Search Documents

By A. Ashrafi

The electrochemical deposition of polypyrrole coating on different pretreated aluminum-alloy 7075 substrates was carried out using cyclic voltammetry, The pretreatment of specimens consisted of mechanical polishing and/or electrochemical etching, In the latter case, an aqueous solution of phosphoric acid and ethanol was used, The electrodeposition solution was 0,25 M pyrrole and 0,1 M oxalic acid in double-distilled water, The cyclic voltammetry scan rate used was 700mv/s, Morphology of the coatings was examined using scanning electron microscope (SEM), Using the Tafel experiment, corrosion resistance of the coated substrates was investigated in 0.1 M NaC1 solutions, Results obtained revealed that electropolymerization of polypyrrole on 7075 aluminum alloy would increase the resistance against corrosion in 0,1M NaC1 solution, Also it was observed that, compared with mechanical polishing, electroetching pretreatment would be more effective.

Jan 1, 2005

By William Priestley

IN THE manufacture of gun forgings and other steel parts that, in service, are subject to sudden high stresses and shocks, it is most desirable to use steel possessing the greatest toughness and ductility possible without sacrifice of strength. In order to obtain this condition, it is necessary to procure steel that shows the highest possible elongation and reduction of area without lowering the tensile strength and elastic limit. Proper heat treatment of the steel can control this condition within certain limits. When heat treatment has failed to produce the desired results, metallurgists have used steels containing molybdenum, zirconium, vanadium, chromium, tungsten, etc. The purpose of this paper is to describe a method by which these desired physical properties may be procured-by the elimination of certain impurities that inherently exist in steel made by the open-hearth process, and without the use of expensive alloys. DESIGN OF GUN FORGINGS In the manufacture of gun forgings, a certain elastic limit is fixed by the designer, and the walls of the gun are made of the proper thickness, allowing a suitable factor of safety for the high stresses and sudden shocks that occur during gun firing. The elastic strength of the gun is about 1.4 times the stress set up at any point along the bore of the gun during firing with the maximum powder charge.

Jan 12, 1921

By A. Khan

The effect of sulfur dioxide on collectorless and collector induced flotation of chalcopyrite was studied by cyclic voltammetry on a rotating disc electrode. Contact angle measurements were made to determine the effect of sulfur dioxide concentration and electrochemical treatment. The benefits of sulfur dioxide in enhancing the selectivity of separating chalcopyrite from complex sulfide ores are discussed.

Jan 1, 1996

By C. W. Parmelee

THE ideal fuel for burning ceramic wares is the one that, among other characteristics, has little or no sulfur. For that reason wood was long considered the most desirable fuel but its high cost has practically eliminated its used except in regions where it is very abundant or other circumstances warrant its choice. The fuels commonly employed are natural and producer gas, oil, and coal. The last named is undoubtedly the most important, not only in this country but abroad. Occasionally anthracite is used but the larger part is bituminous. The quality of the coal used depends on the kind and the value of the products being manufactured. For some materials, such as common brick, hollow block, etc., the quality of the coal is of less importance than in the manufacture of polychrome terra cotta, pottery, porcelain, etc. It is obvious that in burning clays that contain notable amounts of pyrite, marcasite or gypsum, as is the case with many common clays, the sulfur content of the fuel is of much less importance. The permissible amount of sulfur in the coal used will depend on the kind of product being manufactured. "A good sample' of coal commonly used in pottery ovens has something like this quantity of sulfur." PER CENT. Total sulfur 1.20 Sulfur in the ash 0.11 Volatile sulfur a 1.09

Jan 9, 1919

By K. D. Mehta

Copper concentrate containing complex sulphides of Cu-Ni with 14.13% Cu and 10.04% Ni besides impurities such as 0.33% Co and 0.71% Mo, is not acceptable to the copper smelters due to the smelting problems. Selective bioleaching of nickel from the concentrate can be considered an an option to make it suitable for copper smelter. Effect of elemental sulphur and pyrite on the bioleaching of Ni and Co has been investigated using a mixed culture of Acidithiobacillus ferrooxidans (A.f.) and Acidithiobacillus thiooxidans (A.t.). Parameters such as pH, temperature, particles, size etc. were optimised to understand the role of additives in the bioleaching. With 2% S at 308K, 2.0 pH, 5% pulp density and 200µm size particles while shaking at 100 rpm, 79% Ni, 41% Co and 5% Cu were bioleached as compared to the leaching of 81% Ni and 45% Co in presence of 10 wt% pyrite in 60 days; 27% Ni, 24% Co and 4% Cu were recovered in sterile experiment. The selective dissolution of nickel and cobalt as compared to copper may be explained by galvanic interaction between chalcopyrite: pentlandite / pyrrhotite. Bioleaching was facilitated by strong oxidizing conditions due to higher Fe3+/Fe2+ ratio/redox potential (ESCE) as a result of improved interaction of minerals through biooxidation of sulphur and accelerated galvanic interaction by pyrite. The mechanism of selective leaching of Ni and Co was established by XRD phase identification.

