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By M. Moats, I. E. Paschalidou, K. Awuah-Offei

Tellurium (Te) is a rare metalloid that is predominantly produced from the treatment of anode slimes formed during copper (Cu) electrolytic refining. The US Government lists Te as one of the 50 critical minerals, partly, because of its use in thin-film photovoltaic (PV) technology. Given policy initiatives to increase Te production, it is important to evaluate the life-cycle environmental impacts of Te recovery as a by-product of Cu processing. The literature contains a few specific life cycle assessment (LCA) studies of groups of metals that include Te without proper regard to impacts per life-cycle stage of Te production or the effect of allocation on the results. This study builds an LCA model of the production system of Te from anode slimes treatment to evaluate the effect of allocation on life-cycle impacts. We build life cycle inventories using data from the Ecoinvent v3.7.1 database, literature, and engineering calculations and allocate impacts in proportion to products’ mass and economic value. The results show that economic value-based allocation yields greater impacts than mass-based allocation indicating the significant effect of the allocation approach on life-cycle impact estimates.

Feb 1, 2023

By T. P. Meloy

Like our wives, the comminution of brittle solids is easy to recognize but difficult to describe. However, describing it we must. Describing the fracture mechanism of brittle solids permits the eventual mathematical quantification of the results, process optimization and control strategies. This paper presents a physical model of brittle solid comminution that explains why the slope of the log-log size distribution curves have a slope of one or less in the smaller particle sizes. To develop the hypothesis, modifications of the Gaudin Meloy physical model are made. In brittle solids, comminution takes place by cracks propagating through the material. These cracks may bifurcate as they move. Cracks may terminate either on the original surface of the material, or on a secondary crack within the material formed earlier in the comminution process.

Jan 1, 1994

By Tyler A. Dawson, Ryan P. Butler, Timothy Gualandri, Jason R. Edberg

"In the early 1920’s, the City of Tulsa, Oklahoma constructed an approximately 8,238-foot long tunnel, the Tiawah Tunnel, through bedrock. Voids behind the concrete tunnel liner were detected via probe drilling in early 2000 as part of an interior visual condition assessment. In 2012 and 2015, conditions along the entire tunnel were efficiently assessed through geophysical investigation using ground penetrating radar (GPR) along the inner tunnel crown and at various select locations within the tunnel. Fifty-seven (57) potential voids, extending up to 19 inches in depth and 12 feet in width, were detected with 1,000 MHz GPR and confirmed through probe drilling with approximately 80% accuracy. GPR proved to be an efficient and reliable technology for void detection behind concrete tunnel lining. This paper highlights the geophysical investigation and how geophysical efforts were combined with other investigation efforts to definitively determine the presence of voids outside of the tunnel lining.INTRODUCTION The city of Tulsa, Oklahoma has a population of about 400,000 people. The original source of water for the city was the Arkansas River. The first pumping operation provided untreated water to homes and businesses in 1904. The residents of Tulsa found this water to be unacceptable due to the high levels of salt and gypsum present. As the city grew, land and storage/treatment facilities were acquired in order to obtain and distribute a more suitable raw water. The raw water needs for the city are currently satisfied by transport and treatment of about 100 million gallons per day (MGD) of water from surface water sources. Water is transported many miles from Spavinaw/Eucha and Oologah lakes to Yahola Lake and the Lynn Lane Reservoir (totaling over 3-billion gallon capacity). From here, the raw water is treated and transported to the various customers (City of Tulsa 2015). The Tulsa Metropolitan Utility Authority (TMUA) is responsible for the operation and maintenance of the raw water transport system."

