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By Colin Barratt

The East Side Access (ESA) project is the largest underground rail infrastructure project under construction in New York City, USA. The Manhattan segment of the project is to be mined through rock and consists of 4.1 miles of Tunnel Boring Machine tunnels for track work and mined excavations to house rail switches, air plenums, and other rail facilities. This paper considers different methods for concrete lining, such as the use of fixed forms, adjustable forms, and pneumatically applied shotcrete. The advantages and disadvantages of these methods are discussed and the basis for considering one over the other are illustrated. Further discussions on design development and preparation of documents to facilitate quality and constructability in the field are presented.

About 20 percent of world gold production has been contributed by gold deposits in Archaean greenstone belts, of which ca 2100 tonnes of gold has been produced from Archaean greenstone belts in Western Australia (Phillips, in press). These deposits are, therefore, important exploration targets and an under-standing of their nature and genesis can help to formulate exploration strategies and delineate potential targets.A literature survey of Archaean granitoid-greenstone terrains indicates that a wide variety of lithologies host gold deposits. The major part of production from the Yilgarn Block, Western Australia, has come from mafic volcanics andintrusives (70% of production),with significant contributions from BIF-hosted ores (15%) and low production from sediments, felsic volcanics, porphyry intrusives and granitoids (Groves et al., in press). Similarly, most

Jan 1, 1984

By Junmo Ahn

This study investigated leaching kinetics by alternative lixiviants for copper leaching from chalcopyrite (CuFeS2), the most abundant copper resource in the world. As a refractory sulfide mineral, chalcopyrite shows low copper extraction due to passivation on chalcopyrite surface. Also, decrease of copper grade with high portion chalcopyrite requires the alternative leaching procedure to increase copper recovery. Therefore, alternative lixiviants such as sulfurous acid and methanesulfonic acid (MSA) were tested for both concentrate and low grade ore to enhance copper extraction. Also, an oxidant, hydrogen peroxide, was compared to ferric to find out the improvement of leaching kinetic. In concentrate leaching tests, 30 g/L MSA showed the highest copper extraction (47%), compared to other lixiviants at 75 °C. Periodical H2O2 addition enhanced copper extraction, and above 90% of copper extraction was observed within 96 h by periodical addition of 0.6% H2O2 at 75 °C. The activation energy of chalcopyrite leaching by MSA and H2O2 achieved 40 kJ/mol, which is chemical reaction control. The results of low grade ore leaching tests indicates that no significant difference among lixiviants (H2SO4, H2SO3 and MSA) with ferric was observed, all of which achieved around 37% within 24 h at room temperature. However, significant increase of copper extraction (>80%) was observed at both 20 g/L MSA and 10 g/L H2SO4 conditions by the addition of 10% H2O2.

By Cristian Saavedra, Patricio Zarate

Flotation collectors play a crucial role in mineral flotation by selectively adhering to mineral surfaces and aiding in their separation from gangue material. They are heteropolar molecules, as defined by Sutherland and Wark (1955), featuring non-polar hydrocarbon chains and polar groups interacting with mineral surfaces to induce hydrophobicity selectively. The importance of collectors in mineral processing, as underscored by Lotter and Bradshaw (2010), lies in their ability to enhance recovery rates and improve selectivity, thereby optimizing the extraction of valuable minerals from complex ores. Collectors are classified based on their mechanism of action, as proposed by Laskowski (2010). This classification categorizes collectors into three groups: water-soluble compounds, water-insoluble “oily” collectors, and water-insoluble amphipathic compounds forming molecular films at the water/gas interface. This complements the chemical structure-based classification by Sutherland and Wark (1955) and Suoninen and Laajalehto (1993), offering a comprehensive understanding of collector diversity in flotation systems. Collector selection is an iterative process crucial for optimizing mineral processing efficiency, as emphasized by Lotter and Bradshaw (2010). Understanding the significance of collector mixing or synergy outcomes is paramount for enhancing mineral flotation efficiency and sustainability. Taguta, O’Connor, and McFadzean (2018) demonstrate that mixed collector systems enhance interaction enthalpies and microflotation recoveries, indicating improved performance. McFadzean, Castelyn, and O’Connor (2012), along with Critchley and Riaz (1991), delve into investigating synergistic interactions between collectors, offering insights for strategic selection. Observations from the study of collector synergy, as noted by Wakamatsu et al. (1980), reveal nuanced relationships surpassing individual collector behaviors. The methodology outlined in this paper provides valuable guidance for classifying and selecting collectors based on specific application needs, while also suggesting the potential for synergistically improving recovery across fine, intermediate, and coarse particles.

