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By Harry F. Weaver

WHEN 1 was assigned by the Director of the United States Bureau of Mines to present a paper at this annual meeting of the Mining Society of Nova Scotia, 1 was grateful, honoured, and elated to realize finally a life-long desire to see your beautiful land and visit with you who have the good fortune to live and work here. Naturally, in preparing for this important event, 1 wanted to give you something of special interest within the limits of the subject so I chose an area dose to my heart -the operation of our Federal coal mine inspection service, which has, as its fundamental purpose, the prevention of accidents in and around ?Coal mines. In 1957 the United States had 10,879 active coal mines scattered throughout 28 States and the Territory of Alaska. The production of coal for the year was about 515,472,000 tons, including 2.5,472,000 tons of anthracite and 490,000,000 tons of bituminous coal and Hgnite. Anthracite is mined principally in a comparatively small area of one State. AU the 28 States and the Territory produce bituminons coal and/or lignite. The beds mined range from 18 inches to more than 100 feet in thickness and from the horizontal to the perpendicular.

Jan 1, 1958

By C. Piribauer, E. Feichtenhofer, A. McEneaney

"As part of a major diversification project, RHI AG, through its plant in Drogheda Ireland, has developed a Caustic Calcined Magnesium Oxide (CCM) for use in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry. In the course of the project, the company investigated the chemical and physical properties of a number of different Magnesia’s used in Co & Ni hydrometallurgy applications and has been able to determine the important parameters for a successful Magnesia for this application. A number of live plant trials have confirmed the results of this testwork and the company is now proceeding to produce this product in commercial quantities at Premier Periclase Ltd., the RHI AG plant in Drogheda, Ireland. This paper will outline the development work conducted by the company and highlight the important chemical and physical properties that make a successful CCM. Much of the research was conducted at the RHI Technology Centre in Leoben, Austria. In addition, a number of external laboratory studies were conducted on behalf of RHI AG. The result of this work has allowed the company to develop a Magnesia product with optimised properties for use in the Cobalt and Nickel hydrometallurgical extraction process.INTRODUCTION Premier Periclase is part of RHI AG, a globally operating supplier of refractory products, systems and services, headquartered in Vienna, Austria. The company produces Magnesia from seawater at its plant in Drogheda, Ireland. While the main focus is on production of refractory grade Dead Burned Magnesia for the steel industry, the plant also produces a number of different grades of Caustic Calcined Magnesia as well as Magnesium Hydroxide products. As part of a major project to diversify the company’s product base, the use of CCM in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry was investigated. One of the company’s highly reactive grades of Caustic Calcined Magnesia was found to be particularly suitable for this application. In an effort to understand what makes a successful Magnesia for hydrometallurgy the chemical and physical properties of different Magnesia’s used in Co & Ni hydrometallurgy were investigated. This paper and conference presentation outlines the findings of this process."

Jan 1, 2017

By H. Saeedi Ali, A. J. Monhemius

"Anglo Asian Mining’s Gedabek mine is situated in the Lesser Caucasus mountains in Western Azerbaijan. The ore body is a complex copper-gold porphyry deposit, comprising intermixed oxidized, transition and sulphidic gold and copper-bearing ores. Gold in the sulphide ores is generally not refractory and is recoverable by cyanide leaching, but the secondary copper minerals, which are also cyanide soluble, lead to high cyanide consumptions. Ore processing at Gedabek is by agitation leaching for high grade ore (>1g Au/t) and heap leaching for lower grade ore. In order to cope with the high copper concentrations in the cyanide leach liquors, a unique combination of resin-in-pulp for selective gold extraction and SART processing for copper removal and cyanide recovery is used. In 2015, a flotation plant was added to treat the tailings from the agitation leach plant before the tails are sent to the tailings dam. This plant produces a copper sulphide flotation concentrate and also recovers some of the residual gold and silver in the tailings. Since February 2017, due to lower grades of gold and higher copper in the feed ore, the decision was taken to alter the flow sheet and to carry out flotation ahead of agitation leaching, to reduce the cyanide consumption during leaching by removing soluble copper minerals. The paper compares and contrasts the performance of the plant in the two configurations, namely, (i) leaching followed by flotation and (ii) flotation followed by leaching.INTRODUCTION In May 2009, Anglo Asian Mining started open pit mining for gold on its Gedabek property in the Lesser Caucasus Mountains in western Azerbaijan. Gedabek is situated on the highly mineralized Tethyan Belt that runs from the Himalayas to the Balkans. The ore body at Gedabek is a complex copper-gold porphyry deposit, comprising intermixed oxidized, transition and sulphidic gold-bearing ores. The sulphidic ores contain mainly pyrite and chalcopyrite, with some secondary copper sulphide minerals, such as bornite and chalcocite, and minor amounts of sphalerite, galena and tetrahedrite. Gold in the sulphide ores is generally not refractory and is recoverable by cyanide leaching, but the secondary copper minerals, which are also cyanide soluble, lead to high cyanide consumptions and passivation of free gold."

