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By V. A. Nieberlein

An extractive process was developed applicable to submarginal titanium deposits containing valuable minor constituents; such as columbium (niobium) and iron. The process consisted of reducing the mineral concentrate with coke at high temperature to form a carbide-suboxide sinter, chlorination in the 400° -500° C. range, and fractional condensation of the chlorides. The chlorination procedure recovered 97, 83, and 87 percent of the titanium from brookite, rutile, and ilmenite sinters, respectively, while simultaneous columbium recoveries on the same materials were 85, 50, and 87 percent.

Jan 1, 1957

By Richard D. Graves

Pitch from low-temperature carbonization of bituminous coal was hydrogenated at cracking conditions in a continuous bench-scale unit to produce low-molecular-weight oils and tar acids. The pitch contained 15.6 pct benzene-insoluble material, 4.0 pct hexane-soluble oil, and 80.4 pct asphaltene by weight. At 475° C, 7,500 psig, and 1.5 hours residence time, hydrogenation products, based on the weight of pitch, were about 36 pct oil boiling below 325° C, 24 pct hexane-soluble heavy oil, 17 pct asphaltene, 1 pct benzene insolubles, and 12 pct hydrocarbon gases. The yield of tar acids boiling below 250° C was 4.3 pct, and the yields of C6 to C8 paraffins, naphthenes, and aromatics were each less than 1.0 pct. The yield of tar acids was within the range of yields obtained by hydrogenation or high-temperature carbonization of bituminous coal (2 to 5 wt pct). Yields of oil boiling below 325° C increased with increased residence time or temperature. There was little or no effect of residence time on yields of alkali- soluble material which contained tar acids. Yields of hydro-carbon gases increased markedly with an increase in temperature from 475° to 500° C. Lowering the hydrogen pressure to 4,500 psig resulted in yields similar to those obtained at 7,500 psig.

Jan 1, 1962

By Laxman S. Sundae

In the vast majority of American coal mines, roof bolt holes are drilled dry, mainly because of mine operator concern with the spent water creating adverse working conditions. Wet drilling, however, can increase drilling rates and the effective lifetime of the drill bits used. This study, carried out as part of an ongoing cooperative research program between the U.S. Bureau of Mines and the University of Missouri-Rolla, shows that the large volumes of water conventionally used in wet drilling are not necessary, and the performance benefits from wet drilling can be achieved with total volume flows on the order of 0.4 L per hole. This conclusion is validated based on the measured respirable dust generated in drilling Berea sandstone. The results are confirmed using a variety of bit shapes, which are also shown to have a significant effect on penetration rate.

Jan 1, 2010

By Charles L. Kimbell

This study summarizes and amalgamates much information collected, compiled, and utilized by the Bureau of Mines numerous country specialists and branch chiefs for inclusion in their country and regional reports that comprise the five other volumes of the international studies of the Minerals Yearbook. Because of the plethora of sources used in preparing these regional studies, it is impossible to cite all sources of information used in preparing this summary, but some recognition seems due. Generally speaking, the preparation of this study, and its related detailed studies on countries and areas, would be impossible without the efforts of the personnel of our counterpart agencies throughout the world. Information that they collect, compile, and then publish, either in their own volumes or in publications of central statistical agencies in their countries, are the foundations upon which this work rests. Thus, we must begin by expressing our appreciation to the multitude of persons employed by these agencies for their contributions.

Jan 1, 1992

By D. L. Hollis

An arc plasma reactor, constructed and used for studying extractive metallurgical processing, was adapted by the U.S. Bureau of Mines to separate gases of different masses by using the high rate of plasma rotation. With argon and helium as input gases, peripheral reactor outlet ports had a measured average increase of about 10 pet in argon concentration relative to helium with the plasma on compared with plasma off for the same gas inlet concentrations in both cases. Approximately the same average increase in argon concentration occurred from the peripheral outlet port compared with a central outlet probe with the plasma on. There was no difference with the plasma off.

