by reducing the chlorination roasting temperature through mechanical activation.

Aug 1, 2023

By Bahaa Alyosif, Murat Erdemoğlu, Muhammet Kürşat Aydemir, Turan Uysal

The effect of intensive milling on the conversion of microcline ( KAlSi3O8) to potassium chloride (KCl) occurred during the chlorination roasting process for artificial KCl production was investigated. A feldspar ore with 10.89% K2O grade and containing microcline was dry milled by a planetary ball mill for mechanical activation. Milled ore mixed with calcium chloride was roasted at temperatures between 500 and 1000 °C to get the chlorination roasting process. The product was then leached in water to dissolve KCl occurring during the roasting, which will be precipitated from the pregnant leach solution by evaporation. Results showed that potassium recovery from the unmilled ore increased rapidly up to 800 °C, and dramatically decreased at higher temperatures due to the removal of KCl from the furnace by means of evaporation. A potassium recovery of 31.95% was achieved by the unmilled ore, whereas it was 88.43% when 15 min milled ore was roasted at 750 °C. It was concluded that intensive milling caused mechanical activation of microcline to reduce the roasting temperature of the chlorination roasting process.

May 31, 2023

By A. Delgado-Jiménez, O. J. Restrepo-Baena, G. Aristazabal

"Mining industry as a source of raw material is essential to society however, it lacks of good reputation due to the type of management historically applied to many of its social and environmental impacts. It is argued that this situation has hampered the obtaining of social license to operate of a lot of mining projects around the world. The last considerations are very common in Latin American countries. As a result, the mining sector has understood that the viability of the business long term is associated with more profit for the shareholders but also with activities that improve the livelihoods of local communities, enhance the capabilities of local governments and preserve the ecosystems around the projects. Nevertheless, recent studios have shown that most of the current advances to incorporate sustainability concepts in mining have been mainly focused on control and the prevention of environmental and social impacts of extractive activities. Thus, contributing to the development of territories around mining projects constitutes a fundamental aspect of the business competitiveness through reducing cost and risks of stopping projects, innovating new ways of relationship with stakeholders, improving the level of reputation of the industry as well as its position in the market. However, this contribution requires formal strategies and models that enable companies understand the different resources in the territories where their mining activities are developed and those resource transformations, in order to establish the best way to articulate the project with the territory, pursuing an effective contribution to its development, truly sustainable over time even after the mine closure. CONTEXT Currently in the world but especially in developing countries such as Latin Americans, different stakeholders are increasingly vigilant of how mining companies carry out their activities in terms of socio-economic and environmental management of territories, not only for its impact on the livelihoods of the communities that inhabit them, but also because many demanders of raw materials -both countries and companies- have set sustainability standards as a prerequisite to establishing business relationships with mining companies, such as the recently declared Sustainable Development Goals by 2030 (UN, 2015). Accordingly, decide underinvest or not to invest in sustainability issues carries risks for mining companies. However, invest much in the wrong way may involve the same risks. Managers are concerned to ensure profits, and therefore they decide carefully how to invest in the areas of production, R & D or marketing. Likewise, they should think strategically about investing in initiatives related to sustainability. This if they really want that those investments in fact help to improve the competitiveness of the company. The mining industry benefits from natural capital that extracts, so it should implement strategies that lead to remunerate such benefit to the territories (Almaguer, 2007). One option is through the transformation of natural capital in other types of non-existent capital or poorly developed in their areas of influence. In this way, the value generated by the extraction of underground resources is shared and additionally contributing to improving the quality of life of the communities. Historically, mining industry has been into several problems to achieve this, which represents one of the aspects that has most influenced the current reputation of mining industry in some regions of Latin America. Many communities, local governments and civil society organizations continue to associate this activity with the destruction of the social fabric and ecosystems in the territories, and their opposition against companies working in the areas has led to affect the operational continuity of many projects (Hamann, 2003; Prno and Scott, 2012; Slack, 2012)."