Jan 1, 2017

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By Pura Alfonso, Teresa Escobet, Hernan Anticoi, Eduard Guasch, Josep Oliva, Sarbast A. Hamid

"The liberation modelling of mineral particles using mineral liberation analysis have been used in the past to model comminution and concentration processes. In this work this concept has been taken a little further, using comminution and concentration for applying the mineralogical characteristics of particles. This approach is shown using the image analysis, mineral liberation analysis and the distribution density functions for liberation modelling. The work focused on the effect of comminution on mineral liberation for liberation modelling. To model this, effect the mineral liberation of the particles using distribution density and the cumulative distribution was linked to the image analysis of the ore particles. These properties have been estimated by statistical measures such as the distribution density and liberation grade, which were extracted from MLA data and images analysis, using proper image analysis and techniques based on MATLAB software. A comparison of different tungsten ores of liberated particles, has been introduced and evaluated by estimated results and image analysis.INTRODUCTION The chief economic minerals of tungsten are wolframite [(Fe,Mn) WO4] and scheelite(CaWO4), and approximately two-thirds of the world tungsten reserves consist of scheelite deposits (Lassner and Schubert, 1999). Tungsten has unique properties and is widely used in various industrial high strength and high temperature applications. It occurs coarsely aggregated in low grade ores. Most of tungsten ores, particularly scheelite, wolframite and ferberite, occur in deposits with very low content of WO3 (0.1–2.5%) that is not economically viable to apply directly metallurgical methods to extract tungsten (Martins, 2014). Tungsten is considered as a critical metal by the European Union by the economic importance and also the high supply risk (European Commission, 2014; Chakhmouradian et al., 2015).Currently, scheelite is playing an increasingly important role in tungsten industry because the mineral reserve of wolframite is getting depleted after gradual exploitation and utilization (Min et al., 2016). In mineral processing, the liberation of valuable mineral from the gangue determines the efficiency of subsequent separation processes. The liberation characteristics of an ore are primarily dependent on its texture, the association of mineral in the host matrix of gangue minerals, and to some extent on the grinding process (Zhang and Subasinghe; 2013)."

Jan 1, 2017

By V. Prasad, A. Afacan, K. Popli, S. Dubljevic

Froth flotation is one of the most common and widely used separation processes in the mineral processing industry; however, its complexity means that complete understanding of the process has not yet been achieved. A dynamic fundamental model is needed to enhance the understanding of the process and to improve process control. It is challenging to capture all the phenomena involved; hence, we propose a multiscale modeling approach with a framework ranging from macroscopic (equipment scale) to microscopic (attachment, detachment) models along with distribution models for ore particle sizes. Real-time froth properties are obtained using a vision-based sensing system. These measurements can be used for developing a soft sensor for grade using statistical methods such as PCR (principal component regression) and PLS (partial least squares) regression. The fundamental model is updated in real-time using extended Kalman filtering. Attachment dynamics are studied for different particle size distributions. The modeling and soft sensing is tested on batch flotation cell for the pure mineral galena with different particle size distributions using Xanthate and MIBC as collector and frother, respectively. The model, online measurements and soft sensor are useful in developing monitoring methods for froth flotation.

