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By Ian Ewart, Trevor Bergfeldt, Gourab Satapathy, Ajay Patel

"Conventional electrowinning (EW) of nickel from sulfate electrolytes is complicated by several factors including the requirement for a diaphragm cell to separate the anolyte and catholyte and the need to minimize nickel mist emissions. Developed and commercialized by emewCorporation, this novel process electrowins high purity nickel cathode (99.5%) from copper refinery bleed streams using the proprietary emew vortex EW technology. The emew nickel process incorporates high flow rate in an enclosed cylindrical EW cell operating at high current densities that overcomes the challenges of conventional nickel EW and completely eliminates the risk of nickel mist emissions. The tubular cathodes are easily harvested and mitigate the effect of plating stresses inherent in nickel EW. The present paper describes the emew nickel process and its most recent application to copper refinery bleed streams at full-scale.INTRODUCTION To meet the stringent demand of customers, nickel producers are giving prime importance to production of high purity nickel cathodes. The major challenge for refineries is to improve cathode quality and appearance despite fluctuating electrolyte impurity levels. The basis of achieving good quality cathode includes the control of electrolyte impurities and consistency of specific process conditions. The commercial operation of emew nickel technology has been successfully implemented and has demonstrated the ability to produce high quality nickel cathode from refinery bleeds. This paper emphasizes the importance of upstream impurity removal to achieve the required nickel emew feed composition by evaluating the benefits of using selective precipitation as a purification scheme with the aim of improving the overall nickel recovery while ensuring suitable nickel concentration in the advanced electrolyte is achieved. Nickel electrowinning is similar to other electrowinning processes that employ insoluble metal anodes & cathodes. It requires the passage of direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. For the recovery of nickel from solution, the most common methods are electrowinning and hydrogen reduction. Electrowinning usually occurs from sulfate, chloride or mixed sulfate/chloride electrolytes. In sulfate electrolytes, nickel electrowinning cells are normally designed to achieve specific criteria as outlined below (Robinson & Tuppa, 2002):"

Jan 1, 2017

By R. A. King, B. G. Hunt, C. E. T. White

"This paper reviews the history, occurrence, properties, and uses of indium, and describes the commercial production and fabrication of that metal by The Consolidated Mining and Smelting Company of Canada, Limited (Cominco), at Trail, B.C'. Indium is produced commercially at Trail from dross retreatment furnace D.R.F.) slag, a complex by-product of the lead smelting operations. Furnace feed prepared from this slag is smelted with coke and limerock in an electric furnace. The e1ectric furnace bullion is parted electrolytically, producing a market-able lead-tin alloy containing about 8 per cent tin, and leaving the indium in the anode slime. Recovery of indium from the anode slime involves roasting the slime with sulphuric acid, followed by leaching with water, purifying the leach solution, recovering the indium by sponging with zinc or aluminum, and re-fining electrolytically. This process yields standard grade (99.97+ per cent) indium which is either sold or refined •to high purity ( 99.999 per cent) indium for special uses requiring higher purity metal."

Jan 1, 1959

By E. Tondu

Separation Technologies Inc.’s (STI) electrostatic separation technology is a dry, continuous process for the separation of discrete particles. This high-volume process does not require any additives nor is any additional waste produced. In December 1993, STI, in cooperation with New England Power(NEP), installed an 18-t/h (20-stph) prototype electrostatic separator at NEP’s Salem Harbor plant. The plan was to convert waste streams of type F fly ash into commercially valuable products. In July 1995, a second separator was installed at NEP’s Brayton Pointplant. Fly ash feed, ranging from 6% to 25% carbon (loss-of-ignition fly ash or LOI), is separated into <3% LOI “clean” ash and sold as a portland cement substitute in the New England concrete markets.

Jan 1, 1996

By Ronald L. Bruening

IBC Advanced Technologies, Inc. (IBC) has developed and commercialized SuperLig® materials based on Molecular Recognition Technology (MRT), which have proven to be very effective for the removal of bismuth from hydrometallurgical sulfuric acid process streams. The most common application is its removal from copper refinery electrolytes, where bismuth control is extremely critical. IBC has also developed an MRT system for extraction, recovery and refining of palladium from a copper refinery by-product stream originating from the treatment of copper tankhouse slimes. A high purity palladium salt is produced which meets market specifications. Results are reviewed and discussed.