Feb 1, 2025

By K. Schwerdtfeger

Data are presented on the effect of iron oxide on the electrical conductivity of CaO-SiO2-FeO-Fe2O3melts, and on limiting current and impedance in direct current or alternating current charge transfer at iron electrodes. The strong influence of iron oxide content can be utilized for in situ determination of total iron oxide content and Fe3+/Fe2+ratio. The possible probe designs are presented and the principles and procedures of the measurements are explained. Keywords: in situ probe for iron oxide determination in steelmaking slags, electrical conductivity of CaO-SiO2-FeO-Fe2O3slags, direct current over voltage and alternating current impedance at iron/slag electrodes.

Jan 1, 2004

By Jürgen Antrekowitsch, Harald Osthof, Stefan Steinlechner

"In the case of feasibility assessments or feasibility studies, an important point of discussion is often how to calculate the capital (CAPEX) and operating expenditure (OPEX) of a plant. Generally, there is also the request to know how the CAPEX varies when the size of the plant is increased. Nowadays, many databases give an indication of specific equipment costs in relation to the production rate. These data are based on cost information from equipment suppliers and have to be continuously updated by the owner of the database. The approach presented here is a model which allows sizing of process equipment, for example a leach tank, based on process data in combination with the calculation of mechanical properties. Furthermore, it calculates the CAPEX based on construction material cost and adequate machining surcharges. Thus, a single cost model for a leach tank is adequate for both copper and other hydrometallurgical plants and stays valid with changing construction material prices. To summarize, the advantage of this model is the more versatile approach and thus the flexibility due to the inclusion of design aspects, process and mechanical engineering aspects and an updatable database. The database, which is in regard to material cost and is the basis for the cost estimation, is easily updatable from commonly accessible data. This model thus approaches the procedures of an engineering company when designing a plant and executing a cost calculation. INTRODUCTION Hydrometallurgy nowadays plays an important role in processing of primary and secondary resources. In copper metallurgy, hydrometallurgy accounts for roughly 20 % of worldwide primary production, especially in the case of oxide or low copper-containing ores. Zinc smelters changed their method of production from a pyrometallurgical-dominated concept decades ago to mainly hydrometallurgical routes today. Gold production processes using leaching, especially, have a long history without any development which would not be competitive if not based on hydrometallurgical concepts (Pawlek, 1983; Winnacker-Küchler, 2006)."

Jan 1, 2015

By E. Snyders

Two alternative processes for the manufacturing of zircon products were investigated by the South African Nuclear Energy Corporation (Necsa). These were the synthesis of doped-zircon pigments from plasma dissociated zircon, and an upgrading process to convert an inferior grade of zircon into a superior opacifier for ceramic applications. A solid-state reaction process was used to produce doped-zircon pigments. The influence on the colour intensity of the pigments on a ceramic tile were compared for milled and un-milled plasma dissociated zircon (PDZ) material, prior to calcination. Pr-yellow and V-blue zircon pigments produced from PDZ with different degrees of dissociation, were also evaluated. The second zircon beneficiation process entails the upgrading of an inferior grade of zircon to a superior opacifier for ceramic applications. A calcining process in the presence of mineralizers was used to produce the product in a conventional muffle furnace. A pre-milled inferior grade zircon concentrate, with a relatively high iron and alumina content generally not suitable for high quality ceramic applications, was used in this study. The influence of the upgrading process on the opacifying properties of the zircon material was compared to that of commercially available prime grade zircon opacifier products currently being produced in South Africa. The influence of a calcining step in the presence of mineralizers with regard to the milling characteristics of the treated zircon material was also evaluated.