Sep 1, 2012

By A. Haldar

This study focuses on the flow characteristics of hypereutectic Al-Si alloys in thin sections. The pattern assembly consisted of spiral horizontal patterns, 6.25 mm (0.25 inch) and 12.50 mm (0.50 inch) in thickness with a common sprue. Al-Si alloys with silicon levels of 14%, 18% and 22% were poured with superheats of 60°C, 115°C and 170°C. It was observed that metal fluidity (in terms of flow length and metal velocity) increased with increase in silicon levels and superheat for both section thicknesses. It was also observed that, for a section thickness of 6.25 mm (0.25 inch), silicon level had more pronounced effect on the metal fluidity. For 12.50 mm (0.50 inch) thickness, both silicon level and superheat affected the metal fluidity. The surface hardness of the castings increased with an increase in silicon level of the alloys at the gate and the flow tip. Detailed study of the flow tip was also carried out with a view to understanding the effect of silicon level and superheat on undulated flow length, surface hardness and microstructure.

Jan 1, 2007

By A. F. Abd El-Rehim

The behavior of both transient and steady state creep of Al-4.5 wt% Cu and Al-4.5 wt% Cu-0.1 wt% In alloys was investigated using a constant stress where torsional oscillations of different frequencies and shear strain amplitudes were operated at various working temperatures. An augment in both transient and steady state creep rates was observed by increasing both frequency and shear strain amplitude of the applied oscillations. The mean values of the activation energy of both alloys for both creep stages were found to be equal to that quoted for dislocation intersection mechanism.

Jan 1, 2006

By Débora Cardoso de Oliveira Silveira, Jean-Christophe Huber, Hamzeh Hamadeh, Kateryna Pastel, Guillaume Brosse

The dynamic behavior of oxygen gas flow, determined by the lance nozzle and blow pattern, is a key factor for determining jet efficiency in BOF Steelmaking. The present work compares the performances of Laval and parabolic nozzles with the aid of the Computational Fluid Dynamics (CFD). The Method of Characteristics (MOC) was applied to design a minimum length parabolic nozzle. The results show that the parabolic nozzle generates more uniform and stable jet, with 2% longer potential core and supersonic length and less shock waves. For the parabolic nozzle, the pressure nearby the nozzle wall is higher, which can protect this region from reverse flow of converter gases and offer longer life for the lance tip. Likewise, the flow rate variations would affect less this nozzle. In addition, the nozzle wear was investigated, and the parabolic nozzle has proven relatively less sensitivity to the presence of this deformity.

Oct 1, 2019

By Darrell Wilder

When designing excavation support systems in urban environments, it is often necessary to consider the effect of vertical surcharge loads from adjacent structures. Several methods are used in practice to establish the horizontal surcharge-induce pressure on the excavation support. According to the experience of the authors, these methods often seem to overestimate the effect of the surcharge and may have significant impact on the construction costs. This paper explores several of these procedures and provides a discussion as to the reasons for the differences in surcharge effect predictions between different procedures. It also provides practical recommendations for designers dealing with excavation support design.

Jan 1, 2006

By X. Zhang, E. Li, Y. Xiao, Z. Yu, H. Han, J. Xie, J. Tian, W. Sun, K. Hong

In a pulp environment, the surface properties of magnesite and dolomite tend to be similar, due to the re-adsorption of dissolved calcium species, which makes the flotation separation difficult. In this paper, the chelating reagent EDTA is introduced to eliminate the adverse influence of the calcium species and to restore the selectivity of magnesite-dolomite separation using sodium hexametaphosphate (SHMP) as a depressant. Flotation experiments confirm that the recovery of magnesite improves significantly in the presence of EDTA. Zeta potential experiments confirm that the negatively charged EDTA4+ and HEDTA3+ species can form soluble and stable chelates with positively charged Ca2+ and Ca(OH)+ species preventing their adsorption on the magnesite surface. Adsorption measurements prove the addition of EDTA can decrease the adsorption of depressant SHMP on the magnesite surface. X-ray photoelectron spectroscopy (XPS) measurements further confirm the transformation from the surface of magnesite to dolomite in the presence of calcium ions, and the possible adsorption mechanism of EDTA and SHMP on the magnesite and dolomite surface. Key words: Magnesite; Dolomite; Surface dissolution; Flotation separation

