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By J. J. Baz-Dresch

"The Cannon Mine, a joint venture between Asamera Minerals (the operator) and Breakwater Resources, is located in the centre of Washington state at the eastern base of the Cascade Mountains. The mine complex is located three blocks south of the city limits of Wenatchee, part of an urban area with a total population of 47 000. The closest residence is 350 feet from the mine portal.The B-Neath zone is a narrow, high-grade, downward extension of the southern tail of the mine's main ore body, the B-North zone. It also underlies the northernmost portion of the B-West zone (Fig . I) . The ore is usually reasonably competent but completely surrounded by very weak rock consisting of shear zone and unsilicified sandstones and siltstones.The zone has maximum dimensions of 420 ft in thickness, 500 ft in length , and 200 ft in width . The economic reserves extend from the 70-ft elevation (elevation above sea level) to the 630-ft elevation and consist of about 1.3 million tons of geologic reserves (proven and probable) at an average grade of 0.33 ounces per ton.Acquisition and ExplorationInitial DiscoveryThe initial discovery of the B-Neath zone was made by Tenneco Minerals during July through September, 1984. Their 22-hole surface drilling program consisted of 18 200 ft of drilling. Tenneco Minerals had acquired the 91/2 acre lease from United Mining Corporation.Asamera Minerals subsequently purchased Tenneco's lease in July, 1985; Tenneco retained a royalty position which was later purchased by Echo Bay Mining.Follow-up drilling by Asamera Minerals consisted of both surface and underground drilling. Eight surface holes (7200 ft) were drilled commencing in December, 1985. Following evaluation of the geologic data, an access drift was driven on strike along the top of the ore zone on the 500 level. Diamond drilling from this platform consisted of 17 200 ft in 79 holes."

Jan 1, 1990

By Gunnar Nord

Introduction ??Atlas Copco has customers both amongst Miners and Contractors ??We believe that the contractor's approach to tunnelling is worthstudying ??For a tunnel contractor the incentive is speed as ?30 % of the costs are material related ?70 % of the cost are time related ?A tunnel contractor favours utilizing of the face ?A miner favours utilizing of the gear ??Statement; In mining, a long term average advance rate of more than 10 m / day can be achieved with the excavation techniques availabletoday

May 1, 2009

By S. Mostaghel, S. Nicol, M. Y. Solar

Once upon a time, the process engineer developing the design criteria for a new saprolite ferronickel smelter had it easy: most ores were around 2.5% Ni, with a Fe/Ni ratio of 4 to 5 and a SiO2/MgO ratio of about 1.6; to use the French word: garnierites. The ferronickel grade selected was the conventional 20 to 25% Ni and the impurity levels could be predicted from well established [C], [Cr] and [Si] vs (FeO) graphs. However the process engineer can no longer depend on statistics to design smelters: Ni grades are decreasing while the goethite contents are increasing; SiO2/MgO ratios vary from 1 to 3; and Al2O3 concentrations are reaching levels that cannot be ignored. Mechanistic models must be developed to select or predict essential parameters such as kiln and furnace reductions, ferronickel grade, slag losses, metal and slag liquidus, operating temperatures, etc. But these models must be simplified so that they can be used on a routine basis; and they must be calibrated against a wide range of commercial operations in order to yield the most realistic predictions possible. The present paper proposes one possible approach, using FactSage as a basic source of thermodynamic data. The predictions thus obtained are compared to actual performance for two well documented operations, as well as to the predictions made with other tools that might be more accessible.

Jan 1, 2014

By Derek V. Ellis, Jack L. Littlepage

"Marine ecosystem effects ar1smg from the discharge of man-generated wastes to the sea can be schematized as: acute poisoning, chronic poisoning, enrichment, suffocation, temperature effects, salinity effects, toxin bio-concentration, changed production rates and changed species equilibria. A professionally designed site-specific monitoring program to check for such effects can not only safeguard the marine ecosystem from degradation, but it can also protect the industry involved from unanticipated remedial action after expensive construction has been undertaken. Monitoring programs should consist of three steps. Step 1 is an ecosystem survey which should be undertaken prior to final design of the discharge system and submission of applications for permission to discharge, because there can be considerable cost savings in obtaining information at an early stage in development. Step 2 involves location of the effluent field at the time of starting discharge, and analysing its dispersal behaviour. Step 3 consists of ecosystem monitoring with sampling stations and specific tests based on the accumulated prior information."

