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By A. Demers, M. Chapman, N. Reynier, R. Lastra, M. Courchesne, C. Laviolette

Historic medical isotope production at Canadian Nuclear Laboratories (CNL) in Chalk River involved the dissolution of irradiated isotope targets prior to extraction of Mo-99. This process generated liquid waste that was cemented in 5-gallon containers and transferred to an outdoor waste-management facility for intermediate storage. Research was undertaken to develop an innovative method for uranium, mercury and cesium recovery from the radioactive cemented waste (RCW). Regulations prohibit the removal of active radioactive waste from the Chalk River facility. Thus, CanmetMINING produced surrogate material following the same procedures and conditions to those used at CNL. The selective recovery of the uranium from the surrogate radioactive cemented waste (SRCW) could offer CNL more disposition options for the resulting wastes. Leaching tests were performed using four different SRCW at 1 kg scale. Different conditions, operating parameters, and the presence of plastic and corrosion products were evaluated on solubilization. The research investigated the use of potassium iodide with the sulphuric acid leach to increase metals recovery. Iodine improves the solubilisation of metals and the U dissolution reached 99%. The increase of leaching time reduces the U solubilization due to silica gel formation. Therefore, it will be important to control leaching time to avoid the loss of U during the pilot scale experiments. For Hg, the solubilization ranged from 60 to 80% due to the presence of metallic mercury and mercury sulphide found in SRCW cured at 60°C and/or aged for 30 months. Ion exchange (IX) was found the best method to separate the uranium from the impurities and produce a purified and concentrated uranium solution suitable for yielding a uranium product (yellow cake).

Jan 1, 2020

By Y. Vermeulen, J. Simoes, P. Guillo, A. Di Donate

New design techniques have been developed to optimize continuous casting (CC) refractory components. The overall objective is to increase CC productivity as well as steel quality by using optimized refractory from tundish-to-mold. These techniques allow the prediction of steel and refractory chemical interactions and, thus, steel chemistry evolution as well as build up and corrosion occurrence. Specific fluido-dynamic models (CFD) have also been developed to better take into account the physical parameters at the steel/refractory interface and to optimize steel flow control. The CFD model can be coupled with refractory chemical interactions to simulate steel chemical evolution. These two different approaches result in shape and material modifications. They are completed by dedicated thermal stress analysis in order to improve thermal shock resistance. The mechanical FEA evaluations take into account specific mechanical behavior of refractory components as well as high temperature evolution of their properties.

Jan 1, 2004

By Xiao Huang, Jean-Francois Thibault, Ali Merati, Prakash C. Patnaik

Single-crystal nickel-based superalloys are the current state-of-the-art technology for the manufacture of turbine blades. This technological improvement of the turbine blade has brought a considerable increase in its cost. Repair and overhaul of service stressed single crystal turbine components is an economic necessity for life cycle cost reduction of engines since the cost associated with replacement is significantly higher than its counterpart polycrystalline component. This paper will first review the recently reported research in developing repair technologies used for DS and SX components. These techniques repair the crack or defect while at the same time ensuring that the mechanical properties do not deteriorate and, more importantly, that the single-crystal microstructure is not jeopardized. It will then be followed by a brief overview of the research conducted and initiated by the authors with regards to the repair of single crystal alloys.

Jan 1, 2004

By O. -J. Siljan

"Refractory materials are an integral part of aluminium production. One special feature of aluminium making is the prominent role of sodium in all parts of the production process. This presence of sodium inflicts stresses on the refractory materials through reactions and may cause severe damages to the refractory linings. The present paper address possible reactions between sodium and refractories in anode bake furnaces, electrolytic pots and casting furnaces. The discussions presented in the paper points to the importance of selecting materials with excellent alkali resistance in all parts of the aluminium making process, although alkali resistance is not the sole parameter to determine refractory life-time. ""Acid"", i.e. silica-rich alumino-silicate refractories are shown to be the best materials for aluminium electrolysis cell potlinings, whereas high- alumina refractories based on minerals like andalusite seems to be the preferred choice for anode bake furnaces as well as cast house furnaces."