Jan 1, 2010

By W. D. Riley

The U.S. Department of the Interior, Bureau of Mines, has been conducting minerals recovery research in support of the nation's geothermal program since 1974. The Bureau's program of laboratory and field studies has focused on determining the materials of construction for geothermal resource recovery plants and an the recovery of mineral values from the geobrines. An analytical program has been conducted at the Avondale Research Center to determine the chemical constituents of some high- and low-salinity geobrines found in the Imperial, Valley of California. Data are reported for the early stages of brine production of femur geothermal wells--the low-salinity, medium-enthalpy brines from the East Mesa Known Geothermal Resource Area (KGRA), Mesa 6-1 and 6-2, and the high-salinity, high-enthalpy brine from the Salton Sea KGRA, Magmamax 1 and Woolsey 1. The reported results indicate the importance of the operating and engineering history, the operating parameters during sampling, and the method of sampling in order to evaluate the chemical analyses.

Jan 1, 1980

By W. Hermanson

This report presents the results of a task to complete a final design of a remote controlled hi-roof bolting machine for high roof areas in coal mines. The project was begun by visiting several coal mines to become familiar with roof fall areas. Several machine concepts were generated and presented to the design committee for criticism. A preliminary design was completed, as covered by this report. A Final Design and Final Report will be issued incorporating the committee comments at the Preliminary Design review and comments received concerning this Preliminary Design Report.

Jan 1, 1979

By Michael G. Zabetakis, Israel Liebman, Henry E. Perlee

Flammability studies conducted to date on stratified methane - air and pentane - air mixtures in air indicate that location and extent of a flammable layer are affected by molecular diffusion , gas motion , and propagation of flame . In initially quiescent mixtures , the lower limit - of - flammability zone may be determined by assuming molecular diffusion alone governs mixing rate . The upper limit - of - flammability zone can be predicted in this manner only for stratified layers with small concentration gradients ( less than 0.2 volumepercent per inch ) ; where large concentration gradients are encountered ( for example , as much as 30 volume - percent per inch ) , the initial - mixture methane concentrations that yield flammable mixtures are larger than anticipated . Flames propagating through heterogeneous quiescent methane - air atmospheres in the direction of the concentration gradient exhibit flame speeds at any point that corresponds to the flame speed of the homogeneous gas mixture having the same gas composition as that of the point in the heterogeneous system . In flowing mixtures with large concentration gradients , the degree of mixing prior to ignition does not appear to affect the flame velocity and emitted radiation appreciably in a 6.5 - ft - diameter gallery .

Jan 1, 1964

By B. J. Dalton

The Bureau of Mines Helium Research Center has developed a computer program for solving two-phase equilibria data for binary mixtures and for evaluating thermodynamic functions of interest, including all critical points. This computer program was used to calculate equilibrium points on the PVTu surface for the helium-nitrogen system as predicted by the Van der Waals equation of state. Numerical values are tabulated and illustrations are presented for 1,279 equilibrium points and for quantities needed to construct Ponchon diagrams. Equilibrium ratios as a function of pressure at constant temperature and of temperature at constant pressure-are also shown graphically. In addition, saturated partial molal volume and partial molal enthalpy data are given. It is shown that the Van der Waals helium-nitrogen system exhibits retro-grade condensation of the second type for liquid helium concentrations of about 0.07 mole fraction or less and pressures below about 45 atm. It is also shown that the critical point is at a -maximum value of pressure (at constant temperature) and of temperature (at constant pressure).

Jan 1, 1971

By Hal J. Kelly

A picture of the ceramic industrial potential of the Pacific Northwest States is presented by reviewing the present ceramic industries, raw-material resources, and current market demands. A resume is given of the industrial plants manufacturing ceramic ware as well as available information on raw-material resources. No attempt was made to prospect for new deposits but rather to evaluate, insofar as possible, those already known. Since much of the industry is concentrated on the Pacific coast, most of the information available on resources concerns deposits in that area. Large, undeveloped districts in Montana and Idaho, however, offer promise of larger reserves of ceramic raw materials. Average annual production, some operating costs, and annual power consumption are given for each of the plants. Production and some cost figures are listed to show the limited nature of the present industry and to suggest fields open for new development.