Jan 1, 2016

By Vasiliki Founta, Andrew J. Whittle

"This paper describes the development of a 3D finite element model for predicting ground movements caused by construction of 7.1 m diameter twin bored tunnels for the Crossrail project in London using Earth Pressure Balance (EPB) machines. The model uses the commercial FE code, Plaxis 3D, to represent the face pressure, conical shield, grouting process and activation of precast segmental concrete lining systems through a set of boundary conditions that advance through the soil mass along a prescribed trajectory. Soil behavior is described using the Mohr-Coulomb soil model with input parameters calibrated from laboratory element tests. The analyses focus on the performance of the EPB tunneling machines in greenfield conditions beneath Hyde Park, where the tunneling occurs within deep layers of relatively uniform London Clay. The model predictions are in good agreement with surface and sub-surface vertical settlements measured at a well-instrumented section, but tend to overestimate the measured lateral displacements towards the tunnel. Ongoing studies are focused on the role of soil behavior and the approximations in FE model predictions of tunnel-induced ground deformations. Introduction Since their introduction in the 1970’s, closed-face Earth Pressure Balance (EPB) machines have become widely used for soft ground tunnel construction. The EPB design relies on a screw conveyor system to regulate the pressure of the excavated soil/spoil within the head chamber and hence control stability at the face of the machine. One of the key design issues in the application of EPB machines is to establish how control parameters, including the advance rate, face pressure and grouting processes (used to compensate for the tail void at the rear of the shield and to infill gaps between the precast lining rings and surrounding soil) affect and/or control the far-field ground movements. For closed-face systems, short-term deformations are associated with ground losses at the face, overcutting and ploughing of the shield and poor control of grouting in the tail void; while long-term deformations can occur due to consolidation and creep within the surrounding soil (and are closely connected to the seepage boundary conditions;e.g., Laver & Soga, 2012). The control parameters for advancing the EPB machine can have a significant effect on the magnitude and distribution of the far-field deformations. Therefore, analyses of the ground response to tunneling require accurate modeling of the soil stratigraphy and constitutive behavior as well as the construction process. Finite element (FE) methods have been used to simulate tunnel construction since the early 1980s, but only a few studies involved three-dimensional modelling of mechanized tunneling (e.g., Finno and Clough 1985; Bernat and Cambou 1999; Swoboda and Abu-Krisha 1999; Dias et.al. 2000; Melis et.al. 2002; Kasper and Meschke 2004; Möller 2006). In order to get a better understanding of the effect of the construction process and soil properties on the development of the ground deformations more comprehensive models of tunnel excavation and tunnel support are required in order to capture the 3D nature of mechanized tunneling and the effect of construction parameters such as advance rate, face and grout pressure."

Jan 1, 2016

By L. J. Vincze

The program of study of pellet binder materials was begun by the ORF in 1963 to examine various Canadian materials as substitutes for bentonite which is imported in large tonnages (199,270 tons in 1969) from the U.S.A. for Canadian pellet plant operations. Most of the raw bentonite used in Canada originates in Wyoming, North Dakota and more recently Greece, resulting in relatively high transportation costs to pellet producers. Some Canadian bentonites available in Western Canada (Alberta) can be beneficiated for uses as pellet binders but could not compete in cost with U.S. sources due to the cost of beneficiation and the higher rail transport charges to Eastern Canada. It is difficult to find a substitute for bentonite, and many materials have been investigated by research groups but, so far, no economic substitute is in use. However, some success is apparent in studies of low cost materials such as clays, sea weed, peat moss and low grade coal, The work done by the ORF over several years has covered systematic test¬ing of Ontario clays, lignite, some types of tree bark, waste sulphite liquors of various kinds, and peat moss as binders for iron ore pellets. The major effort has been concentrated on peat moss and has included a study of the influence of different additives. Since analysis of peat moss for humic acid is difficult and time consuming, a certain amount of time was devoted to development of improved methods, the most useful of which was a spectrophotometric method based on extraction of peat by sodium pyrophosphate for determination of humic substances. In the present paper, only the most recent work concerning the use of peat moss with suitable additives is discussed in detail, since it is the most conclusive and best documented portion of the program.

Jan 1, 1971

By James M. Barker

The occurrence of borates and zeolites at Mesa del Alamo is well documented by McAnulty and Hoffer (1) and Lefond and Barker (2). Further investigation indicates the presence of priceite and meyerhofferite in addition to the howlite (1) and colemanite (2). Analcime occurs in addition to the clinoptilolite and phillipsite (2). The Mesa del Alamo area is about 200 !a south of Tucson, Arizona, and 13 km southeast of Magdalena, Sonora, Mexico, just south of the unpaved road to Cucurpe (Figure 1). The geology and mineralogy of northcentral Sonora is known only on a regional basis except for small areas mapped in detail during copper exploration. The study area is within the Basin and Range province of North America from which borates and zeolites are now produced in California. The borates and zeolites at Mesa del Alamo occur in geological environments similar to those of the Mojave and Death Valley regions of California (3, 4). Thus, a detailed exploration pro- gram in the Magdalena area could result in the discovery of economic borate and/or zeolite deposits.

