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By Edwarde R. May

The Flambeau volcanogenic massive sulfide deposit located in northwestern Wisconsin occurs within the southern lobe of the Canadian Precambrian Shield. The steeply dipping tabular body occurs in a complex pile of cyclic schistose intermediate to felsic fragmental volcanics. No chloritic alteration pipe is recognized but adjacent rocks have undergone magnesia metasomatism and subsequently were metamorphosed to the upper greenschist and lower amphibolite facies. Although modest in size the deposit is of special interest in that it has an extensive and well preserved supergene enrichment blanket. Economic minerals found within a pyritized quartz-sericite schist are chalcocite and bornite overlying primary chalcopyrite.

Jan 1, 1976

By F. D. Fox

The Flambeau and Ridgeway Mines, both owned and operated by wholly owned subsidiaries of Kennecott Minerals Company, were located very close to populated areas having initial concerns about health, safety and the environment. The success of both operations depended upon developing a framework of community support and enhancing sustainable development opportunities throughout the entire life cycle of the mining operations to address these concerns. The protection of the Flambeau River was the cornerstone of the Flambeau Mine’s success. The highest priority for the Ridgeway Mine was to ensure long-term physical, chemical and ecological stability of the reclaimed mine site. Both of these goals have been achieved and are discussed in this paper, which highlights Kennecott Minerals Company’s integration of sustainable development principles into its business decision-making and management processes.

Jan 1, 2003

By G. G. Bowser

Introduction Flame shots are of very infrequent occurrence in the coal mines of Nova Scotia. Probably not more than one is recorded in three months. Many shot-firers have never experienced one, and many never will. As a consequence, although all such occurrences are very carefully investigated, information concerning the cause of flame shots is somewhat meagre. In the course of the years, however, something has been learned of the practices and conditions that are responsible for them. During the past ten? years, over seventeen million shots were fired in the coal mines of Nova Scotia and only fifty-two faulty shots were reported or investigated during that time. In thirty-nine of these, flames were reported; in five, sparks only; and in eight, smoke only. In eight of these occurrences, unburned explosive was found after firing. In one of these eight, flame was seen in the back part of the hole, and an accompanying hissing sound pointed to burning explosive. In four of them, there was no evidence that gas was not ignited. All samples of explosives from these faulty shots which were submitted for analysis were found to be normal, except two, in 1937, which contained excessive moisture. These two samples were from two following shots in the same room on the same day. The initial cause of trouble with all eight shots was one or several of the following: explosives in poor condition, separation of cartridges, incorrect priming, shot hole in poor condition or not properly cleaned. In the case of sixteen or seventeen of the thirty-nine shots which flamed, data are insufficient for conclusions to be drawn as to the cause of the flame.

Jan 1, 1947

By Carleton Ellis

(Presented at a meeting of the New York Local Section of the Institute, Apr. 12, 1912.) I. INTRODUCTION. THE problem of the influence of hot surfaces upon gaseous combustion is one which, from a purely scientific stand-point, has engaged, for many years past, the attention of Prof. William A. Bone, of Leeds University and the Imperial College, London; and as his recent work has been the direct outcome of earlier scientific investigation, it will be appropriate, by way of introduction, to review briefly the present position of science with respect to this important subject, as stated by Professor Bone. One may perhaps best arrive at an understanding of the term " ?flameless " or " surface " combustion by considering certain facts which differentiate it from the more familiar processes of combustion as they occur in ordinary flames. All hot surfaces have an accelerating influence upon chemical changes in gaseous systems. If, at any temperature, a gaseous system, A, tends to pass over into another system, B, contact with a solid at the same temperature will accelerate the process. To take a very simple example, if a mixture of hydrogen and oxygen in their combining proportions (electrolytic gas) were maintained in an inclosure with smooth glass walls at a temperature of, say, 450° C., there would certainly be a tendency to form steam, but the rate of change would be negligibly small. If, however, there were brought into the system some porous solid material at the same temperature, so that a large surface was exposed to the gases, the rate of change would at once be rapidly accelerated in the layer of gas immediately in contact with the hot surface. Steam, the product, would diffuse outward from the surface, and the supplies of hydrogen and oxygen at the surface would be renewed by diffusion inward. Thus combustion would proceed heterogene-

