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By Conochie D. S, Grave N. C

Disposable-tip emf cells at present used in liquid steel can be used to measure the state of oxidation of high-iron slags produced in non-ferrous smelting. This provides a new tool for the control and evaluation of pyrometallurgical operations.An investigation of oxygen potential variations throughout a typical nickel smelter using the flash smelting technique gave a valuable insight into the process. Correlations of oxygen potential with ferric to ferrous oxide ratio and nickel content in slag were in reasonable accord with equilibrium data in the literature indicating that the probes may be used both as a plant investigation tool and possibly as a means of obtaining thermodynamic data for slags.

Jan 1, 1979

By J. Ji

Oxygen requirement during acidic pressure oxidation of sulphide concentrates can he as high as 800 kg/(m3.h) in the first compartment of an autoclave when the total oxidation residence time is shortened to 30 minutes. To achieve such a high oxygen transfer rate while maintaining satisfactory oxygen utilization, a pilot plant campaign was launched at the Placer Dome Research Centre in 1998 to measure the oxygen mass transfer coefficient in a 5 m3 pressure vessel at a total pressure close to 500 psig with a 30 HP gassing agitator. Maximum oxygen flowrate to the pressure vessel was designed at 3 600 kg/h. In this paper, a great deal of information is provided on the gassing agitator, pressure vessel. measurement procedure and results. Without oxygen sparging, the oxygen mass transfer coefficient is 2 600 h-1 with a mixing power input of 5.0 kW/m3 in solution. With oxygen sparging, the oxygen mass transfer coefficient increases to 3 500 h-1 with a mixing power input of 4.0 kW/m3 in solution.

Jan 1, 2004

By Alexander RB, Hollis AJ

The magnitude of the payloads carried by mine haul trucks can have a strong influence on the mine production rates and costs. Consequently control of truck payloads is highly desirable, but in many mines the unavailability of means for measuring payloads reliably, accurately and easily has resulted in a low level of control over truck payloads. Consideration is given to two techniques which are applicable to the measurement of payloads carried by mine haul trucks, namely truck weighing and direct measurement of payloads with truck based systems. Accuracy assessments for two types of truck weighing platforms and two prototype truck based direct payload measurement systems are provided. Results show that weighing platforms based on hydraulic components have proved inadequate, while strain gauge type weighing platforms can estimate payloads to within 2% of true payload when installed, maintained and used correctly. The assessment of the two prototype truck based direct payload measurement systems shows that a high proportion of payloads were estimated to within 5% of the payloads derived from accurate weighing platforms and that these systems appear to have the potential to provide convenient and accurate measurement of payloads. This should enable payloads to be much better controlled than has been possible to date. Predictions of the effect of payloads on production rates and some components of truck haulage costs are possible and some typical results are presented. Accurate prediction of the effect of payloads are not yet possible for some major components of truck haulage costs.

Jan 1, 1986

By Madsen I. C, Langberg D. E

Recent advances in X-ray diffraction (XRD) technology have made it possible to conduct powder XRD measurements on samples at high temperatures during reaction. State-of-the-art detectors are now capable of rapidly acquiring diffraction patterns across a wide angular range (typically 120"20) enabling phase transformation rates to be measured directly during sample reaction. In this study, the phase transformations during the reduction of hematite to metallic iron by five per cent hydro ºen in nitrogen gas mixtures, were measured in situ between 500 - 700 C. Complete X-ray diffraction patterns were acquired within 15 seconds every one minute, enabling direct measurement of the transient phase abundances during the reaction. The data were quantitatively analysed by the Rietveld method to yield the abundances of hematite, magnetite, wustite and metallic iron, as functions of time during the reduction process. A first-order reactions-in-series model was proposed, and the reaction rate constants and activation energy were determined from the time-dependent phase abundance data.

Jan 1, 1999

By Jason Baird, Philip Mulligan, Caleb Baumgart

This report details the pressure variances, measured at four pressure sensors placed equidistant from the center of an airburst explosion, as the blast pressure from a single charge expands radially. Many of the empirically derived equations used for predicting the blast pressures of an explosion, assume a point source detonation and that the radial pressure expansion is equal. The authors understand that the equations used to approximate the blast pressure may not have 100 percent agreement with the observed pressure. However, during previous research at Missouri University of Science and Technology (Missouri S&T) the pressure variances had a range of 1,200 psi, between the four pressure sensors placed two feet from the center of a 1/2-pound (226.8 gram) of hand packed C4. The variances indicated that at the close distance from a suspended explosive charge the pressure does not behave as that observed from a point source.

