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By Gurupraveen Ramanathan

Shallow-dipping orebodies (45°–60° dip) present significant challenges for underground longhole stoping, particularly due to limited gravity flow, drill misalignment near the footwall, increased potential for dilution from hanging wall overbreak, and deviation from drill string sagging at shallow angles. These geometrical and operational constraints often lead to unblasted ore wedges and excessive overbreak when standard practices are applied. This study develops a structured, data-driven framework to optimize longhole stoping in such conditions by integrating five key focus areas: (1) mining method selection, (2) stope and drift design, (3) drill and blast optimization, (4) equipment selection, and (5) performance evaluation. The suitability of longitudinal longhole stoping was validated for narrow vein geometries using orebody analytics and prior case studies. Geometric modeling was employed to determine optimal stope height (15–20 m) and stope width (1.5–2.5 m), with drift widths adjusted based on orebody dip to maintain drill access and minimize unbroken ore. Drill and blast design emphasized sequential blasting over multi-ring methods to improve void control, reduce wall damage, and enhance fragmentation. Specific burden and spacing guidelines (e.g., 1.8–2.3 m burden; 2.5–3.0 m spacing) were applied based on stope width and dip angle, and patterns were selected based on geometry—dice-5 for narrow stopes, and 3-hole rows for wider stopes. Drill rigs—including top hammer and ITH models from Sandvik, Epiroc, Boart Longyear and CMAC-Thyssen—were evaluated for compatibility with drift dimensions and alignment accuracy. Equipment was matched based on dip, drift width, and the ability to access the footwall at shallow angles. Sensitivity analysis quantified how changes in geometry, drilling accuracy, and blast design affect ore recovery, dilution, and operating cash flow. Results show that tailored drift and stope geometries, combined with proper blasting and rig selection, can boost ore recovery to over 95% and reduce dilution to below 5% in optimal conditions. This methodology offers a practical and economically optimized solution for shallow-dip mining scenarios.

May 4, 2025

By I. Southern, S. Kelebek

"Smelting furnace bricks contain significant quantity of base metals trapped in refractory material. A series of flotation tests were carried out on samples of old bricks from Sudbury area to examine upgrading behaviour for recycling purposes. Depending on the grind size used nickel recoveries varied from 60 to 90.6% with corresponding grades of 20% and 14.7%Ni. There is a trade-off between nickel and copper. The nickel has responded well to fine grinding, however, the copper recovery suffered from it. Mineralogical characteristics and flotation behaviour of the brick material are discussed in reference to those from the primary ore. INTRODUCTIONMineral processing is well recognized as a mature technology not only for the mining industry, but also for the environmental industry for the purpose of remediation and recycling. Materials available for recycling are usually the products of many years ago. There are multiple stake holders in this area. In general, when the processing results in a product that can be reused or sold, the company carrying out the remediation makes a profit, while the regulators and the public are pleased due to a cleaner environment. From these points of view, there have been many papers published over the years on various mineral processing techniques applied to separation of many different materials including from mining and metallurgical industries (Wilson et al., 1994; Tsunekawa et al., 2005; Saikia et al., 2012).Flotation may be viewed as the backbone of the mining and metallurgical industry since its invention for separation of solids from one another almost a century ago. It is capable of recovering a variety of finely divided different solids following their liberation from each other. Its versatility and highly competitive nature in terms of cost per tonne of material processed, accounts for its occasional uses in the environment engineering area. In the mining industry, flotation is the standard method used for the sulphide ores. It can be applied as a bulk flotation and/or differential flotation. Bulk flotation, which refers to co-flotation of several components from their source, is most suitable for environmental cleanup objectives. Desulphurisation of various plant tailings is a typical example of this (Benzazzoua et al., 2000)."