Sep 1, 1912

By Michael G. Zabetakis

THIS is a summary of the available limit of flammability, autoignition, and burning-rate data for more than 200 combustible gases and vapors in air and other oxidants, as well as of empirical rules and graphs that can be used to predict similar data for thousands of other combustibles under a variety of environmental conditions. Specific data are presented on the paraffinic, unsaturated, aromatic, and alicyclic hydrocarbons, alcohols, ethers, aldehydes, ketones, and sulfur compounds, and an assortment of fuels, fuel blends, hydraulic fluids, engine oils, and miscellaneous combustible gases and vapors.

Jan 1, 1965

By J. Budac, R. Kofluk, D. Belton, M. Sjogren

A series of tests were performed to determine the flammability limits of mixtures of oxygen, ammonia, steam and nitrogen, over a solution, in a sealed autoclave. The partial pressures of ammonia and oxygen in the vapour space were varied by adjusting the character of the solution and by adjusting the oxygen concentration in the oxidant gas respectively. The data shows that flammable conditions can be minimized by controlling the operating temperature, reducing the ammonia content in the solution, increasing the concentrations of Ni, Cu and Zn in solution and keeping the % oxygen in the gas phase less than 15.5. Observations were also made that suggest that the presence of an aerosol in the vapour space may hinder ignition.

Jan 1, 2004

By James H. Rowland

The Mine Improvement and New Emergency Response Act of 2006 (MINER ACT) established a Technical Study Panel (The Panel) to provide recommendations on the utilization of belt air and new technology that may be available for increasing the fire resistance properties of conveyor belt used in underground coal mines. The Panel Report recommended use of the Belt Evaluation Laboratory Test (BELT) as the method for testing and approval of flame resistant conveyor belts used in underground coal mines. The research conducted to establish the correlation of the BELT with large-scale belt fire flammability tests was done using 36- to 42-in wide conveyor belt. Due to today?s coal haulage capacity, the mining industry is using 72-in and wider conveyor belts. The National Institute for Occupational Safety and Health (NIOSH) conducted a study to determine if the BELT will also qualify wider belts as fire resistant for use in underground coal mines. This paper describes the results of recent experiments comparing results from using the BELT and the large-scale tests for six different belts.

Jan 1, 2010

By A. C. Smith, J. H. Rowland III

The Mine Improvement and New Emergency Response Act of 2006 (MINER Act) established a Technical study panel (the Panel) to provide recommendations on the utilization of belt air and new technology that may be available for increasing the fire resistance properties of conveyor belt used in underground coal mines. The Panel Report recommended use of the belt evaluation laboratory test (BELT) as the method for testing and approval of flame resistant conveyor belts used in underground coal mines. The research conducted to establish the correlation of the BELT with large-scale belt fire flammability tests was done using 91 - 107 cm (36- to 42-in.) wide conveyor belt. Due to today’s coal haulage capacity, the mining industry is using 183 cm (72 in.) and wider conveyor belts. The U.S. National Institute for Occupational Safety and Health (NIOSH) conducted a study to determine if the BELT will also qualify wider belts as fire resistant for use in underground coal mines. This paper describes the results of recent experiments comparing results from using the BELT and the large-scale tests for six different belts.

Jan 1, 2011

By Michael Casson

With the mining industry changing rapidly due to mergers, acquisitions and fluctuating market pricing, today?s market for coal, minerals, ores and aggregates demands electrical apparatus that perform every time with maximum efficiency and with consideration for personnel safety. This is especially true in existing mining operations where every payload counts. Draglines are the workhorses of surface mining operations, and reliable and efficient operation is absolutely critical to success. However, the inherent disadvantages of using dc motors and motor-generator (MG) sets can significantly impact productivity and return on investment (ROI).