Jan 1, 1972

By Joe Zhou

"Mineralogical characterization and metallurgical extraction of silver is challenging due to its complex mineralogy and chemistry. Over 200 Ag-bearing minerals have been identified and a silver-rich ore body would typically contain 5 to 10 different silver minerals. Silver can occur not only as discrete microscopic (visible) silver minerals but also as submicroscopic (invisible) silver in other minerals. During processing, silver may form passivation compounds such as silver hydroxide, silver sulphide, jarosite-like silver sulphate, silver halide or silver cyanide precipitate, all of which may negatively impact on silver extraction. Knowing the deportment of silver in the ore and its metallurgical products is important in flowsheet design and plant optimization. This paper begins with the classification of silver ores and minerals and a review of processing techniques, and focuses on the major mineralogical factors to explain why and how these factors affect silver extraction. Case studies are provided to demonstrate the application of silver process mineralogy in flowsheet design and plant optimization.INTRODUCTIONSilver was known to and utilized by mankind since ancient time. Actually, it was one of the earliest metals discovered and utilized by mankind after gold and copper.Silver is the whitest metallic element. It is rare, strong, corrosion resistant, and unaffected by moisture, vegetable acids, or alkalis. Silver is also resonant, moldable, malleable, and possesses the highest thermal and electric conductivity of any substance. The chemical symbol for silver is Ag, from the Latin argentum, which means white and shining. Although silver does not react with many chemicals, it does react with sulfur, which is always present in air at trace amounts. The reaction causes silver to tarnish, and consequently it must be polished periodically to retain its luster.Silver possesses many special physical characteristics and qualities that make it useful to a variety of industries. The photography industry is the biggest user of silver compounds. Silver forms the most light-sensitive halide salts, which are essential to developing highquality photographic prints. Silver also has the highest electrical conductivity per unit volume of any metal, including copper, so it is used extensively in electronics."

Jan 1, 2010

By B. Tonn, F. Kröger

"The continued development in engine technology is leading to an augmentation in power density which steadily elevates the requirements for thermally and thermo-mechanically highly loaded components such as cylinder heads and pistons. Due to these high performance requirements conventionally applied Al-Si alloys have reached their application limits, since their mechanical properties deteriorate quickly under the influence of heat. Improved applicability is given by Al-Cu-based casting alloys which have a superior high-temperature strength than Al-Si alloys. Since Al-Cu alloys exhibit insufficient casting characteristics, especially regarding hot tearing susceptibility and increased tendency for porosity, it is currently not possible to cast geometrically complex components in robust permanent mold casting processes. The further development of Al-Cu alloys is aimed at finding an optimum between improved castability while high-temperature strength and thermal conductivity are not deteriorated. It is known that a high amount of eutectic reduces the hot tearing susceptibility of an alloy, but it reduces thermal conductivity at the same time. In this paper it will be presented how the conflicting objectives – improved high-temperature strength, good thermal conductivity and reduced hot tearing susceptibility – can be brought together to develop an optimized Al-Cu alloy for application in permanent mold casting.INTRODUCTION At the beginning of the 21st century car, engine blocks were primarily made of gray cast iron (GJL). Less than half a decade later, the choice of material had shifted towards lightweight materials. Ever since, the car engine manufacturing is dominated by aluminum-based alloys. The weight of car engine blocks could thus be reduced by around 50% due to the lower specific weight of aluminum alloys compared to gray cast iron. Furthermore, the high thermal conductivity of aluminum alloys allowed a reduction of complex cooling channel systems and thereby promoted the advancement of this material group. The further development in engine technology leads to an augmentation in power density which elevates the requirements for thermally and thermo-mechanically highly loaded components. For example, in diesel-powered car engines the upper required limits can reach an ignition pressure as high as 230 bar and gas temperatures of up to 1000°C. Thereby, thermal loads can cause high alternating thermal stresses (Grzincic, 2003) which can effectively be reduced by providing high thermal conductivity."