Jan 1, 2017

It is well known that the electrochemical precipitation of metals from aqueous solutions is conducted by the electrochemical standard potential scale. This scale indicates the order of nobility of different metals. Consequently, the standard potential scale shows the nocivity of metals when they are present as impurities in aqueous solutions containing metals. In the hydrometallurgy of cobalt, nickel and zinc are co-deposited during cobalt electrodeposition. Nickel has almost the same chemical, physical and electro-chemical properties as cobalt. Furthermore, the electrochemical potential of nickel is relatively higher than that of cobalt. For this reason nickel is preferentially reduced at the cathode in the presence of cobalt. The presence of small amounts of zinc in solution leads to contamination of cobalt electrowon. In spite of its lower electrochemical potential in comparison to cobalt, zinc is reduced on the cathode because of its higher hydrogen-overvoltage. But, in the hydrometallurgy of zinc, small amounts of cobalt present solution will contaminate the zinc reduced at the cathode. This is easily explained by the fact that cobalt is more electropositive than zinc. The co-deposition mechanism of sulphur at the cathode is not yet well understood. Great attention has to be paid to the mechanism of co-deposition of sulphur during cobalt electrolysis. This work aimed to investigate the influence of some parameters on the co-deposition of nickel, zinc and sulphur during cobalt electrowinning. The following parameters have been investigated: Co2+concentration in the electrolyte, current density and ammonium sulphate (NH4)2SO4additions. It has been established that important nickel, zinc and sulphur co-deposition takes place at relatively low Co2+ concentration in solution. The behaviour of these elements with regard to the cathodic phenomena has been established.

Jan 1, 2005

By R. V. Ramani, S. Shankar

"A convective dispersion model has been utilized to calculate the real-time airborne dust concentration in mine airways using re-entrainment as the only source term for airborne dust. It incorporates two important sources of re-entrainment in mines -- air velocity and movement of objects. The model has a sink term accounting for the deposition of particles along the airway. The model is solved using a finite difference scheme which is coded for computer. The computer model outputs airborne respirable and total dust concentrations along the airway as a function of time. The real-time and average gravimetric concentrations from several in-mine experiments were compared with the results from the simulation of the experimental conditions. This model can be used for estimating airborne dust entrainment due to air velocity, equipment movement, and persons walking. INTRODUCTIONEdwards and Ford (1988) developed a model for coal dust explosion suppression and utilized a predetermined value of threshold velocity for flowing air to pick up dust from floor. Depending on the strength of the removal forces, re-entrainment can increase the airborne dust concentration in mine airways. The most prevalent forces causing re-entrainment in mine airways are the drag and lift forces due to flowing air, and removal forces due to the movement of persons and vehicles. Shankar and Ramani (1991) have investigated the unique characteristics of the re-entrainment phenomenon in mine airways. Experiments on re-entrainment of coal dust particles were conducted in mine airways, and in a wind tunnel (Shankar and Ramani, 1994a, and 1994b). The results from the two experimental studies were found to compare well (Shankar and Ramani, 1995). There is no reported model to determine the airborne dust concentrations due to airflow or persons walking under conditions existing in mines. The present study is a part of a continuing research project in the Generic Mineral Technology Center for Respirable Dust on the spatial and temporal behavior of airborne dust in mine airways (Ramani, 1983)."

Dec 1, 1996

By O. Guven, I. Karaagaçlioglu, O. Ozdemir, M. Çelik

In this study, the effect of morphological properties such as shape factors and roughness of the glass beads on their flotation efficiency were determined using image analysis and profilometer methods. There is a considerable correlation between the shape factors, surface roughness and flotation behavior of the glass sample. These results indicate that as the particle shape is away from roundness and smoothness, it acquires more hydrophobicity.