Jan 1, 2020

By M. Rafieazad, P. Fathi, X. Duan, M. Mohammadi, A. M. Nasiri

"Direct metal laser sintering (DMLS) is a metal additive manufacturing technology that creates highly complex components by fusing metal powder into a solid part. In this study, the impact of surface roughness on corrosion resistivity of AlSi10Mg_200C alloy manufactured through DMLS was investigated. The as-printed DMLS-AlSi10Mg _200C alloy was subjected to various surface finishing processes including grinding and sandblasting. The corrosion performance of the surfaces was then evaluated using potentiodynamic polarization testing and electrochemical impedance spectroscopy (EIS) in a 3.5 wt.% NaCl solution to mimic seawater environment. Surface characterization and corrosion morphology of the samples were assessed by Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) spectroscopy. The results of this study show that the surface finishing process and the resultant surface roughness has a significant impact on the corrosion resistivity of the DMLS-AlSi10Mg_200C alloy in the seawater environment.INTRODUCTION Direct Metal Laser Sintering (DMLS), also known as Selective Laser Melting (SLM) (Sames, List, Pannala, Dehoff, & Babu, 2016), Laser Beam Melting (LBM), or Laser Metal Fusion (LMF) (Herzog, Seyda, Wycisk, & Emmelmann, 2016), is an additive manufacturing process that utilizes a precise, high-power laser to micro-join powdered metals and alloys layer by layer to form almost fully dense and functional components in three dimensions from the 3D computer-aided design (CAD) data. Complex geometries not possible with conventional manufacturing processes can be readily manufactured with high accuracy using the DMLS process with no need to time-consuming tooling."

Jan 1, 2018

By Fumihiko Sumiya, Kunihisa Katsuyama, Yuji Ogata, Yuji Wada, Yukio Katoh, Yoshikazu Hirosaki

In our previous work, the results of photographic observation using a high speed framing camera showed that the difference between precursor air shock wave velocity and detonation velocity was primary factor for the channel effect. It is assumed that the decreasing precursor air shock wave velocity can prevent the channel effect in charge hole.

