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By A. M. Venter, C. W. Siyasiya, N. K. K. Arthur, M. G. Willemse, D. Marais

Although additive manufacturing is fast gaining traction in the industrial world as a reputable manufacturing technique to complement traditional mechanical machining, it still has problems such as porosity and residual stresses in components that give rise to cracking, distortion, and delamination, which are important issues to resolve in structural load-bearing applications. This research project focused on the characterization of the evolution of residual stresses in Ti-6Al-4V extra-low interstitial (ELI) additive-manufactured test samples. Four square thin-walled tubular samples were deposited on the same baseplate, using the direct energy deposition laser printing process, to different build heights. The residual stresses were analysed in the as-printed condition by the neutron diffraction technique and correlated to qualitative predictions obtained using the ANSYS software suite. Good qualitative agreement between the stress measurements and predictions were observed. Both approaches revealed the existence of large tensile stresses along the laser track direction at the sections that were built last, i.e., centre of the top layers of the samples. This in addition leads to large tensile stresses at the outer edges (corners) which would have the effect of separating the samples from the baseplate should the stresses exceed the yield strength of the material. Such extreme conditions did not occur in this study, but the stresses did lead to significant distortion of the baseplate. In general, the microstructures and spatial elemental mapping revealed a strong correlation between the macro-segregation of elemental V and the distribution of the β-phase in the printed parts.

Feb 6, 2023

By C. Holmes, T. Holmes

Engineered-in material handling problems are responsible for significant unrealized value in mineral processing plants. At the root, is a lack of awareness and understanding of bulk material handling science and how important it is, especially in early design stages. Mineral processes add value to mined raw feedstock through physical and chemical transformations in unit operations, but only if the material can flow through them. Essentially, each unit operation receives a unique feedstock and produces a unique product to be collected, transported, and fed into the next unit operation. Such material-handling systems can only be expected to achieve design throughput if the system equipment is designed to the materials’ characteristics, over their full range of conditions. This requires quantification of flow properties to support the necessary customized equipment designs. Too often, assumptions or “library values” of a material’s properties are used as the basis for flow modelling and conceptual, and sometimes even detailed, design. This is especially true for hazardous materials like uranium ore, for which the additional precautions, costs, and time necessary for safe handling are often used to rationalize postponing or even bypassing testing. The surprises that often transpire in the wake of insufficient material handling consideration can have acute and costly effects. Fortunately, there is a better way.

Jan 1, 2020

By Schonert K

The throughput of a HP-roller mill is determined by the acceleration of the feed material within acceleration zone and introduction into the compression zone. Both processes depend on the internal friction and the friction of the material on the roller surface which is influenced by the surface structure and adhering of material. The particle motion in the acceleration zone has been investigated with high speed videos showing the effect of the centrifugal force and the slip on the roller surface. The throughput is discussed in the term of the specific throughput which can be approximated by a linear function characterised by the throughput number and the throughput elasticity. The throughput number is a helpful measure for investigating the influence of the feed material and the surface structure. The experimental results give some guidance for chosing an optimum corrugation profile.

Jan 1, 1993

By Thomas M. Barczak

Secondary roof support systems play a vital role in preserving the safety of underground mine workers by preventing the unintentional collapse of the mine roof. Hundreds of thousands of standing roof supports are constructed each year in underground coal mines. Historically, wood and concrete cribs and timber posts have been used for secondary roof support. These support constructions require the handling of heavy and bulky materials, causing numerous injuries to the mine workers and resulting in more than 40,000 lost workdays in the past 9 years. Since 1993, various alternative support technologies have been developed. These new support technologies not only provide superior roof support, but many also have significant material handling advantages by using smaller and lighter weight materials, fewer components, mechanically installed support systems, and pumpable support systems. The National Institute for Occupational Safety and Health (NIOSH) has conducted extensive material handling research and has developed recommended lifting thresholds to reduce material handling injuries. An analysis of roof support construction reveals that conventional support materials used in wood and concrete cribbing exceed the recommended lifting thresholds, while the engineered support systems are closer to the recommended weight thresholds. Finally, recommendations are made relative to proper lifting techniques and material handling practices to prevent injury to mine workers when constructing roof supports in underground coal mines.