Jan 1, 2017

By Marcondes Lima Costa

Abstract-The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes, and the younger ones on widespread hilly to flat lowlands. Both types show complete or truncated profiles, generally covered by deep yellow to brown topsoils. The mature laterite profiles contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic profiles. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature profiles. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epigenetic alteration types. The lateritic profiles show a well-developed ore zonation which is related to specific lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold; and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire profiles include titanium (as ilmenite and anatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly as ilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic profiles, has led to the formation of high-grade kaolin and refractory bauxites. The laterites in the Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By Marcondes Lima Costa

The Amazon region is characterized by the development of deep chemical weathering represented by widespread lateritic covers and soils. Two distinct periods of laterite formation can be distinguished: mature laterites from the Eocene-Oligocene (and locally from the end of the Cretaceous), and immature laterites from the Pleistocene. The older laterites occur on plateau landscapes,and the younger ones on widespread hilly to ?at lowlands. Both types show complete or truncated pro?les, generally covered by deep yellow to brown topsoils. The mature laterite pro?les contain high concentrations of gibbsite and/or aluminum phosphate, whereas the immature ones are poor in these minerals. The Amazon region is rich in mineral deposits related to lateritic pro?les. Some mineral deposits are of primary origin but were concentrated to economic grades by lateritic processes. The most important ore deposits are of iron, aluminum (bauxite), kaolin, manganese, gold, nickel, copper and phosphate. These are mainly related to mature pro?les. The wide spectrum of ore deposits and mineralogical and geochemical complexity of the Amazon laterites has been promoted by: (1) the prevalence of ideal conditions for laterite formation throughout much of the Tertiary; (2) the presence of varied basement lithologies due to contrasting geological environments; and (3) a variety of epi-genetic alteration types. The lateritic pro?les show a well-developed ore zonation which is related to speci?c lateritic horizons. Iron and gold deposits occur in the ferruginous horizon, which is nearest the surface; the central aluminous horizon hosts bauxites, aluminum phosphate, strontium and gold;and the lower clayey horizon contains deposits of manganese, nickel, copper and kaolin. Resistate phases which residually accumulate throughout entire pro?les include titanium (as ilmenite andanatase), chromium (as chromite), tin (as cassiterite), yttrium (as xenotime), and niobium (mainly asilmenorutile). Epigenetic alteration, caused by swamp environments developed above truncated lateritic pro?les, has led to the formation of high-grade kaolin and refractory bauxites. The laterites inthe Amazon region contain most of all known kinds of ore mineralization related to laterite processes.

Jan 1, 1997

By H. H. Bleakney

The merit of reduction-in-area as a criterion of quality in metals is shown to lie in its influence on breaking stress, but the virtue of elongation is not easy to find. In order to assess the value of elongation, either as a measure of quality or as a guide to design, it will be necessary to separate the overall de-formation occurring in tension tests from the localized deformation associated with localized reduction in area. The obstacles to a successful solution of this problem have been shown to be more formidable than is generally appreciated, and a new solution to the problem has been suggested. This solution involves a de-vice by which an electric circuit is broken when the particular value of strain is reached that is to be taken as the point of separation between general and localized deformation. The report presents results from a number of tests on both low-carbon and alloy steels. These results indicate that the selected criterion of separation is accurately identified by the proposed method; that it

