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By Arthur L. Miller

Recent studies suggest that trace metals emitted by internal combustion engines are derived mainly from combustion of lubrication oil. This hypothesis was examined by investigation of the formation of particulate matter emitted from an internal combustion engine in the absence of fuel-derived soot. Emissions from a modified CAT 3304 diesel engine fueled with hydrogen gas were characterized. The role of organic carbon and metals from lubrication oil on particle formation was investigated under selected engine conditions. The engine produced exhaust aerosol with log normal-size distributions and particle concentrations between 105 and 101 cm-3 with geometric mean diameters from 18 to 31 nm. The particles contained organic carbon, little or no elemental carbon, and a much larger percentage of metals than particles from diesel engines. The maximum total carbon emission rate was estimated at 1.08 g h-1, which is much lower than the emission rate of the original diesel engine. There was also evidence that less volatile elements, such as iron, self-nucleated to form nanoparticles, some of which survive the coagulation process.

Jan 1, 2007

By E. D. Gardner

The mine of the Eureka Standard Consolidated dining Co. is at Dividend, Utah, in the Tintic mining district. It is operated under the same management and controlled by the Antic Standard Mining Co.; the two properties adjoin each other. The Eureka Standard is worked through a vertical shaft; the ore is mined by a stringer-set-and-fill method. One hundred and thirty men were employed in April 1933. The normal daily tonnage is 100 tons; the ore is shipped to the smelter at Garfield, Utah.

Jan 1, 1935

By G. S. Scott, L. D. Schmidt, J. A. KELLEY, E. L. FISH

One of the war problems with which the Bureau of Mines is concerned is to increase production of iron and steel , in which coke is one of the major factors . The output of byproduct coke for use in iron blast furnaces is insufficient and is being supplemented by coke from beehive ovens (figs . 1 , 2 , and 3) . Some difficulties that cause a reduction in iron output have been reported in the use of some of the beehive coke.6/ About 20 years have elapsed since beehive coke was made on a large scale , and many of the skilled operators of those days are no longer available . Furthermore , in many instances the quality of the coal supplied to the ovens has not been as good as formerly. The ash and sulfur contents are often abnormally high; and in other instances they vary greatly in amount, so that a nonuniform coke is produced . To assist operators to improve quality and yield of beehive coke , the Bureau of Mines equipped a truck as a field laboratory ( fig . 4 ) and sent the authors with it into the Pennsylvania beehive district . The truck contains necessary equipment for sampling and analyzing coke oven gases , measuring temperatures , screen - sizing coal, and float -and - sink testing coal . Coal specimens may be sent to the Pittsburgh laboratory for analysis . Beehive plants producing good coke were visited first to observe details of operation and to collect data on the operating process . These covered temperatures , analyses of the exit ( or trunnel) gases , and coal quality, and were to be utilized in searching for faults in plants not producing good - quality coke and to assist in improving such plants or their operation .

Dec 1, 1943

By Richard F. Hewlett

This Bureau of Mines report presents the computer programing methods and mathematics required to generate either random numbers or normal random numbers to be used for the construction of statistical probability models for simulating mineral deposits by Monte Carlo techniques . Theoretical frequency functions are evaluated as an illustration of simulation applications . Numerical and analytical methods of simulating and dissecting some complex frequency distributions are described .

Jan 1, 1964

By Alphonso Cornejo, Galen H. Clevenger

This bibliography was compiled in connection with an investigation of the Caron process for the treatment of manganese - silver ores , conducted by the T. S. Bureau of Mines in cooperation with the Netherlands East Indies Government . The object of this investigation was to develop a practicable method for treating the refractory manganese- silver ores found in these two countries . The results of the work will be published as a bulletin of the Bureau of Mines . This bibliography summarizes the available information on the subject previous to the investigative work embodied in the forthcoming bulletin, and may be useful to those metallurgists or others conducting work along this line .