Jan 1, 2012

By Cris Sideco

This paper describes the concentration processes of the Sullivan. Concentrator, including crushing , transportation, sink-float, grinding , flotation and dewatering. Handling of hot muck has had a deleterious effect on most of the processes, resulting in significant operating problems and poorer metallurgy. These problems are described -in detail. THE SULLIVAN CONCENTRATOR is situated in Kimberley, high up in the Purcell Range of the Selkirk Mountains, at an elevation of 3,600 feet, approximately 4 miles from the Sullivan Mine (see Fig. 1). The original plant went on stream on August 23, 1923 at a designed capacity of 2,500 tons per day. This has been increased in stages to its present rated capacity of 11,000 tons per day. The latest stage was in 1949, when several major projects, including the underground crushing plant, the sink-float plant and the installation of a rod mill, were completed. Some 112,800,000 tons of ore have been treated in this concentrator to November 1975. The plant started on a 48-hour/ week schedule, but was reduced to 44 hours/week in October 1946 and down to 40 hours/week by the end of 1949. Except for a 6-month period in 1952 when the mill operated continuously, the 40-hour/week, Monday to Friday schedule was in effect.

Jan 1, 1977

By H. C. Cooke

This paper will discuss two comparatively unrelated subjects; first, a general review of the advances made at the more important properties in the last year; and second, a statement of the conditions controlling the deposition of the copper ores in the Rouyn area, as determined by last summer's field work. FIRST PART Development has been very rapid since I stood before the Institute one year ago to discuss this same subject. Then, there were many properties on which gold had been discovered, any of which might develop into a mine. Further work has eliminated the most of them as possible mines, or at least has shown that before they can attain that status further discoveries must be made on them. Then, all gold veins held forth much the same promise; now the indications are that one particular type of gold vein is of greater prospective value than others. Then, all eyes were turned toward gold as the metal of prime economic importance; now copper has taken the centre of the stage, and gold is distinctly in the background.

Jan 1, 1926

By T. J. Wells

THE blast furnace is the base of the steel industry, since there is no commercially practical way of converting iron ore directly into steel. In three hundred years, the blast furnace has developed from a small unit using charcoal as fuel and producing about one ton of iron in twenty-four hours to a furnace making upwards of 1,500 tons a day. The principle of the blast furnace is briefly this: A descending column of stock, consisting of ore, fuel, and flux, is met by an ascending stream of gases, consisting in part of gases formed by the combustion of the fuel and in part of pre-heated air which is blown into the lower part of the furnace. The flux combines with the impurities in the ore and the ash in the fuel to form slag, which is drawn off as liquid.

Jan 1, 1943

By G. Beckstead, L. F. Sawatsky, R. Nutbrown, D. Long, G. Gould

"This paper presents a case study for optimizing water management at Gregg River Coal Mine located near Hinton, Alberta. The optimization study was derived based on a review and assessment of existing management practices and plans for future operation and final reclamation. A proactive water management strategy was developed to assist mine staff in adopting a rational, environmentally sound, and economical approach to water management. A plan was developed to provide for safe operation, self-sustaining operation, low maintenance, minimum negative environmental impacts, and anticipation of future needs for existing and future operations. A plan for final reclamation drainage was developed including establishment of effective, sustainable, and maintenance-free water management systems. The study demonstrated the importance and benefits of a proactive approach for integrated mine water management. This approach is recommended for other similar mine operations because it will improve environmental compliance and reduce costs of water management. IntroductionGregg River Resources Ltd. (GRRL) operates an open pit coal mine on the eastern slopes of the Rocky Mountains, located about 45 km south of Hinton, Alberta. GRRL opened the mine in 1982 and expects to continue operations after Year 2000. GRRL has progressively reclaimed the disturbed area and expects to complete mine-land reclamation shortly after mining in the area is complete. The existing disturbed area and reclaimed area covers approximately 9.5 km2 and will expand to about 10.5 km2 upon mine closure.Like other coal mines in the mountainous areas of Alberta and British Columbia, the GRRL coal mine is subject to highly variable temperatures and moisture conditions. Average monthly precipitation varies from a low of 12.6 mm in January to a high of 113.0 mm in August, based on the precipitation record at the mine site since 1982. Despite the relatively high rainfall during the spring and summer months, excess water problems during rainfall events are quickly replaced by water deficit conditions during periodic droughts. Surface runoff varies from near zero in the winter to a mean annual monthly maximum of 78 mm during the month of June. The mean annual surface water yield is 345 mm."