Jan 1, 2014

By Gérald Riverin

Over the past century, exploration methods for volcanogenic massive sulphide deposits have evolved in response to a decreasing number of discoveries made by traditional surface prospecting and by ground and airborne geophysics. Statistical trends support the concept that fewer and fewer outcropping and sub-cropping VMS discoveries will be made in the future. In turn, this creates new opportunities to develop more sophisticated exploration models and techniques to explore at greater depth and to make blind discoveries. Current exploration models include various combinations of geological, geochemical and geophysical criteria which have been based on the results of land-based VMS research. The role of seafloor research in the development of these models has so far been only of a subordinate nature, perhaps due to a lack of direct involvment of the exploration industry in the seafloor research, and vice-versa for the seafloor researchers in VMS exploration. Another contributing factor is that exploration relies on exploration criteria that result from detailed geological, geochemical and geophysical studies of both footwall and hanging wall rocks, studies that are not possible in modern sea floor environments. Nevertheless, seafoor research has contributed to our understanding of the growth of sulphide mounds, the mechanism of sulphide deposition and of the chemistry of fluids involved in VMS systems. In particular, the role of structure and of tectonic setting has been clarified through observation of active seafloor hydrothermal systems. In turn, observations made in land-based VMS research has helped seafloor researchers to focus on key issues which, will eventually contribute to improved exploration models.

Jan 1, 1998

By R. V. Ramani, W. Miola, R. Srikanth, S. C. Soboleski

"Dust control in high-production longwalls requires attention to operating practices and ventilation schemes. Several studies have shown that the shearer is the major source of dust on a longwall face. Support movement has not been regarded as a major source of dust in US longwalls. Yet, under certain conditions, 31% of the shearer operator's dust exposure can be due to support movement.Several methods have been developed for the control of shield-generated dust. But the need for better methods is apparent. In this paper, the amount of airborne, respirable dust generated per shield move is estimated from specially designed experiments on longwall faces. Ten experiments were conducted on five longwall faces in four mines. Each experiment involved one face visit and lasted three to six hours. The contribution of shield movement to the airborne, respirable dust concentration immediately downwind of the shield move varied between 0.12 and 1.75 mg/m3 in the five longwall faces. The mass of airborne, respirable dust gener-ated by shield movement was found to vary between 39 and 386 mg per shield move. The results from this study reveal that control of dust from longwall shields requires a combi-nation of approaches involving alternative operating prac-tices, reducing shield dust generation rate, increasing face air flow and decreasing personnel exposure.IntroductionIn 1992, longwall mining accounted for about 36% of US underground coal production, a 240% increase from a decade ago. The absolute longwall tonnages were 46 and 133 Mt (51 and 146 million st), respectively. Compared with room-and¬pillar mining systems, the longwall mining system is charac¬terized by higher recovery, enhanced safety and higher pro¬ductivity.However, personnel dust exposure on a longwall face is higher than in other types of mining. According to Mine Safety and Health Administration (MSHA) data, fewer longwalls were in continuous compliance with the applicable dust standard in 1992 than in 1989.Controlling shearer-generated dust and reduction of per-sonnel exposure to airborne dust have commanded attention in the design of longwall faces, operational practices and ventilation schemes. Studies in the United States and abroad have revealed that support-generated dust can be a major obstacle to compliance under certain conditions (Becker et al., 1989; Bradley et al., 1983; Jankowski and Organiscak, 1983; Jankowski et al., 1990; Organiscak et al., 1985)."

Dec 1, 1996

By G. Kritikakis

Rehabilitation of sites contaminated by oil products and chlorinated organic compounds is a costly task which affects the planning of urban and infrastructure development. An integrated approach based on the non-invasive geophysical technology is utilized for subsurface characterization of contaminated land. In this approach the localized information, provided by chemical analysis of soil samples collected from bore-holes, is used for the calibration of the geophysical data. This information is subsequently extrapolated to the area under investigation by combining it with the geophysical results, providing thus information about pollution accumulation, contaminants? flow and pollution sources. Two case studies are presented from sites contaminated by heavy metals (Venice, Italy) and oil products (Athens, Greece). Resistivity, electromagnetic and seismic methods were used in this approach. Namely, electrical tomography, electromagnetic mapping, ground penetrating radar (GPR), multichannel analysis of surface waves (MASW) and seismic refraction experiments were conducted. In Italy, the sections from the multichannel analysis of surface waves imaged successfully a buried channel where the pollution is concentrated. Preliminary results are also discussed from the geophysical survey in Greece where the thickness of the oil phase located on top of the water layer is 60 cm.

