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By T. Krumins, L. Zunti, R. Frischmuth

"Titanium and titanium alloys are commonly selected for pressure oxidation autoclave vent piping and pressure control valve components, as well as autoclave internals and other process piping. In the autoclave vent application, titanium ignition risk is controlled by limiting oxygen concentration, and preventing high gas velocity gas impingement on surfaces. Oxygen concentration is dependent on the autoclave pressure and temperature operating conditions and therefore oxygen concentration and the associated titanium ignition risk is dependent on standard operating procedures, process control interlocks and permissive conditions. It is not uncommon for these standard controls to be deficient during atypical operating conditions, or for operations to deviate from the operating procedures, increasing the potential for a titanium ignition incident. Titanium ignition risk caused by elevated oxygen concentration in autoclave vent systems can be reduced with the introduction of an online autoclave overpressure calculation and the configuration of associated interlocks and permissive conditions. INTRODUCTION High temperature pressure oxidation (>190°C) is a well recognized and versatile metallurgical oxidative pre-treatment process commonly used to liberate gold from refractory sulphide ores and concentrates before conventional leaching with cyanide. Titanium and titanium alloys are highly corrosion resistant in pressure oxidation process conditions and are therefore commonly selected as materials of construction for many components including: autoclave internals, agitators, process piping, and components in autoclave vent systems. Operations that anticipate or have experienced aggressive corrosion in the vent system often have little choice in material selection other than the use of titanium (Krag & Henson, 1992). Titanium is not suitable for use with elevated oxygen concentrations and is considered a restricted material because of its high pyrophoricity and combustion propagation properties (Beeson, Smith, Stewart, 2007). Several serious incidents have occurred in which titanium materials have ignited in autoclave applications (Zawierucha, McIllroy, Million, 1995). In autoclave vent applications, titanium ignition risk is reduced by preventing elevated oxygen concentrations, maintaining low gas velocities, and minimizing the potential for gas impingement on surfaces. Oxygen concentration in the autoclave vapour phase and vent system is dependent on the autoclave operating pressure and temperature conditions and therefore titanium ignition prevention controls typically include process interlocks and operating procedures based on the selected nominal design operating conditions. However, it is not uncommon for these controls to be deficient or for operations to deviate from the nominal operating conditions over time, increasing the risk of titanium ignition. The introduction of an online calculation of autoclave overpressure and a maximum target autoclave pressure as well as associated process control interlocks and permissive conditions can alert the autoclave control room operator and prevent an elevated oxygen concentration from developing, and therefore reduce titanium ignition risk in autoclave vent systems."

Jan 1, 2016

By V. Madhusudhan Rao

Fly ash is a finely divide non ? combustible material obtained as a by ? product of coal combustion. It is a major by ? product of coal based thermal power stations. Until recent past it was considered as a waste and highly polluting material. However its formation can only be minimized by using suitable technology in the boilers. In recent past it is found that Fly ash has many end uses and it has proven itself to be a potential construction material. But the suitability of fly ash for various applications largely depends on the amount of unburned carbon, which is turn depends on the firing method. Fly ash samples from various power plants existing in India using a fluidized bed method and pulverized bed were analyzed and a comparison of these two firing methods was carried. This paper deals with the compositional requirements for fly ash used for the fabrication of insulating doors using AAC (Aerated Autoclave Concrete) and the methods employed to make fly ash suitable for this purpose. It also includes the latest ?U? beam technology for effective fly ash recycle. If the by products of coal combustion from power plants like fly ash as the paper stresses are utilized properly, it is not an exaggeration to say that power generation is possible with absolutely zero cost.

Jan 1, 2006

By A. K. Ratte, C. M. Brown

"IntroductionIn autogenous mills, grinding of the ore feed is accomplished by the direct action of the variously sized rocks making up the feed on each other and the mill interior. Size reduction is achieved without the addition of grinding media foreign to the mill feed, differing in this respect from rod, ball, and pebble milling. The term ""semi-autogenous"" has entered common usage in the industry to describe autogenous mills to which supplementary grinding ball additions are made to increase the rate at which size reduction of the mill feed occurs, beyond that achieved solely by the action of rock on rock. In a semi-autogenous grinding (SAG) mill, 50Jo to 10% of the mill volume may be occupied by grinding balls, whereas a range of 25% to 45% is more usual in ball milling.The comminution of mineral ores using ""conventional"" techniques has been described in previous papers. In conventional operations, size reduction of mined ore, and liberation of the valuable mineral content, is typically accomplished using flowsheets employing two to four stages of crushing. Crushing is followed by one to three stages of grinding and classification using various combinations of rod, ball, and pebble mills. This paper describes operations employing autogenous or semiautogenous grinding as the principal stage in the comminution process. Primary crusher discharge, or in some instances run of mine ore, is fed directly to an autogenous or semi-autogenous grinding circuit. Final product sizing may be accomplished in a single grinding stage, the mills operating in closed circuit with classification equipment, or in several stages using autogenous and semi-autogenous mills for primary grinding, and ball or pebble mills for secondary grinding. In several operations a portion of the primary mill discharge is crushed in an intermediate comminution step, these circuits being called autogenousball- crusher circuits (ABC). Many different flowsheets exist, but common and important to most are crushed ore stockpiles, reclaim feeder and mill feed conveyor systems, pumps, screens, and classifiers. Autogenous grinding is employed in both wet and dry processes, although today wet predominate."

