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By Patrick R. Taylor

A kinetic study of the fluosilicic acid leaching of galena was performed under the presence of different oxidants. Fluosilicic acid concentration, agitation speed, concentration of solids and particle size, type and concentration of oxidant, and temperature were the variables studied. Hydrogen peroxide was found to be the most effective oxidant, its effectiveness being proportional to its concentration. As expected, an increase of leaching temperature increased the overall extraction and extraction rate. The same was found by decreasing the galena particle size. It is thought that leaching using hydrogen peroxide is controlled by fluid film mass transfer due to the calculated apparent activation energy. Reaction by-products such as sulfur and sulfur compounds retard the leaching rate. A mathematical model is proposed and compared to experimental results.

Jan 1, 2003

By R. M. Foley, Hidesaburo Kurushima

About 25 pct of all Japanese pyrite comes from the Yanahara mine on Honchu Island. For the past 40 years lack of an economical recovery process forced the operator, Dowa Mining Co., to sell the pyrite for its contained sulfur only, leaving 7 million tons of high grade iron ore waste. Introduction of the Dorrco FluoSolids roasting system enabled the company to make use of its iron sulfides and also to find a market for the mine's considerable pyrrhotite production. The success of this project is of great importance to Japan's economy since it points the way toward material increase in her natural resources. Prior to use of the present process, no practical method was available for commercial exploitation of known large tonnages of pyrrhotite, while the copper content of the even larger deposits of pyrite made the roasted residue unacceptable for the iron and steel industry. In Europe, large amounts of copper-bearing pyrite cinder are given a chloridizing roast for separation of the copper and iron but this treatment is not economical in Japan where salt is imported from as far away as Egypt.

Jan 10, 1958

By Robert B. Parsons

"Investors in flow-through shares are going to need an expanded road map to find their way through a growing maze of tax rules affecting such shares. At the end of 1985, no fewer than three new sets of important tax amendments were tabled which could have a significant effect on flow-through share issues. This proposed legislation is discussed this month in Tax Notes.IntroductionIn a flurry of legislative activity at the end of 1985, the federal government tabled legislation which includes the introduction of new rules which will have a notable effect on investors in flow-through shares and on companies that issue such shares.First, on November 26, 1985, Bill C-84, the legislation to implement most of the changes announced in the May budget, was introduced in Parliament. This legislation includes the rules for the $500,000 capital gains exemption, a matter of considerable interest to flow through share investors.Next, on December 2, 1985, the government tabled a Notice of Ways and Means Motion which would extend the time horizon for spending flow-through share funds to include the 60-day period following the calendar year. But all news was not good news. On December 4 the government released its proposals for a minimum personal income tax, which would include rules that would catch an investor's CEE expenses and capital gains."

Jan 1, 1986

By Kelly Cristina Ferreira

Na operação do alto-forno é comum observar flutuações em seu comportamento, seguindo o ciclo de vazamento de gusa e escória. O acumulo de liquido no cadinho e sua influência no aumento da força hidrostática são as principais causas dessa flutuação.O cadinho é uma parte crucial na operação do alto-forno por muitas razões. No entanto, por ser o local de acumulo de gusa e escória, este deve ter volume suficiente e facilitar uma drenagem sem distúrbios. Por isto, o estado do redutor/combustível, chamado “homem morto” desempenha uma importante função. Este trabalho apresenta uma breve revisão sobre os principais indicadores do estado interno do homem morto no cadinho do alto-forno.

Aug 16, 2017

By Gerald W. Longenecker

For decades, traditional hydraulic engineering approaches have been used for sizing stream channels when stream relocation efforts have been necessary to allow for the advancement of quarry and other surface mining operations. These approaches have been based on various ydraulic models to design channel cross sections and slopes that could pass the required regulatory design storm such as the 2-, 5, lo-, 25-, 50-, or even loo-year events. Designing the stream channel to handle these more extreme ,storm events would often lead to large channel designs which required extensive bank and channel bottom stabilization techniques including concrete, rip rap, gabions, or other expensive approaches. The constructed channels often required ongoing maintenance to remove accumulated sediment and other debris which would settle out and reduce the hydraulic capacity of the channel.