Jan 1, 2006

By Ricardo Chavex, Adrien Letellier

Flyrock remains one of the most critical issues in open-pit blasting. Despite the significant improvements made with modern surveying methods, the necessity remains to define sensible danger zones around blasting areas. Therefore, many semi-empirical models predict flyrock distances based on trajectory calculations and probabilistic adjustments. However, most are merely based on nominal parameters, even though a considerable amount of precise data is nowadays available thanks to modern measurement techniques using lasers, GPS, drones, and probes. These data provide accurate information about the actual field circumstances of a blast concerning geometry and rock-mass conditions. So how can we use and integrate them into existing flyrock models? The answer to this question can significantly improve the accuracy of flyrock prediction models and enhance safety. This paper will present a method to adapt existing models to actual field data using appropriate software and digital tools during the blast design process. In addition to calculating a more pertinent danger zone perimeter, this method provides an efficient and practical tool that helps prevent flyrock incidents. Indeed, it allows the blast designer and shot firer to be warned if there is a hazardous critical deviation due to local conditions. Moreover, it also enables blasters to communicate better and share the visualization of the blast-specific evacuation zone. The paper will also discuss how this method can be calibrated and how it has been used to analyze some actual flyrock incidents.

Jan 21, 2025

By K Kongolo, M K. Kalenga

It is well known that the electrochemical precipitation of metals from aqueous solutions is conducted by the electrochemical standard potential scale. This scale indicates the order of nobility of different metals. Consequently, the standard potential scale shows the nocivity of metals when they are present as impurities in aqueous solutions containing metals. In the hydrometallurgy of cobalt, nickel and zinc are co-deposited during cobalt electrodeposition. Nickel has almost the same chemical, physical and electrochemical properties as cobalt. Furthermore, the electrochemical potential of nickel is relatively higher than that of cobalt. For this reason nickel is preferentially reduced at the cathode in the presence of cobalt. The presence of small amounts of zinc in solution leads to contamination of cobalt electro won. In spite of its lower electrochemical potential in comparison to cobalt, zinc is reduced on the cathode because of its higher hydrogen-overvoltage. But, in the hydrometallurgy of zinc, small amounts of cobalt present into solution will contaminates the zinc reduced at the cathode. This is easily explained by the fact that cobalt is more electropositive than zinc. The co-deposition mechanism of sulphur at the cathode is not yet well understood. Great attention has to be paid to the mechanism of co-deposition of sulphur during cobalt electrolysis..This work aimed to investigate the influence of some parameters on the co-deposition of nickel, zinc and sulphur during cobalt electrowinning. The following parameters have been investigated : Co2+ concentration in the electrolyte, current density and ammonium sulphate (NH4)2SO4 additions. It has been established that important nickel, zinc and sulphur co-deposition takes place at relatively low Co2+ concentration in solution. The behaviour of these elements with regard to the cathodic phenomena has been established.

Jan 1, 2005

By René Winand

The paper gives a synthesis of research work performed in the department during the last ten years and dealing with cobalt , copper and manganese electrodeposition in chloride aqueous solutions. Special emphasis is given to electrocrystallization. For copper, properties of the electrolyte such as solubility limits, electrical conductivity and complex ions stability are discussed in connection with leaching, purification of the electrolyte, and metal recovery. When possible, kinetic parameters and probable electrode mechanisms are given. Problems that are still to be solved are also listed.

Jan 1, 1985

"Quang Ninh province is located in the north east of Vietnam and the coal mining in the province generates two thirds of the province’s GDP. The coal is extracted from both open pit and underground mines for the country’s complete coal export and by a share of more than 90% for domestic coal usage. Overburden generated through open pit mines is piled up nearby in the form of large waste rock dumps. The side-hill fill dumping near open pit mines is the source of environmental degradation in the region. Among the current problems at solid waste rock dump sites are dust emissions during and after dumping as well as Acid Rock Drainage (ARD). One of the major existing problems at waste rock dumps is dump stability (comprising erosion, sliding and subsidence issues). The RAME R&D project (Research Association Mining and Environment in Vietnam) is - among other activities - actively involved in the research for stabilisation and rehabilitation of mine waste rock dumps in Vietnam in the form of several sub-projects. The Institute of Mining Engineering I of RWTH Aachen University is leading the sub-project of mine waste dump stabilisation in co-operation with Chair of Geotechnical Engineering and Brenk Systemplanung GmbH. Mine waste dumping in the form of layers as an alternative to the side-hill fill dumping is expected to bring up environmental and economical benefits by minimising the problems of dump sites with the contribution to a sustainable development. Reduction of the post construction settlements, long term stable dump profile with minimum erosion, improvement of material parameters for geotechnical slope stability through compaction from hauling trucks as well as economical evaluation of new dumping concepts are the areas of the current research. The project has been financed by German Federal Ministry for Research and Education (BMBF). The ultimate aim of the sub-project is the compilation of the project results in the form of a "Best Practice Guide" and software based "Decision Support System" for planning and management of solid mine waste dumps."