Jan 10, 2000

By Robert B. Crookston

Oil from shale has been produced in foreign countries for more than a hundred years; however, except for short-lived, small operations, no commercial quantity of oil shale has yet been produced in the United States. Efforts to develop a viable oil shale process have been underway domestically for many years. At the present time, with the need for energy so urgently upon us, almost a dozen development ventures are underway or planned in Colorado and Utah. Of these several ventures, only Colony Development Operation has completed the development, testing and design of a ready-to-go 50,000 barrel per day com¬mercial project. Colony is a joint venture of the Atlantic Richfield Company, Ashland Oil Company, Shell Oil Company and The Oil Shale Corporation, more commonly known as TOSCO. TOSCO is the exclusive licensor of the TOSCO II retorting process and other oil shale technology, which includes mining, crushing and spent shale disposal techniques. This paper will deal, however, with only the materials handling aspects of the commercial oil shale operation. Oil shale handling for this infant industry is unique in that an understanding of the physical characteristics of the ore and the demands on material handling to the plant must he understood. Colony Development has completed ten years in the research and development of techniques and processes for mining, crushing and retorting raw oil shale and the disposal of spent or processed shale. A great deal has been learned about oil shale, in many cases confirming our intuitive analyses and the work of others, but more specifically we have brought it all together to a point where equipment performance and the specifications have been established and a design for the first commercial plant is now mature.

Jan 1, 1975

By J. F. Oyler

One of the most important applications of material handling engineering technology occurs in iron ore pelletizing plants. Although the total installed value of material handling systems in such plants, as well as in many other modern process plants, is a relatively small percentage of the value of the plants (5 to 10% perhaps), their significance is considerable. Indeed this significance equals that of the more expensive process equipment in the plant, since the failure of any component of any system causes, shutdown of the entire plant. It is because of this increased consequence of failure that design criteria for process plants are more conservative than for conventional material handling applications. A second unique characteristic of material handling technology applied to process plants in general is the variety of materials being handled and the wide range of problems this variety presents. One extreme encountered is the stickiness of filter cake. Here the entire design effort is aimed at keeping the material flowing through transfer points and preventing it from building up on components. Another extreme is the conveying of fired pellets - hard spheres with a very flat angle of repose and abrasive characteristics severe enough to make conventional wear plate materials impractical.

Jan 1, 1976

By R Stefansen, T Wisdom, A Nicholson, K Rahal

The challenges of increasingly scarce water resources and the risk of dam failures has seen the mining industry turn to sustainable tailings management solutions such as dewatering and dry stacking. Filtering tailings has been seen in the past as a cost-prohibitive process for larger throughput mines. However, as larger pressure filters are developed, the economic case for filtered tailings has gained traction.Focus has largely been placed on the correct design and operation of the filters. It is critical, however, that the material handling portion of the disposal system is also properly designed and operated. Thorough testing at laboratory and pilot scale to determine the conveying properties of the filtered material needs to be conducted. This testing will insure the material handling system meets the important availability needs of the mine even during periods of variability in the upstream processes and mine plan.The control system must also be robust and flexible in design to compensate for this upstream process variability. The control system needs to allow for different flowsheets including straight filtered tails as well as EcoTails™, a low-energy solution for co-mingling waste rock and filter cake.This paper will present case studies of different material handling solutions, the testing required for them and the lessons learned from each.CITATION:Rahal, K, Nicholson, A, Stefansen, R and Wisdom, T, 2018. Material handling testing and control system requirements for dry stack tailings, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 361–368 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By John W. Fredland

Many accidents occur in the mining industry as a result of the instability of material during handling and processing operations. Accidents due to dump point instability at stockpiles, and at spoil or waste piles, for example, occur with alarming frequency. Miners must be trained to be better aware of these hazards. Information on safe working procedures at stockpiles and surge piles is provided. Mine operators must review their training and operating procedures regularly to ensure that hazardous conditions are avoided.