Jan 1, 1998

By Animesh Jha, Chris Dometakis

"Without the use of a flux, only a poor dispersion of ceramic phase can be achieved. A molten-flux-assisted ceramic phase dispersion technique for producing aluminium alloy metalmatrix composites has been developed. In this paper, we report the physical chemistry for the dispersion of TiB2 in molten aluminium. In particular, aspects of the interfacial energy and the thermodynamics of the dispersion reactions are briefly discussed for enhancing the volume of dispersion phase in the molten metal and for controlling their morphology. This investigation also addresses the role of molten flux in the fabrication of AI-alloy mmc using a casting technique. The morphological aspects of the dispersion are explained on the basis of the classical theory· of nucleation.IntroductionMetal matrix composites (MMCs), have long been recognised as an important class of material due to their greater wear resistance, specific stiffness and temperature capability when compared to conventional monolithic alloys. Particulate reinforced composites produced by melt casting techniques have been amongst the first MMCs to achieve commercial market viability. The advent of melt mixing techniques such as the Duralcan™ process have enabled low cost, easily fabricated composites based on the AI-SiC and AIAlz0 3 systems to be produced. In this process, uncoated ceramic particles with diameters 10ltm and larger, are incorporated into conventional monolithic alloys with reinforcement levels up to 25 volume percent. The AI-7Si-SiC metal-matrix composites have good wear resistance, high strength, low density and high thermal conductivity. The combination of these physical and mechanical properties has become a major attraction for the fabrication of light-alloy composite disc rotor brakes for the automotive sector2. However, in silicon-free alloys, SiC is thermodynamically unstable above the composite melting point and is extensively attacked by the melt to form aluminium carbide3 :"

Jan 1, 1996

By Ernest B. Snyder

The word "line" has been used loosely for many forms of the common steel plant flux. For example, many people use the word "lime" for nigh calcium and dolomitic limestone, for high calcium and dolomitic quicklime (also called caustic lime, calcined lime; burnt lime, pulverized and pebble lime) and ;van for clinkered dolomite. Calcium hydroxide, also called slaked lime and hydrated lime, is called "lime" but is seldom used as a flux except when the quicklime air slakes in open boxes or bins. All of the above forms of "lime" are used in the steel plant. Calcium hydroxide is used for water treatment, acid neutralizing, and as a lubricant for wire drawing. All the other limes are used as fluxes in the sintering plant, blast furnace or steel producing furnaces. In the production of self-flux or super-flux sinter, high calcium and dolomitic limestone fines are used. Where quicklime fines are available, they may be added to the sinter mix also. The blast furnace uses both high calcium and/or dolomitic limestone. A few trials have been made using iron oxide stabilized dolomitic lime in an attempt to reduce coke consumption and to increase the production rate. The trials were very successful but would' not be economical, except in periods of coke shortages, with resulting extremely high coke cost and exceptionally high hot metal demand.

Jan 1, 1979

By Raymond D. Potts

"Minntac is a taconite mining, concentrating and pelletizing operation located near the town of Mountain Iron, Minnesota, U.S.A. It is totally owned and operated by USX Corporation and represents its largest source of domestic iron units. Minntac began producing fluxed pellets in 1988 and has produced both acid and fluxed pellets since then. This paper compares the acid and fluxed pellets produced at Minntac. It reviews modifications that have been made to the plant flowsheet and discusses areas recognized for improvement since the beginning of fluxed pellet production. It also comments briefly on the performance of Minntac fluxed pellets in USX blast furnaces and the future of fluxed pellets at Minntac.IntroductionMinntac was built in three steps with each step designed to produce 6 million long tons of acid pellets per year. The actual production has varied though. Figure I shows the production by year at Mirmtac. Step I began production in 1967, Step 2 in 1972 and Step 3 in 1978. Mirmtac produced 16.5 million tons in 1979 but only 3.5 million tons in 1982 when the facility was shut down for six months because of the lack of demand for pellets. Since the initial start up, Mirmtac has produced over 200 million long tons of pellets. Until 1987, all the pellets produced were ""acid"" pellets. In 1987, equipment to produce ""fluxed"" pellets was installed and tested. In 1988, full scale production of fluxed pellets began."