Jan 1, 2013

By W. G. Davenport

The flash furnace is used for smelting concentrate to (i) high-Cu matte and (ii) molten metallic copper. It is also used for converting solidified/crushed matte to molten metallic copper. This is flash converting. It consists (Table 20.1, Fig. 20.1) of: (a)tapping molten 65 to 72% Cu matte from a flash smelting furnace (b) granulating the molten matte to ?1/2 mm particles in a 103 m3/hour water torrent (c) crushing the granulated matte to 50 µm in a vertical roller mill (d)drying the crushed matte (e) feeding the dry particulate matte to a second flash furnace for oxidation converting to molten copper. In 2000, flash converting is being used by Kennecott Utah Copper (George, et al; 1995; Newman et al, 1998, 1999a,b). A second installation is being designed for the Chuquicamata smelter (www.outokumpu.com [October 12, 2000]), The potential uses of flash converting are: (a) as the second half of a flash smelting/flash converting coppermaking sequence (b) as a continuous converting alternative to batch submerged tuyere converting. This chapter uses our flash furnace matrix to determine the %O2-in-blast, industrial oxygen and oil requirements for converting solidified 65% and 72% Cu matte to molten copper. It then discusses choice of feed matte grade and other aspects of the process.

Jan 1, 2001

By L. Betteridge, A. Marks

"An OK 300 cu. ft. Skim - Air cell was installed at the HBM&S concentrator in Flin Flon in 1987. Since that time, 3 additional OK Skim - Air cells have been installed in HBM&S concentrators. The cell treats a coarse 70% solids slurry with a residence time of 2.5 minutes. The product from the cell (a unit cell type application) is a final grade copper concentrate with high precious metal values. Since its installation, the cell has improved gold recovery by 10 - 15%. Process variables such as circulating load, pH, froth depth, feed size, and reagent additions all have an effect on the operation of the cell. Maintenance on the cell has been minimal. Initial operating problems involving level control have been significantly reduced and operations are now relatively trouble free. Although very successful at Flin Flon, site specific operating circumstances will determine the suitability of this cell. INTRODUCTIONHudson Bay Mining and Smelting operates four concentrators in Northern Manitoba. Three treat copper-zinc ores, the fourth mills a copper-nickel ore. The Flin Flan concentrator operates two circuits in parallel which treat copper and zinc ores from the Trout Lake and Callinan mines. Both circuits in the Flin Flan mill have Skim-Air cells integrated into the grinding circuits.The Trout Lake cell was installed first and had a payback period of a few months. Required modifications to the cell were made to enhance its performance. These included changing the discharge valve size, tuning the level controller, and installing an insert into the rubber valve sleeve to increase its wear life. The payback period on the Callinan cell was significantly reduced because these modifications were completed prior to its installation.The cells produce a final grade copper concentrate and since their installation gold and silver recoveries to the final copper concentrate have increased significantly. Operating parameters such as coarseness of cell feed dictate the metal recoveries and froth depth determines the selectivity of the cell and therefore the grade of the concentrate.The Skim-Air cell can be suitable in applications where a final product is generated. However, when a bulk concentrate, which requires further separation, is produced, the coarseness of the product may not make it amenable to conventional flotation.The Flin Flan mills Skim-Air cells have worked exceptionally well with little maintenance required."

Jan 1, 1991

"The first SkimAir flash flotation cell was installed in Outokumpu’s Hammaslahti Copper Concentrator in 1982 to prevent overgrinding of soft sulphides in the milling circuit. Since this first installation the popularity of the flash flotation has fluctuated depending on metal market conditions and regional preferences. Units have been installed in many commodities including copper, lead, gold, PGMs, silver and nickel. Though it has been successfully employed in many operations around the world, flash flotation technology is still not well understood by many in the mining industry. This paper will discuss aspects of flash flotation flowsheet development along with some of the metallurgical and engineering considerations required to successfully incorporate flash flotation into new or existing milling circuits. This paper will also try and debunk some of the myths that exist around flash flotation cells and their operation. Case studies of flash flotation implementation will be discussed.IntroductionModern flash flotation technology was developed several decades ago by Outokumpu, with the first commercial installation of this technology being at the Hammaslahti concentrator in Finland in 1982 (Kallioinen & Niitti, 1985). This was a relatively modestly sized SK80 cell producing final grade copper concentrate directly from the flash flotation cell operating in the grinding circuit. Since that time the size and number of flash flotation cells installed globally has grown considerably to the point where today, it is a widely known application of flotation technology for amenable ores. Owing to their long history in developing the technology, Outotec are the market leader with their SkimAir range of flash flotation cells. Though there is a general awareness of flash flotation process in the mineral processing industry, there is a lack of detailed understanding of the process and the benefits it can provide to new and existing operations."