Jan 1, 1993

By B. S. -J. Kang, M. A. Alvin, J. M. Tannenbaum

"A load-based micro-indentation technique has been developed for damage assessment and non-destructive spallation detection of TBCs at room temperature. This micro-indentation technology has been further extended to the development of a high temperature (HT) test methodology. Elastic modulus calibration tests performed on Hl 3 Tool Steel to 500°C and Haynes 230 at 1000°C displayed excellent agreement with reported values. Moreover, indentation creep tests of Haynes 230 at 1200°C were found to be in agreement with known creep exponents as well. Finally, a HT thermal flux indentation apparatus was assembled for conducting TBC turbine component testing under high temperature moisture-containing environments (= 50% steam with controlled gas content temperatures up to 1250°C). Description and design considerations of this test apparatus are discussed. Preliminary tests of ReneN5/MCrAlY/APS TBC coupons in steam/air environments with in-situ HT micro-indentation testing are conducted. Furthermore, the coupon is removed and examined for damage assessment at periodical intervals.IntroductionLoad and depth relationships acquired throughout the indentation process provide insight to material mechanical properties such as elastic modulus and hardness. Unloading segment analysis of these load displacement curves are utilized in the acquisition of a material's elastic properties. Yet, indentation tests are complex processes involving contact mechanics, material nonlinearity and even fracture mechanics. Thus exact analytical solutions for these processes are difficult to obtain. As a result, much of the current knowledge regarding the indentation process has been acquired through experimental methods and finite element simulations. Initial efforts by Tabor resulted in the application of spherical indentation to obtain post-yielding stress/strain relationships [1]. Soon thereafter, analytical load-depth relations for elastic indentation were developed [2], yet it was Lure who further derived the explicit relationships for both spherical and conical indenters [3]. Improving upon this, these interactions were later extended to indenters with various geometries by various researchers [ 4]. Additionally, by establishing the linearity of the initial unloading slope within the load-depth curve, a relationship between elastic indentation depth, maximum load, unloading slope and indenter geometry was established [5]. From this a theoretical method by which elastic modulus could be determined was established."

Jan 1, 2011

By A. A. Schweizer

Buckhorn ore is hydrous, argillized basaltic andesite, and is at least 60% clay composed of kaolinite and subordinate montmorillonite. Moisture content runs from 10% to 25%. The original crushing plant was a typical compression type, employing a jaw crusher, and two cone crushers. The system was plagued with constant plugging and unable to meet production plans. The three compression crushers were replaced with a Stamler Feeder Breaker followed by a Hazemag Impactor. Production plans are now exceeded. Agglomeration has progressed from an agglomeration drum to cascading conveyors, to introduction of the lime and cement into the primary crusher.

Jan 1, 1987

By Alex Grenoble, Alex Reeb, George Filz, Farzad Abedzadeh

"This paper summarizes available information on the characteristics and properties of deep-mixed soilcement produced by the wet method. The topics covered in this paper include: unit weight, unconfined compressive strength, strength variability for field mixed materials, influence of curing time, influence of consolidation pressure, Young’s modulus, differences in strength and stiffness between small and large samples, creep deformations, Poisson’s ratio, and tensile strength. In addition, this paper discusses the development of design considerations and recommended property values for a project that uses soilcement to protect an existing dam penstock from loads applied by an overlying stability berm. Some of the key recommendations for the deep-mixed soil-cement to be used in this project are that (1) a curved strength envelope that includes tensile strength can be used in the analysis, (2) the stress-strain and strength properties can be characterized using Duncan and Chang's (1970) hyperbolic model, and (3) a specification based on the median unconfined compressive strength value is appropriate.INTRODUCTIONFor many projects, including foundation and embankment support, deep mixing can be designed based on simplified procedures and following standardized guidelines (e.g., FHWA 2013). However for unusually complex or critical projects, it is often necessary to perform numerical analyses, and in order to perform these numerical analyses well, a thorough understanding of the material properties is needed.This paper summarizes information on the characteristics and properties of deep-mixed soil-cement produced by the wet method, and it discusses the development of design considerations and recommended property values for a specific project, herein referred to as the penstock project, that requires numerical analyses. For the penstock project, a horseshoe-shaped enclosure of soil-cement is being considered beside and above an existing dam penstock to protect it from loads applied by an overlying stability berm that will be constructed for seismic remediation. The concept is to use soilcement created by the deep mixing method along the sides of the penstock and to use compacted soilcement above the deep mixing to create the crown of the protective soil-cement zone around the penstock. For this application, the soil-cement stiffness, rather than its strength, is the controlling design parameter. To achieve the necessary soil-cement stiffness, the strength will be high enough that the factor-of-safety values against instability along potential failure surfaces passing through the soil-cement are high. Following conventional practice, the soil-cement acceptance criteria will be based on the unconfined compressive strength, and the specified strength will be selected to produce the desired modulus value."

