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By Kent von Maubeuge, Charles R. Landis

The global bentonite industry is a dynamic market balancing a range of end uses with an ever growing number of bentonite producers. In addition, markets in developed countries are elevating the level of detail and transparency for materials reporting in programs, such as the Registration, Evaluation, Authorization and restrictions of Chemicals (REACH) program in the European Union. Bentonite is impacted by programs of this nature. The majority of the bentonite products sold around the world are sodium bentonites. These sodium bentonites consist either of natural sodium bentonites, or naturally occurring bentonite dominated by divalent interlayer cations (Ca+2 andMg+2) subsequently exchanged with sodium cation. The latter variety is often called “sodium-activated“, or “soda-ash treated” bentonite. Once exchanged with sodium, these bentonites are often difficult to distinguish from natural sodium bentonites using common commercial testing protocols. Due to their similar colloidal and bulk chemical properties; the lack of test procedures designed specifically to identify this product feature; and the failure to completely or effectively explain their differences, sodium-activated bentonite is often considered to be identical to natural sodium bentonite in the industry. This article defines both general types of sodium bentonite and presents a technique that could serve the industry as a tool to confirm the variety of sodium bentonite in question. Specifically, geochemical properties such as carbon (C13/C12) and oxygen (O18/O16) isotopic ratios can distinguish activated, even slightly activated bentonites, from bentonites not introduced to additional sodium during manufacture.

Jan 1, 2004

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By D. A. Ainsworth

"The first known use of activated carbon dates back to the Ancient Egyptians who utilized its adsorbent properties for purifying oils and medicinal purposes. Centuries later, the early ocean going vessels stored drinking water in wooden barrels, the inside of which had been charred. (However, by modern definition the carbon used in these applications could not truly be described as activated.) By the early 19th century, both wood and bone charcoal was in large scale use for the decolorization and purification of cane sugar.However, it was not until the beginning of the First World War that the potential of activated carbon was really capitalized upon. The advent of gas warfare necessitated the development of suitable respiratory devices for personnel protection. Granular activated carbon was used to this end as, indeed, it still is today.By the late 1930's there was considerable industrial scale use of carbon for both gaseous and liquid phase application and new manufacturing processes had been developed to satisfy the needs of industry. During the 1939-1945 war, a further significant development took place - the production of more sophisticated chemically impregnated carbon for the removal of both war and nerve gases."

Jan 1, 1984

By Michael Drozd

"The operation of an activated charcoal system has five separate unit operations. These unit operations have common points for CIP, CIL and CIS system, which vary widely in application.The unit operations are:a. Absorptionb. Desorption (Stripping)c. Acid Washingd. Reactivatione. Carbon Handling (carbon transportation, sizing, dewatering, etc.)Cost optimization starts with the basic operating parameters (design philosophy) set down at the time of engineering design. These parameters undergo almost immediate change due to site specific ore requirements, throughput changes, operator requirements or reagent availability.Activated charcoal is sometimes viewed as simple, uncomplicated reagent that requires not optimization. To some extent, this statement is true, but under most circumstances, if the time necessary to optimize the use of activated charcoal is available, the effort is rewarded with significant savings. CPL-Carbon Link has embarked upon a program of supplying technical support with its activated charcoal. Several operations in the United States have undertaken to have CPL-Carbon Link do an operational survey to determine if potential savings are possible. CPL-Carbon Link has offered to do these surveys for projects that are clients or simply would like to have CPL-Carbon Link review their operation. The information accumulated by CPLCarbon Link is being used to attempt to fashion industry standards so that a common reference point can be established for activated charcoal usage."

Jan 1, 2008

By Jerzy A. Mielczarski

The separation of albites from quartz by flotation applying the conventional HF-methods is no longer acceptable from an environmental and health point of view. Therefore, the search for a new reagent scheme without using HF depressor for separation of albite from quartz is under consideration. The flotation behaviour of ore mineral components depends on the produced hydrophobic or hydrophilic surface coverage (chemical functionalization). Currently we have excellent possibility of monitoring surface composition and structure at molecular and atomic levels at surfaces of natural minerals contacted with aqueous solutions of collectors, activators, depressants which is vitally important for the understanding of the surface chemistry that govern selective and efficient flotation. Detailed surface characterization of minerals before and after their exposition to different solution conditions was performed by the most modern spectroscopic techniques such as developed by us the infrared external reflection technique combined with spectral simulation and X-ray photoelectron spectroscopy (XPS). It is possible to monitor surface reactions which facilitate the separation process and those which bring disadvantage to selective flotation. At first we found that a small amount of ?mineral impurity? presented in natural ore could play important role in selective hydrophobization process. It was found that the pH of solution (parameter possible to control) and natural mineral impurities present in mineral samples (parameter related to ore origin) play a very important role in the separation process. Another important parameter is interaction between minerals, quartz and albite, present in aqueous solution. The limitation of flotation separation resulting from chemistry will be discussed. Moreover, the most promising scheme for separation of albites from quartz will be examined.