Jan 1, 1956

By R. D. Van Zant

The method for smelting zinc in horizontal retorts developed several centuries ago is still in use. This process consists essentially of the reduction of zinc oxide by carbon at 1,200° to 1,400° C. in a fire-clay retort. The reaction is highly endothermic, and a high radiation loss occurs in transferring the heat of reaction through the fire-clay walls. In recent years, silicon carbide retorts with much better heat-transfer characteristics than fire clay have been supplanting the old retorts. The practical impossibility of recovering the carbon monoxide formed in the reduction causes a large loss of fuel. Intermittent smelting is done in small retorts that are manually charged and discharged, and the furnace crews must be specially trained if efficient results are to be obtained. During the past 20 years several processes have been introduced that have substantially improved the horizontal-retort process. One of these, developed by the New Jersey Zinc Co., consists of a continuous process in which a briquetted mixture of zinc sinter, reducing agent, and binder is coked at 750° to 900° C. and charged into a vertical silicon carbide retort. A supply of displacement air or exhaust combustion gas is introduced at the base of the retort at an appropriate pressure in order to keep the zinc vapor from condensing on the cooled residue in the lower part of the retort. Any .oxidizing constituents in the displacement gas are converted to carbon monoxide by reaction with the carbon in the charge. The spent residue is continuously removed at the bottom of tl1e retort. The chief advantages of this process are said to be increased output per man-day, improved working conditions, high recovery of zinc, increased thermal efficiency, and long retort life.

Jan 1, 1950

By W. L. Parker, W. A. Selvig

"Introduction.Powdered or pulverized coal is extensively used as a fuel, the total annual consumption*** in the United States being about 12.000,000 tons, and growing steadily. As the coal is usually pulverized so that 70 per cent or more parses through a 200-mesh sieve, it presents difficulties in sieving, because such finely divided material tends to clog the meshes. A fineness test is desirable in order to judge the efficiency of the pulverizing apparatus, and as an indication of the particle size of the coal being burned.Committee D-5 on Coal and Coke, American Society for Testing Materials, has recognized the desirability' of a standard method for determination of fineness of powdered coal. The Bureau of Mines, in co-operation with this Committee, conducted sieving tests on two standard samples of powdered coal, which are described in this paper. As a result of this work a method for making fineness tests, by band sieving, is recommended as a standard method, while a rapid method, by machine sieving, is given for routine tests.Outline of Investigation.Preliminary trial tests were made by the bureau and tentative methods were formulated for making the sieving tests both by band and by machine.Each of two samples of powdered coal was carefully mixed, and portions were sent to the twelve laboratories mentioned later. These were requested to make duplicate sieving tests on the two standard samples, by the hand-sieving and machine-sieving methods, and to follow the tentative procedure exactly as outlined. All of the laboratories made sieving tests by hand shaking and eight of them made tests by machine shaking."