Jan 1, 2004

By F. Schulz

NA's primary smelter has continually increased its production output in the past decade, making it necessary to improve the lifetime of the casting moulds for copper anodes. The current throughput of more than 1,100,000 tonnes per year of copper concentrates amounts to an output of about 450,000 tonnes per year of anode copper at NA's Hamburg plant. The anodes are cast on a single casting wheel with 24 anode moulds. Besides the stable chemical analyses, the reproducible geometry of the anodes is an important precondition for the success of the subsequent electro-refining process. The anode moulds are subjected to thermally-induced alternating stress and side reactions with the melt. Typical signs of wear will be shown and discussed. Different processes to produce anode moulds will be introduced and the results in terms of their lifetime and the quality of the anodes themselves will be discussed. Finally an outlook is given on possible efficiency improvements.

Jan 1, 2007

By Marc C. Bétournay

A number of successful proof-of-concept projects have been carried out to replace conventional power application, such as diesel and rechargeable batteries, in underground mine vehicles. This has led to the development of the world?s first fuelcell production vehicle, a mine locomotive. A mine loader project has also started and several other projects are planned. These projects are providing the mining industry with the required information to make this technology shift possible. The application of fuelcell power will yield several important benefits such as the elimination of underground diesel emissions, significant reduction in the primary extraction?s sector greenhouse gas emissions and support for a more productive scenario. This article reviews these successes, discusses ongoing and potential projects and presents the technology application benefits that could be possible for mining operations.

May 1, 2003

By C. P. Moore, G. W. Taylor

Vertically dipping lenses of nickel-copper ore at Dumbarton Mines Limited are being mined by a modified blasthole stoping method. The principal access to the mine is provided by a 15-degree decline, which, in conjunction with the use of ramps and declines for secondary access, maximizes the accessibility and mobility of trackless mining equipment. Sublevels are driven in ore on 80-foot vertical intervals and subsequently the ore, ranging in thickness from 15 to 30 feet, is slashed to its limits by a procedure of face sampling and test holing. Two longhole drill jumbos are used to drill off 40-foot vertical slices above and below these levels. Following blasting, the ore falls by gravity to the 500-foot horizon, where it is removed from drawpoints by load-haul-dump units and transported by truck to the main orepass. The rock is crushed to minus 3-4 inches and conveyed to surface by a 30-inch-wide wire rope suspended conveyor. This is achieved in two flights, a lower one of 290 feet and a main flight of 2260 feet. All aspects of the mining operation are discussed in the paper, including ventilation, services and safety.

Jan 1, 1973

By A. Tabereaux

The reduction of perfluorocarbon (PFC) emissions from aluminum electrolytic cells is a key issue in reducing greenhouse gases at all aluminum smelters, The emission of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) gases during anode effects at smelters can be calculated using two different methods; anode effect-minutes slope and anode effect overvoltage, This work demonstrates that the optimum method depends to a large extent on the type of anode effect kill algorithm utilized at each smelter, CF4 emissions vary widely from aluminum cells depending on the type of anode effect kill method utilized; fast, aggressive anode bridge movements vs. slower, moderate anode bridge movements.