Jan 1, 2014

By Rina Kim

The addition of lead to a gold leaching reactor can effectively accelerate or retard the gold cyanidation reaction. This study explored the effect of lead on the gold dissolution kinetics using cyclic voltammetry (CV) experiments. It was illustrated that the gold leaching kinetics in the cyanide solution enhanced with the addition of lead salt in the low overpotential region (–0.35 V vs. Ag/AgCl). The similar behavior was observed in the presence of ore containing 0.25% galena. In contrast, the gold oxidation kinetics retarded at –0.35 V (vs. Ag/AgCl) in the presence of silicate and lead-bearing mineral under certain conditions. Likewise, the lead addition was not functional for the high sulfur ore. This was attributed to the oxidation of the sulfides to the elemental sulfur, which subsequently formed a passivating layer on the gold surface. The results were evidently affirmed by the electrochemical tests and X-ray photoelectron spectroscopy (XPS) analysis.

By Nobuhiro Kuriyama

Electrochemical activation behavior of an AB2-Laves-phase type hydrogen storage alloy, Zr0,9Ti0.lNi1.lCo0.1Mn0.6V0.2 was studied to make clear activation process of pellet-type metal hydride electrodes. An alkaline treatment of the electrodes with heated alkaline solution gave alloy surface enriched with nickel, and the treated electrode was more easily activated. The treated electrode desorbed more hydrogen during the first charge-discharge cycle, and was activated without induction period. A cross sectional view of the activated electrode showed finer pulverization of alloy particles than the annealed alloy, and impedance spectroscopy indicated larger surface area of the electrode using the as-cast alloy. Since the as-cast alloy contains inhomogeneities, multi-phase microstructure and stress in the particle, the finer pulverization of alloy particles with hydrogenation are considered to increase surface area in an earlier cycle in the case of the as-cast alloy, which leads larger reaction area and faster activation of the as-cast alloy electrode.

Jan 1, 2002

By G. Gabra, M. Nagamori, J. J. Panneton

"RESUMELa calcination contrôlée de 10 serpentine permet de produire de 10 magnésie active. Le degré de I'activation est mesure par 10 solubilité du magnésium dans les acides faibles tel que I'acide acétique, La serpentine contenue dans les résidus d'amiante du Québec peut donc être activée par calcination. Le teneur en magnésie active des rejets d'amiante calcinés est fonction de divers paramètres: température, temps de calcination, granulométrie, etc. Les rejets d'amiante de différentes provenances démontrent des comportements thermochimiques différents qui sont étudiés dans Ie présent travail au moyen d'ATD, de TG, de la diffraction des rayons X et de la lixivation par l'acide acétique. On constate qu'un maximum d'environ 80% de la magnésie totale peut être activé dans certains rejets d'amiante du Québec et Ie degré d'activation dépend de la provenance.vIntroductionOn sait depuis longtemps que la serpentine, Mg3Si2O5(OH)4, un silicate hydroxylé de magnésium, devient amorphe lorsqu'elle perd de I'eau d'hydratation entre 600 et 700 °C. La serpentine ainsi calcinée est alors dissociée en magnésie et en silice. Cette magnésie, dite active, est soluble dans un acide faible ou même dans les solutions de sels d'ammonium.Plusieurs precédés chimiques ont été proposés afin d'extraire sous forme de composés magnésiens la magnésie de la serpentine. La plupart de ces procédés comportent une activation par calcination de la serpentine préalablement à une Iixiviation par un acide ou par une solution d'un sel d'ammonium.Malgré la contamination par Ie fer et par d'autres éléments, les compositions chimiques des rejets de différentes mines d 'amiante du Québec, présentées au tableau 1, sont très proches de la serpentine typique. Puisque Ie degré d'activation de la magnésie varie grandement d'une serpentine à I'autre lors de la calcination, la première étape de la recherche sur la transformation chimique des rejets d'amiante du Québec se résume à une étude de leurs comportements thermochimiques."