Jan 1, 2003

By Clifford Frondel

THE aluminum oxide known as corundum has several varieties that have been used as gem materials since ancient times. These include the red variety called ruby, the blue variety sapphire, and the asteriated types of ruby and sapphire. Asteriated sapphire was known to the ancients under the name of astrios, and descriptions of this gem were given by Pliny and other early writers. The relation of these gem materials to each other as varieties of a single species, corundum, was first clearly established by Haüy in 1805 and J. M. Güthe1 in 1809. Natural gem corundum is obtained principally in Ceylon, Siam, Burma, India, and Australia. Star sapphires and rubies always have been highly prized and in recent years have become particularly popular in the United States. Natural star rubies of large size and fine quality are extremely rare and rank with large and fine emeralds and diamonds as the most valuable of gem stones. Interest thus attaches to the recent success in commercially synthesizing star sapphires and rubies of a size and perfection unmatched by nature.

Jan 1, 1954

By Howard E. Kremers

Although more than 100 thorium-rare earth minerals are known, only a few have any commercial significance. Monazite, thorite, bastnasite, and some exotic thorium rare earth ores are reviewed Commercial interest is presently centered on monazite from the Union of South Africa, and thorite from this country. Thorium became commercially important with the development of the incandescent gas mantle about 75 years ago, Gas mantles consist of thorium oxide with small amounts of cerium oxide. The thorium nitrate used to make gas mantles was first obtained from rare thorium minerals, As a matter of fact, this use of thorium is still important and is one of the largest commercial uses for thorium materials. The discovery of monazite sand placer deposits along the coasts of Travancore, India, and in some Brazilian beach s .s, and the development of the old North and South Carolina monazite stream placers gave the mantle industry of 30 to 40 years ago a comfortable inventory of thorium ore. Even today, the thorium industry depends largely upon monazite ores for its source of thorium. This paper will briefly describe some of the major thorium ores and their principal deposits insofar as they relate to the thorium industry in this country. Because of similar chemical and physical properties, thorium always occurs with the rare earth elements and with varying amounts of yttrium. Thorium may predominate over rare earths, as in thorite-type minerals, or may represent only a fraction of the rare earth content. Typical ratios of thorium to rare earths in various minerals are given in Table 1, The average thorium content of the earth&apos;s crust is about 12 grams per ton, and in this respect thorium approximates lead, molybdenum, and some of the rare earths in abundance. The ore minerals of greatest importance to the-thorium-rare earth industry are monazite, thorite-type minerals, bastnasite-type- ores, and the family of minerals which is characterized by a preponderance of the heavy rare earths and yttrium. The latter classification includes xenotime, gadolinite, samarskite, euxenite, etc, The first two, monazite and thorite, are of greatest significance.

Jan 1, 1958

By A C. Robertson

World urban expansion puts constraints on the available land surface area of our major cities both for accommodating people as well as providing infrastructure and services whilst at the same time attempting to preserve the remaining natural environment. Whilst consideration is often given to underground planning for private and public transport infrastructure, the author is of the opinion that the current lack of underground planning of our cities that are suitable for underground development will have major long implications when finally the need for underground space planning is critical and ultimately recognised. This paper identifies the need for our city planners to integrate surface planning and underground planning as a ‘total planning solution’ where the city plan incorporates the elements of underground space planning as identified in this paper. Investigations by the author reveal that there are very few cities in the world that actually incorporate underground space planning in their city plans. The author uses the City of Brisbane as a case study for the potential introduction of underground space planning as part of the city plan. Despite efforts by the author to include the planning concept of underground commercial development in the latest Brisbane City Plan 2014 as well as four underground space workshops in Brisbane over the past 20 year through the Australasian Tunnelling Society (ATS), underground space planning for the City of Brisbane, apart from infrastructure projects, is not considered of significance to the City of Brisbane.CITATION:Robertson, A C, 2014. Commercial underground space – planned development for the future, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 513–518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

Commercialisation of Ni Heap Leaching at Murrin Murrin Operations

Sep 13, 2010

Commercialisation of outcomes from research projects is a process often poorly understood and managed, but has the potential to achieve significant benefits for the industry and community as a whole. JKTech Pty Ltd was established in 1986 to transfer viable research outcomes from the Julius Kruttschnitt Mineral Research Centre (JKMRC) at The University of Queensland, Australia. This paper describes successful and unsuccessful examples of commercialisation by JKTech over the years, and draws some conclusions as to the factors that contribute to success and failure in technology transfer.