Jan 1, 2015

By Scott R. Giese, Lucas Dix

"Recently, there is a growing trend in the aluminum foundry industry to develop· improved melting and casting processes to produce lightweight, high-strength, and thin-wall castings for the aerospace and transportation industry. One casting method that has demonstrated industrial potential for producing clean, thinwall castings is vacuum-assisted, counter gravity casting. This process has the benefit of expeditiously and quiescently filling the casting cavity with a dramatic reduction of furnace related and reoxidation inclusions. Additionally, lower casting temperatures can be utilized because the application of vacuum during filling overcomes the resistive internal cavity pressure resulting in a finer, as-cast microstructure. The paper explores and discusses the processing and design conditions in improving the mechanical properties of A206 casting alloy using the vacuum assisted, counter gravity casting process.IntroductionThe process of metal casting has been, over the centuries, the chief production technique for components used in everyday life. However, the casting process has certain inherent problems that can adversely effect the properties of a finished product. These problems are directly attributable to the gravity pouring technique used to transfer molten metal to the mold and to fill the mold cavity.A recent study for the American Metalcasting Consortium demonstrated reoxidation products created during the casting process are five times more likely to cause product rejects than entrapped molding aggregates, melt slag, or furnace lining materials1. Formation of nonmetallic and intennetallic compounds are more prevalent in aluminum and titanium alloys because of their reactiveness to furnace lining materials and their high affinity for oxygen. The incorporation of undesirable compounds can be attributed to four areas of the casting operation. The sources are charge materials, melting technique, pouring methodology, and casting cavity filling. Aluminum foundry men have addressed the first three areas by selecting high quality melt stock, non-stirring melting equipment, and the use of porous ceramic filters. Unfortunately, little consideration is given to the last, but yet tl.1e most important part of the casting operation, the actual fill mg of the casting cavity.The generation of inclusion defects during the casting process can be described by two methods. As the liquid metal flows in the gating network and casting cavity, abrupt changes in flow d1rect10n cause the metal to become agitated. This mechanism liquid metal splashing, is generated by instability of the advancing liquid metal interface from turbulence effects as schematically illustrated in figure 1a2 . The surface oxide film bursts under high velocity conditions, folds over, and becomes dispersed and incorporated in the bulk liquid. Additionally, fragmented liquid droplets ejected from the disturbed interface oxidize and become dispersed in the metal stream."

Jan 1, 2000

By W. R. Reed, S. Klima, J. Driscoll, T. W. Beck

"Tests were conducted to determine properties of 4 foam agents for their potential use in longwall mining dust control. Foam has been tried in underground mining in the past for dust control and is currently being reconsidered for use in underground coal longwall operations in order to help those operations comply with MSHA’s lower coal mine respirable dust standard (1.5 mg/m3). Foams were generated using two different methods. One method used compressed air and water pressure to generate foam, while the other method used a low pressure air generated by a blower and water pressure using a NIOSH developed foam generator. Foam property tests comprising of a bottle shake test, foam expansion ratio, and water drainage were used to classify foams. The bottle shake tests determined that the lowest concentration of foam agent to be used was approximately 1.5%. Compressed air generated foams tended to have low expansion ratios (10-19) with high water drainage. Blower air generated foams had higher foam expansion ratios (30-60) with lower water drainage. Foams produced within these ranges of expansion ratios are stable and potentially suitable for dust control. The different foam agents produce foams with different material properties. Results of testing eliminated two foam agents for future testing because they had poor expansion ratios. The remaining two foam agents, while having different foam properties, seem to have properties adequate for dust control. These material property tests can be used to classify foams for their potential use in longwall mining dust control. INTRODUCTION About one-half of U.S. underground coal is produced by longwall mining. This technique allows for mining high volumes of coal, producing significant amounts of coal mine dust. This can lead to the overexposures to longwall miners and possibly occupational respiratory diseases black lung and silicosis, which have no cure and can be disabling or fatal. The only method to avoid these occupational illnesses is through elimination of exposure to respirable coal mine dust and crystalline silica (quartz). The current occupational exposure limit for respirable coal mine dust is 1.5 mg/m3 during each shift that a miner is exposed in the active workings of the mine or in mine facilities [1]. When respirable quartz is present, the mine must maintain an average concentration at or below 0.1 mg/m3. If the mine exceeds the 0.1 mg/m3 respirable quartz dust concentration, then the applicable respirable dust standard is reduced, calculated as 10 divided by the percent quartz present [2]. Respirable dust samples collected by U.S. Mine Safety and Health Administration inspectors for the five-year period from 2010 to 2014 found that 5.6% (53 of 943 respirable coal mine dust samples) of the longwall operators on the tailgate side exceeded the coal mine dust standard, and 4.3% (76 of 1768 samples) of the jacksetters exceeded the standard. If silica is present, the reduced standard is implemented, meaning that 11.4% (36 of 316 respirable coal mine samples analyzed for dust) of the jacksetters exceeded the reduced standard. Only 3.8% (18 of 478 samples) of the longwall operators on the tailgate side exceeded the reduced standard [3]. Had the 1.5 mg/m3 standard been in effect during this period, non-compliant samples would have been much higher. For example, over 15% of the samples collected at the tailgate shearer operator occupation exceeded the lower standard."