Jan 1, 1979

Since 1955 Gaspe Mines has produced 144 million tonnes of ore, averaging 0.87% Cu, mined from two open pits and underground workings. In 1994, four exploration drill holes discovered a buried porphyry/skarn Cu-Mo deposit at depths of between 1000 m and 1700 m below the top of Porphyry Mountain. The mineralization and alteration associated with the Porphyry mountain quartz monzonite does not outcrop. A total of 19,500 m of drilling in 12 drill holes has outlined 200 million tonnes grading 0.73% Cu and 0.08% Mo. Mineralization occurs as veins and disseminations of chalcopyrite and molybdenite. Drilling and feasibility studies continue.

Jan 1, 1998

By E. Forssberg

Studies have been carried out with the High Pressure Roller Mill, HPRM, to produce calcium carbonate minus 10 micron. This paper presents the optimization of the specific grinding force of the HPRM system for a maximum energy utilization when limestone is ground. In addition, experimental tests of producing carbonate minerals using the HPRM as a pre-crusher are described in this paper.

Jan 1, 1996

By M. N. Herrera

The bioleaching of mineral sulfide pulps in a bench-scale rotating drum reactor has been studied. The reactor includes horizontal paddles in the inner wall for lifting of the mineral pulp. The performance of the reactor was tested in the bioleaching of a refractory pyritic gold concentrate in the presence of pure Thiobacillus ferrooxidans strain (ATCC 19859). The concentrate was efficiently bioleached at 50% pulp density with the drum operating at 0.5 -1.0 rpm Attempts of bioleaching the concentrate at the same pulp density in conventional stirred reactor showed severe inhibition of bacterial activity. The results demonstrated that the drum reactor allows to operate at much higher pulp densities than the conventional stirred tank reactor. This behavior is explained in terms of an improvement of the bacterial activity due to a better control of the attrition of the mineral particles.

Jan 1, 1997

By M. Moats, J. Young

Short term laboratory cell electrorefining experiments were performed to examine the impact of electrolyte composition, current density and temperature on deposit structure, roughness, and adhesion to 2B mill finished 316L stainless steel. Copper electrodeposits were produced using synthetic electrolytes with thiourea and the continuous addition of glue. Deposit structures were evaluated using X-ray diffractometry. Surface roughness was measured using profilometry and analyzed using scaling analysis. Finally, an internally developed method was used to measure the force required to remove the electrodeposited copper from stainless steel to determine adhesion strength.

Mar 2, 2022

By Francesco Chiappalone, Daniele Nebbia, Lance Waddell, Greg Colzani

As part of the 3RPORT Project, a 5-mile tunnel is being excavated underneath the three rivers of Fort Wayne using a 19-foot diameter Slurry Tunnel Boring Machine. The groundwater pressure at the tunnel axis ranges from 4.5 to 5.3 bar. The rock mass hydraulic conductivity is very high with water inflows up to 10,000gpm imposing significant challenges to the project. After excavating 1,550-feet of the TBM tunnel, major leaks between the tailskin and the segmental lining were observed, indicating the potential deterioration of the tailskin brushes and the need for inspection and eventual replacement. The first part of the paper describes the planning of the intervention, including the design of the polyurethane grouting campaign, the procedures developed for the execution and the controls established during construction to timely assess the presence of potential hazards. The second part of the paper focuses on the experience gained during execution and lesson learned to prevent future occurrences of this nature.

Jun 13, 2021

By S. H. Seyedein, Hamed Tavakkoli, Mohammad Reza Aboutalebi, S. N. Asharafizadeh

The liquid–liquid extraction behavior of lutetium from different acidic solutions was investigated using two extractants, D2EHPA and PC88A, in kerosene. Lutetium extraction reactions with D2EHPA and PC88A from HNO3 and H2SO4 solutions were chemically and thermodynamically analyzed. It was found that each Lu cation was complexed with six monomers of the organic extractant and released three protons. Simultaneously, the Lu cation was instituted in the P–O–H group of the extractants. Thermodynamic analysis of reactions between extractants and acidic solutions showed that the D2EHPA-HNO3 system is the most favorable for extracting lutetium. It is noted that the calculated equilibrium constant of the reaction in this system was approximately six times larger than that of the D2EHPA-H2SO4 system. However, the value of the equilibrium constant for the D2EHPA-HNO3 system was evaluated to be approximately 200 times greater than that of the PC88A-HNO3 system. Therefore, one can conclude that the extraction behavior of lutetium is more influenced by the extractant type than the solutionmedium. The synergistic effect of different mixtures of extractants on the solvent extraction of lutetium was also examined, and the highest synergistic factor was obtained for a binary mixture of PC88A:D2EHPA at the ratio of 4:1 for both aqueous solutions.