Mar 1, 1923

By J. O. Winget

Phosphonic acid and iminodiacetic acid chelating resins were investigated to assess their potential as selective ion exchangers for separating lanthanide elements and yttrium . The affinity of phosphonic acid resin for lanthanides increases with increasing atomic number , and that of iminodiacetic acid resin for lanthanides increases with atomic number to a maximum for element 62 and then declines with atomic number throughout the remainder of the series . Elution sequences of the elements with mineral acid eluants corresponded favorably with equilibrium data , whereas the elution sequence obtained with chelating eluants was proportional to the relative values of the stability constants of the chelating agents with the lanthanides . Separation of lanthanide mixtures into groups of light and heavy elements with iminodiacetic acid resin appears feasible .

Jan 1, 1964

By Martin J. Gavin

The oil- shale studies of the Bureau of Mines , conducted in cooperation with the State of Colorado and the University of Utah , have for their primary purpose the determination of retorting and refining conditions most favorable for obtaining the highest yields of most satisfactory products . Oil shales , typical of the deposits in several States , are retorted in carefully controlled retorts of differe types , the conditions being varied in successive runs as the results indicate that improvement in the yield and quality of the products most desired may be expected . Each shale presents a somewhat different problem , for it has been found that different shales treated under similar conditions yield products of different natures , and also that the same shale will yield products of different natures when retorted under different conditions . Some shales apparently can not be made to yield , under any set of conditions , products of so high an order as are yielded by other shales . This indicates that the oil -yielding materials of certain shales differ in constitution and in their manner of breaking down when undergoing destructive distillation . Other shales appear to contain oil - yielding materials that resemble each other closely as regards chemical constitution , yet they require some. what different conditions of treatment , if products of similar nature are to be produced from each . In such cases the controlling factors seem to be the richness of the shale that is , its content of oil -yielding material and the physical and chemical nature of its mineral parts .

Mar 1, 1922

By F. C. Gregory

"The ""safety bonus"" in metal mining is a sum in addition to the regular wage, paid to foremen or bosses for keeping the accident rate down to a specified minimum. It has been used with success for some time by certain companies as a regular part of their safety work. It is desirable from the employer's point of view in that the desired results in accident reduction must be accomplished before the bonus is earned; and from the standpoint of the recipient, in that he receives a reward for the additional effort which he has put forth in order to earn the bonus.While this paper relates to the safety bonus as applied in the metal mining industry, the bonus system discussed herein will apply equal well to coal mining, oil-field work, and other mineral industries.Various estimates have been made as to the percentage of accidents that can be prevented through physical safeguards, adoption of safe working methods, and other safety measures which can be initiated and carried out wholly through the management or the safety department. This percentage will always be a vari¬able according to the local plant and conditions. But all who have been engaged in accident prevention agree that such work alone cannot bring the accident fre¬quency down to where it should be, and that it is very necessary to work directly with the workmen, in an effort to make each individual do his share in making the work safe. In this latter phase of the work, the boss who has immediate super¬vision of the men is the one who can do the most, since he is in daily and frequent contact with the men while they are at work. In the metal mines, the shift and stope bosses are the key men; in the oil fields, the ""tool-pushers"" or sub-foremen, and the same applies to all industries. So it becomes necessary to keep these sub-foremen constantly interested in accident prevention, both because they are in personal touch with the men and because they are responsible for production and hostile to any plan which they think will interfere with their output. In large organizations it is the shift boss who represents the company and its policies to the man on the job."

Jun 1, 1924

By C. Kenneth Eilerts

A method is described for controlling instability in finite-difference computations of liquid saturation near the borehole of a recovery well. Differences of pressure-and saturation-dependent variables are indexed offcenter, upstream and downstream alternately, to provide a stabilizing average. It was found that size of the time step could be increased by a factor of 4 without loss of numerical stability. Finite differences of the variables occur in a variety of relative numerical sizes and combinations. Those relationships of the differences that contribute to instability may be identified by the computing program in which they occur and modified to assist convergence of the computations and execution of the partial differential equations of liquid and gas flow.