Jan 1, 1997

By Jeremy G. Berg, James B. Mulligan

"There is a very small fraction of wireless experts in the world with experience in underground installations and an even smaller fraction that have experience specific to building mine shafts. This is why in 2009, Redpath created its own system to meet the demands specific to shaft construction. Today, after a dozen shaft installations and several design iterations, Redpath has the expertise and experience required to implement a proper wireless system in any shaft configuration.This document will explain multiple proven wireless communication designs optimized for shaft construction and suitable for permanent use. This includes line of sight installations up to 1200m, short range mesh networks, and the latest patent pending Integrated Leaky Feeder Mesh Network. Additionally, this document will explore the lessons that Redpath learned in its effort to interconnect the people and tools needed to build a mine shaft.INTRODUCTIONAfter a decade of research, several design iterations and a dozen application examples, Redpath has resolved two wireless network architectures to best serve mine shaft construction projects.The long range line-of-sight (LOS) wireless network is the most cost effective and easiest to install, but requires an unobstructed line of sight between the working area and the shaft collar. As such, long range LOS is best suited for ventilation shafts or during the first phase of shaft sinking, before the shaft is equipped.Alternatively, a mesh network uses radios installed at pre-determined intervals in the shaft and on each conveyance. A wireless mesh uses antennas to bridge intervals between shaft radios, whereas Redpath’s integrated leaky feeder mesh network (patent pending) bridges these intervals with radiating cable, commonly referred to as a “leaky feeder” cable. Both of these mesh configurations can provide continuous reception for hoist conveyances travelling in shafts without line-of-sight, making them ideal for shaft equipping and even permanent installations in both mine shafts and lateral drifts.BACKGROUNDHoist operators receive operating commands using what are commonly referred to as “bell signals.” These instructions are delivered in a series of coded pulses on a spring returned pull cord or push button that is typically hardwired back to the hoist operator’s control room from one of many locations in the mine shaft. During the construction phase of a traditional mine shaft, a worker riding inside the sinking bucket would have to reach out to a pull cord installed on the shaft wall to send a stop command to the hoist operator. Today, Redpath’s modern shaft sinking projects use fully enclosed personnel carriers to protect the workers riding inside, specifically preventing workers from reaching out into the shaft while the hoist is in motion. The enforcement of this safety feature on all shaft projects in 2008 forced the engineering group at Redpath to find a suitable wireless solution for hoist communication to facilitate shaft construction.THE IDEAL COMMUNICATION SYSTEM FOR MINE SHAFT CONSTRUCTIONIdeally, the shaft communication system should not transform the tools to which the miners have grown accustomed. It should support the push-to-talk functionality of traditional VHF handsets and the standard belling system that has been used for decades. Additionally, it should be able to support a vendor independent framework upon which new devices and features can be added. The following paragraphs summarize some of the important requirements Redpath has identified.Support for voice transmission: Low latency is critical to prevent jitter during voice transmissions. The system must be compatible with commercially available mobile handsets and support several simultaneous conversations with the ability to broadcast a voice message to all users on a select channel using a “push-to- talk” microphone and loudspeaker.Transmission of PLC data: Low latency is required to"

Jan 1, 2019

Cansolv® S02 Scrubbing Technology was described in a paper in Copper/Cobre 03. Four years on, the technology is operating at a full scale production facility.Hindustan Zinc Limited expanded their capacity by installing the AUSMELT process. The process proceeds through smelting, slag reduction, slag cleaning and holding stages sequentially in the same vessel, resulting in widely varying off gas characteristics. The off gas is suitable for treatment is a conventional acid plant for a modest proportion of the day, but at other times produces off gas too high in S02 to be discharged to atmosphere. Cansolv® S02 Scrubbing Technology was identified as a means of effectively removing the S02 down to low levels from the off gas during all stages of the pyrometallurgical process. Furthermore, the Cansolv® S02 Scrubbing System Technology produces high purity S02 that allowed for the captured S02 to be directed to an existing acid plant, avoiding the capital cost of new acid making capacity.