Jan 1, 2017

By N. Behnood, W. Pascheto

"Laboratory wear tests are important tools that can be used for the evaluation of materials for wear applications and mitigation of wear problems in the mining industry. However, laboratory test parameters must be fully characterized and test results must be carefully interpreted if a material selection is to be made. Failure to do so may lead to erroneous conclusions. Suitable lab-oratory tests are valid only if they reflect the field conditions to which materials are subjected. Therefore, it is important to know, in detail, the field conditions, as well as the wear test techniques being considered. It is important to recognize the limitations of the various wear tests and the wear test data published in the literature. This work will review present wear testing technology, including the various wear tests avail-able, wear test equipment and test limitations. Several wear test procedures will be related to common equipment used in the mining industry.IntroductionThis paper will concentrate on non-lubricated wear mechanisms, because they are the most costly to the mining industry. Very frequently we are faced with the task of selecting materials for wear applications or improving existing systems that are giving poor performance. There are plenty of examples in the literature of practical wear cases and ranking of materials for wear applications. It is also very common to find materials manufacturers’ data -sheets listing wear tests results by comparing their materials performances against those of competitors. Much of the published wear data lack the description of the type of wear test, test parameters and the type of wear mechanism to which the data should be applied (if any).Before considering wear test data for a specific problem one should ask which type of wear mechanism is involved? What type of test and what test parameters were used to produce the results? Even if the type of wear tests and parameters are known, how accurate and useful are the published wear data? How are the results related to a particular type of wear? It is important to point out that even the standardized wear tests, such as those in ASTM standards, have limitations. Such limitations are recognized and clearly spelled out in the standards themselves. Basically, wear tests may lead to erroneous results if the test is not able to repro-duce the same wear mechanisms encountered in the field. Therefore, the use of published results may be helpful, as a starting point, but may be of little value for a final material selection.This work will discuss the main types of non-lubricated wear mechanisms encountered in the mining industry. In addition, it will discuss the many wear tests available and their correlation with the various types of wear mechanisms. The limitations of several standardized wear tests and the limitation of using published wear data will also be discussed."

Jan 1, 1997

By Sanjeeva Latchireddi

The effective utilization of the energy in comminution devices depend on how efficiently the broken particles leave the breakage field as soon as they reach product size. In crushers the transport of broken particles smaller than CSS is done by gravity (vertical) thus allowing the energy to be applied to new particles. However, in AG/SAG mills, gravity becomes the energy field and the transport of particles is horizontal which needs a suitable discharge mechanism and has been found to have significant effect on grinding efficiency. The material transport in AG/SAG mills depend on how efficiently the discharge system (grate and pulp lifters) operates. Material transport plays a significant role on efficiency of horizontal grinding mills ? AG/SAG/Ball mills. The magnitude of benefits that can be achieved with efficient material transport in AG/SAG mills has been demonstrated in a Greenfield milling operation at Mirabela Mineração?s SantaRita Nickel operation located in northeastern part of Bahia in Brazil. This grinding circuit was commissioned in October 2009, which was designed as a typical SABC circuit to grind 4.6 mtpa (575tph) to produce a P80 of 125um with 10-12% ball charge in SAG mill. However, it has been operating as ABC circuit without any grinding media in SAG mill. The nameplate design capacity has been achieved in few days and has gradually increased to an average of +800 tph and still it is operating in ABC mode. The milling circuit commissioning resulted in small and relatively simple measures to rectify, which was reflected in the rapid commissioning of the milling circuit and it achieved the nameplate capacity within days. The Santa Rita grinding circuit consists of one 30?x 15.4? 8.5MW SAG Mill fitted with Outotec patented Turbo Pulp Lifters (TPL TM ) in close circuit with HP400 short head pebble crusher and one 20? x 28.4? 5.5MW Ball Mill in closed circuit with Warman cyclone cluster fitted with 10 x 26? CAVEX cyclones. This paper examines the comminution design process, operating philosophies, experiences, post commissioning optimization, and future development works. Evaluation of the milling circuit performance relative to the design criteria is also discussed. Keywords: Autogenous Grate (AG), Semi-Autogenous Grate (SAG, Turbo Pulp Lifter (TPL)