Jan 1, 1962

By R. E. Michelutti

"The Sudbury area environment became drastically altered commencing in 1871 with lumbering, repeated fires and early open roasting operations from 1887 to 1929. These combined factors had such a pronounced effect that approximately 24 square miles were totally denuded of any vegetation and 87 square miles were semi-barren to somewhat stressed.The two nickel producing companies in the area have reduced the sulphur dioxide emissions considerably over the years. Falconbridge Limited, alone, reduced sulphur dioxide emissions by 77% from 1971 to 1984.These reductions have resulted in improvements to the air, soil, lake and vegetation quality in the Sudbury area.INTRODUCTIONThe Sudbury area environment became drastically altered commencing in the 1870's with lumbering, repeated fires and early open roasting operations from 1888 to 1929. These combined factors had such a pronounced effect on the Sudbury environment that approximately 24 square miles (64 sq. km.) were totally denuded of any vegetation and 87 square miles (225 sq. km.) were semi-barren.Over the years, the Sudbury area environment has improved considerably. This has been due to emission cutbacks by both Inco Metals and Falconbridge Limited, coupled with industry, government and community reclamation programs. Before the improvements are discussed, a better understanding of the historical degradation is required."

Jan 1, 1986

By G. M. Ritcey, K. E. Haque, S. H. Lucas

"Laboratory-scale hydrochloric acid leach tests were conducted on an Elliot Lake uranium ore. Hydrochloric acid leaches without an oxidant or with molecular oxygen (i.e., air or pure oxygen gas) as an oxidant favoured uranium and radium extractions. Conditions for maximum uranium, thorium and radium extractions with hydrochloric acid in the presence of sodium chlorate were determined. The highest extractions of uranium (96%), thorium (81%) and radium (91%) were obtained using a mixture of 44.0 kg HCI and 2.5 kg NaCIOJ per tonne of ore at 75°C with 18 hours ' retention.Flowsheets for two-stage leaching are proposed. The residues obtained from the second-stage leach contain uranium (0.002%), thorium (0.006%) and radium (15 to 20 pCi/g). Tailings of this nature are considered suitable for mine backfill, and, if pyrite is removed, suitable for surfacedisposal.IntroductionThe nuclear energy industry forecasts an increasing demand for uranium. This increasing demand requires not only largescale mining and processing of conventional and complex uranium ores, but also leads to the consideration of new and nonconventional sources of uranium, e.g., black shales, phosphate rocks, granite, sea water and fossil-fuel ash.Sulphuric acid leaching is the most widely used process to extract uranium from the ore(l). The leach liquor is separated from the solids (tailings), purified, concentrated in various intermediate stages, and finally a semi-purified product, yellow cake (80-85070 U30 8) , is precipitated. The tailings, which constitute nearly 98% of the total bulk of most ores, are usually discarded in surface disposal areas.The Elliot Lake region of Ontario is one of the major uranium producing areas in Canada. The principal uranium minerals are brannerite and uraninite, present as microscopic grains in the matrix of quartz-pebble conglomerates. The average grade is between 0.10 and 0.15% UPs. Up to 6.5% pyrite is also present in the conglomerates. Because pyrite is less reactive toward sulphuric acid leaching, almost all the pyrite goes into the tailings and eventually into' the disposal sites."

Jan 1, 1980

By G. M. Ritcey, K. E. Haque, S. H. Lucas

"Laboratory-scale hydrochloric acid leach tests were conducted on an Elliot Lake uranium ore. Hydrochloric acid leaches without an oxidant or with molecular oxygen (i.e., air or pure oxygen gas) as an oxidant favoured uranium and radium extractions. Conditions for maximum uranium, thorium and radium extractions with hydrochloric acid in the presence of sodium chlorate were determined. The highest extractions of uranium (96%), thorium (81%) and radium (91%) were obtained using a mixture of 44.0 kg HCI and 2.5 kg NaCIOJ per tonne of ore at 75°C with 18 hours ' retention.Flowsheets for two-stage leaching are proposed. The residues obtained from the second-stage leach contain uranium (0.002%), thorium (0.006%) and radium (15 to 20 pCi/g). Tailings of this nature are considered suitable for mine backfill, and, if pyrite is removed, suitable for surface disposal.IntroductionThe nuclear energy industry forecasts an increasing demand for uranium. This increasing demand requires not only largescale mining and processing of conventional and complex uranium ores, but also leads to the consideration of new and nonconventional sources of uranium, e.g., black shales, phosphate rocks, granite, sea water and fossil-fuel ash."