Jan 1, 1991

By Dawei Yu, Kinnor Chattopadhyay

In the nickel industry, molten slags produced from a Pierce-Smith converter contain significant amounts of valuable metals in the forms of oxides and physically entrained matte droplets. A slag cleaning step, which takes places in an electrical slag-cleaning furnace, is therefore required to recover the valuable metals as a common practice. Utilization of a waste material from aluminum industry (i.e. spent potlining) as a flux to improve the slag cleaning in terms of both the metal recovery and the operation efficiency was studied by simulation with FactSage program. Results show that the addition of SPL could substantially reduce the slag viscosity due to its fluoride values, thus accelerating the settling of matte droplets. The carbon value in the SPL could also help increase the metal recovery by reducing the valuable metal oxides followed by settling.

Jan 1, 2015

By K Vallo, T Haimi, J Pihlasalo, J Hamuyuni, M Lindgren, F Tesfaye

Decarbonisation of the steel industry has recently attracted a lot of research and technological development. Most of the technological developments are centred around the replacement of blast furnace (BF), which has been the main primary smelting furnace in the ironmaking step of steel production. Replacement of the BF is not an easy task because of BF’s many established capabilities over the years, especially its ability to use low-grade iron feed. In this regard, Metso has developed its own technology, Metso’s Outotec direct reduced iron (DRI) smelting furnace, to tackle this problem. The recently developed six-in line electric furnace for DRI smelting can be used for primary smelting of DRI from blast furnace grade iron ore. Unlike the electric arc furnace (EAF), the DRI smelting furnace can handle larger slag volumes that emanate from the high gangue in BF grade DRI. Therefore, fluxing plays an important role in operating the DRI smelting furnace. This paper presents fluxing options and proposes slag quality and operating windows for the DRI smelting furnace. Also, the effect of slag on refractory durability will be discussed.

Jun 19, 2024

Silica and limestone fluxing levels in copper smelting slags were studied. Copper concentrates with flux additions were smelted to matte (55.5 per cent Cu) and slag in a pilot scale submerged combustion furnace.Results indicated that oxidic and sulphidic copper levels in slags were minimised with a slag Si02 level of 36 per cent and a SiO2/CaO ratio of 5.5. Total copper losses in slags were 0.6 per cent under these conditions.To produce the desired slag chemistry, additions of bulk silica and limestone to copper concentrates of fluctuating grades were predicted numerically. The method employed the solution of two simultaneous equations, each respectively for silica and limestone calculations.The predicted flux additions were applied in a further series of tests and the resultant stages were found to be satisfactory. The method is applicable to smelting 'operations which employ two flux bins, with weigh feeders, so that slag chemistry may be controlled with the flux/concentrate feed mix.

Jan 1, 1985

By Johne Jesus Mol Peixoto, Itavahn Alves da Silva, João Víctor Gomes Guimarães Ananias, Salvatore Giuliano Peixoto Tropia de Abreu, Weslei Viana Gabriel, Thiago Araujo Santos de Oliveira

O fluxo de aço em um distribuidor de lingotamento contínuo é um dos fatores que ajuda a determinar a qualidade final do aço. O presente trabalho aborda o caso de fluxo assimétrico em um distribuidor de dois veios provocado pelo posicionamento descentralizado da válvula longa, avaliando o efeito de diferentes configurações de barreiras e diques na assimetria, além da influência nos campos de velocidades. Foram realizados testes em modelo físico de acrílico, utilizando água para simular o aço e KCl como traçador para obtenção das curvas de Distribuição de Tempo de Residência (DTR). Simulação computacional e a técnica PIV também foram utilizadas para análise do fluxo. Foi possível verificar que a utilização de barragens e diques melhoraram as condições para a flotação de inclusão, devido ao aumento do tempo mínimo de residência do aço, além da diminuição de zonas mortas e da quantidade de descarte gerada durante a troca de panelas. A utilização de barragens e diques em conjunto foram eficientes para uma melhor distribuição do fluxo na superfície livre do distribuidor, o que também favorece a limpidez do aço.