Jan 1, 2015

By Ainul Akhtar, Steve Cockcroft, Jixiang Xu, Daan Maijer, Lu Yao

"Nitrogen rich Ti-N inclusions are one of the more difficult inclusions to remove during liquid metal refining of titanium. If present in the final component, they can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading. Understanding the kinetics of dissolution of Ti-N particles during consolidation/melting of titanium can help us better operate and design the melting processes to minimize their occurrence in Premium Quality Titanium production. A numerical model based on finite difference method has been developed to calculate the dissolution of a spherical Ti-N particles in molten titanium. Analytical solutions were used to verify the finite difference code for calculation of concentration profile and the dissolution of spherical solids. Taking into account the limitations in these approaches for the different cases examined, the invariant field approximation showed good agreement with the results from the numerical analysis. Evolution of the size of a spherical Ti-N particle during dissolution was predicted by the numerical model and the particle dissolves in 163 s.INTRODUCTION Properties like low density, high specific strength and excellent corrosion resistance make titanium attractive for a variety of applications. Key characteristics in the processing of titanium and its alloys include its high sensitivity to impurities, especially atmospheric oxygen and nitrogen and its high reactivity in the molten state. Nitrogen rich inclusions Ti-N, also known as Type ? or hard alpha defects, usually have substantially higher hardness and lower ductility than the surrounding material. Because they can act as fatigue initiation sites, Ti-N inclusions can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading, even in minor amounts (tenth of a percent) (Lampman, 1990; Moiseyev, 2005; Lütjering & Williams, 2007). Ti-N encompasses as a broad range of nitrogen contents from a few wt% up to stoichiometric TiN. The liquidus temperature of Ti-N titanium increases substantially with increasing nitrogen content. Consequently, depending on the concentration of nitrogen, the melting point of Ti-N inclusions can be above bulk liquid metal temperatures during melt processing. Thus, removal of Ti-N defects hinges on dissolution and not melting."

Jan 1, 2017

"Real-time, on belt analysis of minerals is becoming increasingly important and critical in modern operations, especially in the mine-to-mill. Prompt gamma neutron activation analysis has long been utilised for real-time elemental analysis in bulk materials, with Scantech's GEOSCAN being the instrument of choice in the minerals sector. Working in the minerals space for 15 years, the GEOSCAN has been successfully implemented in a wide range of minerals applications including iron, copper, lead-zinc, manganese, phosphate and more, and it caters for the very high demands and increasing requirements of a contemporary processing facility. An area of focus has been on increasing the analysis frequency to allow for rapid analysis results with the same high degree of accuracy typically expected of the GEOSCAN. This paper discusses the underlying research and technology that has enabled such rapid analysis and presents a range of examples using a thorough statistical approach on real production material, demonstrating achievable accuracy over a short analysis time, and dispelling common myths about the speed of the technique. Potential applications are discussed to conclude the paper.INTRODUCTION Technology and the information it can provide plays a critical role in the evolving modern mineral processing landscape. The importance of technology to analyse various features of ores and concentrates being processed is obvious, and recent years has seen the advance of numerous technologies to provide a variety of real-time measurements on conveyed material flows. From sampling apparatus to particle size analysis to weight and density meters to full elemental analysis, the availability of information enables a variety of improvements in the process leading to improved efficiency and increased revenue. To maximise the potential benefits, access to real-time information is imperative, and rapid updates of information become necessary to make appropriate process control decisions based on the most relevant and up-to-date information."

Jan 1, 2017

By F. Henríquez, V. Iriarte, L. Vinnett, J. Yianatos, F. Díaz

Metallurgical characterizations of the collective (Cu/Mo) and selective flotation plants were carried out in Minera Los Pelambres, Chile. The selective plant allows the valuable minerals of Cu and Mo to be separated. The evaluation involved two surveys consisting of metallurgical sampling as well as residence time distribution (RTD) measurements to determine load distribution. The RTD data were obtained in real-time by means of the radioactive tracer technique. In addition, metallurgical data was reconciled and supported by effective residence times. In the collective plant, a performance comparison of parallel rougher circuits was carried out, which included a bank of six mechanical cells of 250 m3 and banks of nine mechanical cells of 130 m3. In the selective plant, the Cu and Mo evolution along the plant was evaluated. The results in the selective plant allowed for performance evaluation of mechanical and pneumatic cells in primary flotation. In both plants, mineral losses were evaluated and their relationship with circuit configuration (cell types and circuit layout) was determined. The metallurgical characterization was a powerful tool to evaluate circuit performance and to detect improvement opportunities at industrial scale.