Jan 1, 1971

By D. Bienstock

The Fischer-Tropsch synthesis is practicable in a reactor where the exothermic heat of reaction is removed by circulating large quantities of recycle gas through a catalyst bed of high-voids content. At an hourly space velocity of 1100, the feed gas, a mixture of 1.5 parts hydrogen to 1 of carbon monoxide, was converted 90 percent, producing hydrocarbons predominantly in the gasoline range. At these conditions a recycle-to-fresh gas ratio of 40:1 was enough to give excellent temperature control with a pressure drop of 1.5 p.s.i. per foot of bed using a steel catalyst in the form of lathe turnings. Steel parallel plates, although offering lower resistance to gasflow, were less reactive and less durable. INTRODUCTION The Federal Bureau of Mines has been engaged in a research and development program since 1944 on the synthesis of gasoline from coal. Gasification of coal with steam and oxygen to yield a synthesis gas--a mixture of carbon monoxide and hydrogen--is being investigated at Morgantown, W. Va.; and the synthesis of gasoline by catalytically reacting the carbon monoxide and hydrogen over iron by the Fischer-Tropsch reaction is being investigated at Bruceton, Pa.

Jan 1, 1960

By Thomas E. Popplewell

This paper is one of a series being prepared for and published by the United States Bureau of Mines describing the mining and treatment methods and costs obtained in sand and gravel plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By Hylton R. Brown

Although extensive research has been carried on to determine the factors affecting the explosibility of carbonaceous dusts, as much has been published on coal-dust and grain-dust explosions recent reports of loss of life and property in explosions if metal dusts emphasize the lack of information on the extent of the dust-explosion hazard in plants manufacturing or handling; aluminum, magnesium, or zinc powder, as well as other metal or mineral dusts. Early investigators believed that only the carbonaceous dusts formed explosive mixtures with air, and it was not until near the beginning of the present century that the explosibility of certain metal and mineral dusts was recognized generally. In his book, entitled "Fire and Explosion Risks," published in 1904, Von Schwartz called attention to such hazards. Many vague references to metallic-dust explosions are found in the literature, such as "a severe explosion of aluminum dust occurred in the Middle West several years ago," but very little information seems to be available on the extent of the hazard, the number of explosions, or the amount of loss caused by explosions in pants handling metallic or mineral dusts or powders other than those of a carbonaceous nature. A search of the records of insurance companies, rating bureaus, fire underwriters,and fire-protection associations as well as the files and records of Government agencies has been made to obtain authentic data on explosion losses. To indicate the extent of the hazard a summary of laboratory tests covering the explosibility of certain metal dusts, with brief reference to their uses and Methods of manufacture, and the data compiled from the information available on losses are presented in this publication.

Jan 1, 1941

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by The Bureau of Mines at its bauxite project in Saline and Pulaski Counties, Ark., has been given in Report of Investigations No. 4251. The factual data obtained during the project are reported in a series of Reports of Investigation beginning with No. 4251, of which this is the fourth. The data are accompanied by maps showing the location of holes drilled and the deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township map. The description of each half township is followed by a description of each deposit developed in that half township. The 14 half-township maps and 77 detail maps of the bauxite deposits in this series of reports give the locations and numbers of all the holes drilled on the project except the deep holes drilled to test the geophysical anomalies. The locations of those holes show on Figure 13 in Volume 1. The descriptions of the deposits developed are followed by complete detailed logs of the drill holes. Many of the widely spaced exploratory holes did not discover bauxite of minable thickness and grade. The pertinent information obtained from the widely spaced exploratory drill holes has been summarized and tabulated, and a table for each half township-is given with the discussion covering that area.