Jan 1, 2005

By J. P. Nicoud

"The Frog's Leg project is located in the Kundana mining centre 22 kms West of Kalgoorlie, in Western Australia. The Mines and Resources Australia (MRA) Dioro Exploration Joint Venture has had considerable exploration success centred on the high grade Frog's Leg discovery. A gold resource of 930,000 ounces has been defined. At Frog's Leg there have been three discrete resource domains recognised - Supergene, Contact, and Quartz Lodes. This paper describes the metallurgical test work undertaken.The selection of the drill core was a joint effort by the MRA Senior Geologist and Mineral Engineering Technical Services (METS) to ensure the samples were representative of the ore body. Optimisation of gold recovery was essential as both the Contact and Quartz Lodes have exceptionally high percentages of free gold as well as significantly higher grades than the typical open pit ores found in Western Australia. The metallurgical scope of work included documenting all of the metallurgical test results, establishing the comminution characteristics, determining the percentage of gravity recoverable gold, evaluating the cyanide leach characteristics and determining the tailings characteristics. These studies were used as the basis of flow sheet design to treat both ores and to discuss the advantages and disadvantages of alternative flowsheets. Investigations also included toll milling options at various plants as well as second hand and transportable plants. Considerable technical effort has been put into ore characterisation by way of test work aimed at managing the process risk at each stage of project development, including mitigation. MRA also carried out detailed mineralogical analysis of the ores."

Jan 1, 2005

By Rodney S. Read

This paper outlines a reasoned argument why no large-scale fracturing or faulting will be induced in the host rock by a deep geological repository (DGR) for nuclear fuel waste. Four DGR designs in three possible host rocks, including crystalline and sedimentary rock types, are considered. The reasoned argument draws from results of previously conducted thermal- mechanical analyses and new scoping calculations, along with evidence from experiments conducted in Canada and elsewhere. It is concluded that large-scale fracturing in the far-field is implausible given the expected in situ stress conditions in relation to rock strength. Near-field damage development and fracturing are expected in DGR scenarios in the different rock types, but these near-field effects are not expected to lead to large-scale fracturing that could compromise the integrity of the DGR and surrounding rock mass. Additional analysis and characterization activities are recommended to further validate the reasoned argument. Thermo-poroelastic loading of the rock mass is identified as one possible driving mechanism that should be studied further.

May 1, 2009

A series of small scale tests have been conducted to evaluate the effect of micro-fracture development, imposed by blasting, on the material properties of the rock as well as its resistance to crushing and grinding. The uniaxial compressive strength, tensile strength, Poisson?s ratio, P-wave, Swave velocity, point load test index, crushing and grinding work indices were evaluated for samples without any blasting load and for samples which had received a variety of blast loads ranging from a single impact with low strength detonating cord, to combination of impacts at different times and significant impacts with powder factors close to those used in practical blasts. It was shown that the rock mechanics parameters change even at low impacts, suggesting easier crushing of the rock. Damage values appear to be affected by timing as stress wave superposition affects the damage process. Fragmentation is achieved at higher impact levels while work index modification of the fragments is also observed when high powder factors are used, suggesting improvements in grinding.

May 1, 2003

By U. Martin

Advanced copper materials for conducting applications require an optimal combination of high mechanical strength at ambient and moderately elevated temperatures together with superior electrical and thermal conductivity. Mechanical alloying under repeated cooling of the milling vials in liquid nitrogen has been applied to produce ultra-fine grained (UFG) oxide dispersion strengthened (ODS) copper with a high yield strength at ambient temperature. In the present study ODS copper was manufactured by mechanical alloying of copper powder and 3% by volume of incoherent oxide dispersoids. During the high-energy milling a homogeneous distribution of fine dispersoid particles (diameter nearly 100 nm) can be achieved in the powder. Samples with a density of more then 97% of theoretical value were produced by uniaxial hot pressing under 650 MPa at 600°C for 20 minutes. The high yield strength at ambient temperature can be described by a linear superposition of the Orowan stress for particle hardening and of ultra-fine grain strengthening according to the Hall-Petch mechanism. Simultaneously, a best value of 75% IACS could be obtained for the electrical conductivity. The creep behaviour of ODS copper in the temperature range from 500°C to 700°C is described within the frame of diffusional creep deformation.