Jan 1, 2005

By E. S. Forbus

A process for producing reductive bleach in-situ in kaolin slurries has been developed. The bleach is formed by mixing an iron sponge powder (-325M) with slurry treated with SO2. The process has been successfully demonstrated in production, and applied to several grades. The color, brightness, and viscosity of the bleached product is equivalent to or better than that of product bleached with commercial sodium hydrosulfite . The tested products can be bleached at a cost, which is 38-54% of those associated with the use of commercial bleach.

Jan 1, 1993

A Life Cycle Assessment (LCA) of stainless steel production, including that of the nickel, ferronickel, ferrochromium and iron feedstocks was carried out using inventory data derived from the literature. The environmental impact categories considered in the study were Global Warming Potential (GWP), Acidification Potential (AP) and total (or full cycle) energy consumption. The effects of different sources of electricity (black coal, natural gas and hydroelectricity) were also examined in the study. The results of the LCA showed that when ferronickel is used as the nickel source, the total energy consumption for stainless steel production is approximately 50% higher than when nickel metal is used as the nickel source (75 MJ/kg cf. 49 MJ/kg). This result comes about largely because the Fe units in ferronickel have a much higher energy intensity than do the Fe units in pig iron, and the greater the use of the former at the expense of the latter, the greater is the total energy consumption. The results also showed that the production of ferronickel made by far the largest contribution (59%) to the total energy consumption for stainless steel production when this feedstock is used as the nickel source, but when nickel metal is used as the nickel source the contributions of the various stages are more evenly distributed. It was also observed that the electricity consumption of the electric furnaces used in the production of ferronickel, ferrochromium and stainless steel contributed approximately 50% to the total energy consumed in stainless steel production. Given the relatively low efficiencies associated with electrical power generation, significant reductions in the total energy of stainless steel production could be anticipated if more direct use of thermal energy was made in the ferronickel, ferrochromium and/or stainless steel smelting stages, for example by utilising bath smelting processes.

Jan 1, 2004

By A. J. Jager, D. P. Roberts

The stoping of platinum orebodies in the Bushveld has in the past been accomplished by using in-stope pillars to ensure stability of the workings. In the future, the use of continuous mining machines to mine the platinum orebodies is probable. It is not envisaged that such machines will cut in-stope pillars. This paper describes the alternative support systems that will replace the pillars and the stope geometries that will be required for this type of mining. The paper describes how the support resistance provided by in-stope pillars in current mining was determined and then evaluates support systems that can substitute for these pillars. Conceptual layouts based on existing breast mining layouts are presented. The layouts consist of panels of up to 100 m face length between rigid strike stabilizing pillars. A number of design charts are then proposed that allow for the design of appropriate support systems.

Jan 1, 2004

By D. P. Roberts

The stoping of platinum orebodies in the Bushveld has in the past been accomplished by using in-stope pillars to ensure stability of the workings. In the future, the use of continuous mining machines to mine the platinum orebodies is probable. It is not envisaged that such machines will cut in-stope pillars. This paper describes the alternative support systems that will replace the pillars and the stope geometries that will be required for this type of mining. The paper describes how the support resistance provided by in-stope pillars in current mining was determined and then evaluates support systems that can substitute for these pillars. Conceptual layouts based on existing breast mining layouts are presented. The layouts consist of panels of up to 100 m face length between rigid strike stabilizing pillars. A number of design charts are then proposed that allow for the design of appropriate support systems.

Jan 1, 2005

By Marco Túlio Santiago Ferreira, Nilton Carlos Torquato, Washington Pirete da Silva

In 2005, with the significant reduction of iron content in the “Quadrilátero Ferrífero” reserves, Vale began the study of alternatives for the tailings disposal in other structures, that are not tailings dams. In 2011, after bench-scale and pilot-scale tests, it was defined to implement the project "Alternative methods for tailings disposal", including the construction of experimental drainage piles to get mineral and geotechnical process parameters for future projects. The result of this study shows that it is technically possible to replace traditional tailings disposal (dams), to dry stacking, with the proportion up to 20% of ultrafine tailings in the total tailings composition, however, this study is in evolution and the scale of the project / pile is being gradually increased to guarantee a good performance for the mineral and geotechnical process.