Jan 1, 1948

By A. C. Rice

This report describes a chemical process for preparing solutions of trivalent rare-earth chlorides from sulfate solutions obtained by treating bastnasite concentrate. The chief impurity in the final solution is cerium, and this element is less than 1 percent of the rare-earth oxides. The solution is used directly in the separation of rare-earth elements by ion-exchange methods. The attractive features of the process are that the chemicals are inexpensive and the steps few. The process starts with precipitating the rare-earth hydroxides from sulfate solutions with caustic soda. After the hydroxides are dried to oxidize the cerium, they are treated with dilute hydrochloric acid to dissolve away the trivalent rare-earth elements, leaving the tetravalent cerium. Details for controlling the leaching step are described. The process shortens older procedures by omitting the usual oxalate or double-sulfate-precipitation step.

Jan 1, 1959

By K. A. Johnson, H. F. Yancey

"INTRODUCTION Coals vary so widely in their burning characteristics that all coals prepared for domestic stoker use cannot be burned efficiently on every type of stoker. The overfeed stoker, a large number of which are in use in the Pacific Northwest, operates satisfactorily when burning low- to high-ash, noncaking bituminous or subbituminous coals, whereas on the clinkering-type, underfeed, bituminous stoker both caking and noncaking bituminous and subbituminous coals are burned, generally with ash contents below 12 percent and ash-softening temperatures between 1,800º and about 2,600º F. Because fly ash continues to be one of the most troublesome factors in domestic underfeed stokers, noncaking coals especially must be chosen carefully with respect to size composition, particularly as regards the exclusion of excessive fines. Their formation as a result of degradation in storage handling or because of crushing in .the stoker worm will increase the fly-ash nuisence.Bituminous and subbituminous coals with higher ash-softening temperatures and, often, higher ash contents have not been able to enter the domestic stoker-coal market in the Pacific northwest because clinkers are not formed readily during clinker-type underfeed-stoker burning, especially in mild weather, and because of the labor and attendant inconvenience required in handling larger volumes of ash. The work described in this report was undertaken to enable mines producing coals of the kind described to enter the stoker-coal markets. The anthracite stoker selected was one that conveys the refuse from the ash pit of the furnace and deposits it into one of two covered, dust-tight disposal cans."

Dec 1, 1945

By Walter R. Storms

This paper, which describes the mining methods of the Potash Co. of America in Eddy County, N. Mex., is one of a series being prepared by the Mining Branch, of the Bureau of Mines on mining practices and methods in various mining districts of the United States. 4, T. The mine and plant of Potash Co. of America are situated in sec. 20 S., R.. 30, E.,. N. M. P. M., about 22 miles by paved road northeast of Carlsbad (fig. 1). A spur line of the Atchison, Topeka & Santa Fe Railroad also connects the mine with Carlsbad.

Apr 1, 1948

By L. C. IlsLey

It is most unfortunate that a few must often suffer , and perhaps die , that many may benefit from a fuller appreciation of the dangers surrounding mining operations , and the proper use of safeguards designed to offset these dangers . This has been the case during the last few months in the anthracite field , where several explosions , resulting in burnings and fatalities , were undoubtedly caused by the use of defective or improperly assembled flame safety lamps . Had this same lack of understanding regarding the proper assembly of this safety device , and had the same indifference on the part of the user in keeping the lamps locked at all times and in proper condition , been permitted in a region where the coal dust was explosive , a terrible disaster would surely have resulted . In nearly every coal -mining country , including the United States , the Davy and Clanny type of lamp has been superseded , and rightly so , by some kind of bonneted lamp . Bonneted lamps , especially of the naphtha type , while much safer than the unbonneted , have more parts and need more care in assembling . For this reason the burden of responsibility for their being properly assembled rests with the lamp man ; therefore , it is extremely important that only competent , conscientious men be given this work .