Jan 1, 1982

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By Qinbo Cao, Qianshan Peng, Heng Zou, Xingcai Yu

In this work, a new flotation strategy was proposed for the flotation of rutile. In this strategy, rutile was activated by Pb(NO3)2 and then floated with amyl xanthate (AX) as a collector at pH 8. Pb(OH)+ was the dominant lead species in the solution at pH 8 and is believed to be the major species reacting with the rutile surface. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) study revealed that the lead activation products were well distributed on the rutile surface, and AX− could further bind with the Pb atom on the Pb-activated rutile surface. In this regard, the Pb-activated rutile could be floated by AX. Furthermore, X-ray photoelectron spectroscopy (XPS) analysis indicated that Pb(OH)2 was generated on the Pb-activated rutile surface. The electron transfer during the adsorption of the AX− on the Pb-activated rutile surface was also investigated by XPS analysis.

By M. Hao, S. Hu, X. Lyu, M. Lian, C. Anning, G. Yao, Z. Wang

The results revealed that the pozzolanic activity of the gold mine tailings and their main mineral phases improved by mechanical activation. Under the same activation conditions, the activated mica powders possessed the highest pozzolanic activity index, followed by the activated feldspar, and the activated quartz exhibited the lowest pozzolanic activity index. The addition of calcium oxide promoted the formation of amorphous C–(A)–S–H gel for all paste samples, and stratlingite and hydrotalcite were observed in calcium oxide activated mica paste. The addition of natural anhydrite promoted the formation of ettringite for the pastes of calcium oxide activated aluminosilicates materials (gold mine tailings, mica, and feldspar). Furthermore, the pozzolanic activity indexes of the mechanically activated gold mine tailings and their main mineral phases were tested to be qualified for use as supplementary cementitious material in cement. This paper provided an innovative approach for recycling gold mine tailings as supplementary cementitious materials in cement, which would be environmentally friendly and cost-effective. Keywords: Mechanical activation, gold mine tailings, supplementary cementitious material, hydration properties, pozzolanic activity

Jan 1, 2020

By T. Qiu

"The purpose of this study is to investigate the effect of the dosage of sodium hypochlorite as activator on the flotations of depressed marmatite and depressed chalcopyrite, with a focus on activation-flotation kinetics. Four flotation kinetic models were applied to test data using 1stOpt statistical analysis software to estimate the relationships between the maximum flotation recovery rates for the depressed marmatite and depressed chalcopyrite, the flotation rate constants and the sodium hypochlorite dosages. Within the range investigated, the highest flotation performances of depressed marmatite and depressed chalcopyrite were obtained at 2.5 mL/L sodium hypochlorite with zinc recovery rate of 93.8 percent and 3 mL/L sodium hypochlorite with copper recovery rate of 94.6 percent, respectively, after four minutes of flotation. A second-order model with rectangular distribution of flotabilities gave the best fit to test data collected at various sodium hypochlorite dosages. For the highest flotation performances of depressed marmatite and depressed chalcopyrite, the respective equations of their flotation models were derived and presented.IntroductionCyanidation tailings are the solid residues generated by gold plants that use cyanide to extract gold (Lv, Ding and Qian, 2015; Zhang, Li and Yu, 2013). Because of increasing demand for gold, the Chinese gold industry has developed rapidly, with production amounting to 451.799 tons in 2014, an increase of 5.5 percent from 2013. Chinese gold production has been the highest in the world for eight consecutive years. As a result, more than 2.45 million tons of cyanidation tailings are estimated to be discharged into tailings ponds every year (Li et al., 2010; Lv, Ding and Qian et al., 2015; Wang et al., 2015; Zhang, Li and Yu, 2013; Zhang, Li and Yu, 2012), and approximately 300 million tons of cyanide tailings are stockpiled in China, with the potential to cause serious environmental pollution as well as death to wildlife (Adams and Lloyd, 2008; Donato et al., 2007; Hewitt, Breuer and Jeffery, 2012; Velasquez-Lopez et al., 2011; Stephen et al., 2009; Zagury, Oudjehani and Deschenes, 2004). Concerns over cyanidation tailings are not exclusively environmental but also economic, as tailings occupy considerable land area, and tailings storage facilities increase the production costs of gold enterprises (Donato et al., 2007). Tailings often contain other valuable metals such as zinc, lead and copper. For example, the cyanidation tailings of Gaoyao Hetai Gold Plant in Guangdong Province contain 2.5 percent copper (Cu), 0.31 percent lead (Pb), 0.23 percent zinc (Zn) and 15.36 percent iron (Fe) (Shi, 2008), and the tailings of Tianshui Gold Plant in Gansu Province contain 1.94 percent Cu, 5.96 percent Pb, 0.27 percent Zn and 24.62 percent Fe. Cyanidation tailings have therefore been increasingly viewed as a secondary resource rather than waste."