Jan 1, 1996

By L. M. Demers, D. C. Kuhn

"Kuhn, Douglas C., and Laurence M. Demers. Effect of surfactant on basal and silica-induced eicosanoid production by the alveolar macrophage. Am. J . Physiol. 269 (Lung Cell. Mol. Physiol. 13): L165-Ll 70, 1995.-Infiammation and fibrosis subsequent to the inhalation of certain mineral dust particles has been suggested to result from the activation of eicosanoid synthesis by the alveolar macrophage (AM). To determine if surfactant modifies dust-induced generation of eicosanoids by the AM, we evaluated the effect of the surfactant lipid dipalmitoyl lecithin (DPL) on the production of eicosanoids by rat AM exposed to respirable silica dust in vitro. During the first 24-h exposure period, DPL alone significantly increased basal production of eicosanoids but completely inhibited silica-induced thromboxane A2 synthesis. In contrast, leukotriene B4 (LTB4 ) production was only partially reduced by DPL. During a second 24-h exposure period, LTB4 production in response to the highest dose of silica remained significantly elevated in the presence of DPL. Similar results were obtained when the surfactant preparation Survanta was evaluated. These results suggest that 1 ) DPL and Survanta independently activate AM eicosanoid production, 2) DPL and Survanta modulate the response of the AM to silica dust, and 3) L TB4 may be the most important eicosanoid mediator of the long-term effects of silica dust exposure on lung pathophysiology. THE OXYGENATED METABOLITES of arachidonic acid (AA) (here collectively termed eicosanoids) have been implicated as important regulators of lung physiology and are thought to be involved in pathophysiological sequelae such as acute respiratory distress syndrome, asthma, and the pulmonary complications of sepsis (20). This role is manifested through both direct effects on lung physiology as well as through an indirect modulatory effect on the release of other mediators of lung injury, in particular profibrotic cytokines such as the interleukins and tumor necrosis factor (15). Recently, exaggerated eicosanoid production by both the alveolar macrophage (AM) and the type II epithelial cell has been demonstrated to result from the exposure of these cells to several particulates, including crystalline silica (quartz) dust (5, 9, 17). These observations have led to the suggestion that eicosanoids play a major role in the etiology of pneumoconioses.Another secretory component of the pulmonary environment, surfactant, has been shown to modulate crucial AM functions, such as bactericidal activity and the recruitment of circulating immune cells (25). Indeed, an important feature of the lung's reaction to inhaled mineral dust is an increase in surfactant production, perhaps as a compensatory or protective response (1, 16). In addition, the alteration of the surface properties of mineral dust by surfactant or its components has been shown to influence the biochemical response of the AM to the dust, perhaps by altering the surface charge of the dust particle (11, 29, 32). And recently, Wallace et al. (28) have shown that the coating of mineral dust with surfactant, and its subsequent removal by lysosomal phospholipase, unmasks differences in dust cytotoxicity that are not apparent when AM are exposed to uncoated dust. Thus it appears that the inclusion of surfactant in in vitro exposure studies may be important in evaluating both the absolute levels of eicosanoid production by the normal and dust-exposed AM and the temporal relationship between dust exposure and the production of inflammatory mediators by the AM. Therefore, we characterized the effects of the surfactants dipalmitoyl lecithin (DPL; the primary lipid component of natural surfactant) and Survanta (a commercially available surfactant derived from bovine lung) on basal and silica-induced AM eicosanoid production during two 24-h periods after exposure to dust particles to both allow the enzymatic removal of surfactant from the particle surface and evaluate the k"

Dec 1, 1996

By H. Polat, Q. Hu, S. Chander

"The collection efficiency of dust particles was determined in a laboratory dust chamber equipped with a water spray. Measurements were made in the presence of selected nonionic, cationic and anionic surfactants. For the nonionic and the anionic reagents, efficiency was maximum in a narrow range of concentration. The surfactant concentration corresponding to high collection efficiency was usually much below the commonly used concentration of l "", however. In comparison, much higher collection efficiency was observed for a cationic surfactant at extremely low concentrations. For delineating the mechanism of capture of dust particles, surface tension and contact angle results were used to obtain a correlation between the work of adhesion and the efficiency of collection. Such a correlation was reasonable for the nonionic surfactants but not for charged surfactants. In the latter case, electrostatic interactions between charged droplets and particles were more important, especially for the cationic reagent. INTRODUCTIONSeveral methods are used to control dust in mines. These include: ventilation, foam, scrubbers and sprays. This article is concerned with improving the effectiveness of water sprays, which are widely used to remove dust particles during continuous mining, by adding small quantities of surfactants. Water sprays produce small droplets which act as collectors of dust particles suspended in air. Sprays directed at the actual source of dust have the additional property of wetting the coal before the ·particles become airborne (Hamilton, 1974). Wetting agents, also called surfactants, arc known to play an important role in many applications where dust is a problem. However, conflicting reports exist in the literature with regard to the effectiveness of surfactants in water sprays (for a review, see Chander et al., 1988). In spite of the conflicting reports, the use of surfactants for dust control has increased over the years. In a recent study by the Bureau of Mines, a 27'6 reduction in respirable dust levels was observed in a mine test when surfactants were added to sprays (Foley, 1991)."

Mar 1, 1992

By H. Polat, Q. Hu, S. Chander

The collection efficiency of dust particles was determined in a laboratory dust chamber equipped with a water spray. Measurements were made in the presence of selected nonionic, cationic and anionic surfactants. For the nonionic and the anionic reagents, efficiency was maximum in a narrow range of concentration. The surfactant concentration corresponding to high collection efficiency was usually much below the commonly used concentration of l%, however. In comparison, much higher collection efficiency was observed for a cationic surfactant at extremely low concentrations. For delineating the mechanism of capture of dust particles, surface tension and contact angle results were used to obtain a correlation between the work of adhesion and the efficiency of collection. Such a correlation was reasonable for the nonionic surfactants but not for charged surfactants. In the latter case, electrostatic interactions between charged droplets and particles were more important, especially for the cationic reagent.