Jan 1, 2017

By W. G. Davenport

This chapter demonstrates how our matrices can be used for controlling a flash furnace. Specifically, it shows how we can determine the adjustments in industrial oxygen, air, oil and flux input rates that will; (a) correctly alter product temperatures and compositions to newly targeted values (b), maintain set-point product temperatures and compositions with varying feed compositions and feed rates. It also discusses corrective actions that might be taken when furnace temperature and matte grade unexpectedly change.

Jan 1, 2001

By W. G. Davenport

A flash furnace can be run many different ways. It can, for example, be operated with: (a) highly 02"enriched, ambient temperature blast and no fossil fuel (b) considerable fossil fuel and hot, slightly Or enriched blast. It can also produce different grades of matte. With all these possibilities, the flash furnace operator can benefit from any technique that will indicate the 'best' way to operate his furnace. One such technique is Excel's 'Solver'optimizationroutine#. This chapter shows how our matrices and Excers optimization.abllity can be used to optimize a flash furnace operation. The chapter sets three optimization goals: (a) minimum industrial oxygen + oil cost, $ per tonne of concentrate (b) maximum smelting rate, tonnes of concentrate per hour (c) maximum profit, $ per hour.

Jan 1, 2001

By Elliot B. J

Flash smelting is a complex and capital intensive technology. Although in use for 50 years the technology is still not well understood from a fundamental point of view and thus uncertainty is evident when significant change to the practice is necessitated. The application of effective design and process simulation tools has significant advantages when process change and improvement is required. Mathematical models have been used to simulate the processes occurring in the shafts of copper flash smelters. The present approach to flash furnace modelling differs from earlier work in that the burners were modelled in detail, the output from the burner model becoming the input to the shaft model. This paper serves as an introduction to the modelling process used to analyse the performance and provide a better understanding of the parameters applicable to the flash furnace at the Kalgoorlie Nickel Smelter.

Jan 1, 1992

By Nickolas J. Themelis

The flash oxidation and smelting of mineral sulfides is a very prominent metallurgical achievement of the second part of this century. Its initial industrial implementation owes much to the work of Petri Bryk, in Finland, and Paul Queneau, in Canada. However, attempts to develop flash reduction pro- cesses, such as the reduction of iron oxide concentrates with hydrogen, have not yet been successful. The author, on the basis of experimental studies on both kinds of flash reaction systems, examines the respective rate controlling phenomena and the relative rates of flash oxidation and flash reduction.

Jan 1, 1993

By F. R. Milliken

EXPERIMENTS, in what has come to be known as flash roasting began some ten years ago. The principle underlying the operation was not a new one, but the experimental work started at that time was the first that was carried through to a logical conclusion, followed by construction and operation of a pilot plant, and then full-scale production. For a short working definition, flash roasting may he considered the instantaneous and complete oxidation of finely ground sulphide particles, partially suspended in air or gas, the oxidation reaction evolving enough heat to make the reaction self-sustaining, or nearly so.