Nov 1, 1923

By C. P. Fang, V. A. Marple, K. L. Rubow

"Studies of the flow fields and particle impaction characteristics are more complicated in multi-nozzle impactors than in single-nozzle impactors, since the jets of air must penetrate cross-flowing air to impinge on the impaction plate. Results of heat and mass transfer analysis are employed to describe the cross-flow pattern in multi-nozzle impactors. A cross-flow parameter has been derived to predict the deflection of the air jet by the cross-flow. This parameter is expressed as a function of the geometric parameters for the multi-nozzle impactor. DnN 4D,, where N is the number of nozzles, Dn the nozzle diameter and D, the nozzle cluster diameter. Empirical particle collection data show that multi-nozzle impactors operate satisfactorily, if the cross-flow parameter is less than a critical value of 1.2. Impactors operating with a cross-flow parameter larger than this critical value are shown to possess poor particle collection characteristics.Inertial impactors of many designs have been used for sampling aerosol particles. Impactors can be single stage, consisting of a nozzle and an impaction plate, or a cascade impactor with several stages in series. The simplest design for a stage is a single nozzle with a flat impaction plate. However, many designs use stages with multiple nozzles of identical size, which allows for compact impactors to be designed at rather substantial flow rates and moderate pressure drops.Nearly all of the theoretical work, and much of the experimental work, has been performed on single-nozzle impactors. The results of single-nozzle impactor analysis are often applied to multiple-nozzle impactors, which are assumed to be a group of individual nozzles, each operating as though they were single nozzles. However, an important fact is often ignored: the interaction of flow from adjacent nozzles can change not only the fluid mechanics in the impaction region, but also the locations of the jet stagnation points, and the impaction characteristics of each nozzle.The effect of multiple nozzles on the particle collection characteristics of impactors has been studied by a few investigators. May (1964), Fletch et al. (1967), Friedrichs (1968), and Vaughan (1986) reported that the quantity of particles in deposits of nozzles in the first two stages of the Andersen multi-nozzle cascade impactor were not equal. The inner deposits appeared to contain fewer particles than the outer ones. However, Vaughan (1986) in addition showed that many of the deposits in the outer three rows were missing on the first stage, even though the outer deposits that were present were larger than the inner deposits.May (1964) conducted experiments and explained the phenomenon of smaller deposits near the center than near the edge. He noted that in Andersen cascade impactors the air issuing from the nozzles moves radially outward along the narrow channel between the nozzle plate and the impaction plate. This flow at 28.31min -1 created a pressure difference of about 1 mm water between the inner and outer sections of the channel. The effect was most pronounced in the first two stages, where the pressure drop across the nozzles was also about 1 mm water. Here, the flow velocities in the nozzles, and hence the deposits, were smallest at the center and increased toward the periphery of the impaction plate. since the pressure drop across the nozzles was the smallest at the center and a maximum at the periphery. This effect was negligible in the lower stages because of a larger pressure drop across the nozzles. According to May (1964), this effect could be eliminated by increasing the nozzle-to-impaction-plate distance to three nozzle diameters and improving the nozzle arrangement to allow air flow to escape to the periphery more easily."