Mar 15, 2021

By Yuanhong Qi, Xun Fu Wang, Tao Fu, Kunkun Cui, Yingyi Zhang, Jie Wang, Junmao Qie

With the sharp decrease of sulfide nickel resources, the nickel laterite is becoming more attractive as nickel oxide, nickel matte, and nickel-iron. This study investigated the mineral phase structure, chemical analysis, thermal properties, and element distribution characteristics of the rotten rock layer deposited in the Southeast Sulawesi Ophiolite Belt. The results show that the nickel laterite deposited in Southeast Sulawesi Island, Indonesia, belongs to the typical high-nickel and low-iron garnierite-type laterite. The concentrations of nickel and iron of the nickel laterite are 1.99 wt% and 17.55 wt%, respectively. The serpentine, olivine, clay, chlorite, hematite, and magnetite are the major minerals, and the pyroxene, actinolite, limonite, and chromite are the minor minerals in the nickel laterite in Southeast Sulawesi, Indonesia. Serpentine and olivine are the main nickel minerals with an average nickel concentration of 3.65 wt% and 1.73 wt%, respectively. The Fe and Ni have homogeneity and symbiosis in the serpentine and olivine, and their concentrations are often positively correlated.

Experimentation was performed on the flotation of apatite and dolomite separately using anionic collectors in the presence of Mycobacterium phlei. Also, the flotation of mixtures of dolomite and apatite in the presence of anionic collectors and in the absence and presence of the bacterium were studied. It was found that M.phlei functions as a depressant for both minerals. However, it functions as a better depressant for dolomite than for apatite. Experimentation was extended to two different Florida dolomitic phosphate rocks. In this investigation a concentrate grade of less than 1.0% MgO was achieved.

Jan 1, 1997

By W. R. Dearman, N. Turk

The theoretical relations between the strain and stress Mohr circles make it possible to establish a relation between the internal friction angle [ ] and the Poisson's ratio (v) of rocks. The internal friction angle is related to the Poisson's ratio as Sin [-] = (1 - v)/(l + v). This relation gives lower friction angle values than the triaxial Mohr envelopes and higher values than those given by surface sliding friction tests.

Jan 1, 1986

By W. L. Fourney, D. C. Holloway, J. W. Dally

Introduction Improvements in the process of rock excavation by blasting involves better control of one or more phases of the fracture process immediately after detonating the ex- plosive charge. Total control of the process involves individual control of (1) The number of fracture planes. (2) The crack initiation sites. (3) The direction of crack propagation (usually radial). (4) The stress field driving the fracture front. Fracture plane control is usually accomplished today by using the smooth wall blasting method; however, investigations by the authors (1) indicate several areas where this method could be improved. These improvements include: a) generation of stress concentration factors at the location of the initiation sites; b) protection of the remaining region of the borehole wall to inhibit initiation of any cracks not associated with the fracture plane and fragmentation pattern; c) limit peak detonation pressures to avoid borehole crushing and maintain by stemming residual gas pressure in the bore- hole during the crack propagation period. This paper describes experiments con- ducted with a charge holding device fabricated from thin-wall steel tubing which was partially slit at fracture locations. The tube lined the bore-hole in laboratory tests to simulate smooth wall blasting. Results showed close control could be achieved relative to both the number and the location of the fracture initiation sites.