Oct 3, 2019

By R. E. Molnar, P. A. Riveros, V. M. McNamara

"This paper describes some recent research done at CANMET in the areas of ion exchange and A VR (Acidification- Volatilization Reneutralization), as applied to the recovery of gold and cyanide, respectively. It also discusses the ways in which these two technologies may be combined in order to minimize the environmental impact of gold milling operations and optimize reagent usage. IntroductionGold milling operations can essentially be divided into those that carry out a liquid/solid separation after leaching and those that recover gold directly from a leach pulp. The former produce a barren solution which may contain considerable amounts of cyanide, either free or cornplexed with metals. The latter produce a similar solution but this is now part of a slurry rather than a clear stream. Due to its toxicity, any excess cyanide must be destroyed before the effluent is discharged into the environment. Ideally, this should be (and sometimes is) accomplished by natural degradation. However, in many cases natural degradation alone cannot remove the last traces of rnetallocyanide compounds from the effluent and , as a result, most Canadian gold producers utilize a supplementary chemical oxidation system. This not only increases the operating costs, but concerns have also arisen in recent years about the formation of ammonia as a result of the chemical oxidation of cyanide (via CN--CNO--HCNO-NH3) ·"

Jan 1, 1993

By W P. Darcey

Jabiru Metals completed a feasibility study on the Jaguar Base Metal Project in July 2005. The study was based on conventional truck haulage via a decline. Conveyor haulage was considered but not in sufficient detail to provide a meaningful comparison. The current study investigates the cost and productivity of alternative ore transport systems for the Jaguar project. The options considered are conventional underground truck, conveyor, road train, rigid frame truck, monorail haulage and shaft hoisting. Shaft hoisting was not considered in detail due to the high capital outlay for such a relatively short mine life of less than six years. This study goes beyond the common approach of evaluating haulage systems in isolation; it includes development costs, timing of ore production and costs associated with mine services as well as administration and milling costs. The results of this study indicate that the best haulage option for the Jaguar project is conventional truck using the Hitachi AH400 trucks. The net present value (NPV) for this option is A$8.13 million higher than the next best option namely the Kiruna E635 electric truck. The conveyor option has the lowest operating cost per tonne of ore but the longer development time negatively impacts on its NPV. The monorail option is considered impractical due to the number and length of trains required to achieve production targets.

Mar 21, 2011

A simple and cost effective technique to increase fragmentation and burden velocities without making major modification to the overall blast design is with ALTERNATE VELOCITY LOADING OR BOOSTERING OF ANFO. The technique requires the placement of a cartridge or slug of explosive, having higher density and detonation velocity than ANFO, every few feet in an ANFO column. The greater the difference in density and detonation velocity of the Alternate Velocity Load to ANFO, the more pronounced are the results. Emulsions were selected as the Alternate Velocity test explosives because they detonate closer to ideal conditions than most other commercial explosives.

Jan 1, 1989

By Nicholas P. Kripakov

The unpredictable massive collapse of roof in openings developed under apparently safe and stable roof conditions in coal mines of the United States has been of much concern for many years. One type of massive caving phenomenon is often attributed to cutter roof, a failure that initiates at one and/or both upper corners of an entry and propagates nearly vertically resulting in overall failure with little or no warning. This paper reviews current methods being used to control cutter roof and suggests new alternatives. The impact of basic parameters that include mine geometry, overburden geology, rock properties, and in situ stress conditions is discussed in the context of their relationship to this problem. The effects of various stress control measures are investigated with model analysis to gain insight into means of reducing the high level of stress known to exist at the entry corners of a West Virginia coal mine prone to cutter roof. The results are presented in the paper and the feasibility of their practical implementation is discussed.