Jan 1, 2007

By Bruce A. McFarlane

"I WOULD LIKE TO SAY how honoured I am that I have been invited to participate in this panel discussion. I have taken the liberty of narrowing my topic somewhat so that instead of speaking on the Sociology of Professions as a whole I will speak on one aspect of it, that is, on Manpower Problems in the Minerals industry of Canada, with some reference to a new social role for the professionals engaged in this industry. This probably means that I will be encroaching on areas covered or to be covered by other speakers, but I hope that when I do so I will do so from a slightly different vantage point. That is, from a sociological perspective rather than from a historical, industrial, business or professional perspective. I plan to divide my discussion into three areas, namely: (i) problems of ownership and control; (ii) environmental problems; and (iii) manpower and recruitment problems. I do not plan nor am I able to provide clear-cut solutions to the various problems I raise under these three headings. Rather, I hope that my discussion of the problems may form the basis for an extended discussion here and elsewhere. Because of the limitations of time, I will only briefly discuss the first two problem areas noted above – (i) ownership and control and (ii) environmental problems - and I plan to concentrate on the manpower issue."

Jan 1, 1972

By M. Myllymäki

"Pre-treatment of mill feed in a minerals processing plant enables for higher production efficiency per ton of product, reduction of consumables and diverting mineral feed types. Sensor based particle sorting allows for pre-concentration of the run-of-mine (ROM) material prior to other concentrating process. Various sensors provide different responses from the minerals in measured particles. The capability of “accepting” or “rejecting” particles based on sensor responses is investigated in specific test work for each project. Modern sorting machines use pneumatic actuators to divert the reject particles from the material stream. This paper discusses the incorporation of ore sorting test work in processing and plant design. When taking the effects of a sorting circuit into account early in the process planning phase, the downstream process can be adequately sized and impacts evaluated. Potential benefits include but are not limited to increased head grade, lower tonnage to the mill, increased mining operations, removal of deleterious elements and changed properties in the process feed. In a case study we present the Keliber lithium project in central Finland. The plant will produce 9000 tons of lithium carbonate per year from a spodumene ore. Ore sorting and flotation tests were carried out in laboratory and pilot scale. Process models were designed and simulations performed using Outotec’s HSC Chemistry Simulation software. Changes in the flotation performance (grade, recovery, impurity levels) were simulated with and without the pre-concentration of the ROM material. The metallurgical performance and mine economics of the different operational scenarios were evaluated using the Ore-Met optimizer module of the simulation software.INTRODUCTION Challenges in the recent years such as declining ore grades, increasing energy prices, scarcity of water and increasing environmental regulations raise the demand for more efficient processing technologies. Sensor based sorting offers a method for pre-concentration or waste rejection at an early process stage. The technology analyzes each rock particle separately for their unique physical and chemical properties, and diverts the particles into separate material streams by high pressure air jets. Successful implementation relies on ore heterogeneity, differential sensor response and suitable feed preparation."

Jan 1, 2018

By H. H. Gardner

INTRODUCTION THE problem of mechanization is one of the most vital in the minds of Alberta coal operators today. In these times of constantly increasing operating costs, any way of decreasing the cost of a ton of coal must be explored to the limit. There seems no better field for such effort than the successful application of power to the mining and loading of coal. We are fortunate in having neighbours to the south who have made .remarkable progress in recent times along these lines. Higher tonnages per man have resulted in higher wages to the employee and lower cost to the employer. It might seem that our problems could be solved merely by imitating our neighbours. Unfortunately, neither practice nor experience substantiate this conclusion. It is with the purpose of reviewing our accomplishments, as compared with practice in the United States, and at the request of the Prgoramme Committee for this meeting, that this paper is written. The Committee believes that such a general discussion and comparison may well lead to further advances in our mining methods. SUMMARY OF PRACTICE IN THE UNITED STATES A visit to the highly mechanized coal mines of the United States is always most instructive and encouraging.