Jan 1, 2007

By T. Belem

In-stope backfill will cure under effective stress, which develops due to a combination of mechanical consolidation (free draining material) and ??chemical consolidation?? (self-desiccation mechanism). A good knowledge of all the drainage and consolidation characteristics of cemented paste backfill is crucial for a better design of underground backfilling sequencing. From many of the existing results and studies done by various authors, as well as the availability of some in-stope backfill pressure data measurements during and after filling, it is possible of developing a procedure of backfilling sequencing. Hence, the objective of this study is to provide a guide for underground backfilling sequencing in the view of preventing the development of excess pore pressure that will affect both the stability of the barricades and the strength development of the backfill. This will be possible by considering the interaction between consolidation/drainage rate, filling rate and binder hydration rate.

Aug 1, 2013

By Mario A. Morin

Over the years, several sources have stressed the need to better integrate the underground mine design and planning processes. The belief is that with better integration, better designs and plans will result - designs that are ?optimized?. Some researchers have focused their efforts on data integration, others have looked at closing the loop between production control & monitoring with mine planning & scheduling. In spite of all these efforts, fully integrated applications combining geological modeling, stope design and geomechanics, mine planning and scheduling, rock extraction and material handling system design, mine support systems, economic analysis with production control do not yet exist for the underground hard rock mining industry. There are several likely explanations - some economic, some technical. It is certain that the design and planning processes are interrelated and interdependent and thus are extremely complex to describe and understand. The mining engineer has an appreciation of the complexities involved - but how does he convey this knowledge to a programming team responsible for developing an integrated design & planning system. This paper will focus on software engineering methods, and other possible approaches, to describe and manage the complexities inherent in the underground mine design and planning process and the development of an integrated computerized system.

May 1, 2001

By Bruce C. Smart

"Very little attention was given to the regulation of uranium mills by the Atomic Energy Control Board prior to 1974. The ore grade treated by Canadian mills in the past was in the order of 0.08 - 0.3% U and it was not difficult to keep the exposure of workers well below regulatory limits. Furthermore, uranium milling has also been substantially free of occupational illness because environmental control has been generally satisfactory (l).The discovery of higher grade ore bodies in Canada has resulted in higher radiation levels in one mill and this has partly contributed to a need for increased radiation monitoring in the mill. In addition, as greater insight is gained on the effects of radiation, the implementation of the ALARA principle is being stressed at all mills.The concept of ALARA was emphasized by the ICRP (International Committee for Radiological Protection) in 1977 and stands for '""as low as reasonably achievable'"". It is based on the premise that no proven threshold for potential effects of radiation exists and that the actual individual exposure should therefore be kept as far below the regulatory limit as possible, economic and social factors being taken into account."

Jan 1, 1982

By K. Oishi

We have developed a 76Cu-3Si-21Zn alloy "ECOBRASS®" containing no lead. When 3% Si is added to a 78Cu-22Zn alloy, kappa and gamma phases participate uniformly in the alpha matrix. When being machined, stress concentrates on these hard phases, namely kappa and gamma, and thereby lowering the required cutting force and yielding segmentalized chips without lubricant. Kappa and gamma phases transform into beta phase under high temperature, which makes it easier to extrude and/or forge the alloy. When 0.08% P and 50 ppm Zr are co-added, the grains of ECOBRASS® castings are refined significantly to become as small as several dozens of micrometers. The grain refinement by the co-addition of P and Zr improves castability, tensile strength and elongation of ECOBRASS® castings. Meanwhile, the lead leachate from an ECOBRASS® water meter, field-tested in pH 6.8 drinking water for one year, was less than 5 ppb without correction. No indication of dezincification corrosion was observed, either. ECOBRASS® is equally suitable for rods, forgings and castings, and makes it possible to produce a complete set of plumbing parts (valves, faucets, etc.) by its own. This way, not only improving recyclability, ECOBRASS® also realizes size and weight reduction due to its good corrosion resistance and high strength.