Jan 1, 2012

By Kathryn C. Sole

A novel solvent-extraction process for the refining of gold was recently commercialised, with the commissioning in May 1997 of a 24 t a-&apos; refinery at Harmony Gold Mine in Virginia, South Africa. The MinataurTM Process (Mintek Alternative Technology for Au Refining) uses solvent-extraction technology to produce gold of 99.99% purity from the cathode sludge arising from a conventional carbon-in-pulp / electrowinning circuit. Implementation of this process introduces significant cost benefits compared with the conventional dore smelting / toll-refining route previously followed. This paper outlines the process, presents selected operating results obtained during the first few months of operation, and provides some details of the associated techno-economic advantages.

Jan 1, 1998

By Hemendra N. Kalia

Several attempts have been made in the past sixty or so years to commerciliaze the vast oil shale deposits of the United States of America. However, the industry has yet to become viable and economic. To date, it has not been possible to produce oil from the oil shales at a competitive price when compared to the oil produced from oilfields by conventional methods. However, the development work has been quite fruitful in furthering the art of thick bed mining and technology of in situ retorting. The in situ method has the potential of recovering oil from thick beds and the resource recovery potential is much greater than that from underground mining and surface retorting. In situ methods require that the shales/ marlstones be fragmented &apos; in place to induce adequate porosity and permeability to allow in situ&apos; heating of the fragmented shales. This can be accomplished by using explosives. However, it has been found that the existing blasting systems, though very efficient, are somewhat lacking. The explosive become insensitive when shot in multiple vertical decks. They can also become insensitive when spaced horizontally at close proximity to other charges. Also, since the blasting is done in a very limited free face, this limits the delay time that can be allowed between charges. Consequently it is not always possible to predict the performance of the blasting system on a routine basis. Furthermore, since it is not possible to undertake secodary blasting, it is imperative that the blast design function properly. Recent, successful retorting by Occidental Petroleum Company of retorts seven and eight suggests that some of these problems may have been overcome. This paper addresses some aspects of in situ retorting and problems those have impeded the development of a viable oil shale industry in the U.S.A.

Jan 1, 1983

By J. Stiksma, K. Buban, J. Oftsie, R. Kalanchey, S. Sadykov, E. McConaghy

The Kazakhmys zinc refinery in Balkhash, Kazakhstan, which employs the Dynatec Zinc Pressure Leach Process, officially launched autoclave operations on December 27, 2003. The Kazakhmys plant is the world&apos;s first greenfields zinc refinery based on Dynatec&apos;s two-stage pressure leach technology. Production of zinc was realized on February 9, 2004, when the first cathode was stripped. Currently the plant start-up is ongoing, with progression to two-stage zinc pressure leach operation and ramp-up to full design capacity continuing through 2004.