Mar 1, 1992

By R. V. Ramani, J. Qin

"During the mining process, the insitu material is broken into different size ranges, from very, large pieces to very fine particles. Some of the fine particles become airborne. In underground coal mining, airborne respirable. dust is associated with health and safety of the miners: The amount and size distributions of airborne dust are important parameters to effective dust control measures. The design of underground mine experiments, including sampling procedures and sample analyses methods to determine these parameters are presented in this paper.. A total of fifteen continuous miner cuts were sampled. The amount of dust generated during the cutting process and the relationship between total and respirable airborne dust concentrations and amounts are examined.The amount of respirable dust airborne is on the average only. 0.016% of the respirable dust generated. On the average, 61% of the total .airborne dust measured is in the respirable size range. The amount of respirable airborne' is on the average 36% of the respirable size fraction in the total airborne dust. For equal proportion of rock and coal material cut, rock contributes about twice as much fines (<0.22 mm) as coal. Additional fundamental research is necessary to further the understanding of 'the airborne propensity of respirable dusts in mine atmospheres.INTRODUCTIONMining is a sequential process of breaking, gathering, loading, and transporting the in-situ .materials.' In underground coal mines, duet in both the non-respirable and respirable size ranges is generated and entrained in every phase of the process. Even though large amounts of dust particles' adhere to run-of-mine coals, part of the dust generated becomes airborne (Cheng and Zukovich, 1973). Studies have shown that bit type affects the amount of dust generated'(Evans and Pomeroy, 1966; Kurth et al., 1975; Roepke et al., 1976; Stecklein et al., 1982; and Khair and 'Reddy, 1986). Deep cutting can reduce airborne dust generation (Black and Schmidt, 1977 arid, Black et 1978). Mechanical properties of. coal seams are also important factors in dust generation. Laboratory studies have shown that Hardgrove Grindability Index (HGI) of the coal has a relationship with the amount of respirable. dust generated (Beafi and Ramani, 1979; Moore and Bise, 1984; and Moore, 1986). However, these relationships have not yet been validated with' data from the mines. The amount of dust airborne depends on a number of factors. Suppression of the airborne propensity of dust by water sprays is'widely practiced and is very effective. Water flow rate; pressure and configuration of water sprays have been identified as major factors affecting dust capture by sprays (Courtney and Cheng, 1977; Courtney et al., 1978; and Kissell et al., 1979). Ventilation is a very important means of controlling the dust level at the coal face (Jayaraman, 1977). According to a National Academy of Sciences study (1980), the mechanism of dust generation and the process by which the generated dust becomes airborne are complex and not yet completely understood coal seams are also important factors in dust generation. Laboratory studies have shown that Hardgrove Grindability Index (HGI) of the coal has a relationship with the amount of respirable dust generated (Beafi and Ramani, 1979; Moore and Bise, 1984; and Moore, 1986). However, these relationships have not yet been validated with data from the mines. The amount of dust airborne depends on a number of factors. Suppression of the airborne propensity of dust by water sprays is widely practiced and is very effective. Water flow rate; pressure and configuration of water sprays have been identified as major factors affecting dust capture by sprays (Courtney and Cheng, 1977; Courtney et al., 1978; and Kissell et al., 1979). Ventilation is a very important means of controlling the dust level at the coal face (Jayaraman, 1977). According to a National Academy of Sciences study (1980), the mechanism"

Jan 1, 1989

By W. G. Hopkins

The development of systems for location of miners who have become entrapped following a mine disaster has been one of the major research goals in the Bureau of Mines. This study details the preliminary development of such a system. Current technologies for locating trapped miners from the surface are either simple direction finders or time difference pulse systems that have accuracy limitations. Developing technologies using full vector field measurements at several receiving points are currently being studied. The necessity of measuring field strength with great accuracy can be a drawback in these systems. A system that operates with continuous wave radio signals, whose phase differences can be measured accurately even in weak signal conditions, greatly improves the location accuracy. A microcomputer would be used in conjunction with the system, to gather and manipulate the data to automatically pinpoint the location of the trapped miner. Comparison of this system with existing technology indicates a favorable accuracy/complexity ratio for the phase difference of arrival technique.

Jan 1, 2011

By Christopher Van Dyke, Knox Van Dyke, Lixin Wu, Jaime Gutierrez

"I. INTRODUCTION(SILICA, THE LUNG, INFLAMMATION, AND FIBROSIS)Inhalation of respirable-size silica (0. I to 5 µm in diameter) deposits the particles in the deep spaces of the Jung where oxygen is exchanged. The resulting pattern of inflammation is substantially different compared to that observed from other inhaled substances such as carbon, polystyrene titanium dioxide etc. 1 Following the inflammatory reaction the body attempts to isolate the damage by walling off the area via fibrosis. 2 The unique nature of the inflammatory response to silica makes it logical to infer that fibrosis is a later-stage manifestation of the initial inflammatory damage. In addition to the inflammation extensive lysis and cellular death particularly to macrophages and neutrophils, can occur, depending on the dose of silica.' The ingestion of significant amounts of silica by macrophages and neutrophils produces an inflammatory sequence which activates the lipoxygenase pathway of arachidonic acid metabolism and produces platelet activating factor (PAF) and leukotrienes (LT).4·5II. CALCIUM IONOPHORE MIMICS SILICA TOXICITY IN VITROPhagocytic cells exposed to silica in vitro produce PAF and LT. This response is reminiscent of phagocytic cells exposed to the calcium ionophore (A23 l 87) in the presence of ionic calcium.6-8 A23 l 87 forms a complex with free ionic calcium which passes through cellular membranes, thus transporting calcium inside the cell. The increased intracellular calcium concentration triggers the production of small amounts of prostaglandins large amounts of LT. PAF and. depending on dose cellular death (see Figure 1 ). Could silica cause LT production and cellular death by a similar mechanism? How could silica - an inert solid - act in a similar fashion as a soluble stimulant? Clearly the negative SiO2 and OH- surface of silica can bind calcium ions9 and therefore could theoretically act as a solid-state ionophore releasing bound calcium inside of cells following phagocytosis."