Jan 1, 1989

By C. A. Rowland

When studying the feasibility of using autogenous or semi-autogenous grinding, operating and engineering companies frequently request assistance from the mill manufacturers in three areas - 1. Recommendations for studying the suitability of autogenous or semi-autogenous grinding for the specific ore. 2. Mill sizing, to accomplish required grind. 3. Recommendations on mill design and operation. Rod mills and ball mills are selected by the use of bench scale standard grindability tests and established calculation procedures, of which the most frequently used are the Bond Grindability tests and the Bond Work Index equation(1). The accuracy of these have been reviewed by C. A. Rowland in his papers, showing the correlation of work indices calculated from plant operating data and laboratory grindability tests(2)(3). The selection of autogenous and semi-autogenous primary mills has not reached the stage where mill size selection can be made from bench scale tests. Considerably more extensive testing will be necessary than required for selecting rod mills and ball mills.

Jan 1, 1974

By J. H. Bassarear

Conventional crushing and grinding circuits are compared to semiautogenous circuits. Recent installations of each circuit are reviewed and seven methods of using autogenous or semi- autogenous techniques are described. Steel and power consmption data are reported and benefits of a dedicated digital computer are discussed.

Jan 1, 1981

By Jr. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Jan 1, 2012

By Chen Z, Dong H

This paper describes the autogenous carrier flotation of 0 - 20 ¦m ilmenite using 40 -- 80 }tm ilmenite as carrier. Investigation is made of the influence of main technological parameters on autogenous carrier flotation. The mechanism of autogenous carrier flotation is discussed using extended DLVO theory. The main conclusions are as follows: 1. the smaller the fine particles the more easily they adhere.to carriers; 2. the selectivity of autogenous carrier flotation depends on the selectivity of adsorption of collector. In the autogenous carrier flotation of ilmenite/plagioclase mixture assaying 15.35 per cent TiO2, a concentrate containing 47.17 per cent Ti02 can be obtained by primary separation with a recovery of 93.05 per cent. KEYWORDS: Autogenous carrier flotation, extended DLVO theory, ilmenite, styrylphosphonic acid.

Jan 1, 1993

By P. Wanjara, M. Xiao

During fusion welding of aluminium alloys, the avoidance of defects (such as porosity, oxides, hot cracking, undercutting) as well as the ability to optimize the microstructure-property characteristics in the assembly are critical for the stringent manufacturing specifications in the aerospace industry. In this work, aluminium alloy (AA) 2024 was electron beam welded autogenously as part of a study to determine the influence of parametric conditions on the characteristics of the heat affected and fusion zones to obtain optimal welding conditions. In particular the evolution in the weld geometry, microstructure and mechanical properties were examined as function of the processing conditions, including beam current, beam focus, beam oscillation, linear heat input and welding speed. For optimized parametric conditions, microstructural examination of the joints revealed narrow fusion and heat-affected zones comprising of dendritic structures without the occurrence of defects that enabled a maximized joint efficiency.

Jan 1, 2006

By Howard W. Adam

Mill length was the primary variable investigated in an autogenous pilot mill circuit. The 5-1/2' diameter mill had both pebble ports and 1/2" wide slotted grates. The plus 1/2" mill product was crushed in a cone crusher and returned to the mill feed along with the minus 1/2" plus 4 or 6 mesh fraction. Tests were run with a short mill, inside length of 26-3/8", or diameter-to-length ratio of 2.50 to 1. The same mill was then lengthened to 48-3/8", diameter-to-length ratio of 1.36 to 1. The effect of mill length on circuit product characteristics was studied. Results show that (1) circuit throughput or grinding rate is lower per foot of mill length in the longer mill, (2) the long mill product is finer than the short mill product, and (3) KWH per ton of circuit product is slightly higher with the longer mill; however, KWH per ton of minus 200 mesh material (finer fraction) produced is essentially the same in the long mill as the short mill, It is not known whether the relationships found for the pilot mill are valid for commercial size mills.