Oct 1, 2019

By Weslei Viana Gabriel

Por meio do uso de técnicas de modelamento físico e matemático, caracterizou-se o fluxo de líquido, no interior de um molde de beam blank, quando alimentado por apenas uma válvula submersa constituída por três portas de saída cilíndricas e espaçadas de 120°. Verificou-se que o fluxo do jato de líquido que atravessa a alma se espalha ao longo de toda a superfície do flange antes de se recircular na região central do molde. Através da técnica de injeção de traçador e análise do perfil de velocidade, percebe-se que os jatos direcionados para as quinas do flange recirculam rapidamente e, por isto, se espalham numa pequena região. Este tipo de válvula se caracteriza também por ter uma maior intensidade de oscilação da superfície do que a válvula do tipo tubular. Foram realizados testes para simular a taxa de remoção de inclusões. Os dados obtidos mostram que esta válvula é mais eficiente na limpidez do aço do que uma válvula tubular simples.

Oct 30, 2017

By J. G. Groppo

In 1992, 48 million tons of fly ash (not including bottom ash, boiler slag and FGD material) was produced in the United States, according to the American Coal Ash Association. Of this amount, 27.2% was utilized; although the percentage of fly ash utilized increased from 20% in 1980, there is significant potential to increase utilization. One of the primary driving forces behind increased utilization is increased disposal costs due to more stringent environmental controls and regulation. Fly ash is classified as a natural pozzolan and finds significant use as a cement additive. It has been found to increase the plasticity of the cement mixture while lowering the amount of mix water needed. In addition to improving leveling and finishing properties, fly ash improves pumpability as well as decreases the heat of hydration of the concrete mix which is particularly important in massive concrete structures such as dams where the concrete needs to cool as quickly as possible. The Loss on Ignition (LOI) of fly ash is an important quality when considering utilization. The LOI is primarily due to the presence of unburned carbon and the standard specifications for the use of fly ash as a mineral admixture in Portland cement concrete are given in ASTM C618-89a. which sets an LOI limit of 6%. However, many states have set a more stringent limit of 3%. The primary reason for the lower LOI specification is that carbon adsorbs air entraining agents which limits freeze-thaw resistance. This is particularly important in climates such as the midwestern US where multiple cycles of freezing and thawing are typical in winter.

Jan 1, 1995

By C. E. "Sam" Lovewell

In approaching a discussion of production of cement, I hope I won't be like the porter in the bank who was asked if he could give some details on the rediscount rate. He replied, "Boss, when I said hello, I told you all I know." Need for change every so often is illustrated by the story of the little boy four years old who had not spoken a word in those four years. One morning he said, "This damned oat meal is burned'." His Dad was amazed and said, "Son, how come you haven't said a word for four years and now out of a clear, blue sky you say, "The oat meal is burned." Johnny said, "Well, up to now everything has been all right." Not being a mining engineer myself, and my subject not dealing with mining engineering directly, I can only hope that you will agree that the subject has current relevancy by the feet that it can materially improve our environment by putting to good use a potential environmental polluter; namely, fly ash. The profitable utilization of fly ash can reduce cost of use of coal as an energy source. Therefore, it behooves us all to explore to the greatest depth, the pluses and minuses occasioned by its use wherever possible. My particular subject and my particular interest lie in its utilization as a blend in the production of Type IP Portland-Pozzolan Cement meeting requirements of ASTM C-595, Type IP.

Jan 1, 1974

By D. Randall Crooke, Ron R. Jorgenson

Many coal combustion products (CCPs) have historically been unsuitable for placement as mine backfill because of their physical and geochemical properties and/or regulatory status. However, innovations in paste production and transport of CCPs utilizing the high, fine particle contents of these fine-grained waste materials and their water retention colloidal properties produce a non-segregating, self-cementing material that may be environmentally suitable for placement as mine backfill. Both industry and the regulatory agencies are enthused by the possible cost reductions, both in design and construction of disposal sites, and the reduced environmental impacts of CCP realized by implementation of this new use/disposal technology.