Jan 1, 2014

By L Tatnell, R Mackay, A Tolooiyan

The multi-reversal direct shear test (MRDS) method is commonly used to measure the residual shear strength of soils. However, when the standard direct shear (DS) apparatus is used, the MRDS method is prone to two major sources of error: load cap tilting and specimen loss. These two sources of error can cause erratic behaviour in the residual shear strength curve, making it difficult or even impossible to determine the correct residual shear strength value of the specimen being tested. This paper presents the results of new modifications to the standard DS apparatus that prevent load cap tilting and specimen loss. Consolidated drained testing was performed on highly-over consolidated cohesive soil samples from a Latrobe Valley open pit mine, with results obtained from the modified DS apparatus showing a great improvement in the residual shear strength profile compared to those obtained using the standard apparatus. Large numbers of reversals (up to 14) conducted on a single specimen in the modified DS apparatus showed no notable load cap tilting and no specimen loss occurred. The modifications are easily applied to the standard DS apparatus, and analysis and correction of the data are simple.CITATION:Tatnell, L, Tolooiyan, A and Mackay, R, 2014. Measurement of residual shear strength using a modified direct shear apparatus, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 425–434 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By C. Zhou, R. Jacksha

This paper reports measurement results for radio frequency (RF) propagation around 90° corners in tunnels and underground mines, for vertically, horizontally and longitudinally polarized signals. Measurements of signal power attenuation from a main entry into a crosscut were performed at four frequencies — 455, 915, 2450 and 5800 MHz — that are common to underground radio communication systems. From the measurement data, signal power loss was determined as a function of signal coupling from the main entry into the crosscut. The resultant power loss data show there are many factors that contribute to power attenuation from a main entry into a crosscut, including frequency, antenna polarization and crosssectional entry dimensions.

Jan 1, 2016

By L. A. Panek

When rock is subjected to a load it is deformed. Ordinarily this is observed in a mine as the displacement of one point with respect to another-the deflection of the roof, which may be observed as a convergence between roof and floor; or the extrusion of material from the rib, which may be observed as a decrease of the distance between the rib and the post of a timber set. The effect of excessive pressure may be a rockburst if the rock is strong, or it may be "squeezing" ground if the rock is "soft". Some desirable effects of high stress (high in relation to strength) are the caving of roof in a longwall mining operation, the caving of ore in block caving, and the decrease in mechanical energy required to break down the mineral seam in a retreating pillar-robbing operation. In any case, whether the observable effect of rock load is desirable or undesirable, it is a displacement, and depends on the following four factors:

Jan 3, 1961

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

"K. A. DIGREGORIO, E. v. CILENTO, AND R. c. LANTZ. Measurement of superoxide release from single pulmonary alueolar macrophages. Am. J . Physiol. 252 (Cell Physiol. 21 ): C677-C683, 1987.-An electrooptical method was developed to quantify superoxide (02) release from single rat pulmonary alveolar macrophages (PAM) during adherence to the bottom of a culture dish. This was done by measuring the reduction of nitro blue tetrazolium (NBT) to a diformazan precipitate at 550 nm from videorecorded images of individual cells. Temporal changes in cell optical density, which are proportional to the mass of diformazan produced, were calculated from videophotometric measurements of the change in light intensity over individual cells. Total diformazan produced increased 78 and 1263 with an increase in NBT from 0.5 to 1.0 and 2.0 mg/ml, respectively. Total diformazan produced and maximum rate of production among individual PAM varied two- to threefold providing strong evidence for heterogeneity in 02 production. Specific inhibition of 02 production by superoxide dismutase, iodoacetate, and chlorpromazine significantly reduced the total diformazan produced and maximum rate of diformazan production. Hydrogen peroxide was not involved in NBT reduction, since catalase alone did not significantly change diformazan production. This novel method to quantify 02 release from single PAM should be valuable in analyzing heterogeneity and single cell kinetics of O; production, in assessing the effects of exposure of cells to particulates on O; release, and in relating release to electrophysiological measurements.rat; nitro blue tetrazolium; macrophage heterogeneity; single cell kinetic PULMONARY ALVEOLAR MACROPHAGES (PAM) protect the lungs by phagocytizing foreign debris and bacteria (24). This process involves ingestion as well as destruction of foreign matter. Phagocytosis is usually accompanied by a respiratory burst that increases cellular oxygen consumption and glucose metabolism in the hexose monophosphate shunt (7), which leads to the release of highly reactive oxygen metabolites at the surface of the · plasma membrane (6, 27). These agents have been implicated in the killing of bacteria by phagocytes (22), but have also been shown to be toxic and have been linked to cancer, emphysema, arthritis, diabetes, and other diseases (17, 22, 30). Toxic effects may be a result of either an abnormally low production of metabolites, resulting in damage to lung tissue by respirable bacteria and dusts, or an abnormally high production, resulting in direct damage to lung tissue by metabolites themselves."