Jan 1, 1982

By Leonard Sugin

Recent changes in the field of ore and bulk commodity handling has forced a reevaluation of previously conceived notions. When vessels were small, and sources of raw material were reasonably close to areas of need, the role of the shipping terminal was of secondary importance. Now terminals must be built to take advantage of the economic benefits of the supercarriers. The shipping rates of the 80's will not be determined by the 60,000 DWT or even 150,000 ton capacity bulk carrier, but rather by the supercarriers in the 250,000 DWT class or larger. When the Suez Canal was closed, the shipping industry took a hard look at the economics of the large bulk carrier. Naval architects overcame the problems and successfully designed large supertankers, which today are plying the seas in excess of 350,000 DWT. Orders have been placed for tankers of 480,000 DWT. The shippers of dry bulk materials are now coming to similar conclusions about the economics of supercarriers. As of today, over 40 orders have been placed for vessels in the 250,000 DWT class, representing an investment of over 11/2 billion dollars, and many more are being considered. These vessels are being designed as combination ore/oil (0/0) or ore/bulk/oil (OBO's) carriers. The oil industry has seen the need for terminals which can accommodate these supertankers. The dry bulk shippers, and particularly ore shippers, must now act.

Jan 1, 1972

By E. James Quinn

Solvent extraction technology using EHEHPA (2-ethylhexyl phosphonic acid, 2-ethyhexyl mono ester) is the norm for industrial separations of rare earth elements. This process has some shortcomings, including a large number of stages compared to most SX processes and high acid requirement for stripping of the heavy rare earths. In this work, we examine a number of alternative mixed solvent extraction systems: (i) Mixtures of organophosphonic and phosphinic acids such as EHEHPA/Cyanex 272 or Cyanex 572; (ii) Ionic liquid mixtures of EHEHPA with quaternary ammonium chloride (Aliquat 336); and (iii) Mixtures of carboxylic acids for yttrium/lanthanide separations. We discuss and compare the efficacy of these systems with reference to the Nd/Sm separation, which is of industrial significance. Based on the extraction chemistry and the use of modelling tools to define the counter-current solvent extraction circuit, we present a techno-economic analysis of a separation plant and discuss the impact of various solvent systems on the capital expenditure (CAPEX) and operating costs (OPEX).

Conditional simulation can be used to determine the probabilities of block iron-grades being above selected cut-offs. However, there are much faster alternatives that can produce acceptable results. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody is used as the basis of a case study to assess alternatives to simulation. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce data subsets. A complete distribution of iron grades for points or blocks is obtained utilising the data subsets and the following techniques: conditional simulation, median indicator kriging, the probability from conditional expectation and confidence intervals attached to the estimation of blocks in the framework of the discrete Gaussian model. The complete blasthole dataset is considered to represent the true iron grades at sample point support while the ordinary kriging estimate derived from these samples is considered to represent the true block grades. The distributions obtained from point estimates, block estimates and simulations are compared to each other and to the true estimates of iron grades using graphs and statistics. The conditional expectation technique reproduced the results obtained from conditional simulation extremely well and it is a viable alternative to simulation at point support. At block support the confidence intervals technique reproduced the results of the conditional simulation more closely than the median indicator kriging and in the data subsets tested the confidence intervals technique actually reproduced the true grade distribution more closely than the conditional simulation.

Jan 1, 2005

By Francis J. Kiessling

Energy and the conversion of potential energy into alternate forms is becoming a topic of household conversation for a larger segment of the world's population as mankind's desire for products derived from the vast array of technological developments continues to expand. The world's use of steel and the high energy consumption related to the production of steel promotes an awareness of the limitations of existing technology and a search for more economical alternates. Terminology such as (BF) Blast Furnace, (BOP) Basic Oxygen Furnace, (EAF) Electric ARC Furnace, (DR) Direct Reduction, (DRI) Direct Reduced Iron and (FC) form coke is becoming commonplace as alternates are being sought to alleviate the energy crunch. Coke production by various methods was developed as early as the seventeenth century in Europe to replace the disappearing hardwood forests that supplied the initial blast furnace fuel in the form of charcoal. In 1880, the Semet Solvay by-product coke oven design was introduced to the United States at Syracuse, New York, to supply coke for use in the production of soda ash, coke oven gas and its by products as the primary source of many organic processes. Although the Semet Solvay coke oven has not been marketed for decades, these coke oven batteries are in use today producing metallurgical coke, coke oven gas, and related by-products.

Jan 1, 1980