Jan 1, 2001

By Donald C. Violetta

During 1963 more than 200 million tons of coal was consumed by the public utility industry. Ash residual, from the burning of this coal has caused disposal problems. In order to prevent air pollution, dust collection systems have been installed to suppress the fine ash emitted from boilers before it is discharged into the atmosphere. The collected ash, called fly ash, must be removed from the dust collection facilities and disposed in some manner, usually at a substantial cost to the utility. Many years ago fly ash disposal was not a serious problem because the demand for power was relatively low and coarse coal was burned on stoker type traveling grate machines. The low burning rates utilized on these grates did not produce large quantities of air-borne coal ash while the mechanics of this system of burning resulted in a clinkered residue of cinders. Both of these conditions resulted in the production of only small quantities of fly ash. As the demand for electricity increased, a method of burning pulverized coal was developed and was introduced to the public utility industry in 1918 at Milwaukee, Wisconsin.1 This method of firing was considered a significant advance in steam electric generation as it (1) permitted the use of coals that could not be economically fired by other methods and (2) has generally resulted in improved efficiency, greater generating capacity and lower costs.2 The utilization of larger generating units using pulverized coal substantially increased the quantity of fly ash which resulted in a' more severe disposal problem.

Jan 1, 1966

By D. Tao

A novel rotary triboelectrostatic separator has been developed and patented recently at the University of Kentucky with unique features, including a high efficiency rotary charger, charger electrification, laminar air flow, etc. A parametric study has been performed with a coal combustion fly ash sample to investigate the effects of major operating parameters on the process performance. Most significant operating variables and optimum conditions were identified. Separation tests performed with four fly ash samples indicated that the rotary triboelectrostatic separator showed effective fly ash separation.

Jan 1, 2014

By F. R. Nogas

"Because of the elements of uncertainty and instabilitp associated with single-enterprise communities, there is increasing interest in the alternatives to developing additional new communities of this nature. Gulf Minerals Canada Limited has chosen a unique alternative means to accommodate employees at a new uranium mine/mill complex at Rabbit Lake in Northern Saskatchewan. Gulf has adopted a fly-in program which moves their staff from a 450-mile radius, in and out of the on-site facilities, on a 7-day rotation."

Jan 1, 1976

Western Australia has often been referred to as the fly-in, fly-out capital of the world. Fly-in, fly-out is a commonly used practice in Western Australia due to the geographic size and isolated location of the vast resource projects. In the State today, approximately half of all resource sector employees operate on a fly-in, fly-out basis, with a minority utilising drive-in, drive-out arrangements. fly-in, fly-out arrangements are generally beneficial from a sustainability perspective, delivering significant economic, social and environmental benefits to regional communities, the State and nation as a whole. Skills shortages and labour supply issues mean that the industry will be required to discover new ways of attracting and retaining employees, one of which is the adoption of fly-in, fly-out work journey arrangements. By 2015, the minerals sector in Australia will need to employ 70 000 more employees than it currently employs to achieve predicted increases in output. Of the 70 000 additional employees required, 42 000 will be required in Western Australia, almost 15 000 in Queensland and approximately 5000 in both New South Wales and South Australia. The fly-in, fly-out lifestyle as a preferred method of employment should be recognised as a valid lifestyle choice by all members of the community, offering a profound improvement in the quality of life for large numbers of employees and family members. It should be acknowledged that whilst fly-in, fly-out is a preferred option for many companies and their employees, individuals who make a choice to engage in fly-in, fly-out must balance the difficulties associated with the work û isolation and separation from family and friends û against the economic and lifestyle benefits that the work offers. This paper aims to illustrate the significant steps that the resources sector has taken to facilitate the fly-in, fly-out choice by ensuring that the commute option is a safe, attractive and manageable work journey arrangement.

Jan 1, 2008