Jan 1, 1951

By F. Rivard, M. G. Drouet, W. S. Ruff, P. Carabin

"In both the hot rotary-salt-furnace (RSF) treatment of aluminum dross and the cold ball-millsieving (BMS) treatment of zinc dross, enormous amounts of energy and recoverable metal are wasted and large amounts of greenhouse gas are produced. Such wastes and the environment pollution could be avoided by using the DROSRITE PLUS™ technology. Economic and GHG production comparisons between the presently used industrial treatment processes and DROSRITE PLUS™, supported by over one hundred tests conducted in Canada, the US and Europe, are presented. The savings, with DROSRITE PLUS™, would be about $191 and $418 per MT of aluminum and zinc dross, respectively.INTRODUCTIONDross is a material, which forms on the surface of molten non-ferrous metal, such as aluminum or zinc, during melting, metal holding and handling operations when the molten metal is in contact with a reactive atmosphere. Dross normally consists of metal oxides entraining a considerable quantity of molten free (unreacted) metal, and for economic reasons it is desirable to extract the free metal before discarding the residue. In the case of aluminum dross, recovery of the metal is usually carried out by treating the dross in a furnace at a high temperature (Peterson et al., 2002). By contrast, cold zinc dross is crushed in a ball mill followed by sieving to separate the coarse metal portion from the fine oxide residue.The conventional aluminum dross treatment process, using gas or oil-heated rotary salt furnaces (RSF), is thermally inefficient and environmentally unacceptable because of the salt slag and CO2 produced from the combustion of fossil fuels. In the past several years, a number of salt-free processes have been developed and some of these have found limited commercial use (Gripenberg et al., 1994; Lavoie et al., 1990). In all these dross treatment processes, heating of the cold dross in a rotary furnace requires an external energy input that varies between 375 and 2,500 kWh per (metric) tonne of dross. Molten metal separated during processing of the heated dross is tapped, and the remaining solid residue is discharged from the furnace."

Jan 1, 2012

By Anoush Ebrahimi

Mining dilution is one of the most important factors affecting the economy of mining projects. Ore losses and dilution are present at all stages of mining and while several models can investigate the influence of dilution it is its quantification that poses the most serious challenge (Pakalnis et al., 1995). This paper introduces a methodology to quantify dilution factor in open pit mines. The proposed approach makes use of general mining software available in most mining companies. Therefore it is amenable to most mining operations and provides a readily available tool for understanding mining dilution for operators and consultants. To illustrate the methodology the author uses an example from a hypothetical mine. Dilution increases the operating costs in the mill by increasing the tonnage of material to be milled. In addition to its direct impact on short term income of a mine, dilution causes significant changes in other factors that on the long term reduce the overall value of the project. For example, it prolongs the mine life by reducing mill?s effective capacity. It also reduces the feed grade. In most cases, lower feed grade means lower mill recovery. Dilution also increases the cut-off grade which in turn reduces the overall ore utilization of a mine. In some cases, to take advantage of economies of scale, mining operations tend to plan for higher mining rates. Moving to a larger scale of operation means less selectivity, hence more dilution. This is true for all kind of deposits. High level and uncontrolled dilution may ultimately defeat the purpose of increasing production rates. If not impossible in theory it is nevertheless extremely difficult and expensive to eliminate dilution in practice. Some amount of dilution is practically unavoidable in most mining operations (Scoble and Moss, 1994). Although completely avoiding dilution may be impossible, we can measure and control it. By better understanding the root causes of the dilution and planning accordingly, it can be controlled and reduced. While we do our best to identify and calculate all the other cost items of a project, no matter how small, it is common to make general assumptions about dilution instead of quantifying it. It is common to assume a general dilution such as 5% for massive deposits and 10% for tabular shape deposits. While these figures may be a good starting point in early stages of mining studies, it does not take in to consideration the complexity of the problem. Dilution factor varies within a single mine for different benches and zones. This is due to changes we see in grade distribution and shape of ore body. It also varies based on commodity price. It is necessary to make sure that these variations are taken into account when designing or evaluating a mine. Dilution varies in different mines based on the deposit characteristics, operational aspects and economic cut-off grade. For instance, shape of the deposit, bench height, equipment size, and market conditions will have an impact on the level of dilution in a mine. It is paramount for mining projects to have a better understanding of dilution right from the beginning. In times like today, where mining operations must operate at peak efficiency, it is even more crucial to be able to calculate and have a better grasp of all the parameters influencing the economics of a project including dilution. In order to produce better project evaluations, dilution studies should be an integral part of any project.