Jan 1, 1989

By Armstrong M

The Coal Mining Engineering Branch of the New South Wales (NSW) Department of Mineral Resources, in its continuing effort to improve coal recovery from underground coal mining operations, has undertaken a study of the mechanics of sub-surface deformation caused by caving of the extracted area behind retreating longwall faces. The strata movement was monitored by a multi-wire borehole instrumentation system consisting of mechanical anchors installed at different horizons in a borehole extending from the surface to the coal seam. The mechanical anchors were connected to the suspended weights on the surface by stainless steel multi-strand wires. The movement of these weights was monitored as the longwall face approached and retreated past the borehole. The anchors started subsiding as soon as the face retreated past the borehole and continued to subside until the subsidence levelled off when the face retreated 900 m past the borehole. The zone of major caving and bed separation extended to roughly 10 to 13 times the extracted seam thickness and high tensile strains developed inthis zone. The bulking factor of broken strata was less than 1.14 which indicated that the roof layers collapsed in big blocks. The goaf compaction was almost complete when the face retreat was 200 m. Low tensile strains prevailed in the strata overlying the zone of caving and bed separation.

Jan 1, 1986

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

"An electro-optical method was used to quantify superoxide (SO) release from single rat pulmonary alveolar macrophages (PAM) exposed in vitro to respirable quartz and kaolin dusts and in vivo to quartz. Release was determined by measuring the reduction of nitroblue tdrazolium (NBT) to a diformazan precipitate at 550 nm from video-recorded images of individual cells. In vitro exposure to 0.025 or 0.05 mg/ml kaolin for 40 minutes resulted in no significant differences in either the total diformazan produced (max) or the maximum rate of diformazan production (R)./n vitro exposure to 0.025 mg/ml c1uartz decreased max 38 percent while no significant change was found using 0.05 mg/ml. However, R was decreased 31 percent and 24 percent for the low and high dose, respectively. In contrast, PAM obtained from animals exposed in vivo to quartz dust for two or four weeks in inhalation chambers exhibited increased production of diformazan. However, only PAM analyzed three days post-exposure showed significant increases, while PAM from animals sacrificed ten or 31 days post-exposure were not significantly different from control. The combined in vitro and in vivo quartz results might suggest that there is an initital acute response to exposure that decreases the ability of PAM to produce SO, followed by recruitment of production of PAM with increased SO producing capability. It appears that removal of animals from the source of exposure permits PAM to return to control levels of SO production by31 days. Whether this would be true for chronic exposure remains to be elucidated.IntroductionPulmonary alveolar macrophages (PAM) protect the lungs by phagocytizing foreign debris and bacteria.(1) This process involves ingestion as well as destruction of foreign matter. Phagocytosis usually is accompanied by a respiratory burst which increases cellular oxygen consumption leading to the release of highly reactive oxygen metabolites.(2) These agents have been implicated in the killing of bacteria by phagocytes, but they have also been shown to be toxic and,have been linked to cancer, emphysema, arthritis, diabetes, and other diseases.(3) Toxic effects may be a result of 1) an abnormally low production of metabolites, resulting in damage to lung tissue by the respired bacteria and/or dusts; or 2) an abnormally high production resulting in direct damage to lung tissue by metabolites themselves."