Jan 1, 1992

By Devin Burns, Saima Ghazal, Michael Owusu-Tweneboah, Kwame Awuah-Offei

Trust in AI systems and the nature and amount of information about the system can influence decision-making. It is, therefore, crucial to understand how AI-powered monitoring systems (e.g., gas monitoring systems) influence miners’ trust and decision-making in emergency evacuation. This work focused on measuring the differences between how participants respond to a simulated underground mine emergency evacuation situation when warnings are represented as coming from a human or AI-based monitoring system. We also manipulated the amount of information participants received about the system, yielding a 2×2 between-participants survey design. The participants received an alert message about rising gas levels in a mine and provided a response on how they would react and reported their perceived safety. We also asked questions to assess their trust in, preference for AI over human-based gas monitoring systems, and whether they are willing to delegate the duties of underground gas monitoring to AI systems. The experiment results show the amount of information had a significant influence on miners’ trust and decision-making. The safety perception of participants based on age, number of children and ethnicity was significantly different from one category to another. This work provides valuable insights as the mining industry deploys AI systems to aid mine safety.

Feb 1, 2025

By K. Meshinchi Asl

In this study the effects of T4 and T6 heat treatments on microstructural characteristics of AZ91 alloy containing Rare Earth elements have been investigated. Formation of intermetallic Al1 1RE3 needle shape particles which have a good thermal stability reduces both formation of ß(Mg17A112) and discontinues precipitation in AZ91 alloy which are dominated at the grain boundaries and are responsible for poor mechanical properties specially in elevated temperatures. For AZ91-RE samples both T4 and T6 heat treatments led to a continuous precipitation of ß particles at the grain boundaries after aging. However, in AZ91 samples (with no Rare Earths) precipitation was discontinuous at grain boundary areas. This type of precipitation is one of the main reasons of poor mechanical properties of this alloy at elevated temperatures.

Jan 1, 2007

By M. Rafati

In this investigation, the effects of T4 and T6 heat treatments of AZ91 magnesium cast alloy have been studied. The effects of different microstructural details such as morphology, size and distribution of precipitates and their influence on fracture mechanisms were investigated by optical and scanning electron microscopy. The mechanical strength of the alloy after T6 treatment was found to increase in comparison to the T4 treatment, due to the formation of discontinuous precipitates in the grain boundaries. Precipitation in this alloy occurs in two ways: continuous precipitation, which nucleates and grows inside the grains, and discontinuous precipitation, which forms at the grain boundaries. During ageing, the length of the continuous precipitates increases, and, hence, interprecipitate distance decreases. The formation of discontinuous precipitates causes initiation and propagation of cracks at and the weakening of the grain boundaries. This is the principal reason for the reduction of the ultimate tensile strength in T6 heat treatment in comparison to the T4 condition.

Jan 1, 2006

By Cheng Yan, Yugang Li, Qian Wang, Lizhi Zhang

In continuous casting process, mold powder has lots of metallurgical effects, such as covering the molten steel to prevent liquid steel from oxidation by air, preserving heat for top layer liquid steel, lubricating initial shell and so on. However, mold powder also can deteriorate the quality of final products obviously after the entrapment of mold powder in steel. In the present work, based on the similarity theory the effect of technological parameters on mold powder entrainment was investigated by water model. Experiment was carried out in the water mold using oil and water to simulate slag and steel, respectively. The results showed that increasing casting speed increased the water-oil interfacial fluctuation and entrainment frequency; viscosity of oil also had a great impact on the interface fluctuation and entrainment; water-oil interfacial tension effect the entrainment while not changing the interfacial fluctuation; submergence depth had little impact on entrainment and interfacial fluctuation.

Jan 1, 2015

By Wu Y. H, Lu J. P

Slope stability has now become a practical tool in the design and oper- ation of open pits. The stability of rock slope depends on many factors, including not only structural geology, the existence of weak layers, ground- water, blasting and weathering, but also the virgin stress field. This paper presents an application of a numerical method to investigate the effect of the virgin stress on slope stability. The finite element method is employed to simulate the excavation of open pits. Redistributed stress fields in the slope of open pit are computed for several different virgin stress fields. Based on the redistributed stress fields, the shear force which tends to produce sliding of a rock mass and the frictional resistance to sliding are evaluated. The possibility of potential failure is assessed by the limit equilibrium method. The combination of the finite element method with the equilibrium method provides a powerful analytical tool for slope stability. The significant effect of virgin stress on the stability of slopes is shown by studying a typical case.

Jan 1, 1989