Jan 1, 2015

By M. Sukhram

In the year 1992, T.A. Utigard published a paper titled "The measurement of the heat-transfer coefficient between high temperature liquids and solid surfaces." In that work, he instrumented an agglomerate of materials with thermocouples to infer the heat transfer coefficient of a high temperature liquid on a solid. The purpose of that research was to help in the design and operation of metallurgical reactors. Since that time there have been many researchers that have worked to characterize heat, mass, and momentum transfer phenomena in high temperature metallurgical processing operations. This paper presents results from the author’s experience with instrumenting thermocouples in copper elements coated with carbon to infer velocity of high temperature liquid metals. It also presents a methodology to determine velocity of a high temperature liquid by inferring the local heat transfer coefficient at a solid-liquid interface

Jan 1, 2015

By J. Sliwinski, H. Kikutani, J. Atwood, D. Larimer, J. Pyecha

"The Pogo mine start-up milling targets of 2005 are vastly different than the targets of today. Improvements have been driven by unintentional design oversight, continual circuit optimization or optimization due to changing mineralogy. The more significant process improvements to date have occurred in the gravity, flotation and leach/CIP unit operations. Details of the significant improvements are presented along with the impacts to the process.INTRODUCTION Deposit Overview Pogo mine is located along the Goodpaster River, southeast of Fairbanks, Alaska. This deposit sits in the center of the Tintina Gold Province (Figure 1), a region of similar Intrusion Related Gold deposits in Interior Alaska, the Yukon and British Columbia Canada (McCoy et al., 1997). The Pogo deposit is hosted in a rock sequence of amphibolite-grade gneisses intruded by mid-Cretaceous granitic plutons and dikes, which in turn, were cut by and host the auriferous quartz veins of the Pogo deposit.The Pogo deposit is comprised of three distinct zones of auriferous quartz veins spatially adjacent to each other. These are the Liese Zone, North Zone, and the East Deep Zone. The Liese Zone consists of three stacked, massive quartz veins, designated the L1, L2, and L3. Vein thickness averages 3.0 m, with variations from 0.3–18 m thick. The North Zone mineralization is comprised of four veins with more consistent thickness, between 1 and 1.5 m. The East Deep deposit lies northeast of the Liese Zone ore body. It is separated by a post mineralization, quartz diorite pluton. The East Deep Zone is comprised of two stacked massive quartz veins with similar orientation as the Liese Zone."

Jan 1, 2017

By S. Beskri, N. Geoffroy

When metallurgical plants are designed, a lot of consideration is almost always given to material selection and possible damage mechanisms. Materials engineers are generally involved and will strive to select optimal alloys or refractories for the design conditions. Once in operation however, things often change. Equipment is overstressed to increase production, corrosive leaks are not always promptly addressed, proper welding procedures are disregarded, etc. This paper describes various cases from the mining and metals industry where serious mishaps, associated consequences, and costs could have been avoided if simple and proactive steps had been taken. It also presents a strategy, based on safety reviews, to help predict and prevent damage to critical pieces of equipment.