Sep 1, 2012

By Jorge Tramaglia

En la naturaleza existe elementos radioactivos naturales conocidos por las siglaS NORM ( naturally occurring radioactive material) que desde su origen en el reservorio, se movilizan acompañando al petróleo hasta las instalaciones de proceso en superficie. En ese sentido, el presente texto señala la radioactvidad de esto materiales, transporte y acumulación, procesos de separación, valores de contaminación, las formas de irradiación y la espectometría.

May 1, 2015

By D. J. Archambeault, A. Saigal

Substantial cost savings have been demonstrated by material design changes after initial product development. As more information about a product's operating environment becomes available to a designer, it is possible to consider a more costeffective material that still meets or exceeds the design intent, such as minimum low cycle fatigue life. This is especially true in the aircraft engine industry, where precise operating cycle data is not available until after the first engine is built and tested. A methodology for predicting estimated low cycle fatigue life has been developed to investigate potential material change candidates for an aft cooling plate. A twodimensional macromechanical finite element model (FEM) has been developed using ANSYS and used to determine the effects of varying material properties. It is shown that slight changes in density, coefficient of thermal expansion and modulus of elasticity have profound effects on component and effective stresses, and therefore, estimated low cycle fatigue (ELCF) life. Aerospace

Jan 1, 2006

Despite modest improvements in the performance of domestic interest rates and gross national product,1 fixed investment in domestic producers' durable equipment continued to weaken during the second quarter of 1982 and declined at a 12.8 percent annual rate compared with the first quarter.2 Large declines occurred during the second quarter in expenditures on many of the major mineral-consuming industries such as aircraft, computers, agricultural and construction machinery and mining and oil field equipment. These data appear to be consistent with the low level of business investment plans for 1982 reported in the DOC's Bureau of Economic Analysis survey of expenditures on new plant and equipment.3 Domestic and foreign industrial production and mineral industry production activities continued to decline in the most recent period because of weak demand conditions (Tables 1 and 2). The U.S. mining production index declined 7.7 percent between April and June as compared with 1.2 percent for total U.S. industrial production (Table 1).

Jan 1, 1982

By N. Behnood

"This paper describes how material selection, quality assurance, and failure investigation play important roles in the efficiency and safety of mining and metallurgical operations.INTRODUCTION Material selection, quality assurance, and failure investigation are all complementary elements of materials engineering in the application of materials technology for failure prevention. Based on commodity price increase of 300% between 2002 to 2013 [1] and increased cost ofcapital projects and operation, equipment failure, which in some cases causes complete shutdown of the operation, becomes a vital importance in mining and metallurgical plants. The following sections present a number of examples from many failure cases experienced by the author during his three decades of work as a materials engineer in the mining industry."

Jan 1, 2015

By Jewel A. G. Gomes

Electrocoagulation (EC) has been performed with Al-Fe electrode system with changing polarity for the removal of arsenic from water. The removal process has been studied using ICP-AES and Anodic Stripping Voltammetry with a wide range of arsenic concentration (1-1000 ppm) at various pH (4-10) and residence times (1-60 min). Electrochemically generated by-products have been analyzed using XRD, FTIR, XPS, SEM/EDS and Mössbauer Spectroscopy. Results revealed expected crystalline iron oxides (magnetite (Fe3O4), lepidocrocite (FeO(OH)), iron oxide (FeO)) and aluminum oxides (bayerite (Al(OH)3), diaspore (AlO(OH)), mansfieldite (AlAsO4?2(H2O)), as well as some interaction between the phases. The amorphous or ultra-fine particular phase was also found in the floc. The substitution of Fe3+ ions by Al3+ ions in the solid surface has been observed, indicating an alternative removal mechanism of arsenic in these metal hydroxides and oxyhydroxides by providing larger surface area for arsenic adsorption via retarding the crystalline formation of iron oxides.

Jan 1, 2006