Aug 1, 2013

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By T. Boyd, K. McTaggart, J. Qiu

"Hudbay Minerals’ Flin Flon process plant produces a copper concentrate and zinc concentrate from the three ores it processes: 777, Reed and Lalor. Unlike many Cu-Zn ores, the average Zn: Cu ratio in feed is around 2:1, whereas, in many Cu-Zn separation plants the Zn: Cu feed grade is substantially higher than 2:1. The lower Zn: Cu in plant feed is a challenge for limiting Zn recovery to the Cu concentrate. While total recoveries of Cu and Zn at Flin Flon are very good; selectivity is the key challenge and small changes in ore or plant, can result in quite variable Zn recovery to Cu concentrate, and accordingly, Zn recovery to Zn concentrate. Magnetic conditioning has been shown to be selective between the two paramagnetic minerals chalcopyrite and sphalerite. Statistical testing of magnetic conditioning was undertaken at Flin Flon with the objective of increasing Cu recovery to Cu concentrate without increasing the Zn recovery to Cu concentrate - in effect increasing Cu-Zn selectivity. This has been achieved elsewhere with magnetic conditioning with the probable mechanism being an increase in fine chalcopyrite recovery, and a reduction in entrained, ultrafine, non-activated sphalerite to Cu concentrate. The results did indeed show an increase in Cu recovery to Cu concentrate of 0.8% to high confidence, but the decrease in Zn recovery to Cu concentrate was not to high confidence. This is effectively an increase in Cu: Zn selectivity in the Cu circuit – higher Cu recovery with no change in Zn recovery. However, while there was an increase of 1% in Zn recovery to Zn concentrate with magnetic conditioning, the variability in this parameter meant that this increase, though larger in magnitude than the Cu result, was not to high confidence."

Jan 1, 2019

By R. Carter, C. S. Samis

"SummaryThe results of this investigation indicate that the gold in the cyanide tailing of refractory gold cyanides is occluded in fused •particles formed during roasting. This conclusion was reached following microscopic examination of calcines produced at various furnace temperatures with different atmospheres, and a •comparison with calcines produced by decomposing samples of completely sulphated concentrate under conditions such that the maximum particle temperature varied between 6•50°C. and 1,100°C. This comparison showed that the particle temperature during a normal roast may be several hundred degrees higher than the furnace atmosphere, or that the fusion is associated with a low melting (950°C.) eutectic mixture of FeO and FeS.Because of the unavoidable particle fusion during a furnace roast, and because low particle temperatures are essential for gold extraction by cyanidation, aqueous medium oxidation under high oxygen pressures was studied. Gold recovery from calcines produced by this means was over 98 •per cent •compared with a maximum of 80 per cent from furnace calcines.IntroductionMANY arsenical gold ores are called 'refractory' because much ' of the gold cannot be satisfactorily extracted by cyaniding the raw ore or concentrate. Even when such ores are roasted to oxidize .the iron and arsenic and 'release' the gold, often 10 to 25 per cent of the gold present is lost in the cyanide residues."