Jan 1, 2004

By E. R. Johnson

The copper concentrator of the Braden Copper Co. is at Sewell, Chile, on the westem flank of the main Cordillera of the Andes, at an air distance of approximately 50 miles southeast of Santiago, the capital of Chile. The region is mountainous and space is at a premium because of the rough terrain and the danger of snowslides. The ore, a porphyry copper, is mined by a block-caving method in the El Teniente mine. It is hauled to the crushing plant, a distance of 2.6 miles, through a tunnel because of the severe climatic conditions. The usual large, coarsely set, primary reduction machines found in many ore-treating plants are not required because of the mining method employed and the limiting 12-in. spacing of the grizzlies at the head of each ore pass in the mine. It is the purpose of this paper to describe the numerous improvements made in the crushing section of this large flotation concentrator during the past I5 years to increase the efficiency of the plant and to raise the daily output from around 20,000 to 30,000 tons. The reader should keep in mind that all changes were made within the existing building because of the limited space and the high cost of the heavy mill construction required to withstand the snow loads. The present plant, as well as the former, operates on a 24-hr, 7 days a week basis. The crushing plant commenced operations at its present site in 1921, the main equipment being No. 7½ gyratories, followed by 48-in. horizontal Symons disk crushers. Fines were removed by I-in. stationary grizzlies ahead of each unit. In 1924 a third stage of crushing was provided by the addition of 55½-in. rolls in open circuit. During 1925, the Symons disks were replaced by 73½-in. rolls. All the rolls were changed to closed circuit, with elevators and screens to give a final product of 9 pct plus 3-mesh. The flowsheet of a typical crushing section of this period is shown in Fig I. The ore was withdrawn from a common bill serving the five crushing sections in the plant by means of any number up to six 36-in. wide-apron feeders, which discharged onto a common conveyor belt. This conveyor was equipped with a magnetic head pulley and the crusher attendant was stationed near the discharge end to pick out pieces of mine timber that might be in the ore. The ore was discharged over a 13/4-in. spaced bar grizzly and the oversize of this grizzly was crushed by a No. 7½ McCully gyratory crusher set at 13/4-in. opening on the closed side. The grizzly undersize joined the gyratory discharge and was conveyed to a set of 73½ by 20-in. Garfield rolls set at I in. These rolls operated in closed circuit with a bucket elevator and two vibrating screens placed in parallel.

Jan 1, 1949

By Gary Jobson

The Mt Todd Gold mine is situated near Katherine in the Northern Territory of Australia. Commissioning of an 8 Mtpa processing facility incorporating a four stage crushing circuit, ball mills, flotation, concentrate regrinding, high rate thickening and CIL processing was commenced during late 1996. A 4.5 M tonne /annum crushing and heap leach facility was commissioned during late 1994, and was subsequently upgraded to a nominal 6 M tonne / annum circuit during 1995. Processing equipment used included primary gyratory, secondary cone and tertiary Barmac VSI crushers. Some of the features of that crushing circuit and heap leach facility were presented at the Randol Perth 95 conference by myself. The location is described as sub tropical with average climatic conditions including 1100 millimetres annual rainfall, predominantly during the December. to March wet season, and 3000 millimetres evaporation and maximum temperatures ranging from around 26 to 46 °C. The main gold occurrence at the Mt Todd site is the Batman deposit, with current published Reserves of some 60 Mt@ 1.20 g Au / tonne ( 0.0425 oz Au / ton ). The primary ore from the Batman deposit is an extremely competent greywacke and is very hard at an average Bond Ball Mill Work Index of26.5 kWhrs/ tonne. Other indicators include a Bond Impact Crush Work Index of 20 kWhrs I tonne, an Abrasion Index of 0.15 and Ultimate Compressive Strength values of 100 - 200 MPa. The main gold occurrence is very finely disseminated free gold (at an average grain size of around 5 micron) within a combination of quartz and mixed sulphide. This gold bearing component is confined to largely parallel veins ranging from 0.5 to 25mm wide within a greywacke matrix. Although the gold is essentially non­refractory, there is a strong recovery versus grindsize relationship due mainly to the liberation characteristics and the relatively low permeability of the host greywacke rock.

Jan 1, 1997

By Thomas Mütze, Anja Hirte, Ursx Peuker, Thomas Kuhn

"The comminution behavior of two ferromanganese nodules samples of the equatorial northeast Pacific has been examined as a basis for the separation of two kinds of metal-rich layers. Those layers were finely grown together during nodule formation and are one reason that the exploration of deep-sea minerals calls for the development of new mineral processing concepts. Therefore fundamental analyses of the fracture behavior have been made under compressive and impact stress. Further experiments took focus on the crushing behavior in a jaw crusher and a small scale impact crusher as well as the milling behavior in a dry vibrating mill, a wet planetary ball mill, and a wet agitated ball mill. The comminuted products were characterized by PSD, particle shape, particle density, and porosity. The experiments show a low stress resistance of the ferromanganese nodules. Compared to compressive stress, impact stress turned out to be the more effective for crushing. Both samples showed no significant difference in the comminution behaviour which makes differing mechanical treatments unnecessary. In both cases particle sizes below 1 µm were achieved by wet grinding. This particle size is necessary to separate the two kinds of metal-rich layers which is part of continuative studies."