Mar 1, 1989

By R. A. Williams

Electrical impedance tomographic methods have been applied to a variety of mineral and chemical processes in the laboratory and on plant. This review paper surveys technical developments in measurement methods to enable quantitative extraction of key process information in the form of mapping of concentration profiles, mixture homogeneity and suspension velocity. The methods for determining velocity are summarized, since this is of especial interest when applied to opaque systems where most conventional optically based measurements fail. A recent significant development is the use of ultra-high speed measurement that now allows velocity vectors to be extracted for fast moving mixtures and fluids (up to several metres per second). New data are reported pertinent to low and high solids concentration flow in pipelines. Use of the methods offer improvements to design of such systems but also points to the use of tomographic electrical sensor as online flow measurement and fault detection. This offers new opportunities for applications and benefits in the design and monitoring of mineral slurries and sludges.

Jan 1, 2008

By BHAMIDIPATI S. SASTRY, Pavan Kumar Kattamuri, ADITYA PANDEY

The thermal conductivity of rock surrounding the airway is one of the most important thermal properties for estimating strata heat transfer into the mine air and for designing the air-cooling strategies. Several laboratory methods are available for the determination of thermal conductivity; however, most of them are complex and cumbersome. The present study explains the working principle of Lee’s apparatus which is relatively simple, easy to fabricate and use, and provides consistent results. In the present study, thermal conductivities of sandstone cores obtained from an Indian coal mine are determined using Lee’s apparatus. An approach is discussed for determining the temperature gradient of sandstone specimens while cooling and used for calculating thermal conductivity. The thermal conductivity of different sandstone specimens attains values between 2.37 and 2.59 W m− 1 °C−1. For different sandstone cores obtained from the field, properties including specific gravity, specific heat capacity, thermal diffusivity, and porosity, along with thermal conductivity, are determined and highlighted in this study.

Jul 20, 2021

By BHAMIDIPATI S. SASTRY, KATTAMURI PAVAN KUMAR, ADITYA PANDEY

Several laboratory methods are available to determine the thermal conductivity of rocks, but most of them are complex and cumbersome. The present study explains the working principle of Lee’s apparatus, which is relatively simple, easy to fabricate and use, and provides consistent results. In the present study, thermal conductivities of sandstone cores obtained from an Indian coal mine are determined using Lee’s apparatus. An approach is discussed to determine the temperature gradient of sandstone specimens while cooling and is used to calculate thermal conductivity. The thermal conductivities of different sandstone specimens have values between 2.37 and 2.59 Wm−1°C−1. For different sandstone cores obtained from the field, properties including specific gravity, specific heat capacity, thermal diffusivity and porosity, along with thermal conductivity, were determined and highlighted in this study.

By S. J. Buckler

Many chemical and metallurgical processes use submerged gas injection to increase contact area between gas and liquid phases in order to promote faster overall reaction or refining rates. The total interfacial area produced by gas injection through lances, nozzles or tuyeres is both an important design parameter for new vessels and a measurement for estimating the maximum processing capacity of existing equipment. Estimating total interfacial area from submerged injection into industrial pyrometallurgical vessels from existing knowledge is a problem with two aspects. The first difficulty is the difference in behaviour of cold (aqueous) and hot (molten metal) systems, implying that existing models and correlations of gas-liquid behaviour developed in low temperature systems are not necessarily appropriate for estimation of high temperature behaviour. The second difficulty is the issue of scale-up of correlations from laboratory to industrial sized vessels. The work presented in this paper is part of an ongoing experimental investigation, at the GK Williams CRC for Extractive Metallurgy, to quantify the total gas-liquid interfacial area available in pyrometallurgical vessels using chemical measurement methods. The effects of three operating variables, injected gas flow rate, nozzle diameter and nozzle submergence, on total interfacial area are quantified in a IOOL aqueous system - the first stage of a three stage process in examining the implications for scale-up of high temperature, medium-scale results are discussed. The results of work at high, injected gas flow rates (up to 500/min) show that the submerged Froude number is not sufficient for use as the sole variable in a predictive model of total interfacial area. Further work is being undertaken to identify other dimensionless variables that will better represent the gas-liquid characteristics in submerged injection that influence the formation of total interfacial area. The second and third stages of the experimental investigation involve measuring the total interfacial area in a large-scale (1000L) aqueous sodium sulphite and small-medium scale molten metal baths.