Jan 1, 1998

By Frank W. Sansom

This paper is one of a series of articles dealing with milling methods and costs at metal mines in the United States, written in accordance with an outline prepared by engineers of the United States Bureau of Mines and published by the bureau. The Netta mine and concentrator is the largest of the plants of the Eagle-Picher Lead Co, It is located in Ottawa County, in the extreme northeast corner of Oklahoma, and in what is known as the Tri-State zinc and lead mining district, embracing the northeast corner of Oklahoma, the southwest corner of Missouri, and the southeast corner of Kansas. A majority of the production comes from the Oklahoma section, with Kansas second, and Missouri third.

Jan 1, 1930

By Benjamin W. Haynes

As part of the first-order assessment of potential manganese nodule processing reject waste materials, the Bureau of Mines estimated the physical and chemical characteristics of reject waste materials that would be generated from each of five potential process flowsheets. These processes were chosen because of their economic and technical feasibility for first-generation nodule processing. A brief description of the five processes is given to show process inputs and outputs, The physical characteristics are predicted based on land-based laterite processing where applicable, and where no land-based analog exists, on the basis of process chemistry. The probable chemical characteristics such as element content and compound form are tabulated for each process for 16 elements: As, Ba, Be, Cd, Go, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, TI, and Zn. These elements were chosen based on their presence on the toxic substance list of priority pollutants, EP toxicity criteria, and major and minor elements of economic importance (Co, Fe, Mn, and Mo). Physical and chemical analyses as well as results of the EP toxicity test of one industrially supplied pilot plant reject waste material are presented.

Jan 1, 1982

By A. R. Rule

Research was done by the Bureau of Mines to determine the effect of a low-molecular-weight polymer on wet grinding of quartz, dolomite, and a copper ore. A 5-in ball mill equipped with a torque sensor for precise measurement of input energy was used for batch grinding tests. Grinding parameters were determined from size distribution data on the feed material and ground product. Zeta potential measurements were made to determine the effect of the polymer on the surface properties of the three materials, and a viscometer was used to measure the effect of the polymer on slurry viscosity. The addition of the polymer caused a sharp increase in the negative value of the zeta potential for all three materials, indicating that pronounced adsorption was taking place. At a constant slurry percent solids, addition of the polymer caused a similar reduction in slurry viscosity for each material. For quartz, dolomite, and the copper ore, grinding efficiency, as measured by kilogram of product per kilowatt hour passing a given screen size, was not affected by the addition of the polymer. However, the lowering in slurry viscosity caused by addi-tion of the polymer permits grinding at a higher slurry percent solids.

Jan 1, 1985

By L. E. Schultze

As part of the Bureau of Mines research program on recovering alumina from domestic resources, methods for extracting iron from aluminum sulfate solutions (obtained by leaching kaolinitic clay with dilute sulfuric ,acid) were investigated. In countercurrent extraction experiments at a l-gal/hr flow rate of aluminum sulfate leach liquor, the iron concentration &apos;was decreased from 1.4 g/l to 0.01 g/l after four stages of using a primary amine extractant. The iron-loaded amine solution was regenerated in five stages using 3[N] sulfuric acid or in four stages using 6[N] sulfuric acid. The aluminum sulfate solution obtained was suitable for the preparation of alumina meeting cell-grade standards of less than 0.01 pct iron.

Jan 1, 1979