Jan 1, 1980

By Mehmet Canbazoglu, Kaarlo Haavanlammi, Hannu Laitala

Cobalt is currently a critical metal because of the increasing number of electrical vehicles forecast for production. Copper and zinc are base metals that are used in many everyday applications, including vehicle production. Eti Bakir Co. Mazidagi Phosphate Plants in the Mazidagi district of Mardin, Turkey is a multi-product facility that produces cobalt, copper, and zinc, as well as fertilizers, from the roaster calcine. Roaster off gas is treated in a sulfuric acid plant (SAP) and the acid itself is utilized in fertilizer production. The comminution circuit, roaster, SAP, and calcine leaching process were developed by Outotec and integrated with the fertilizer production process implemented by Eti Bakir A.Ş. This paper describes the hydrometallurgical calcine leaching process used at the plant, with a focus on the oxidative pressure leaching of the cobalt, zinc, and copper-containing calcine. The cold and hot commissioning phases of the pressure leaching autoclave start-up are discussed together with experiences from the ramp-up period. The production processes of the copper cathode and cobalt and zinc-containing salts are also presented together with some of the plant’s operating parameters. INTRODUCTION The ETI Bakir A.S. fertilizer plant, Turkey, is located in Mardin Province near the border with Syria, (Figure 1). The leaching plant project was started in 2012. The purpose of the plant is to separate the valuable metals from the calcine produced by the pyrite roasters, which are used to produce a SO2 containing gas for the new sulfuric acid plant. Fertilizer production requires sulfuric acid, and for this reason a sulfuric acid plant was built; customer already had access to pyrite concentrate, which is used as the roaster feed. During the engineering phase of the roaster and acid plants it was noticed that the roasted calcine contained considerable amounts of valuable metals like cobalt, copper, and zinc. To recover these metals, a calcine leaching process was developed at the Outotec Research Center in Pori, Finland. The main process connections of the Mazidagi site are shown in Figure 2.

Jan 1, 2019

By E. Amini

"While methods exist to allow the simulation and optimization of existing flotation operations, there is a deficit in the ability to predict the performance of a new ore type pre-processing. A laboratory scale batch flotation testing methodology has been developed to assess the flotation potential of ores (known as the JK Floatability Index or JKFI). Previous work conducted by Alexander and Collins (2008) showed that the test could be used to predict full scale results in base metal ores. In this work, JKFI tests were applied to three different types of ore and one blend from a greenfields gold deposit to show the test applicability to flotation of precious metals. The results from the JKFI test on one ore type were then used to predict the response of all ore types (including the blend). To validate the predicted kinetic parameters, a comprehensive survey was performed on a pilot plant where each of ore types was processed in the circuit. An acceptable agreement was found between the experimental recoveries and predicted recoveries which indicate the potential of this method for use in predicting the flotation response of an ore.INTRODUCTIONOver 100 years, flotation has been considered an efficient method to concentrate different types of sulphide and oxide minerals and coal. Thus, numerous research studies have been undertaken to find an appropriate model to predict the behaviour of particles in flotation circuits (Barnwal et. al., 2006; Bascur and Herbst, 1983; Cecile and Villeneuve, 1991; Deng et. al., 1996; Zheng et. al., 2006). Most methods are based on the ore flotation response in an industrial plant which is expensive and time consuming to characterise. It is difficult to reliably predict flotation response for new types of ores in industrial scale plants.The floatability component modelling (FCM) approach, developed within the Australian Minerals Industry Research Association (AMIRA) P9 project, has been used to derive models of operating flotation plants for the purpose of simulation and optimisation (Alexander and Morrison, 1998; Alexander et. al., 2000; Varadi, 2006). This approach has been applied at a large number of operating sites treating a wide variety of ores. The approach requires metallurgical surveys to be undertaken in conjunction with batch flotation tests and cell characterisation. This allows ore and machine parameters to be derived, which are then used in the P9 Flotation Model. The development of a FCM generally requires a large commitment of resources and time. While there has been significant support of this approach in industry, the FCM approach is limited to ores already being processed (Runge, 2004; Wightman, 2006)."