Jan 1, 2015

By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By J. Zhou1

"The extractive metallurgy of gold ores is largely driven by their grade and mineralogy. The concentration of gold in the crust is extremely low and highly variable, resulting ore variability in many gold and copper-gold deposits. More importantly, gold in an ore may occur in two or three forms (i.e. microscopic gold, submicroscopic gold and surface gold), making gold ore processing extremely challenging. Geometallurgy is a technique to document variability within an orebody and quantify and evaluate the impact of many factors including geology and mineralogy on grinding, flotation, leaching and metal recovery processes. The objective of gold geometallurgy is to reduce and minimize the technical risk in project evaluation, plant design, mine planning and production forecasting through geometallurgical modelling, representative sampling and subsequent systematic mineralogical and metallurgical testwork. Gold deportment study is a powerful tool in characterization of various gold ores. Effective and quantitative gold deportment results are critical and useful for predicting gold recovery and building geometallurgical models of gold ores. This paper provides an overview of geometallurgy fundamentals and applications in gold processing, with a focus being on the ore characterization and gold deportment study.INTRODUCTION Geometallurgy is an inter-disciplinary approach which links the geological, geochemical and mineralogical characteristics to the metallurgical performance of an orebody. Combined with mine planning, it has been used in scoping, prefeasibility and feasibility studies, process design and optimization of gold, copper-gold, copper-moly, nickel and iron projects among others (Williams & Richardson, 2004; Dobby, Bennett, Bulled, & Kosick, 2004; Bulled, 2007; Bulled, Leriche, Blake, Thompson, & Wilkie, 2009; Kormos, Sliwinski, Oliveira, & Hill, 2013; Muinonen, Sciortino, Korczak, & St-Jean, 2013; Leichliter & Larson, 2013; Leichliter, Jahoda, & Montoya, 2013; Hatton & Hatfield, 2013; Baumgartner et al., 2011, 2013; Hoal, Woodhead, & Smith, 2013; Zhou, 2013). The goal of a gold or copper-gold geometallurgical program is to characterize and understand the metallurgical variability of an orebody, such as comminution, gravity, flotation and cyanidation parameters and metal recoveries, and to build a geomet model which can be used to assist in mine planning and to predict the plant performance. In any geometallurgical program, representative sampling is the key to ensure the results of a geometallurgical study will reflect future performance once the plant is commissioned. Geometallurgy compliments, but does not replace, the traditional mineralogical and metallurgical approach during the development and operation of a gold or copper-gold project. Geometallurgy is a methodology for testwork design and a framework for mine planning. The first part of this paper provides an overview of geometallurgy fundamentals and application in gold ore processing."

Jan 1, 2017

By Eric Barnard, Andreas Nashitati, John Tero, Guy Deschênes, Setta Mbalamba, John Rajala

The Otjikoto Mine, owned at 90% by B2Gold Corporation, is located 300 km north of Namibia’s capital city of Windhoek. The reserves from the open pit mine, estimated at 25.9 million tons with an average grade of 1.28 g/t Au, contain gangue minerals, pyrite and pyrrhotite, and have an estimated 10 year mine life. The feasibility study included an optimisation of gold leaching using CSTR for the original design. The results of the test work were used to establish the design criteria. Gravity tails from three composites (drill cores), representing the major ore types, were used. The XR3 sample (gravity tails) contained 0.32 g/t Au, while the XR2 and XR1 gravity tails samples (used for variability) contained, respectively, 0.30 g/t Au, and 0.47 g/t Au. The optimum leaching conditions were: a pre-treatment of 7 h at pH 10.5 with 100 g/t lead nitrate, DO > 5 ppm followed by cyanidation at 300 ppm NaCN, pH 10.0, DO > 5 ppm for 48 h. The gold extraction was 91.5% (97.2% overall extraction gravity/leach) and the cyanide addition was 0.57 kg/t NaCN. Increasing the DO to 16 ppm did not show any economic benefits. No pre-treatment or a 4-h pre-treatment reduced the gold leaching kinetics. The XR2 and XR1 gravity tails samples had gold extractions of 92.9% and 92.3%, respectively. At the plant scale, an 11 h pre-treatment is used followed by 42 h cyanidation with 250 ppm NaCN and an average DO of 8 ppm and 230 g/t lead nitrate in 2016. The cyanide addition was 0.49 kg/t NaCN. The commercial operation started on February 28th, 2015. The overall gold recovery and production were 98.4% and 145,696 ounces for 2015 and 98.1% and 166,286 ounces for 2016. It was found that retention times, gold content of leach residues and cyanide addition are comparable for the lab and the plant. Details of the Otjikoto process flowsheet are discussed in this paper along with the results of the lab leach optimisation test program and the plant leach circuit performance and improvements.