Dec 1, 1921

By H. S. Caldwell

A magnesium-base incendiary alloy, containing about 20 percent cadmium, 4 percent aluminum, and 0.5 percent zinc, was investigated in a series of vacuum-distillation experiments to determine the feasibility of recovering magnesium and cadmium as refined metals. Alloys prepared in the laboratory and actual bomb-casing alloy were studied at temperatures of 550° to 750° C. and pressures of 100 to 150 microns. Simple distillation and fractional distillation methods were only partly effective in separating the cadmium and magnesium. They were separated satisfactorily, however, with a special vapor baffle designed to condense the metals selectively. Magnesium and cadmium products were 99 percent pure and together comprised 82 percent of the total condensate. About 17 percent of the condensate was intermediate-grade alloy that could be recycled with new charge and contained about 70 percent magnesium and 30 percent cadmium.

Jan 1, 1959

By R. V. Ramani

This report is volume 1 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation, and ventilation. This volume of the final report contains a statement of the purpose and scope of work of the Grant, and provides an overview of the Master Design Simulator with a brief description of each subsystem. Also included is a discussion of several areas of application for the simulator.

Jan 1, 1975

By X. Shi, K. S. Kaspnak

"The generation of free radicals from reactions of nickel (Il)-thiol complexes with molecular oxygen and model lipid hydroperoxides was investigated by electron spin resonance (ESR) utilizing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. Incubation of nickel (II) [Ni(II)) with cysteine in an aerobic environment generated hydroxyl (·OH) radical, which then reacted with cysteine to generate a carbon-centered alkyl ( · R) radical. Radical generation was inhibited under a nitrogen atmosphere. Model lipid hydroperoxides, cumene hydroperoxide, and I-butyl hydroperoxide enhanced the yield of these radicals and also generated an alkoxyl (·OR) radical. Radical yield decreased by approximately half under a nitrogen atmosphere. Although histidine did not cause radical formation in the reaction between Ni(II) and cumene hydroperoxide under aerobic conditions, the addition of histidine to a mixture containing Ni(ll), cysteine, and cumene hydroperoxide under the same experimental conditions increased the yield of · R radical but lowered the yield of ·OR and ·OH radical adducts. It thus appears that histidine caused the ·OH attack to be more site-specific. Similar results were obtained utilizing 1-butyl hydroperoxide. Penicillamine or N-acetylcysteine yielded similar results except that under aerobic conditions, reaction between Ni(ll) and N-acetylcysteine without hydroperoxide did not generate a significant concentration of free radicals. Under the same experimental conditions, cystine did not generate any detectable free radicals, suggesting an important role of the -SH group in Ni(II)-mediated free radical generation. The results indicate that free radical generation from the reaction of Ni(Il)-thiol complexes and molecular oxygen, and/or lipid hydroperoxides, may play an important role in the mechanism(s) of Ni(II) toxicity and carcinogenesis. INTRODUCTIONWhile nickel is a well-recognized carcinogen [l, 2]. the underlying biochemical mechanisms remain unclear (3, 4). Recent studies suggest that these mechanisms may involve oxidative DNA damage through free radicals, especially the hydroxyl (•OH) radical [5-13]. The mechanisms of nickel carcinogenicity and toxicity may also involve lipid peroxidation [14-21]. Unlike ferrous ion [Fe(II)], the Ni(II) cation itself does not directly react with 02, H2O2, or lipid hydroperoxides to generate free radicals [12, 21]. However, it has been reported that Ni(II) complexes with certain synthetic oligopeptides, e.g., tetraglycine or glycylglycylhistidine, make Ni(II) reactive with 02. This reaction results in transitory formation of Ni(III) and degradation of the organic ligand via free radical reactions [22]. Such Ni(II)-peptide complexes are also capable of reacting with H2O2 to produce oxygen free radicals [11, 12]. Although the cellular environ¬ment may not contain these particular peptide ligands that are known to render Ni(II) redox active in vitro, it does contain a variety of oligopeptides that are capable of forming Ni(II) complexes at physiological pH, and thus may facilitate Ni(II) redox activity in vivo. These oligopeptides include glutathione (y-L glutamylycysteinylglycine), carnosine (homocarnosine (y aminobutyryl-L-histidine), and anserine ( B-alany1-3-methyl-L-histidine)."

Nov 1, 1995