Jan 1, 2002

By H. Gumede

The occurrence of fracturing due to high stress levels is a major factor in hangingwall stability in deep level gold mine stopes. However, rock falls cannot be the result of these fractures alone. Rock falls can result only from the occurrence of unstable rock blocks defined by the interaction of the stress induced fractures and naturally occurring geological planes of weakness. These planes include bedding planes and joint set planes. However, there is a general lack of information on the characteristics of these planes (orientations, spacings and lengths)?it does not appear that any such systematic and quantified information, if collected, has been published. To remedy this situation to some extent, joint mapping exercises have been carried out in several geological environments in two gold mines. The data collected on joint geometry included orientation, spacing and length, and this information is included in the paper. In addition, the paper describes the use of the data collected to evaluate the potential for rock falls and the probability of failure of stope support

Jan 1, 2007

By M. Botz

For leach solutions containing primarily free cyanide, the silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method significantly over-estimates the concentration of free cyanide and under-estimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric titration method for determining WAD cyanide that overcomes issues with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to fully release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, accurate WAD cyanide measurements were achieved using the MP-WAD method. Analyses obtained with the new method were found to be within about ±10% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.

Feb 27, 2013

By I. Ward, E. Milosavljevic, M. Botz

"The silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide in leach solutions that contain primarily free cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method overestimates the concentration of free cyanide and underestimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric (MP) titration method for determining WAD cyanide that overcomes issues associated with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper, and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, analytical results obtained with the new MP-WAD method were found to be within about ±5% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.IntroductionThe silver nitrate titration method is widely used to estimate the concentration of cyanide in leach solution for purposes of cyanidation process control. Cyanide determined by silver nitrate titration is commonly referred to as “free” cyanide, but frequently should be referred to as “titratable” cyanide. By definition, free cyanide is the sum of the concentrations of aqueous hydrogen cyanide HCN(aq) and the cyanide anion CN- (ASTM, 2010). Titration will only yield a reasonably accurate measurement of free cyanide when metal-cyanide complex concentrations (e.g., cadmium, copper, mercury, nickel, silver and zinc) in solution are low. In other words, titration will only yield a reasonably accurate measurement of free cyanide if the solution primarily contains free cyanide."

Jan 1, 2015

By R L. Langak, R A. Heins

The use of differences in specific gravity between minerals to separate them has long been utilized in the extractive industries. The environmental and cost benefits of the commercialized forms of these processes are well understood and widely used. Gravity concentration is used inter alia in the primary beneficiation of gold, diamonds, coal, tin, ferrous metal ores and andalusite. The potential for economic loss due to poor performance of these gravity processes is significant, but diverse in manifestation and regular process monitoring can prevent or at least reduce these losses. The measurement of performance of gravity processes has always presented a challenge, due primarily to the masses of material involved and the physical nature of the processes, generally typified by long reporting time, and hazardous materials (such as Tetrabromoethane) for float and sink type tests. The development of density tracers has improved this situation, however recovery of these tracers from the process streams created the next set of challenges, requiring significant manpower to physically remove tracers from product dewatering screens. Additions to these tracers (magnetic or x-ray fluorescent) eased the recovery mechanism issues but made them much more expensive to produce, hence operators became concerned about losses during process testing. In addition, magnetic recovery of smaller size tracers by a magnet suspended above a loaded screen panel is still problematic. The development of new low cost magnetic tracers has improved statistical significance of tracer tests, as the tracers themselves can be bought and used in much larger quantities, whilst still remaining economically viable. Coupled with the development of effective magnetic recovery technology, such as the Gekko MagScreen, for even fine sized tracers, on-line, continuous tracer testing is now becoming a reality. Whilst the development of high technology radio frequency detection tracer systems continues, enabling the real time measurement of the process and interpretation of results, miniaturization and recovery of these tracers, which is critical given their costs at present, remains an issue. Keywords: Gravity, process measurement, tracers, magnetic recovery

Jan 1, 2006

By D J. Bradshaw

It is well known that the chemical environment determines the success of the flotation process, however its characterization and control is difficult to achieve. This work evaluates the use of various measurements, including mineral potential measurements, in gaining an understanding of the influence of varying parameters such as the milling media and the reagent suite composition on the flotation performance of a platinum group metal (PGM) bearing ore. The results showed differences in the response of the various mineral electrodes to the different conditions, however the changes in flotation performance of the different minerals in the ore could not be wholly described by the electrochemical changes, demonstrating the limitations of these measurements.

Jan 1, 1999