Jan 1, 2007

By T. D. Chatwin

Acid rock drainage (ARD) is one of the most serious and potentially enduring environmental problems of the mining industry. High liability costs carried by many mining companies to cover potential obligations of ARD are a clear indication of the gravity of the problem. Unchecked, ARD can result in water quality impacts that could well be the industry's most significant financial and credibility risk. Effectively preventing acid drainage is a formidable challenge that requires the total commitment of the mining industry throughout the entire life-cycle of a mine. To achieve this commitment a strong business case for ARD prevention must be developed. This paper will address the elements of acid prevention and discuss their importance not only to the company but the entire industry as well. The International Network for Acid Prevention (INAP) is an industry-led group created to help meet this challenge. In 2009, INAP published the GARD Guide (www.gardguide.com), a web-base best practices guide for the prevention of ARD [1]. In this paper, the GARD Guide will be used to identify preventative actions for all mining industry stakeholders. It will, in turn, be used to estimate ARD management and mitigation value accrued to the company from ARD prevention, which will be used in developing a business case for acid prevention.

Jan 1, 2011

By Pavel Vasak

Microseismic monitoring is becoming standard practice in the Canadian mining industry, particularly as mines get deeper. Full-waveform microseismic systems allow the operator to distinguish the event source mechanism, e.g., blast, shear slip or stress-induced fracture. At mine sites that heave a microseismic system operator blasts are manually identified by comparing the event waveform traces to the morning blast logs. However, this procedure is not routinely done at sites where a system operator is not present and this can lead to misinterpretation of the data at a later stage, particularly where the interpretation is outsourced, often many years later. It is critical to improve the microseismic data quality and consistency for processing and interpretation with a reliable technique to filter out blasts and blast related seismicity. This paper presents the development and implementation of a simple blast identification and filtering routine. The routine was developed specifically for Vale?s Creighton Mine about a decade ago, but is made sufficiently general so that it can be used at any mine site with an ESG (Engineering Seismology Group Canada) based full-waveform microseismic systems. The routine is strictly a post-processing procedure developed for use with the Access database data structure used by ESG. The algorithm was tested at Creighton Mine and a success rate of 80 to 90% was achieved, when compared to manual blast picks.

Oct 1, 2010

By J. Bhattacharya, S. K. Mukhopadhyay, S. K. Pal

"While time and again many authors have categorically stressed the restoration of the environment, very little effort has been made in the mineral industry to develop the economy of environmental control. There are many abatement procedures that search a maze of variants. Among them pricing environmental damage seems to be more logical and easily implementable.IntroductionMining as an operation has a severe impact on the Earth's natural resources. While economical environment control is much sought after, solutions are often varied and complex, and can differ in the problems of single or multiple mine sites.Determination of Optimum use LevelsIn “mining environmental control"" it is required to strike a balance to find optimum use levels. The solution is to find where the welfare benefits equal the cost involved to curb the degree of environmental damage (Fig . I) . In the mining industries this can be done by modifying the production/extraction process itself. For most pollutants, the marginal costs of control will exceed the benefits from further reduction of damage long before the zero pollution damage point is reached (Fig. I). From an economic perspective the optimal alteration of environment by mining would occur at z; pollution continues to be caused by ""zy"" control units, but it would be inefficient to pursue the redemption efforts further because the marginal cost involved would exceed marginal welfare benefits."

Jan 1, 1992

By T. S. Wanne

Tunnel sealing experiment (TSX) was conducted between 1997 and 2004 in the Canadian URL located in Manitoba. In the experiment, a tunnel was excavated parallel to the maximum principal stress direction, filled with sand and sealed with bulkheads at both ends. It was then pressurized and heated by injecting hot water. The rock mass response was monitored with seismic methods. The main interest in the numerical simulation was the damage formed during the heating phase. The large-scale PFC2D models replicated a central plane- strain section of the TSX chamber. The models captured the first-order phenomena observed in-situ displaying the difference in the damage in the roof and floor regions, respectively. This difference was due to the filling material confinement of about 100 kPa on the tunnel floor, which occurred in the course of the heated experiment.

May 1, 2009