Jan 1, 2016

Active geothermal fields show many of the characteristics seen in hydrothermal ore deposits but there are important differences as well. There are, for example, many differences in geology and chemistry between individual geothermal fields, even some nearby, and these include variations in host rock types (volcanic, sedimentary, plutonic and metamorphic), structures controlling fluid flow (normal, lateral, and, rarely, reverse faulting occur) and hydrological setting (valleys to elevated terrain).

Jan 1, 1986

By R A. Lynch

The state-of-the-art in cave seismic monitoring is reviewed, with the latest developments in active seismic monitoring included. Seismic monitoring systems are routinely used by most of the world’s block and panel caving mines to track the cave initiation and progression. The current best practice is to use the cloud of seismic event locations as a proxy for cave growth somewhere below. Problems with event location reliability due to seismic ray bending around the (unknown) cave are side-stepped by using sensors installed above the cave. However, the aseismic gap – the (unknown) distance between actual cave back and seismic event cloud – currently hinders reliable estimation of cave geometry.Velocity inversions using the passive seismic data are inexpensive and should be undertaken more routinely. The straight-ray methods should be used with caution, as the underlying assumptions are invalid in caving environments. The double-difference method is more correct for the caving situation, and there have been some promising results published. Constrained geometric inversions make a lot of sense, but have yet to be demonstrated successfully.Two active seismic source have recently been developed for use in the caving environment: a piezoelectric source for ranges up to a few hundred metres and a pneumatically-powered source for ranges up to a kilometre. These sources produce signals on standard mine seismic sensors that can be used to measure seismic velocity variations down to 0.01 per cent resolution. This allows the cave progression to be monitored by measuring tiny changes to seismic velocities as the rock above the cave is fractured and destressed.CITATION:Lynch, R A, 2016. Active and passive seismic monitoring of cave front evolution, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 217–224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By A Späth

Active explosion barriers are used to contain and suppress a methane gas and/or coal dust explosion propagation, including localised mine fires. Early research indicated that these active explosion barriers could be used on a mechanised cutting machine, making it the only technology that could suppress an explosion during its propagation phase at the cutting face. Thereby not only adding protection during mining operations but also reducing the development of toxic gases, fatal temperature increase and fatal overpressure build-up. During their evolution over the last two decades, further advantages of Active explosion barriers were proven in mine operations in countries such as South Africa and China. Characteristics such as effectivity, efficiency, mobility and space restrictions allow these systems to be used in various locations within a mine operation, including highwall operations. This improved technology contribution to safer coal mining was recognised by mine operators, workers and regulators. The Queensland’s Recognised Standard 21 (Resources Safety and Health Queensland (RSHQ), 2021) stipulated active explosion barriers as a technology to ensure the safety within their underground coalmines. The mobility and flexible implementation of the active explosion barriers allow a feasible and practical solution for all critical locations for explosion and fire management in an underground coalmine. The conformance to the Recognised Standard can be achieved all underground coal mining operations such as Bord and Pillar, and Longwall mining. This paper describes the conformance, implementation and use of Active explosion barriers for Longwall mining and development as well as Bord and Pillar mining in Queensland’s underground coalmines.

Oct 12, 2022

By Martin B. Hudson, Andrew K. Cho, Rolff B. Knobel, Les R. Chernauskas, Jonathan L. Ernst