Jan 1, 1937

By David Green

Outokumpu introduced Flash Flotation in the early l 980's for the recovery of floatable material from grinding circuits. The devel­opment came as a result of surveys made in the company's own concentrators, initiated to find ways of improving recoveries with increasingly complex and lower grade feeds. Hydrocyclones make a separation on the basis of particle size and mass, resulting in the "over collection" of fine grained, high S.G. particles. Minerals such as pentlandite, galena and gold are easily caught in the circulating load around the mill until they are overground and rendered more difficult to collect. In the case of downstream flotation this may simply involve a reduction in the rate coefficient due to the finer sizes or, as is commonly experienced in gold operations, the mate­rial is slimed and coated onto non-floating gangue and is eventual­ly lost to tails. At the time of Outokumpu's plant surveys, it was a relatively common practice, particularly in Pb operations, to have a flotation section fed directly from the secondaiy mill discharge. This is called unit flotation and certainly provided an improvement but very high wear rates and frequent sanding out of the cells was com­mon. The development of the SkimAir® Flash Flotation cell by Outokumpu provided a subtle but quite dramatic departure from the unit cell approach. Now it was possible to feed cyclone under­flow into a special purpose-built flotation machine and recover a final grade concentrate from the grinding circuit (see Figure I). The cell was designed to handle the coarse circulating load, per­mitting the coarsest fractions to be short-circuited back to the mill and retain the floatable sizes for a nominal time of 30 seconds to several minutes. The short retention time was possible largely due to the relatively clean content of the cyclone underflow stream. This means that the fine gangue is not present except in small quan­tities and most of the fine to mid-size paiiicles are higher S.G. and more likely represent valuable mineral. This condition provides for very high rate coefficients. Typical operations would recover 40-60% of the valuable mineral in this fashion and improvements in recovery were typically from 2-5% for sulphide minerals to the 5-20% range for gold and silver.

Jan 1, 1998

By W. G. Davenport

Flash smelting is used. mainly for making molten Cu-rich matte* from fine Cu-Fe-S** flotation concentrates. It blows dried concentrate particles into a hot fumace, surrounds them with 01-rich gas and allows them to react. The results are: (a) partial oxidation of Fe and S from the concentrate (b) generation of heat (c) melting of the oxidized particles to form molten Cu-rich matte, ~65% Cu and Cu-barren slag, ~1 % Cu. The melted particles fall to the hearth of the flash furnace where they fonn matte and slag layers, The matte is tapped from the furnace and oxidation-converted to metallic copper. The slag is skimmed, treated for Cu recovery then stockpiled or sold. Figures 1.1 and 1.2 show industrial flash furnaces and the position of flash smelting in the coppermaking flowsheet. ,Fig. 1.3 shows the locations of flash furnaces around the world.

Jan 1, 2001

By Tom Gonzales

At San Manuel, AZ, Magma Metals Co. operates an Outokumpu flash furnace, four Peirce-Smith converters and two anode casting wheels that are supported by six anode vessels. Process gasses from the flash furnace and converters are treated in a two-train/ double-contact sulfuric acid plant. The plant captures 98% of the sulfur. A new flash furnace was commissioned in July 1988. It has since processed more than 2.7 Mt (3 million st) of sulfide concentrate without a major rebuild. The company has gained unique experience in the operation of the flash furnace at high oxygen enrichments with low off-gas dust loadings. New procedures have been developed to maintain secondary material generation at equilibrium and for maintaining metallurgical control of operating parameters. Process flow description At Magma's San Manuel plant, concentrates and other copper-bearing material are blended and conveyed from two separate areas of the plant to three 420 t (465 st) capacity wet charge bins located above the rotary dryer. Flash furnace silica flux is conveyed to a 227-t (250-st) capacity fine flux bin located adjacent to the wet charge bins. The concentrate and flux are blended in controlled amounts and fed into a 168-t/ h (185-stph) gas-fired rotary dryer. The wet charge enters the dryer at 8% moisture and is dried to 0.2% moisture. The dried charge is pneumatically conveyed to a 580-t/h (640-stph) dry charge bin located above the flash furnace. Flash furnace charge is drawn from the bin by two drag conveyors at a concentrate feed rate of 145 t/h (160 stph). The charge is mixed with enriched combustion air and injected into the furnace reaction shaft. In the reaction shaft, the charge is oxidized to form matte, slag and a rich SO, off-gas.

Jan 1, 1992