Jan 1, 2014

By C. B. Wu

This paper presents an analysis of comminution behavior of using cast iron segment (CIS) as fine grinding media with comparison to conventional steel ball. Grinding experiments utilize just one-size medium and mixed size media in laboratory were carried out and its efficiency is expected to be improved. The results show that no matter whether one-size medium or mixed size media employed, grinding efficiency of CIS media can be considerably equal to that of steel ball, on the other hand, grinding product by two kinds of media can conform to Robin-Rammler?s size characteristic curve and distribute in function of . )exp(100nbxy-= Comparing with steel ball, the milling capacity with CIS media could be increased up to about 8.6 percent, overcomminution decreased 3.96 in percentage and qualified size increased 3.98 in percentage in case of grinding fineness retained. At the same time, due to the improvement of grinding product size characteristic and its metal distribution characteristic, the grade and recovery of easy to separation size increased 0.24 in percentage and 6.47 in percentage respectively. Based on these results, the CIS media can be employed as novel fine medium for grinding process substituting for steel ball.

Jan 1, 2014

By T. Fraszczak, U. A. Peuker, T. Mütze, T. Leißner, A. Wikedzi

The present paper highlights on the comminution and liberation properties of two greisen-type lithium bearing-mica ore blends (L1, L2) subjected to different breakage devices; cone crusher (CC), roller crusher (RC), rotor beater mill (RBM) and a screen mill (SM). The particle size distribution (PSD) of the products from each device were evaluated to search for an appropriate PSD model using Gates-Gaudin-Schuhmann (GGS) and Rosin-Rammler (RR) functions. In order to determine an appropriate function that could better describe the PSDs from the devices used, the coefficient of determination (R2) was used as a criterion. In terms of mineral liberation studies, due to costs, only products from rotor beater mill (RBM) were examined through an automated scanning electron microscope (SEM) technique. It was found that RBM, RC and SM products were better described by the RR model than the GGS model with higher R2 values (0.97-1.0). However, cone crusher products for L1 were better described by GSS model, while that for L2 were better described by RR model. In terms of the spread of size distribution as indicated by RR model parameters, RC products were more uniformly distributed compared to products from other devices, for both ore blends. Also the RBM products were more scattered than products from other devices. The results indicate that the composition of individual ore blends affected the comminution products PSDs since different PSD model parameters were obtained for samples comminuted by same devices. The modal mineralogy of the two ore blends indicate both to be rich in quartz, topaz, zinnwaldite and muscovite. Further, the result indicate that, for both ore blends, zinnwaldite phase is more enriched in the fraction < 250 µm. Moreover, better liberation of zinnwaldite is observed for L1 compared to L2. This could be explained by differences of the two ore blends in three aspects; the nature of mineral association, reduction ratio of the fractions analysed and the nature of spread of the size distribution.

Jan 1, 2018

By G. H. Babcock, D. A. Knight, V. G. Medina

"Production commenced at the Golden Sunlight Mine in 1983 and at Kidston Gold Mine in 1985. These projects were both constructed under the management of the Placer Dome Inc. (Technical Services) group of Vancouver, B.C.Golden Sunlight uses a conventional rod mill/ball mill grinding circuit while Kidston uses a SAG /ball mill, and later on, SABC circuit. Since the hardness of the ore and the fineness of the primary grind in both mines are about the same, a meaningful cost comparison can be made. The comparison is made on the basis of capital and operating costs.The result of this study indicates that a significant capital cost savings can be achieved in favour of the SAG /ball mill circuit when the ore is amenable to semi-autogenous grinding. With a good maintenance program, the operating cost for the SAG /ball mill circuit could also be lower that the conventional rod mill/ball mill circuit.HISTORYGolden Sunlight MineGolden Sunlight is a 5 530 t/d gold mine located near Whitehall, a small town 60 km east of Butte, Montana. Originally optioned by PDI U.S. in 1958, the development of the property waited until 1981 when economic conditions became favorable for the project to proceed.Semiautogenous grinding tests were conducted during the final stages of the feasibility study. The hard near surface ore was not quite amenable to semi-autogenous grinding. The best result produced from a series of tests using a 1.83 m diameter mill was a semiautogenous work index of 39. This is substantially higher than the 22 Bond work index of the sample used in the testwork. A conventional SAG/ball mill circuit for this ore will be extremely inefficient, and for this reason, this circuit was rejected in favour of a conventional rod mill/ball mill circuit."