Jan 1, 2011

By R. T. Muller

Contribution to the above paper by R. T. Muller (Visitor) Demands are being made and pressure is being brought to bear on employers in South Africa to narrow or eliminate the wage gap between their White and Black employees. Few thinking people will dispute the fact that a constant improvement in the wages of Black personnel is essential, but this cannot be done merely by a redistribution of income in South Africa.

Jan 7, 1974

Previous investigations of stress conditions under which core discing occurs have concentrated on shear stress as the cause of this phenomenon. In this paper it is suggested that discing initiates as a result of extension strain, which develops in the field of triaxially compressive stress ahead of the borehole end.

Jan 1, 1982

By Elias Rigopoulos

In the present study the reductive behavior of dust from the rotary kilns (RK), in ferronickel production from nickeliferous Greek laterites, is investigated. The study concerns dust of various origins (washing towers, electrostatic filters, polycyclones) and pellets made from the dust. Reducibility was studied in the temperature range of 700 °C to 850 °C in a laboratory tube furnace. Experimental results showed that reduction degree increases with temperature up to about 800 °C. The rate of reduction is great during the first minutes, giving a reduction degree R% equal to about 25%, in only a few minutes. After this, the rate is decreasing until it diminishes to zero after about 10-20 minutes of reaction. Maximum reduction degree achieved is 26 to 28%. Rates and reduction degrees at various temperatures are higher for the dust samples than those of the respective pellet samples. Keywords: Ferronickel, metallurgy, laterites, pellets, reduction

Jan 1, 2004

By Gordon S. Duncan

(New York Meeting, February, 1912 THE U. S. Geological Survey, I believe, has almost completed a study of the Harney Peak quadrangle, preliminary to the publication of a report on that, district. As I was engaged for some months on an investigation of the mode of occurrence of the ore-bearing formation in this area, it has seemed to me timely to make public the results of my study, as a contribution to the consideration of this subject. It seems scarcely necessary to describe the locality and general geology of the Black hills of South Dakota, for since 1846 many have contributed information concerning this region, some of the reports bearing such well-known names as those of Walter P. Jenney, Henry Newton, S. F. Emmons, and C. R. Van Hise, while we have only to glance at Bulletin No. 4 of the South Dakota School of Mines, in which Prof. C. C. O'Harra, of that institution, has given us a bibliography of contributions to the geography and geology of the section, to find that other well-known men have studied the district, and have given us the benefit of their researches. The U. S. Geological Survey has made geological maps of nearly the whole of the Black hills, the only quadrangle yet to be completed being, as stated, the Harney Peak district. During the late summer and autnmn of 1910, it was my lot to examine and report. on a considerable area in this neighborhood, which once had been prospected, and in some cases exploited, for tin. This paper gives an account of certain geological phenomena, noted at that time, which greatly influenced my conclnsions. The predominating formation of the district is pre-Cambrian, represented by a highly-cleaved mica-schist, usually very garnetiferous, and sometimes hornblendic. Rising like an island from the surrounding schist is a large mass of granite, known as