Jan 1, 2009

By Heidi Beers

Teijin Limited ? Global technology-driven group operating in six main fields Advanced fibers and composites business group Healthcare business group Trading and retail business group IT business group New business development group Electronic materials and performance polymer products business group ? Listed on Tokyo and Osaka stock exchanges ? 150 companies and around 17,000 employees worldwide ? Consolidated sales of USD 9.1 billion*

Aug 1, 2013

By Keila Gonçalves, Aline Tavares, Danielly Couto

"The sulphide copper deposits from the Carajás area (North region of Brazil) were generated by the percolation of hydrothermal fluids in volcanic and granitic rock and are denominated as IOCG deposits (iron oxide copper-gold deposits). During these hydrothermal events a wide variety of gangue minerals such as amphiboles, biotite and fluorite were formed. These gangue minerals are enriched in fluorine and chlorine which are deleterious elements in the copper concentrate. Chalcopyrite and bornite are the main copper-bearing minerals and they can occur in veins, in brecchia or disseminated in gangue.The study, which included bench scale flotation tests and minipilot plant tests was aimed at improving the fluorine rejection in the flotation process during the flowsheet design for one of these Carajás sulphide copper deposit. All of the study was supported by quantitative mineralogical techniques such as QEMSCAN and the use of a scanning electron microscope (SEM).This paper describes and discusses the results obtained in the metallurgical tests and emphasizes the importance of the quantitative mineralogical characterization during the process conditions optimization and flowsheet design.INTRODUCTIONIron oxide copper-gold (IOCG) deposits encompass a wide spectrum of sulphide-deficient low-Ti magnetite and/or hematite ore bodies of hydrothermal origin and normally have important copper sulphide reserves. In the Carajás mineral province, located at the southeast part of the Amazon Craton in Pará State (Brazil), there is a variety of world-class (>200 million tonnes) Fe-oxide Cu-Au deposits (e.g. Salobo, Cristalino and Sossego), whose genesis has been assigned to hydrothermal fluid percolation in volcanic and granitic rocks. Figure 1 displays the location of the Carajás area.The hydrothermal thermal fluid composition was extremely variable. It may have contained gases, salts (brine) and metals. The metals were carried as various complexes and it is thought to have involved sulphur, chlorine and fluorine containing species. This resulted in some minerals formed during the hydrothermal alteration having high fluorine and chlorine contents. These elements result in smelter penalties in a copper concentrate because they cause the smelter off-gases to be more corrosive."

Jan 1, 2011

By Mani Manimaran, Inna Dymov, Mariam Melashvili, Chris Fleming, Joe O’Day

This paper presents experimental evidence that supports the use of bromine/bromide as a potential alternative to conventional cyanidation for gold leaching. The study evaluated a brominebased lixiviant, Stabilized Bromine, with considerably lower vapour pressure than liquid bromine. Using a rotating device, the rate of gold dissolution was determined at various concentrations of this reagent. The reactivity of pure pyrite, arsenopyrite and chalcopyrite minerals was also evaluated in stabilized bromine reagent. Furthermore, bromine leaching of gold in a number of gold bearing ores was undertaken. Results showed that significantly higher gold recovery can be achieved with bromine than with cyanide when leaching gold encapsulated in sulphides, but bromine consumption was high owing to simultaneous oxidation of the sulphides. The greatest promise for the bromine leach process was with oxidized gold ores. The recovery of gold from oxide ores with bromine was comparable to that achievable with cyanide and bromine consumption was reasonable when leaching was conducted at a near neutral pH of ~6. In the case of oxidized gold ores containing copper mineralization, it is possible that bromine consumption may be lower than cyanide consumption, since there is evidence to suggest that bromine is less reactive than cyanide with copper minerals.