Jan 1, 1977

By Mark S. Stagg, Michael J. Nutting, Douglas R. Barlet

Single-row bench blasts at a reduced scale in the field were used to study the effects of delay time on fragmentation. Nine shots with a spacing of 21 in. and a burden of 15 in. (S/B = 1.4) and nine shots with a spacing of 30 in. and a burden of 15 in. (S/B = 2.0) were completely screened to determine particle size distributions. Delay intervals between holes ranged from 0 to 45 msec, corresponding to effective delay intervals ranging from 0 to 36 msec per foot of burden. Each shot was instrumented with strain and pressure gages to measure in situ blast dynamics and to evaluate interactions between blastholes. Finer overall fragmentation was produced for shots with delay intervals between 1 and 17 msec per foot of burden. Only for shots within this optimum delay range was it observed that the strains induced by stress waves constructively interacted with strains induced by gas pres- sure from an earlier detonated hole. Coarsest fragmentation resulted at delay intervals less than 1 msec/ft, where stress waves from each hole were observed to interact destructively, and at delay intervals greater than 24 msec/ft, where no inter- action between holes was observed, indicating a condition that can be considered as the firing of single hole shots independently.

Jan 1, 1986

By Nick Barton, Harald Hansteen

The deformations resulting from excavation of very large openings are compared using two-dimensional F.E. continuum analyses and discontinuous physical models (20,000 discrete blocks). Both the joint orientations and the model horizontal stress levels were varied. Some models were dynamically loaded to simulate earthquakes (0.2-0.7 g). Model deformations were recorded using photogrammetry. The changes in deformation when increasing the simulated spans from 20 m to 50 m were of particular interest. High horizontal stress caused surface heave when joint orientations were favourable for arch stability. Joint orientations also determined whether the pillars between parallel openings were in a state of compression or tension. INTRODUCTION The engineering performance of large rock caverns has traditionally been learned from mining and hydro power projects, where the depth below surface is often many times greater than the span of the openings. Deformations measured in the walls and roofs of hydro power caverns generally range from about 5-50 mm, though there is a documented case where a wall moved in 126 mm (1), and another where the arch moved down 147 mm (2). The chief objectives of the present studies of large near-surface openings were threefold: (i) to provide deformation data to compare with monitored data from planned engineering projects involving large span near-surface excavations, e.g. underground sports complexes, civil defense shelters, nuclear power stations,

Jan 1, 1979

By G. M. Molinda

Some of the most difficult coal mine roof in the U.S. can be found in the Illinois Basin. Factors contributing to the high roof fall rate include: weak moisture-sensitive roof rock, high horizontal stress, and limited longwall mining. The depth of cover ranges from 90-1,000 ft and roof damage from horizontal stress can be severe. Moisture sensitive-roof rock is common above the Springfield-Harrisburg Herrin #5 and #6 seams in the Illinois Basin, and contributes to roof skin deterioration. The roof fall rate increases significantly in the humid summer months. The National Institute for Occupational Safety and Health (NIOSH) has shown, using lab and field studies, that highly moisture-sensitive roof rock can be directly correlated to poor roof conditions. Controlling the skin is the key to reducing rock fall injuries, and roof screening is, by far, the best remedy. Illinois Basin coal operators have been successful in reducing the number of rock fall injuries in recent years. NIOSH has documented best practices for screen installation which has resulted in safe, efficient operations. Other solutions to skin failure include: the use of denser five bolts per row patterns to reduce spans between bolts, systematic supplemental support in intersections, straps and large pans protecting operators, and air conditioning to remove moisture from the intake air.

Jan 1, 2008

By Stéphane Servant, Jacques Ouellet, Ferri Hassani

This paper presents essentially the logistic and practical aspects involved for in situ testing of mine paste backfill with a self-boring pressuremeter. The investigation discussed in this paper is part of an extensive and ongoing research project to identify and validate an in situ testing technique for cemented mine backfill such as hydraulic or paste backfill as well as Insitu behavior of backfilled stopes. After a literature review on field testing of soils and past experiments on mine backfill in situ testing, the self-boring pressuremeter was selected as the most appropriate instrument for this task. The authors presents in this paper the technical aspect involved in a field trials that was conducted in a Canadian underground mine using paste backfill. The results of this first successful trials show that self-boring pressuremeter test can provide high quality and reliable backfill characteristics results, using analytical techniques developed for soils (Ouellet et al., 1998). The parameters obtained were: estimation of the lateral stress in the ground, the soil stress-strain response and the soil strength. The logistic and equipment required to conduct such testing underground is fully described. Performance achieved in the field and technical difficulties encountered are highlighted. Recommendations for future experiments with such instruments are given. Some potential technical improvements to better adapt this in situ testing technique to mine backfill are proposed.

Jan 1, 2001