Jul 1, 1912

By D. Karpoff

"IntroductionUNTIL the recent discovery and development of deposits at Allard Lake, on the Lower Romaine river, practically the whole of Quebec's - and indeed of Canada's - production of ilmenite had come from deposits in the vicinity of St. Urbain, Charlevoix •county, a village about eight miles north of Bay St. Paul on the north shore of the St. Lawrence, some sixty miles below the city of Quebec (see Figure l) . Although these deposits were known nearly three hundred years ago and were worked in a small way during the years 1872-74, when a charcoal blast furnace was operated by the Canadian Titanic Iron Company for making white pig iron, it was not until 1908 that more or less continuous production commenced and has •continued to the present by the American Titanic Iron Company. The whole of the output has been exported to the United States.The ilmenite occurs in lenses •and dyke-like bodies within anorthosite. Production has come chiefly from three deposits: General Electric, Furnace, and East and West Coulombe. During 1951 -52, an extensive diamond drilling programme was carded out under the direction of the writer to test the Furnace and the East and West Coulombe deposits (Figures 2 and 3), which form part of the property of St. Lawrence Iron and Titanium Mines, Limited. The average tenor of the orebodies encountered in the course of the drilling was 38.60 per cent TiO2 and, in addition to these high-grade •bodies, there was found a very considerable tonnage of lower grade ore."

Jan 1, 1953

By F. Ajersch, M. Rigaud, M. Jallouli

"Le gonflement des boulettes d'hématite à été étudié à l'aide d'une méthode de mesure standard ISO ainsi qu'à l'aide d 'une méthode de mesure dilatométrique.La première méthode a servi à l'étude des boulettes haute silice (5% SiO2) dont l'indice de basicité (IB = CaO + MgO -i- SiO2 + Al2O3) a été ajustée soit à l'aide d'une addition de dolomie, soit à l'aide d'une addition de pierre à chaux, soit à l'aide d'une addition de ces deux composes. L'indice de basicité variait de 0.05 à 0.12. Les résultats de gonfle ment obtenus à 1000?C dans une atmosphère de 40 CO - 60 N2 ont permis de montrer qu’indépendamment de l'indice de basicité c'est la dolomie qui contribue le plus à diminuer le gonflement par rapport à la pierre à chaux. L'utilisation de l'indice de basicité comme critère de sélection des boulettes est discutée.La méthode dilatométrique a servi à l'étude du gonfle ment de deux types de boulettes préparées à partir de deux concentrés de fer et dont la teneur en silice a été fixée à 2.5% et 0 5%. Ces deux types de boulettes ont reçues les mêmes additions de liant en quantité et en nature. La détermination en continue du gonflement, à 950?C dans 40 CO - 60 N2, a permis d'une part de mieux cerner le niveau de réduction auquel correspond le maximum de gonflement et d'autre part de montrer que l’allure des courbes de gonflement est étroitement liée à la nature du liant. Une augmentation de la teneur en silice des concentres contribue à diminuer le gonflement des boulettes.Des essais de réduction de gonflement non isothermes ont été réalisés à des montées de température à 10 et 20?C/min. Les résultats indiquent que le gonflement déterminé dans les conditions non iso thermes est inferieur à celui obtenu lors des essais isothermes. On discute alors de la validité des essais standards de gonflement qui sont utilisés pour prédire le comportement des boulettes lors de leur réduction dans un haut fourneau."

Jan 1, 1983

Operating well designed and maintained surface mine haul roads is the key to minimising truck haulage costs - in itself a significant component of the total cost per tonne mined. Existing and proposed mining operations are subject to scrutiny, both from the economic and environmental perspectives. In the long run, this scrutiny returns improved efficiencies and leaner, 'greener' operations. The focus of this evolving evaluation process should and will certainly fall on haulage operations - simply by virtue of their contribution to overall cost of operations and sustainability impacts. Whilst the end result - improved efficiency and contributions to resource sustainability - is not in itself problematic, it is the route, or process followed to achieve these improvements that needs to be carefully managed. We can be guided on this journey by our understanding of how a road is designed, and, critically, the technological solutions that can contribute to a company's sustainability initiatives. This paper examines the current state of mine road design and operation, together with the economic and environmental issues associated with under-performance. The paper serves as a basis for evaluating the economic and environmental contributions that technology in road design and management can deliver to sustainable operations. Utilising innovation is the key to long-term sustainability and as a means of positioning the industry for the imminent structural changes to the economy and environment, changes which are now within the operating life of many mines, haul roads and haul trucks.

Jun 1, 2010