Jan 1, 1952

By J. T. Liu, G. H. Han, W. C. Chai, Y. F. Huang

"In beneficiation process, metal ions could adsorb onto clay mineral surfaces or interact with flotation chemicals, and then result in the flotation behavior changing of desired minerals. Al(III) is the dominating ion existing in the bauxite flotation system. In this research, the adsorption behaviors of Al(III) on two silicate clay minerals (including bentonite and kaolin) were investigated by means of UV-Vis spectra, zeta potential testing and scanning electron micrograph analysis. The adsorption experiment results show that the adsorption capacity of clays for Al(III) ions increases with the initial Al(III) concentration, contact time and solution pH. There are some different adsorption behaviours for two clays. Increasing the clay concentration decreases the adsorption capacity of bentonite, while increases first then decreases for kaolin. Higher temperature favours the adsorption of Al(III) on bentonite but goes against for kaolin. The adsorption capacities of bentonite and kaolin for Al(III) respectively reach 12.48 and 0.875 mg/g at initial solution pH 5. Zeta potential results show that the adsorption of Al(III) on two clays is characterized by electrostatic attraction mechanism.INTRODUCTIONIn beneficiation process, there is inevitably a wide variety of metal ions generated from mineral crushing, mineral dissolution and water chemistry conditions. Metal ions adsorb on the mineral surfaces or interact with the beneficiation agents, affecting the flotation efficiency of desired minerals (DiFeo et al., 2001; Parolis et al., 2008; Shackleton et al., 2012; Shengo et al., 2014). Therefore, it is necessary to have a detailed investigation on the adsorption behaviour of metal ions on clay minerals.Having good ion exchange capacity and negative surface charge, the clay minerals could take up various metal ions from the mineral-water system. Bentonite and kaolin are very common aluminosilicate clays in the mineral processing system. These two clays both hold a permanent negative charge, =X- on the basal surfaces, and a smaller variable charge, =SiOH on the mineral edges (Gu & Evans, 2008; (Gu et al., 2010). Adsorption experiments are usually used to study the adsorption affinity of metal ions for clay minerals (Sen & Bhattacharyya, 2012). The adsorption of Zn(II), Cu(II) and Pb(II) onto natural bentonite showed that the adsorption amounts of metal ions increase with contact time, solution pH and metal ion concentration, but decreases with adsorbent concentration and system temperature (Sen & Gomez, 2011; Melichova & Hromada, 2013). Cr(III) adsorption on bentonite was significantly pH dependent. The adsorption process followed pseudo-second-order model and the equilibrium adsorption was consistent with Freundlich isotherm (Lollino et al., 2015). The adsorption behaviours of Pb(II), Cd(II), Ni(II) and Cu(II) onto kaolin indicated that increasing pH favoured the adsorption of metal ions (Jiang et al., 2010). The adsorption of Cd(II), Cu(II), Pb(II) and Zn(II) onto kaolin showed that an ion-exchange reaction occurred at pH<7.0 and inner-sphere surface complexes were prone to form at higher pH (Srivastava et al., 2005)."

Jan 1, 2016

By D. E. Deegan, G. Holcroft, T. P. Johnson

"The rising cost of extracting metals from existing traditional deposits, increasingly stringent environmental regulations and a greater awareness of corporate social responsibility issues are all factors in stimulating the examination of mine tailings and small-scale alluvial deposits as a potential source of new raw materials. Furthermore, despite tougher economic times the demand for commodities remains strong, in no small part as a result of the growth of the world’s emerging economies.This combination of social and economic factors looks set to continue in the long term which will encourage greater recovery of materials from previously ignored sources such as mine tailings and ores from alluvial deposits.An expansion in the recovery of useful materials from mining-related activities is likely to require the use of robust and innovative techniques that have a built-in degree of future-proofing; DC plasma technology is one such technology.As a result of its ability to separate the valuable metal and minerals from the waste material while destroying hazardous compounds, Tetronics’ DC arc technology offers an alternative approach to resource recovery from a wide range of mine ores. Harmful cyanide compounds and the vast quantities of water used in conventional hydrometallurgical processing are avoided when plasma processing is adopted. DC arc technology also brings additional benefits, including: the extremely effective destruction of organic materials, the conversion of the inorganic material into a re-useable aggregate and the high tolerance of the process to fine and dusty materials. This paper presents details of Tetronics’ DC arc technology as one of the key pyro-metallurgical solutions available for the recovery of valuable materials from traditional mine ores and tailings, as well as giving specific examples of how the technology has been successfully employed in the recovery of enriched slags, ferroalloys and other metals."

Jan 1, 2016

By G. W. Norval, V. G. Papangelakis, G. A. Moldoveanu

Smelting has been the primary method of treatment for refractory copper sulfide concentrates such as enargite (Cu3AsS4), but the pyrometallurgical processing generates elevated levels of volatile arsenic. The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H2SO4) and sodium chlorite (NaClO2). The effects of initial oxidant concentration, particle size, agitation speed and temperature on dissolution kinetics and copper extraction were investigated. It was found that a stoichiometric ratio of ClO2:Cu3AsS4 = 9:1 were needed to completely and congruently dissolve the mineral with fast kinetics (<15 minutes) under ambient temperature. The dissolution extent (metal extraction) increases with increasing ClO2 concentration and decreasing particle size of solids, but is not influenced by temperature or agitation speed.

Jan 1, 2014