Jan 1, 1973

By Constance F. Acton

Based on laboratory structure analyses, a pilot plant investigation was undertaken to evaluate a Michigan conglomerate native copper ore. Comminution or sized feed was accomplished using wet, closed circuit autogenous grinding with and without crushing of the recirculating load. Coarse metallics were concentrated in two stages of jigging with fine metallic copper being recovered in a three-stage xanthate flotation circuit. With a feed averaging 2.09 % Cu, copper recovery ranged from 86-93 % Cu with an average grade of 55.5 % Ca. An evaluation of the processing flowsheet is made in terms of pertinent independent, dependent, and external variables and design factors. Rate equations are developed to describe the grinding and flotation circuits separately as well as the entire circuit as a whole. Performance equations for the overall operation and for the unit operation of autogenous grinding alone are developed in terms of suitable capacity, efficiency and energy consumption terms. Thus, the effects of feed rate, recirculating load and flowsheet design can be rationally evaluated. Energy consumption for various conditions in the pilot plant is compared to the laboratory value. Additionally, size and scale up factors are discussed. Recommendations are made for further studies to be undertaken to further quantify the ore characteristics and the nature of the autogenous grinding operation. However, the feasibilty of beneficiation of this type of native copper ore by means of an autogenous grinding/jigging/flotation circuit is clearly established.

Jan 1, 1977

By Ahmet Tezcan, Zeki M. Dogan, Yalçin Kaytaz

Autogenous grinding in Turkey was first applied to quartzite where the mill is grate discharge type with an internal diameter of 2.99 m, having a length of 3.20 m and a capacity of as to 11.0 tons per hour. The second autogenous grinding was applied to a copper ore at Murgul Cakmakkaya Flotation plant of (KBI) Black Sea Copper Works having three mills 26 feet in diameter and 10 feet in length in close circuit with hydrocyclones. Recently, alterations were made in grinding circust by adding pebble mills. Furthermore, rubber liners and lifter bars were introduced pebble extractor and classifier were new features in the primary mills and circulating load was reduced by 20-50 tons per hour. At the end of these charges, capacity of each mill line was increased to 48 tons per hour with a full capacity of more than 9000 tons per day. Thirdly, autogenous grinding has been executed successfully on the slags of Samsun Smelting Plant of (KBI) Black Sea Copper Works with a mill of 20 feet in diameter and 6 feet on length having pebble mill following autogenous grinding.

Jan 1, 1992

By J. V. Bymark

It is the intent of this paper to discuss the autogenous grinding circuit at Hibbing Taconite. The scope of the presentation includes; a brief history, the process flowsheet and the steps taken to improve mill productivity, availability and metallurgical performance. Hibbing Taconite is located near the center of the Mesabi Range in Northern Minnesota 100 miles from the Canadian border and 80 miles north of the Lake Superior Port Cities of Duluth and Superior. A 105 mile railroad connects us with the port of Superior, Wisconsin, where our pellets are loaded into lake carriers for lower lake destinations. It is worthy to mention the Mesabi Range's most famous landmark which is immediately to the south of our mine area. This is the Hull Rust Mahoning Mine which operated until the mid-1970's producing more than 700 million tons of red ore between 1893 and 1973.

Jan 1, 1985

By Olav K1omstad1ien

The lean, but extensive iron ore deposits of the Dunderland Valley north of Mo i Rana, Norway, is the raw material for the Rana Mines which is a division of the state owned steel mill A/S Norsk Jernverk. Activities for the exploitation of the orebodies were commenced in 1902 by the English Dunderland Iron Ore Company. During its operating period the company constructed a total of two large scale concentrating plants. The activities were strongly marked by technical problems and labor disputes. Thus actual production was limited to the years 1904-1908, 1928-1931 and 1937-1939. During these periods a total of 1.9 million tons of crude ore was mined and 0.6 million tons of concentrates produced for export. The present plant commenced operations in late fall of 1964. Up to and including 1976 about 26.6 million tons of crude have been put through the concentrating plant and about 10.7 million tons of concentrate produced.