Jan 1, 1991

By Ausenco Engineering Canada

"This paper demonstrates the selection of grinding circuit technology for a number of recent projects including discussion of the key drivers and the role of energy efficiency. Decreasing head grades combined with a strong and sustained increase in operating costs has forced miners to examine increased project size, increased equipment capacity and efficiency improvements in order to reduce their unit operating costs and improve overall project economics. Comminution energy consumption, safety and capital cost considerations play a critical role in the success of projects. This paper presents some key guidelines for a successful and cost effective comminution circuit design and includes a case study on three projects, outlining the issues and the drivers which led to the ultimate circuit selection and the critical role that energy efficiency played.INTRODUCTIONComminution circuits for minerals processing are selected based on their suitability and efficiency in reducing run-of-mine ore to the desired feed size for the downstream process. The input material (ore) properties and downstream process requirements are the key determinants and there are standard approaches for each circumstance.The minerals processing industry has been a fast adaptor of efficiency improvements based on increasing capacity of equipment (e.g. trucks, crushers, mills, pumps) but less successful in adapting radically new technologies that disrupt incumbent flowsheets or processes.The installed power of grinding mills has increased linearly over the past 25 years (Meka & Lane, 2010) and pumps and classification equipment have kept pace. The autogenous grinding (AG) and semiautogenous grinding (SAG) mills displaced stage crushing as a dominant method of coarse rock breakage in many applications causing crusher manufactures to increase the capacity of cone crushers to meet the competitive demand.Examples of new comminution technology in the 20th and 21st centuries are the development and adoption of cyclone classification in the 1940s (Newtech, 2016), AG milling in the late 1950s, vertical grinding mills in the 1980s, high pressure grinding rolls (HPGRs) also in the 1980s and ultrafine milling technology in the 1990s (Meka & Lane, 2010)."

Jan 1, 2016

By S. Rivard

"This paper demonstrates the selection of grinding circuit technology for a number of recent projects including discussion of the key drivers and the role of energy efficiency. Decreasing head grades combined with a strong and sustained increase in operating costs has forced miners to examine increased project size, increased equipment capacity and efficiency improvements in order to reduce their unit operating costs and improve overall project economics. Comminution energy consumption, safety and capital cost considerations play a critical role in the success of projects. This paper presents some key guidelines for a successful and cost effective comminution circuit design and includes a case study on three projects, outlining the issues and the drivers which led to the ultimate circuit selection and the critical role that energy efficiency played.IntroductionComminution circuits for minerals processing are selected based on their suitability and efficiency in reducing run-of-mine ore to the desired feed size for the downstream process. The input material (ore) properties and downstream process requirements are the key determinants and there are standard approaches for each circumstance.The minerals processing industry has been a fast adaptor of efficiency improvements based on increasing capacity of equipment (e.g. trucks, crushers, mills, pumps) but less successful in adapting radically new technologies that disrupt incumbent flowsheets or processes.The installed power of grinding mills has increased linearly over the past 25 years (Meka & Lane, 2010) and pumps and classification equipment have kept pace. The autogenous grinding (AG) and semi- autogenous grinding (SAG) mills displaced stage crushing as a dominant method of coarse rock breakage in many applications causing crusher manufactures to increase the capacity of cone crushers to meet the competitive demand.Examples of new comminution technology in the 20th and 21st centuries are the development and adoption of cyclone classification in the 1940s (Newtech, 2016), AG milling in the late 1950s, vertical grinding mills in the 1980s, high pressure grinding rolls (HPGRs) also in the 1980s and ultrafine milling technology in the 1990s (Meka & Lane, 2010)."

Jan 1, 2017