ABSTRACT The Bruce Museum, located in Greenwich, Connecticut, is home to an extensive display of art and natural history exhibitions. A large addition was designed to be constructed adjacent to the museum requiring new spread footings to be installed up to 16.5 feet below the existing foundations. The soil conditions at the site consist of highly variable sand and gravel overlying weathered rock and sound bedrock. The Contract Documents called for traditional foundation underpinning. Traditional underpinning techniques, however, presented two major challenges on this Project; (1) deep underpinning pits would be required involving multiple levels and staging with tieback support and (2) the highly variable soil and bedrock composition and elevations presented uncertainty in the design and construction of the pits. In lieu of traditional underpinning, Geosciences Testing and Research, Inc. (GTR) proposed an “active” soil nail underpinning system. A major reason that the soil nail underpinning option was feasible, related to the fact that the soil nails and facing could be installed slightly in front of the existing footings rather than directly underneath the existing footings. The soil nail wall design involved one to four rows of soil nails with nail positions and wall depth able to be adjusted “on the fly” as excavation progressed depending on the field conditions encountered. To create the “active system,” the soil nails were pre-loaded to mitigate wall deformations that would be associated with a standard passive soil nail wall design. To evaluate the performance of the active soil nail wall and confirm design assumptions, an extensive automated monitoring, on-site testing and inspection program was proposed and executed by GTR to monitor deformations of the wall and the museum in real-time, evaluate and confirm bedrock and soil bond stresses and ensure that each soil nail was pre-loaded and locked off. Careful analysis, planning, and use of the observational method illustrates the importance of collaboration between design and construction personnel and applying engineering judgement throughout construction. The use of the observational method includes the potential for modifying design based on conditions observed. This paper presents a unique case study of the “active” soil nail underpinning system to support and protect sensitive structures, close collaboration between design and construction facilitated by real-time deformation monitoring, and its successful application as a safe and cost-effective alternative to traditional underpinning.

Oct 1, 2022

By Camilo Ferreira, Franco Olcese

Hay intensos debates respecto a los impactos de la minería en sobre el desarrollo de las comunidades en su entorno. Inclusive existen corrientes ideológicas que consideran que la minería empobrece y amenaza la salud de las comunidades en su entorno. En esta investigación evaluamos la medida en la cual exista evidencia que sustente estas posturas. Estimamos el impacto de la minería a nivel de los distritos del Perú, tanto mediante el canon como por el valor de la producción minera, sobre el índice de desarrollo humano, ingreso familiar per cápita y esperanza de vida.

Sep 30, 2022

By Georg Petersen

El presente artículo describe la actividad petrolera realizada durante el año 1962. En 1863 el Gobierno del Perú derogó al Ing. A. E. Prentice el estudio de las posibilidades petroleras de Piura y Tumbes, a través de la perforación del primer pozo de petróleo en Zorritos a través de herramientas imperfectas. Ante tal éxito, en 1864 Lama y Rudens gestionaron que se constituya en Nueva York la "Compañía Peruana de Petróleo". Posteriormente, doce compañías petroleras han desarrolado trabajos de exploración y nueve se encuentran en estado de producción. En este plano tenemos a Belcom Petroleum Corporation Perú, Cerro de Pasco Company, Empresa Petrolera Fiscal, Compañía peruana de Petróleo "El Oriente", International Petroleum Company, Mobil Oil Company, Mobil Oil Company of Perú, Compañía de petróleo Ganso Azul, Peruvian, entre otros.

Jul 1, 1963

By Georg Petersen

El presente artículo describe la actividad petrolera realizada durante el año 1962. En 1863 el Gobierno del Perú derogó al Ing. A. E. Prentice el estudio de las posibilidades petroleras de Piura y Tumbes, a través de la perforación del primer pozo de petróleo en Zorritos a través de herramientas imperfectas. Ante tal éxito, en 1864 Lama y Rudens gestionaron que se constituya en Nueva York la "Compañía Peruana de Petróleo". Posteriormente, doce compañías petroleras han desarrolado trabajos de exploración y nueve se encuentran en estado de producción. En este plano tenemos a Belcom Petroleum Corporation Perú, Cerro de Pasco Company, Empresa Petrolera Fiscal, Compañía peruana de Petróleo "El Oriente", International Petroleum Company, Mobil Oil Company, Mobil Oil Company of Perú, Compañía de petróleo Ganso Azul, Peruvian, entre otros.

Jul 1, 1963

By Luis Palomino

El siguiente estudio indica la importancia de la función que ejerce el Departamento de entrenamiento en la Cerro de Pasco Corporation. Para ello, la compañía reconoce el entrenamiento como herramienta básica en el aumento de la producción y reducción de costo, al tiempo que el Departamento asegura el perfeccionamiento de su personal de toda índole. En esta primera etapa de planeamiento, se proponen las siguientes actividades: orientación de nuevos servidores, entrenamiento de supervisores, curso de pre-capataces, curso de instructores, cursos técnicos, cursos vacacionales para universitarios, cursos por correspondencia y clases de castellano. Concluyendo que dicho programa, aumenta el rendimiento de los trabajadores, les crea conciencia y a su vez desarrolla actitudes proactivas, así como se destaca el adiestramiento de los supervisores sobre la técnica de enseñar a sus obreros, y por último, busca que cada compañía elabore su propio programa de acuerdo a sus necesidades de su entrenamiento y según las características de su personal.

Jul 20, 1955