Jan 1, 2014

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By Stephen L. Chryssoulis, Daniela Venter, Stamen Dimov

"Comparative surface analysis of floated and rejected free gold grains from a number of full scale benefication plants and from pilot plant testwork, has shown silver (the most common impurity in gold) and sulphur invariably in greater concentration on floated gold grains, implying that they assisted gold flotation (gold activators). Collector loading measurements on individual gold grains from concentrates of staged rougher flotation tests on a cyclone U/F product of a pyritic gold ore, revealed first progressively lower concentrations of the collector monomer on gold from each follow-up concentrate and secondly a direct proportionality between the surface concentration of silver and the collector monomer. These two observations leave no doubt that silver activates gold and that collector monomers play a significant, previously not fully recognized role in gold flotation.INTRODUCTIONGold to some degree is naturally floatable in industrial systems, which means that it can be recovered without collector addition (Marsden and House, 1992). This is due to the adsorption of hydrocarbons and deposition of sulphur, which are dependent on the metallic properties of gold, particularly its high electrical conductivity, which allows surface electrochemical reactions to occur catalytically and selectively. Cyclic voltammetry has shown that gold can be rendered hydrophobic by deposition of a surface layer of sulphur (Sº) from S2- and HS- solutions (Walker et al., 1984). Twenty monolayers of sulphur were required to produce a hydrophobic gold surface.However, no sulphide flotation plant relies solely on the natural floatability of gold for its recovery. Gold hydrophobicity is enhanced by the addition of flotation collectors such as xanthates (X), dithiophosphates (DTP), dithiophosphinates (DTPI), mercaptobenzothiolates (MBC) etc., as used in sulphide mineral flotation (Dekok, 1973: Adams et al., 1986). The mechanism invoked in enhancing the hydrophobicity of pure gold with the aforementioned four groups of collectors is similar to that of pyrite, whereby collector anions are oxidized at the gold surface to form dimers (Groot, 1987; Marsden and House, 1992; Basilio et al., 1992) As an example, xanthate ions are oxidized at the gold surface to form the neutral dimer dixanthogen (X2):"

Jan 1, 2003

By Eugene Nel, Johan Theron, Chris Martin, Hans Raabe

"Impala Platinum Limited is the world’s second largest platinum producer, producing more than 1.7 million ounces of the precious metal last year, much of this from the UG-2 reef located in the Bushveld Complex, South Africa. As part of Impala’s ongoing expansion programme, tonnage through their principal UG-2 processing facility, near Rustenburg, was increased 40% in 2001.To accommodate the increased throughput, the role of the existing primary mills was converted from conventional semi-autogenous grinding units, to attrition and selective grinding units, operating in fully autogenous mode. The finer chromite and coarser silicate components in the mill discharge are then separated by screening and processed in dedicated circuits downstream. This way, the need to spend considerable capital to increase primary grinding capacity was averted.In the last year, considerable work has been conducted to evaluate and optimise the two downstream circuits. This has involved an optimisation programme of sampling and diagnostic flotation testing, supported with QemSCAN analysis. This paper will describe the operation of the new circuit. It will also describe some of the more novel aspects and interesting findings from the optimisation programme.INTRODUCTIONThe South African platinum industry is the world’s largest producer of platinum and the world’s second largest producer of palladium. Located in a wide area north of Johannesburg, the industry mines ores from the Bushveld Complex, one of the world’s great mineral treasure chests, containing over 70 percent of the world’s platinum, as well as extensive reserves of the other PGE (platinum group elements), chrome, manganese and vanadium. The industry employs about 180,000 people in, predominantly, underground mines, which together form an almost unbroken circle of mining operations 200 km in diameter."

Jan 1, 2004