Jan 1, 1978

By Henry E. Swanson

In the early 1960's the Company, then named the United States Smelting Refining and Mining Company, was drilling the Continental ore body located near Fierro, New Mexico. Reserves of underground ore of sufficient quantity were indicated to build a mill. At the same time some ore from the Continental No. 1 mine was being milled at the Company's Bullfrog Mill, formerly a lead-zinc mill. The copper ore in comparison to the lead-zinc ores was very hard, abrasive, and heavy. These factors pointed out the possibility and attractiveness of autogenous grinding. While prior to this some study had been given to autogenous grinding, no large scale tests had been made. Such a program was carried out and from the pilot plant data the following was established: 1. Grinding of the ore by autogenous means could be accomplished. 2. This could be done in one stage; however, not at a satisfactory tonnage throughput rate. Thus, the use of a secondary unit has been employed. 3. Grinding in the secondary unit could be done by pebbles generated in the primary unit. This resulted in the scheme whereby the ore would be ground 100% autogenously. 4. Liberation of the copper minerals was excellent so that good recovery at a satisfactory concentrate grade would be obtainable.

Jan 1, 1976

By Timo Heikkinen

We have read, with great interest, Mr. Crocker's article on "Recent Trends in Autogenous Grinding," published in the October issue of The Canadian Mining and Metallurgical Bulletin. Referring to our paper, "Two-Stage Autogenous Grinding Investigations at Outokumpu," we can now report that last August we changed to this method at the Keretti concentrator. Prior to the conversion, the Keretti plant (see flow-sheet, Figure 1) had two primary rod mills, 6 ft. in diameter and 12ft. in length, in open circuit, followed by four secondary 9-by 12-ft. pebble grate mills in closed circuit with rake classifiers. Last summer, wl1en the Since August, grinding has been successfully carried out autogenously in two stages, with two mills being employed in the primary stage and four in the secondary. The size of the pebbles in the secondary mills is about the same as earlier -l V: i to 3 inches (Figures 4 and 5). Also, we generally prefer two-stage grinding to single-stage grinding because, in the former,

Jan 1, 1964

By Johann F. Kerl

Autogenous batch grinding tests were performed in laboratory-scale tumbling mills with magnetite, limestone, and sandstone pebbles. The influence of pebble size, feed size, mill speed and loading, and grinding time on the fineness of grinding was investigated. Comparisons were made with the results from ball mill grinding experiments.

Jan 1, 1972

By J. E. Danoczi

ABSTRACT A diamond processing plant is being designed for the Star–Orion South diamond project in central Saskatchewan. Key to the plant is diamond liberation, which occurs in the comminution section and is the process of breaking up kimberlite rock as gently as possible to minimize diamond damage, particularly in larger, high-value diamonds. Kimberlite from the crater area of a volcanic pipe is generally softer than kimberlite from the diatreme zone. Softer kimberlite, comprising the majority of Star– Orion South deposits, can be readily broken up using abrasion and attrition by autogenous grinding mills, the preferred comminution method for minimizing diamond damage.

Jan 1, 2013

By W. D. Bachman

A study has been made of wet, autogenous grinding of disseminated copper ores, including testing of a large number of samples from Kennecott Copper Corporation's Chino mine. The efficiency with which the various samples could be ground was found to vary over an extremely wide range, even among samples taken from different locations within the same ore body. These variations in grindability can be qualitatively correlated with the composition of the rock and the fracturing and alteration that had occurred. Because of the large-scale non-homogeneity of disseminated copper ore bodies, extensive and careful testing of autogenous grinding is needed. An accurate correlation of the grinding data from various samples with the geology of the ore body and with mining plans will indicate if variations in grinding mill throughput can be avoided in practice by mixing or blending of mill feed and if, therefore, autogenous grinding can be applied successfully.

Jan 1, 1970

By S. A. Elmquist

Research activities performed by Cleveland-Cliffs Research and Hibbing Taconite plant personnel during the last decade have resulted in the development of an improved autogenous mill grinding circuit. Minus one (1) inch autogenous mill trommel oversize material, con-sidered to be a critical size, is magnetically cobbed and then crushed to 100% minus 3/8" prior to reentry into the feed end of the mill. Autogenous mill capacity increases, up to 25%, have been measured in pilot plant tests using this approach and are also anticipated for the Hibbing Taconite concentrator which presently has reached a 15.5% improvement.

Jan 1, 1994

By James E. Wennen

The through-put and energy efficiency of an autogenous (AG) grinding mill are adversely affected by variability in rock size and rock competency. This applies to both fully autogenous and semi-autogenous (SAG) grinding circuits. In this paper we focus on an approach to overcome the problem of inconsistent mill through-put related to variability in mill feed size and rock competency. The focus is on ores containing hard, competent rock. This approach consists of preparing feed to an autogenous mill that contains 20% coarse media rock and 80% of material crushed to pass 37 mm. Results of pilot-scale testing for two iron-ores will be presented to show that a 10% to 12% reduction in unit energy consumption is possible with prepared feed, compared with feeding the mill with conventional primary crusher discharge.

Jan 1, 2012