Jan 1, 2017

"The successful commissioning and ramp up of the Albion Process™ at the GPM Gold Project relied on the successful scaling up of the process from batch and continuous pilot plant campaigns (Voigt et al., 2015). Critical information about reaction kinetics and residence time, grind size and pulp density were determined at the laboratory scale and successfully applied to the commercial scale. A limitation of small scale testwork, is that some parameters cannot be measured reliably and scaling up is a function of the physical size of the equipment which isn’t possible to test with laboratory scale equipment. Oxygen mass transfer rate is one such parameter since this is a complex interaction of many factors including slurry temperature, solution and slurry chemistry, slurry viscosity, agitator type, dimensions and power, oxygen bubble residence time, oxygen purity, tank geometry and oxygen injection technique. Oxygen generation represents an important operating cost for the Albion Process™. Pivotal to the Albion Process™ operating economically at atmospheric pressure is the capability to efficiently transfer oxygen while utilising as much oxygen injected to the process as possible. To respond to this Glencore Technology developed the HyperSpargeTM supersonic gas injector. This paper compares the HyperSparge™ against other sparging techniques to quantify the benefits of oxygen injection via a supersonic gas jet on scale up of the oxygen mass transfer system. The paper then examines plant survey data from the GPM Gold Project to demonstrate the very high oxygen utilisation that can be achieved with a correctly designed oxygen mass transfer system.INTRODUCTION One of the main challenges in chemical reactor design is the scale-up of processes from the laboratory to industrial scale. Processes which cannot be faithfully simulated with an experiment at the laboratory scale face challenges due to the physical dimensions and complexity of full scale operation. One example of this is the design of oxygen mass transfer systems in atmospheric oxidative leaching circuits such as the Albion Process™. A number of constraints associated with the use of laboratory scale equipment to design full scale circuits are involved in gas mass transfer processes in agitated slurries such as the Albion Process. Chiefly, typical laboratory and pilot size equipment lacks the required volume to provide useful design data without relying on empirical correlations: the specific agitator power input is artificially high, the bubble residence time in the vessel is artificially low, the oxygen partial pressure at the base of the vessel is artificially low and the oxygen delivery method may differ significantly to the industrial process. Further, the dynamic nature of the process introduces additional impacts on gas mass transfer, including the presence of solids, recycle streams and minor elements, plus the variances within the reality of a process plant such as disruptions or variance of feed quality."

Jan 1, 2017

By Zhou Yanwen, Fudong Wang, Shing Liu

Mixed CrB2 and MoS2 powder (Cr:Mo=1:1 atomic %), without any further process, were used as the targets to be sputtered and deposited onto stainless steel and silicon substrates by pulsed DC power supply. The structures and properties of the CrBMoS films were then analyzed by using SEM, XRD, micro-hardness tester. The SEM morphology of the films showed dense, defect free structure, and the preferred orientations of the films were CrB2 (111) and MoS2 (200) according to XRD spectra. The thicknesses of the films were measured and the relationship between the deposition rates and pulsed factors was determined. The films, with the micro-hardness as high as 19GPa and friction coefficient as low as 0.02, could be considered to be the hard solid lubricant films.

Jan 1, 2015

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By K. Webb

At both the international and country level, the issue of how the mining sector and indigenous populations should engage on issues of mutual interest or concern has emerged as one of central importance and controversy; involving the mining industry, Aboriginal communities, governments, the courts, and other stakeholders. At its heart, stakeholder engagement is an ethical issue, although it manifests itself in international instruments, domestic laws, industry guidance and agreements. At the international level, the concept of ?free, prior and informed consent? (FPIC), while not subject to widespread agreement on the finer details of evolving definitions, seems to be emerging as an increasingly recognized engagement norm. Within Canada, through a series of decisions, the Supreme Court of Canada (SCC) has articulated a fiduciary obligation of the Crown to consult with and accommodate impacted Aboriginal groups on resource management issues. Provincial governments have been variously attempting to adjust their resource management regimes to stay in alignment with SCC and lower court decisions. Mining sector organizations, working with First Nations partners, have developed agreements to work together for mutual benefit. At the individual mine and community level, there have been instances of constructive engagement, as well situations of physical resistance and legal challenges. The purpose of this paper is to examine the potential impact of new rules under the Ontario Mining Act introduced in 2012 and taking full effect in 2013, which amongst other procedural specifications, addresses the issue of mining industry-Aboriginal consultation in exploration and development activities. Leading up to the passage of the regulations, representatives from some junior mineral exploration companies have been highly critical of the new rules. Similarly, there have been a range of responses to the new rules from some in the First Nations community. The paper will review the regulation in terms of its apparent alignment with SCC decisions and the international norm, compare the regulations with existing mining sector organization guidance documents, and it will draw on the stated perspectives and commentaries of First Nations communities, mining firms, governments, nongovernmental organizations, and others. Building on the foregoing, the paper will provide a preliminary analysis of the perspectives and potential impacts of the new regulation on various stakeholders, and on that basis, possible avenues for further consideration will be suggested.

Aug 1, 2013

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015